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By AIME AIME

THE following compilation of State bureaus and officials that deal with mineral resources is compiled in part from a new "Check List of State Agencies and Officials Concerned with the Management of Natural Re- sources," compiled for the National Resources Committee, Washington, D. C., by Clifford J. Hynning. Alabama-Geological Survey of Alabama, University. Walter B. Jones, State Geologist. Chief Mine Inspector: W. B. Hill- house, 614 Lincoln Life Bldg., Birmingham.

Jan 1, 1939

By George C. Reynolds

INTRODUCTION The overall importance of the minerals industry during the next 20 years was highlighted In "The Global 200 Report to the President" (Barney, 1982) in the following terms: "The industrial and agricultural processes that are taken for granted today would be severely disrupted of any one of dozens of critical minerals ceased to be available in dependable, reasonably priced supply. Supply in turn has become highly energy intensive and international In scope ...... because resources are not uniformly distributed geographically, political considerations (also) become an Important determinant of price and trade patterns." In attempting to determine Australia’s contribution of bauxite raw materials to the world of the future, this paper necessarily also concerns itself with the alumina and aluminium industry to which it supplles the raw material. It is an industry which is energy intensive, International in scope and heavily influenced by political considerations. The aluminium industry has shown a remarkably rapid growth during the past 20 years (Fig. 1).

Jan 1, 1982

By Manuel Valerio Ortega

This Mexican amalgamation-process, invented in 1557, at Pachuca, by Bartolome de Medina, has been widely discussed in America and Europe, but thus far there is no universal agreement as to all the chemical reactions involved. Having been, after many trials, the first to succeed in effecting the amalgamation of silver-ores by the same mechanical means, but doing without one of the chemical substances which had been considered indispensable in the practice of 300 Sears, I am led to offer these notes as a contribution to the discovery of an exact theory concerning the patio process. My treatment for silver- and gold-ores being protected by letters-patent in this country, the United States, France, Peru, Bolivia and Chile, I may speak freely concerning its materials and manipulation. I. Patio-Amalgamation. The ore extracted from the mine is sorted by pepenadores, who break the large pieces with hammers, rejecting those which contain no ore, set aside the very rich to be smelted, and deliver the rest to be crushed and pulverized for direct amalgamation in the patio. The broken lumps, of about fist-size, are first ground in Chilean mills, and then reduced, in arrastras or tahonas, to fine slime. After the lama or slime has acquired a suitable consistency by the evaporation, through the sun's heat, of a part of the water which it contained, it is spread upon the patio or amalgamating-floor, where it is mixed with 5 or 6 per cent. of common salt. The next day a certain amount (depending upon

Jan 1, 1902

By S. E. Bretherton

Mr. AllaW Gibb, of Mount Perry, Queensland, Australia, in an interesting and instructive paper,* describes fully the great difficulties metallurgists encounter in seeking to produce marketable copper by smelting refractory ores containing arsenic, antimony and bismuth. After reading this description, I prepared a paper for the Institute, which was, however, through a misunderstanding on my part, published in the San Francisco Mining and S'cie~ztiJic Press of April 4, 1903, after its acceptance by the Council, and without credit to the Institute. Consequently, it cannot be reprinted for the Transactions of the Institute; and I can only here summarize its contents and conclusions, referring the reader to the article above named for further particulars. In that article I omitted the col~sideration of bismuth, which we do not encounter in our smelting at Val Verde, and added lead and zinc, which Mr. Gibb had not discussed; and I undertook to shorn, by the record of a year's practice of the Val Verde Copper Co., Arizona, that copper-ores containing arsenic, antimony, lead and zinc may be successfully smelted, without preliminary roasting, in an ordinary blast-furnace with hotblast, making a normal slag, such as one would aim to make under ordinary conditions with cold-blast, so as to produce a marketable matte, containing not less than 45 per cent. of copper, free from arsenic and antimony, and below the limit in lead and zinc penalized by the refineries.

Jan 1, 1904

By Tell Ertl

THE Piceance Creek Basin in northwestern Colorado is believed to contain the richest large deposit of oil shale in North America. The major portion, about 1650 sq miles, is bounded by the White River on the north, the Grand Hogback, which runs from Meeker to Rifle, on the east, the Colorado River to the south, and the drainage basin of Salt and Douglas Creeks on the west. The Basin is a plateau 7000 to 9000 ft high, composed of 3000 ft of the Green River series of Eocene age and surrounded by a steep escarpment of 1000 to 3000 ft. From the escarpment the beds dip gently toward the center. Although oil shale is found in all members of the Green River series, the rich thick beds are found chiefly in the Parachute Creek member. This is normally capped by 100 to 200 ft of the Evacuation Creek, the youngest member of the Green River series. Actually the Piceance Creek Basin oil shale is not a shale, nor does it contain oil. It is magnesium marlstone holding solid organic matter capable of being broken down by heat into gases, some of which can be condensed into oil. The marlstone is resilient nonporous rock, difficult to sample by pick or hammer and moil. Many companies and individuals prospected the Colorado oil shale shortly after the first World War,' see Fig. 1, but because of the discovery of large quantities of petroleum in the late 1920's in Cali- fornia, Oklahoma, and East Texas, interest in oil shale development waned and did not revive until World War 11. In 1944 the writer, employed by the Bureau of Mines, prospected the high grade oil shale in numerous places along the southern outcrop of the Piceance Creek Basin. Several channel samples about 100 ft in length were cut, see Fig. 2. An eight-man crew needed a week to cut a satisfactory channel 80 ft long in the cliff face. The Phillips Petroleum Co., the Union Oil Co. of California and others also prospected the oil shale outcrop. In 1945 the Bureau of Mines initiated a core drilling program for the purpose of obtaining accurate samples from the Piceance Creek Basin. The U. S. Geological Survey set up a program for the geological study of the Basin that is still going on." Until the end of 1951 a total of 31 holes was drilled for core with diamond drills, and, in addition, cuttings through the oil shale have been obtained from 4 gas wells drilled by standard rotary oil well rigs. The Bureau of Mines drilled 12 of the holes, the Union Oil Company of California 8, the Standard Oil Company of California 6, the Sun Oil Company 3,

Jan 1, 1953

By Tell Ertl

THE Piceance Creek Basin in northwestern Colorado is believed to contain the richest large deposit of oil shale in North America. The major portion, about 1650 sq miles, is bounded by the White River on the north, the Grand Hogback, which runs from Meeker to Rifle, on the east, the Colorado River to the south, and the drainage basin of Salt and Douglas Creeks on the west. The Basin is a plateau 7000 to 9000 ft high, composed of 3000 ft of the Green River series of Eocene age and surrounded by a steep escarpment of 1000 to 3000 ft. From the escarpment the beds dip gently toward the center. Although oil shale is found in all members of the Green River series, the rich thick beds are found chiefly in the Parachute Creek member. This is normally capped by 100 to 200 ft of the Evacuation Creek, the youngest member of the Green River series. Actually the Piceance Creek Basin oil shale is not a shale, nor does it contain oil. It is magnesium marlstone holding solid organic matter capable of being broken down by heat into gases, some of which can be condensed into oil. The marlstone is resilient nonporous rock, difficult to sample by pick or hammer and moil. Many companies and individuals prospected the Colorado oil shale shortly after the first World War,' see Fig. 1, but because of the discovery of large quantities of petroleum in the late 1920's in Cali- fornia, Oklahoma, and East Texas, interest in oil shale development waned and did not revive until World War 11. In 1944 the writer, employed by the Bureau of Mines, prospected the high grade oil shale in numerous places along the southern outcrop of the Piceance Creek Basin. Several channel samples about 100 ft in length were cut, see Fig. 2. An eight-man crew needed a week to cut a satisfactory channel 80 ft long in the cliff face. The Phillips Petroleum Co., the Union Oil Co. of California and others also prospected the oil shale outcrop. In 1945 the Bureau of Mines initiated a core drilling program for the purpose of obtaining accurate samples from the Piceance Creek Basin. The U. S. Geological Survey set up a program for the geological study of the Basin that is still going on." Until the end of 1951 a total of 31 holes was drilled for core with diamond drills, and, in addition, cuttings through the oil shale have been obtained from 4 gas wells drilled by standard rotary oil well rigs. The Bureau of Mines drilled 12 of the holes, the Union Oil Company of California 8, the Standard Oil Company of California 6, the Sun Oil Company 3,

Jan 1, 1953

By P. G. Mason

The upswing in the price of gold in 1979 prompted renewed interest in the Mercur gold property by Getty Oil Company, owner and operator, and Gold Standard Inc. of Salt Lake City, Utah, currently retaining a 15% net profits interest. Extensive geological exploration work resumed to delineate the ore reserves, and metallurgical test work was initiated under the direction of A.H. Ross & Associates. This led to the development of an aqueous pressure oxidation process suitable for treatment of the refractory ores. Subsequent geostatistical studies revealed that the distribution of high refractory ore was less than previously estimated, and thus a higher return on investment could be realized if a direct carbon-in-leach process were used despite a sacrifice in overall recovery. This paper reviews the geological and metallurgical studies that led to this final process selection.

Jan 1, 1984

By Charles B. Dudley

It is evident that, as the size and weight of cars have increased, the demands on the cast-iron car-wheel have become more and more severe. Fortunately, the factor of safety in the cast-iron wheel, as originally made, was so large that it was only when freight-cars approached the capacity of from 80,000 to 100,000 lb. that the question of wheels began to give some anxiety. A moment's thought will show that, as freight- and passenger-cars have increased in weight and size, a much greater duty is required of the same eight wheels than was formerly the case. In other words, although the cars have increased in capacity from 15 tons to 50 tons each, the number of wheels under a car has not been generally increased. It is true, some cars have been equipped with 12 wheels, but this construction is not the rule. Hence the duty which the wheel must perform has become much more severe, and although it was clearly able to stand some increase, there must evidently be a limit somewhere which cannot be exceeded. Meanwhile, it is the part of wisdom to make better wheels if possible, and accordingly, no little study is now being devoted to the requirements for cast-iron car-wheels; and modifications are being made, both by increasing the weight of the wheel and by improving the quality of the metal of which it is made. The desire to improve the quality of the wheel has led to the preparation of specifications for its manufacture; and within the last 15 years a more rigid scrutiny of the wheel is char-

Jan 1, 1905

By R. Costantini

Long-distance transportation of solids by hydraulic pipelines holds promise of great economic benefits. In most mineral processing plants today, moving of solids in slurry-form by pipeline is commonplace. Yet in spite of this, the method is slow in being adopted on a broad scale for moving solids over distances of many miles. This is especially surprising in view of the successful realization of two daring ventures in long-distance solids pipelines in this nation within the last five years. One is the 72-mile long, 6-in. diam. pipeline of the American Gilsonite Co. which has been satisfactorily transporting 700 tpd of gilsonite from the mine at Bonanza, Utah, to the processing plant at Grand Junction, Colo., since April 1957. The other is the 108-mile long, 10-in. pipeline of the Pittsburgh Consolidation Coal Co., which has been transporting about 4000 tpd of finely crushed coal from the mine at Cadiz, Ohio, to the Eastlake Power Plant of the Cleveland Electric Illuminating Co. since January 1958.

Jan 8, 1961

By V. Rajaram, I. P. Nielsen, H. D. Raymond

The Parachute Creek member of the Green River formation in the Piceance Basin, Colorado, contains vast reserves of oil shale, nahcolite, dawsonite, and other accessory minerals. The dry alkali process of sulfur dioxide removal using nahcolite (naturally occurring sodium bicarbonate) has great potential. A room and pillar mining scheme has been designed to extract a nahcolite zone occurring at a depth of 472 m, from the lease application area of the Yankee Gulch joint venture. Geotechnical parameters affecting mine design will be discussed. A preliminary development plan for mining at the rate of 1000 t/d will be described in detail.

Jan 12, 1979

By Rudolph G. Wuerker

WITH the growing complexity of ore dressing processes and the diversity of equipment, efficiency control has become increasingly important in beneficiation. In the case of iron ore dressing, there have been sporadic attempts1-3 to establish the optimum separation for various ores so that grade and recovery would be readily predictable. But no rigorous statistical analysis and graphical presentation of such tests could be found in the literature of this country. Tests Made with Iron Ores Expanding upon existing methods of plant supervision and efficiency control, an investigation was started in the ore dressing laboratory at the University of Illinois on the applicability of distribution analysis to iron ores. A sample of crude ore was obtained from the Ohio mine of Cleveland-Cliffs Iron Co. at Ishpeming, Mich., consisting mostly of alternating bands of hematite and siliceous gangue, both about ¼ in. wide. The ore was heavily coated with limonite, which often filled the cracks.

Jan 7, 1958

By Walter W. Fisher, Samuel Rudy

Secondary treated sewage effluent was substituted for normal process water in laboratory tests simulating froth flotation recovery of copper and molybdenum sulfides. Sewage effluent caused significant detrimental response in the flotation process. First, a voluminous, uncontrollable froth was generated, even in the absence of a frothing agent, that has little mineral carrying ability. Second, sewage effluent caused a small loss in copper recovery and a large loss in molybdenum recovery. The detrimental effects of sewage effluent on flotation were partially overcome by tertiary treatment of the effluent by activated carbon adsorption and anion exchange. The frothing problem was significantly reduced after treating the sewage effluent by foam fractionation. Dilution of the effluent with normal process water resulted in a significant improvement in metal recovery. In addition, the large loss in molybdenum recovery was overcome by using a secondary collector in a combination reagent schedule. However, the secondary collector caused an appreciable loss in copper recovery.

Jan 1, 1979

By W. J. Carlson, I. Iwasaki

A previous article reported a combination process for recovering both metallic iron and metallic manganese from the manganiferous iron ores of the Cuyuna Range in Minnesota.' In this process, the iron was recovered by direct reduction and magnetic separation and the manganese was recovered from the nonmagnetic tailing by leaching and electrolysis. The current efficiency during the electrolysis of manganese is quite low, in the range of 60 to 70%, due to the simultaneous plating of hydrogen.2,3 The parameters that affect the current efficiency are (1) the concentrations of the manganese ion and the ammonium sulfate buffer, (2) the effect of autoxidant, (3) temperature, (4) pH, and (5) current density. To study the plating characteristics of manganese metal.

Jan 1, 1969

By J. E. Schaffer

Drilling activity in Ohio increased slightly in 1939. There were 1020 completions as compared to 910 in 1938. During the past six years the number of completions has varied little (Table 1). Oil production in Ohio has been gradually declining since 1896, when the peak production of 23,941,000 bbl. was reached (Fig. 1). Since that date production has slowly declined to an estimated production in 1939 of 3,144,134 bbl., the lowest in 53 years. This total production is divided approximately into the following grades of crude oil: Pennsylvania, 1,185,456 bbl.; Corning, 1,261,615 Flg 1. bbl.; Lima, 578,500 bbl.; Lodi, Based on figures of U. S. .Bureau of 104,740 bbl.; Cleveland, 13,823 Mines and Oil andGas Journal bbl. Table 2 shows the prices paid for the various grades of crude oil.

Jan 1, 1940

By J. E. Schaffer

Drilling activity in Ohio increased slightly in 1939. There were 1020 completions as compared to 910 in 1938. During the past six years the number of completions has varied little (Table 1). Oil production in Ohio has been gradually declining since 1896, when the peak production of 23,941,000 bbl. was reached (Fig. 1). Since that date production has slowly declined to an estimated production in 1939 of 3,144,134 bbl., the lowest in 53 years. This total production is divided approximately into the following grades of crude oil: Pennsylvania, 1,185,456 bbl.; Corning, 1,261,615 Flg 1. bbl.; Lima, 578,500 bbl.; Lodi, Based on figures of U. S. .Bureau of 104,740 bbl.; Cleveland, 13,823 Mines and Oil andGas Journal bbl. Table 2 shows the prices paid for the various grades of crude oil.

Jan 1, 1940

By W. J. Taylor

IN making heating gas with anthracite coal for roasting ore during the past few years, I hare tried many forms of gas generators. So far, the most successful and satisfactory one has been what we call a fluxing producer, which is simply a small cupola or blast furnace, in which we charge with the coal, say, 30 or 40 per cent. of basic blast-furnace cinder, to unite, when melted, with the ash or earthy matter in the coal, and carry it off as cinder. The producer we have in use at Chester, N. J., has pore of the lines of a blast furnace than a cupola, the hearth being 24 inches diameter and 24 inches high. It then enlarges on an angle of about 25 degrees from a perpendicular to 4 feet, and then is drawn into 3 feet on top ; total height, 12 feet. We use one water coil-tuyere 12 inches above the bottom, and blow through a 11/2-inch nozzle. The depth of coal above the tuyere averages about 6 feet. The producer. is blown with

Jan 1, 1881

By G. W. Cullen

Niobium-tin has been prepared on insulating suhstrates hby simultaneous hydrogen reduction of gaseous niobium and tin halides. Stoichiometric material is greater than 98.8pct theoretical density, appears to he single-phase, and has a total impirity level less than 0.3 at. pct. Transition temperatures and lattice constants may he related to composition. Typical current densities in various fields and orientations are given. IT is known that Nb3Sn carries large current densities in high fields, 1 and exhibits an unusually high transition temperature2 and critical field.3 For these reasons high-field solenoids have been constructed of this material.4 Because of the emphasis on solenoid fabrication, much of the materials research has been directed toward development of wire geometries wherein the brittle Nb3Sn is supported by a more malleable metal or alloy. There are, however, basic studies and applications that can be carried out only on Nb3Sn supported by an insulator. Insulating substrates are desirable for a number of reasons: the substrate does not interact with applied or induced currents and fields; diffusion of metallic species into the de- posit is avoided, both during the preparation and during subsequent heat treatment; irradiated samples are not more active than the deposit itself. Unsupported Nb3Sn geometries may also be prepared by preferential chemical dissolution of the insulating substrate. This report describes the preparation and properties of Nb3Sn deposits on ceramic substrates. Experiments currently utilizing material prepared in the manner described in this report include the following: dependence of current-carrying properties on field strength and orientation 5,6 radiation damage,7,8 tunneling,9 thermal conductivity (substrate removed),1° microwave surface impedance," tube magnetization,6,12 resistivity as a function of temperature,13 and current density and transition temperature as a function of annealing.14 Possible practical applications include magnetic shielding, superconductor generators, and frictionless bearings. PREPARATION Methods for the deposition of elemental niobium and tin by hydrogen reduction of the gaseous metal halides have been known for some time,15,18 but only recently a procedure was developed in this laboratory17 for the codeposition of these two metals on a hotwire as the intermetallic compound, Nb3Sn. This method of simultaneous hydrogen reduction of the gaseous niobium and tin chlorides is used for the preparation of Nb3Sn On ceramic substrates. The procedure differs from that employed on a hot wire in that insulating substrates cannot conveniently be heated to temperatures greater than their surround-

Jan 1, 1964

By E. L. Ickes

DURing the summer and winter of 1918 eleven standard rigs were erected in the United Kingdom to test the petroleum prospects of- ten structures, eight of which were in England and two in Scotland. By the fall of 1921 ten of the wells were completed; the remaining one, the D'Arcy in Scotland, was stopped some months later. The tests were deep ones, five of the wells being 4000 ft. or more, the rest varying in depth between 1810 and 3918 ft. The total footage drilled was 40,047 ft. The holes were put down with standard or cable tools purchased in the United States (except the boilers). The larger sizes of casing, 10-in. and above, were also from America, while the smaller sizes were secured in Scotland. The Hardstoft well in England found a small production of high-grade oil and the D'Arcy well also encountered what is reported as a favorable showing at a depth of 1810 ft. The Werrington and West Calder wells had to be abandoned on account of drilling difficulties. The Apedale well encountered great thicknesses of ash in the Carboniferous and had to be abandoned on account of depth. The results might be summarized by saying that of the ten structures drilled upon, two yielded encouraging showings; three cannot be considered as having been adequately tested; and five produced dry holes, although in some of these small oil showings and gas were met. The total cost of the work amounted to about half a million pounds sterling, which sum includes the cost of all equipment, subsequently sold by the government. The work, under the superintendence of V. L. Conaghan, took place for the most part in the period immediately following the war—a period of high prices, labor and transportation difficulties, and unsettled conditions generally; factors tending to retard the work and affect the costs. The writer, as a member of the staff of S. Pearson & Son, Ltd., had charge of the administration of the work during its later stages and

Jan 1, 1924

By G. Gutzeit

An inner complex is a cyclic chemical structure containing an inorganic cation that is bound simultaneously to several atoms in a single organic molecule; on the one hand by means of ordinary valence bonds (electron exchange), on the other hand through the action of the electric field thus created, which satisfies the so-called secondary valences. The relative positions of the salt-forming and complex-forming groups are such that most frequently a four, five, or six-membered ring results through this double attachment of the cation.1-6 The formation of inner-complex ring systems depends not only upon the nature and suitable position of the salt-forming and complex-forming groups for ring closure, but, to a great extent, also on the nature of the metallic cation entering the reaction. This selective character of chelate-forming organic compounds is one of their most interesting and most valuable properties. As a matter of fact, the largest number of their practical applications is based upon their specificity.4,7-l3 Once a chelate compound is formed, its character is definitely "organic" in nature. In other words, its properties are conditioned to a much larger degree by the carbon chains or rings than by the metallic atom. Many inner complexes are soluble in nonpolar solvents such as benzene, paraffin oil or carbon tetrachloride, while the chelate-forming reagent before closure of the metal-organic ring is water soluble. (Example: copper complex of salicyl-aldoxime') It is obvious that such particular properties as those indicated above can be utilized whenever specificity and practically complete binding of inorganic ions into an undissociable complex are required. One of the well-known applications of chelate-forming compounds has been the development of specific reagents in analytical chemistry, creation of the spot-test method,4,14-16 and the application of the same principles to the contact print method for determining minerals." Chelate-forming Compounds as Collectors In the field of flotation, where selectivity is often a quality of paramount importance for the collector, various workers have lately attempted to apply their knowledge of specific organic analytical reagents to this purpose. A. C. Vivian18 has concentrated cassiterite by using ammonium nitrosophenylhydroxyl-amine (Cupferron) C6H5NO(=NONH4). Holmanl9 has tested dimethylglyoxime for the flotation of nickel oxide minerals, while deWitt has shown in a series of systematic experiments that alpha-diox-imes were generally selective collectors for nickel ores. Taurin NH2(CH2)2S03H has been proposed for the concentration Of Oxidized lead ores.19 Diphenylthio-carbazone

Jan 1, 1947

By G. Gutzeit

An inner complex is a cyclic chemical structure containing an inorganic cation that is bound simultaneously to several atoms in a single organic molecule; on the one hand by means of ordinary valence bonds (electron exchange), on the other hand through the action of the electric field thus created, which satisfies the so-called secondary valences. The relative positions of the salt-forming and complex-forming groups are such that most frequently a four, five, or six-membered ring results through this double attachment of the cation.1-6 The formation of inner-complex ring systems depends not only upon the nature and suitable position of the salt-forming and complex-forming groups for ring closure, but, to a great extent, also on the nature of the metallic cation entering the reaction. This selective character of chelate-forming organic compounds is one of their most interesting and most valuable properties. As a matter of fact, the largest number of their practical applications is based upon their specificity.4,7-l3 Once a chelate compound is formed, its character is definitely "organic" in nature. In other words, its properties are conditioned to a much larger degree by the carbon chains or rings than by the metallic atom. Many inner complexes are soluble in nonpolar solvents such as benzene, paraffin oil or carbon tetrachloride, while the chelate-forming reagent before closure of the metal-organic ring is water soluble. (Example: copper complex of salicyl-aldoxime') It is obvious that such particular properties as those indicated above can be utilized whenever specificity and practically complete binding of inorganic ions into an undissociable complex are required. One of the well-known applications of chelate-forming compounds has been the development of specific reagents in analytical chemistry, creation of the spot-test method,4,14-16 and the application of the same principles to the contact print method for determining minerals." Chelate-forming Compounds as Collectors In the field of flotation, where selectivity is often a quality of paramount importance for the collector, various workers have lately attempted to apply their knowledge of specific organic analytical reagents to this purpose. A. C. Vivian18 has concentrated cassiterite by using ammonium nitrosophenylhydroxyl-amine (Cupferron) C6H5NO(=NONH4). Holmanl9 has tested dimethylglyoxime for the flotation of nickel oxide minerals, while deWitt has shown in a series of systematic experiments that alpha-diox-imes were generally selective collectors for nickel ores. Taurin NH2(CH2)2S03H has been proposed for the concentration Of Oxidized lead ores.19 Diphenylthio-carbazone

Jan 1, 1947