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By E. G. Noble

The effects of hydrogen chloride (HCI) concentration and temperature on the solubility and hydration state of the alkali chlorides LiCI, NaCI, and KCI and the alkaline-earth chlorides, MgCI2, and CaCl2 were investigated by the Bureau of Mines. Saturated aqueous solutions of the chlorides were sparged with HCI gas at temperatures of 20°, 40°, and 60° C. Increased HCI concentration caused decreased salt solubility be-cause of the common ion effect. Aqueous solubilities for the chlorides of Ca, Li, Mg, K, and Na ranged from 42.6, 45.2, 35.2, 25.5, and 26.1 pct, respectively, at 20° C to 56.9, 49.4, 37.6, 31.0, and 27.0 pct, re-spectively, at 60° C. In solutions sparged to HCI saturation, solubili-ties for these chlorides ranged from 22.4, 26.5, 3.0, 1.3, and 0.05 pct, respectively, at 20° C to 53.2, 48.8, 28.3, 2.6, and 0.8 pct, respec-tively, at 60° C. The solubilities of LiCI and CaCl2 in HCI solution were high because HCI solubility is low in these solutions. The chlo-ride salts of Ca, Li, and Mg formed hydrates, which depended on tempera-ture and HCI concentration. Monohydrates for LiCI, tetrahydrates and hexahydrates for MgCI2, and dihydrates, tetrahydrates, and hexahydrates for CaCl2 were obtained.

Jan 1, 1985

By George S. Rice

In response to numerous requests for information as to the status of internal-combustion mine locomotives of the Diesel type that use heavy or non- volatile oil for fuel, with special reference to their safe use in coal mines, the United States Bureau of Mines is issuing this report. Data mere obtained, on application of such locomotives to cod mining only in Belgium, France, Germany, and Great Britain. The locomotives are used in coal mining in other countries, as well as in potash, iron, and other kinds of mining, but their chief development has been in coal mining in Germany, France, and Belgium. Recently popular interest in the Diesel type of engine for motive purposes was aroused in this country by the successful application of Diesel engines to railroad locomotives hauling fast transcontinental trains, and, according to published statements, at a low cost of fuel per mile of run.

Jan 1, 1936

By Robert W. Metcalf

Corundum, natural alumina, or aluminum oxide (A1203) is the hardest mineral known except diamond. Theoretical composition is Al 52.9 percent and 0 17.1 percent, but it always contains small quantities of impurities, chiefly silica, iron, and lime. The melting point of corundum is above 1950° C., and it is insoluble in the strongest acids. Its hardness (9 on the Mohs scale) varies slightly according to purity, and its specific Gravity ranges from 3.95 to 4.10, 4 being a fair average. The index of refraction is 1.760 to 1.768 and its streak is white. Luster is adamantine to Vitreous, come specimens pearly, and color varies widely from white, gray, pink, and blue to black, brown, or bronze. Gem varieties are transparent or translucent, and of more brilliant coloring - red, blue, yellow, purple, or green. Corundum occurs in opaque massive or block structure with parting planes little developed or only roughly delineated and in granular form as minute crystals or small, irregular grains interspersed throughout the contact zones of schists and gneisses.

Jan 1, 1944

By Larman J. Heath

Wellbore enlargement was tested using hydrazine hydrate in a gas-storage well in Ohio to increase the well productivity. The wellbore was to be enlarged by chemical disaggregation of the sandstone adjacent to the wellbore. Productivity immediately declined 49.1 percent and gradually declined to zero in 7 months. A down-hole camera survey showed a white-to-gray precipitate covering the entire wellbore surface. The precipitate was chemically analyzed and identified as mostly carbazic acid, a hydrazine derivative of carbonic acid. Formation of this precipitate was not anticipated; this viscous sub-stance caused the gradual loss in productivity of the well. The wellbore was not enlarged. Laboratory tests were run to determine what clay stabilization measures could be taken in sandstone cores to prevent clay swelling and particle migration caused by hydrazine hydrate. Normal clay stabilization methods did not prevent the virtually complete loss in permeability to hydrazine hydrate. Other laboratory tests using natural gas diluted with small amounts of carbon dioxide confirmed the ease with which carbazic acid could be formed in a hydrazine hydrate-saturated environment within and adjacent to the wellbore.

Jan 1, 1970

By J. B. Salsman

As part of the research effort on investigating the effects of microwave energy on the chemical and physical properties of minerals and ores, the U.S. Bureau of Mines (USBM) Tuscaloosa Research Center has conducted research to measure the dielectric properties of these materials. The objective was to establish a reliable database for use in predicting the effects of microwave heating on a wide range of minerals. The dielectric constants and loss factors of minerals, commonly referred to as the dielectric properties, were determined utilizing the theory of microwave propagation through an open-ended, air-filled coaxial line that was terminated at its open end with the particular mineral under investigation. In this phase of microwave research, the USBM measured the dielectric properties of powdered minerals with medium to high electrical conductivities in the frequency range of 300 MHz to 3 GHz and as a function of temperature from 25 to 325 °C. Since the minerals were prepared as powders, techniques were used to relate the measured dielectric properties of the powdered minerals to the dielectric properties of the mineral at its theoretical or natural density.

Jan 1, 2010

By Boyd Wise

A jet pump injector was developed and successfully tested, thereby demonstrating the feasibility of a jet injector for introducing coarse coal into an operating slurry face haulage system: In Phase I a variety of injection concepts were evaluated, and the jet pump was identified as best, due to its simplicity, compactness and performance potential. In Phase IIA subscale jet pump injector tests were conducted, and a computer model of a jet pump injector was developed whose performance predictions correlated well with subscale test results. In Phase IIB various system configurations were defined for integrating a jet pump injector into a fully operational underground coarse slurry face haulage system, further highlighting the feasibility and practicality of such a system. In Phase III a full-scale mobile haulage vehicle embodying a jet pump injector and coal sizing equipment was detail designed into a practical vehicle with attractive performance characteristics. More importantly, fully operational full scale jet pump injector -and feeder/breaker subassemblies were tested and proven successful in their ability to down-size coal to 3" in all 3 dimensions and to consistantly provide slurry of 4217 weight concentration at 6.4 TPM throughput under a wide range of operating conditions including zero to maximum feed rate within 5 seconds.

Jan 1, 1985

By W. P. Yant, G. W. Jones

"Introduction.During the past two years the Bureau of Mines has conducted a study of natural-gas heaters*** to determine (1) what types of heaters literate carbon monoxide; (2) why carton monocide is liberated; and (3) how, by change of design or construction, the liberation of this gas can be largely eliminated, In addition to the above study the bureau has investigated cases in the Pittsburgh dis¬trict where fatalities have resulted from carbon monoxide given off by natural-gas heaters.Since these fatalities were first brought to the attention of this bureau through the press, it is likely that some cases were missed and thus not listed. On the other hand, some cases reported as being due to carbon monoxide poisoning, on investigation were found to be due to causes other than carbon monoride.The cases listed herein were shown in all probability to be due to carbon monoxide. Those in which there is any doubt have been omitted; so have those in which there was part asphyxiation, where the victims later recovered."

Feb 1, 1924

By V. B. Dale

San Manuel has been a modern prodigy from its inception to its present status as a block-caving operation producing 33,000 tons per day. The deposit was discovered, prospected, and developed with modern techniques, and nearly all planning was done from results of an extensive drilling program through an average overburden of 670 feet. The Federal Government had a prominent part in the discovery and primary development of San Manuel. The first 17 holes were drilled by the Bureau of Mines, and discovery of the large, low-grade, disseminated copper deposit is credited to the Bureau. A loan fund of 94 million was granted through the Reconstruction Finance Corporation to the San Manuel Copper Corp. for development of the deposit and erection of concentrating and smelting facilities. Then, while the mine was still being developed, the Defense Materials Procurement Agency contracted to buy a large amount of copper at a pegged price.

Jan 1, 1962

By G. R. Smith

Critical and strategic metals are often present in small quantities in low-grade domestic ores. When these ores are leached, the resulting solution usually contains the metals in very dilute quantities. Selective electrowinning from dilute electrolytes was investigated by the Bureau of Mines. A metal deposit containing 84 pct nickel was electrowon from the leach solution of a complex domestic ore bulk flotation concentrate originally containing approximately 2 wt-pct nickel. Key to achieving accelerated deposition rates, in the case of dilute solutions, is the rapid movement of the electrolyte through the electrowinning cell. Pure, synthetic nickel electrolytes were used to establish deposition parameters, and to optimize electrolyte velocity or mass transfer rates. Hydrodynamic and electrodeposition parameters for both the synthetic and leach electrolytes are presented and the experimental research described. Selective electrowinning appears to offer a viable alternative to physical separation methods to obtain separate metal "concentrates" from low-grade ores.

Jan 1, 1983

By J. B. Gayle

In a modern blast furnace, production depends, to a large extent, on the rate at which the furnace gases can be forced through the charge. Since these gases must make their way through the voids between particles of coke, ore, and limestone, the size and size distribution of the stock-column materials are of considerable importance. Also, because the coke pieces support the weight of the overburden and provide the majority of the voids through which the gases pass, their ability to withstand the shattering and abrading forces to which they are subjected should be related to the maximum obtainable production for any particular furnace. Although the wide acceptance of this point of view is indicated by the ever-increasing demand for stronger and more uniform blast-furnace cokes, economic considerations demand that a quantitative evaluation of the relation between coke quality and blast-furnace performance be made available to the industry at the earliest possible date. The following studies of size-distribution patterns and breakage processes were, therefore, conducted as a part of a preliminary investigation intended as a basis for future studies of the relation between coke quality and blast-furnace performance. The major findings may be summarized as follows: 1. New evidence for the presence of two independent distributions of sizes in run-of-oven cokes has been obtained, and a method for characterizing and estimating the relative importance of the individual distributions has been demonstrated. This method has also been used to study the different types of degradation taking place during the tumbler test.

Jan 1, 1954

By S. A. Allen

The Eufaula bauxite district of Barbour and Henry Counties in southeast Alabama covers an area approximately 14 miles long, 6 miles wide at the eastern extremity near the Chattahoochee River, and 10 miles wide at the western end near the east fork of the Choctawhatchee River (see figs. 1 and 2). The long axis of this polygon bears a little south of east.

Jan 1, 1949

By Maria I. De Rosa

Table 46 and figure 16 show the number of fires and fire injuries for metal/nonmetal mills by state during 1990-2001. Table 46 also shows the injury risk rates, employees' working hours, and lost workdays. In all, 77 fires occurred in 26 states. Thirty-seven of the fires caused 41 injuries and 1 fatality (including 5 fires and 3 injuries involving contractors). The yearly average was 6.4 fires and 3.4 injuries. Fifty-four fires with 26 injuries and 1 fatality occurred at metal mills; 23 fires with 15 injuries occurred at nonmetal mills. The Ewhr value was 845 x 106 hr (Irr = 0.01), and the LWD value was 6,681. Minnesota had the most fires (16 fires and 5 injuries), followed by Arizona (9 fires and 3 injuries), Wyoming (8 fires and 3 injuries), Nevada (7 fires, 4 injuries, and 1 fatality), and Texas (4 fires and 7 injuries). Of these states, Texas had the highest injury risk rate value (Irr = 0.033). Table 47, partly illustrated in figure 17, shows the number of fires, fire injuries, fire fatalities, risk rates, employees' working hours, and lost workdays by time period. The number of fires increased slightly during the second period, then decreased during the remaining periods. The number of fire injuries show a decrease during most of the periods (an increase is seen during the third period), accompanied by a decline in employees' working hours during most of the periods. The Irr values follow patterns similar to those shown by the injury values. Tables 48-53 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 18 shows the major variables related to fires for 1990-2001. Table 54 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

The realization that there is a limit to our supply of domestic mineral and fuel resources, which have been taken for granted until recently, has stimulated the need for conservation and optimum utilization of the Nation's minerals, metals, and fuels-resources critical to our national economy. The mission of the Bureau of Mines is to develop new technology, improve existing technology, and disseminate information related to mineral resources and industries. Fulfilling the mission is necessary to insure a continuing, adequate supply of minerals and alternative supplies of energy from reliable sources at the lowest possible cost to society and the environment. Established in 1910, the Bureau of Mines under the Department of the Interior is the Federal Government's primary research arm in the mineral field. Since the transfer of the fossil fuels portion of the energy research program to the newly organized Energy Research and Development Administration (ERDA) in fiscal year 1975, Bureau research has been concentrated on increasing mineral production, decreasing energy usage through more efficient processing, and decreasing material losses caused by corrosion. Concurrently, research is being addressed to improved coal-preparation techniques, especially to expanding utilization of low-grade coals and coals difficult to beneficiate, which are essential for reducing the need for petroleum and natural gas supplies and for redirecting our energy consumption. Fluctuations in the availability of foreign sources of minerals, metals, and fuels due to political and economic variability among nations have necessitated intensified investigation into coal mining, uranium-ore processing, and geothermal energy sources-three alternatives that can help to alleviate the dependence of the United States on foreign sources of energy.

Jan 1, 1975

By M. M. Gilkey

Pegmatites in Colorado occur for 150 miles along the Front Range (eastern-most range of the Rocky Mountains) from Larimer County on the north to Canon City on the south, and west into the Gunnison area. Many of the deposits have been classified. Minerals found in the various dikes include beryl, scrap and possibly punch mica, lithium-bearing minerals, columbite-tantalite, feldspar, and several rare minerals. Pegmatites are abundant in the Crystal Mountain district in Larimer County. About 5 miles south of the Crystal Mountain district and often identified with that district is the Hyatt pegmatite area. The Hyatt Ranch deposit has attracted particular attention because of the comparatively high beryl con-tent of the upper part exposed in opencut workings.

Jan 1, 1960

By K. B. Nowels

"INTRODUCTION For the last several years the oil industry has been turning more and more toward conservation arid the study of related production problems. It is generally conceded that ultimate recovery is increased by holding the natural gas in thy sand which is net needed in lifting the oil. The retained gas lowers the viscosity and surface tension of the oil and helps flow the oil from the sand. Lewis states that ""while the operator can not control the original conditions of energy and resistance in the sand, he can partly control the efficiency of expulsion. As it is the energy contained in the compressed and absorbed gas rather than the oil that is exhausted, it is but logical to judge the efficiency of a producing method largely by the relative quantities of gas produced with each barrel of oil. If by a change in method the producer lessons the proportion of gas with each barrel of oil, he should increase the total recovery- of oil correspondingly, even if the rate of production is temporarily reduced somewhat.""The effect of ""pinching in"" or controlling the flow of oil wells in an effort to lessen the proportion of has never been definitely known. The general belief has been that ""pinching"" a flowing well causes the oil and gas volumes to be reduced proportionately, maintaining the same gas-oil ratio as before the reduction in flow was made. Studies of gas-oil ratios in many fields have shown that much gas has been wasted, insofar as its effectiveness in oil production is concerned. Swigart and Bopp carried."

Oct 1, 1927

By S. H. Ash

THE information obtained by examining and analyzing the core drillings from 15 diamond-drill holes shows that with the proper equipment little difficulty should be experienced while sinking the shafts at the 15 selected sites. Although a number of holes penetrated formations containing a high percentage of silica,, the health hazard from dust can be removed by using proper dust-control equipment. Methane was detected in small amounts in only one (hole 5) of the boreholes. The methane hazard should present no difficulty if adequate ventilation is employed while sinking the shafts.

Jan 1, 1952

By E. D. Gardner

Open-cut mining of copper ores in the western United States is a relatively new industry. At first the mining methods were mainly adapted from those used at open-cut iron mines and at quarries, but now efficient practices that are more suitable for the copper deposits have been developed. The pioneer in this field is the Utah Copper Co., of Bingham, Utah, which deserves great credit for working out much of the early procedure. Stripping began at that mine in 1906, and the large Garfield concentrator was put in commission in 1908. Next in order of development were the Nevada Consolidated Copper Co., at Ely, Nev. ; the Chino mine of the Ray Consolidated Copper Co., at Santa Rita, N. Mex. ; the New Cornelia Copper Co., at Ajo, Ariz. ; the Sacramento Hill mine of the Copper Queen Branch, Phelps Dodge Corporation, at Bisbee, Ariz.; and the open cut of the United Verde Copper Co., at Jerome, Ariz. The Sacramento Hill mine began to produce in 1923, and the United Verde open-cut mine has produced ore mainly in connection with stripping. The writer visited the Utah Copper mine in September, 1923; the Nevada Consolidated in August, 1923; the Chino in July, 1924; and the New Cornelia, the Sacramento Hill, and the United Verde open cut at various times during 1922, 1923, 1924, and 1925, mostly in connection with other work.

Jan 1, 1927

By Joseph A. DeCarlo

Coal is one of our basic sources of energy (heat, power, light) and an essential raw material for most metallurgical processing. More than two-thirds of the electricity currently produced by thermal powerplants in the United States is generated by coal, and it is expected that coal will continue to be the major fuel used for this application at least through the 1970's. Coke produced from bituminous coking coal is the principal fuel of iron blast furnaces, and unless ironmaking methods change greatly, coal will continue to maintain a dominant role in iron-ore processing and steel manufacturing for many years. Export markets are expected to increase also, adding to the overall increased demand for coal. Accompanying the increased total requirement, however, will be an ever-increasing demand for higher quality coals, specifically, coals of low sulfur content. Except for special-purpose coals such as those used for the production if coke and ceramics where impurities in the fuel contaminate the end product, the amount of sulfur in coal has been only a minor consideration in the selection of a particular coal for fuel. Major considerations, particularly for the coals used to generate electric power, have been availability and cost. An increased national concern for control of air pollution, however, particularly that resulting from the emission of sulfur oxides in stack gases to the atmosphere, has led to more rigid specifications on coal quality, and the sulfur content of coals will become increasingly more important in the future.

Jan 1, 1966

By Joseph A. DeCarlo

Coal is one of our basic sources of energy (heat, power, light) and an essential raw material for most metallurgical processing. More than two-thirds of the electricity currently produced by thermal powerplants in the United States is generated by coal, and it is expected that coal will continue to be the major fuel used for this application at least through the 1970's. Coke produced from bituminous coking coal is the principal fuel of iron blast furnaces, and unless ironmaking methods change greatly, coal will continue to maintain a dominant role in iron-ore processing and steel manufacturing for many years. Export markets are expected to increase also, adding to the overall increased demand for coal. Accompanying the increased total requirement, however, will be an ever-increasing demand for higher quality coals, specifically, coals of low sulfur content. Except for special-purpose coals such as those used for the production if coke and ceramics where impurities in the fuel contaminate the end product, the amount of sulfur in coal has been only a minor consideration in the selection of a particular coal for fuel. Major considerations, particularly for the coals used to generate electric power, have been availability and cost. An increased national concern for control of air pollution, however, particularly that resulting from the emission of sulfur oxides in stack gases to the atmosphere, has led to more rigid specifications on coal quality, and the sulfur content of coals will become increasingly more important in the future.

Jan 1, 1966

By J. P. Morris

"INTRODUCTION In the investigation being conducted by the Bureau of Mines concerning the production and utilization of sponge iron, it soon became evident that more information was needed regarding methods for determining the degree of reduction attained in the manufacturing process. Sponge irons made by different processes vary in physical characteristics and chemical composition, and a method of analysis that is suitable for one type is not necessarily applicable to all others. For example, the hydrogen-evolution method, which measures the volume of hydrogen evolved upon treating the sample with acid, accurately determines the oxygen content of some types of sponge iron. However, when the sponge iron contains combined carbon, hydrocarbon gases are also-evolved and large errors may result. Probably no single method will give accurate results in all instances, and for this reason it is desirable to have several reliable procedures available and to know the limitations of each.For measuring the degree of reduction, determination of either metallic iron or oxygen should suffice, although for practical application of sponge iron to the production of steel the oxygen content is more significant. After consideration of proposed methods of analysis in regard to their suitability for routine use and the probable influence of other substances, four procedures were chosen for investigation:(1) Mercuric chloride method.(2) Copper sulfate method.(3) Hydrogen-reduction method.(4) Hydrogen-evolution methods."

Sep 1, 1945