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By Charles A. Sorrell

Two red muds, two fly ashes, and several aluminosilicate minerals were subjected to direct treatment with concentrated H2SO4 at temperatures of 175°C and below. X-ray analysis showed that virtually all the sulfate reaction products remained in the solid residue because of their low solubilities in x SO Substantial portions of the Al2O3 Fe2O3TiO2, Na2O, and K2O components of the materials reacted to form water soluble sulfates, which were then removed by H2O leaching at 55°C. The solid residue after water leaching consisted largely of amorphous silica and, in lime bearing compounds, CaSO4, The reaction and leaching processes were effective in removing all or nearly all the Al2O3. Fe2O3, TiO2, Na2O, and in lime components in the fly ashes, red muds, china clay, bentonites, the nephelioe fraction of nepheline syenite, and a plaster insulating brick composed of anorthite and mullite. Reaction with potassium feldspar and petalite took place, with formation of alkali aluminum sulfates, but the reaction rates and yields were extremely low. Potassium feldspar can be heated with Na2O and x O in air at 700°C for 24 hours, or with CaO at 1000°C for 24 hours, after which the reaction product kaliophilite, nepheline, and leucite-like phases, prove to be very susceptible to H2SO4, reaction and H2O leaching, providing yields near 100% of the Al2O2 content. An alternative method of H SO treatment consists of heating the sample in a silica tube and passing H2SO4 vapor over it. Preliminary results indicate that this method can be effective in enhancing the kinetics of reaction with the Al O component of potassium feldspar and offer the possibility that formation of Al2 (SO ) Fe2(SO4)3 and TiOSO4 can be accomplished selectively by taking advantage of the fact that the upper stability limits of the respective sulfates in the presence of H2SO4 vapor will be different.

Jan 1, 1982

By L. W. Beckstead

The use of acid ferric sulfate solution as a lixiviant for chalcopyrite concentrates has been of little interest from a practical standpoint due to the formation of a tenacious layer of elemental sulfur which severely impedes the reaction progress. CuFeS2 + 4Fe+3 ?Cu+2 + 5Fe+2 +2s° For example, an acid ferric sulfate leach of chalcopyrite concentrate results in only 12% copper extraction in a three hour leach at 93°C. Experimental results suggest that particle size is the only controllable variable which has a significant effect on the rate of acid ferric sulfate leaching at ambient pressure. Size reduction of the concentrate prior to leaching was exam¬ined using various methods of grinding. Of the grinding methods considered, attrition grinding was found to be the most effective. Leaching of an attritor-ground product (median particle size 0.5 microns) resulted in approximately 90% copper extraction in a three hour leach at 93°C. Energy measurements suggest that the costs associated with attrition mill¬ing are not unreasonable. Evidence indicates that "activation" or stored strain energy is not responsibile for the enhanced reaction kinetics of the finely ground concentrate, but rather the experimental results can be explained simply in terms of the increased surface area due to size reduction. Leaching reaction mech¬anisms operative in the acid ferric sulfate system are discussed and the application of ultra-fine grinding technology to other systems is considered.

Jan 1, 1976

By A H. Clemens, P Lindsay

Acid producing potential static tests have been undertaken on sample lithologies from New Zealand coal mines, to rank the lithogies into acid producing waste rock and stable non-acid producing waste rock. Results indicated that the main acid producing waste rock in the Waikato coal region are the marine Whaingaroa siltstone and the Glen Massey formations and the main alkaline producing lithologies were the Tauranga group volcanic-derived sediments (A & D) and the Mesozoic basement. Coal ash analysis of 28 samples from 28 mines have also been analysed for reactive S percentage and their base potential has been quantified by the chemical index of alteration (CIA). The results provide mine management in the Waikato Coal region with a classification of problematic and stable waste rock types. XRF and CIA values determined from wash drill cuttings would provide a method of determining waste rock volumes and magnitude of palaeo-weathering underground.

Jan 1, 1999

By A R. Gerson

Pyrite, chalcopyrite and mixed sulfide samples, with and without quartz (5 wt per cent S), were subjected to column leaching to mimic natural weathering (cyclic wetting and drying). The pH and SO4 2- concentration of the column effluent was measured over a period of 78 weeks. The pH of the pyrite-only containing column rapidly decreased and remained under pH 4 after 12 weeks of leaching. The pH calculated assuming a 2:1 ratio of H + generation and SO4 2- release was slightly lower than that measured. However, a reduced H + to SO4 2- ratio of 1:1 is predicted if the release of aqueous Fe 2+ is assumed rather than the formation of Fe(OH)3. The pH of all columns containing only chalcopyrite or a 1:1 mole ratio of chalcopyrite and pyrite remained at or above pH 5 for the duration of the leach even though significant SO4 2- was released. One column containing the same initial surface area of pyrite and chalcopyrite but only approximately 0.10 the mole fraction of S as chalcopyrite maintained a pH of greater than five for the first 56 weeks of leaching and showed sporadic acid production thereafter. It is well established that oxidation of chalcopyrite results in a surface layer of polysulfide material. It is the formation of polysulfide that neutralises the acid produced on S oxidation through to SO4 2-. Hence where polysulfide formation occurs extensively on chalcopyrite the resulting solution pH decrease will be less than that based on SO4 2- production. The oxidation rate of sulfide minerals increases with decreasing pH and hence acid formation via sulfide oxidation to SO4 2- causes the subsequent oxidation rate to increase. The addition of calcite (CaCO3)to a pyrite column not only neutralises the acid formed but also decreases the rate of release of sulfate to solution by a factor of approximately 30. This is also the case where chalcopyrite is present mixed with pyrite. The rate of release of sulfate from the mixed sulfide mineral columns (after the initial release of the sulfate already present) was between one-fifth and one-tenth that in the absence of chalcopyrite.

Jan 1, 2003

By P. G. West-Sells

At Barrick's Zaldivar Copper Mine in Chile, the addition of sulfuric acid to the ore going to heap leaching is a major expense. A process in which a portion of this acid is replaced by elemental sulfur added to the heap has been developed by Barrick and Westcoast Biotech that has the potential for significant cost savings. Initial shake flask tests with plant raffinate solution indicated that oxidation of elemental sulfur by a culture of sulfur-oxidizing bacteria, some indigenous to the Zaldivar heap, showed a significant lag period. This lag period could be reduced by dilution of the raffinate, but dilution would not be economical to implement at Zaldivar. Short (0.75 m) column tests indicated that after the initial lag period, sulfur biooxidation occurred steadily and the acid requirement for obtaining the same copper recovery as the control without sulfur was reduced by as much as 13 kg/t. These tests were followed by taller (5.1 m) column tests that confirmed the reduction in acid consumption, with no negative effect on copper extraction.

Jan 1, 2007

Mineralogical analysis of a nickeliferous laterite from the Rockhampton region shows that the nickel is largely associated with the manganese wad and opaline silica. The laterite also contains an appreciable chromite content (about 12 per cent Cr2O,) although this tends to be poorly liberated.Leaching with hydrochloric or sulphuric acid, at atmospheric pressure at the boiling point is non-selective with respect to iron dissolution.The degree of dissolution increases as the acid concentration and retention time are increased; cobalt dissolution requires less aggressive conditions than does the dissolution of an equivalent amount of nickel.Leaching with sulphuric acid at elevated temperatures and pressures leads to a minimum amount of iron dissolution, is rapid, and requires a reduced acid addition rate. Nickel and cobalt recovery from the clarified leachate would be simplified because of the leach selectivity.Pressure leaching appears to be the most practical route for treating the Rockhampton laterite. The economics of processing would be made more attractive by the recovery of a chromium concentrate from the leach residue. This would typically contain about 45 per cent Cr2O, and could be used as a source of chromium chemicals.

Jan 1, 1986

By T. Sharma, T. C. Rao

Laboratory studies have been carried out on acid leaching as a possible route for the extraction of potassium from glauconitic sandstone. Leaching efficiencies with sulphuric, hydrochloric and nitric acids were investigated. The effects on potassium dissolution of temperature, concentration and type of acid, stirring speed and leaching time were also studied. The results show that it is possible to recover 87.5, 93 and 85% potassium with 5 M H2SO4, HCl and HNO3, respectively. During the initial stages of the sulphuric acid leaching process the chemical reaction at the mineral surface is the rate determining step, whereas during the later stages diffusion through the product layer is rate-controlling. Overall, the process follows a mixed-control model that includes both chemical reaction and diffusion. The activation energy for the dissolution of K was found to be in the range 25.79-106 kJ/mol.

Jan 12, 1992

By F. Enslin

Heavy metals and sulphates in acid mine drainage (AMD) can beadsorbed onto bentonite clay, leaving clean water and a heavy metal loaded clay precipitate as products. Due to the toxicity of heavy metals, the clay could not be disposed of safely in the past. A method was thus required to remove the heavy metal content from the clay. Acid leaching was proposed to liberate the heavy metals from the loaded clay. Sulphuric, nitric and hydrochloric acid were considered as lixiviants. Loaded clay samples were leached over a range of pH values from 1 to 3.5 to identify an optimum leaching condition. From the results it was found that metals can berecovered from loaded bentonite clay by means of acid leaching and the optimum pH for heavy metal liberation was found to be 2.5, with uranium as an exception, being optimally leached at a pH of 3. This allows for the possibility of selective leaching. Furthermore, X-ray diffraction analyses indicated that the clay structure did not deteriorate significantly during acid leaching, suggesting that the bentonite could be reused. The treatment of AMD with bentonite clay, and subsequent acid leaching of the clay, is a sustainable solution, and current outcomes could possibly lead to industrial implementation of the process during water purifying and metal recovery from waste streams. Keywords: Acid mine drainage, bentonite, heavy metals.

Jan 1, 2010

By Shiou-Chuan Sun

This paper is to be presented at the Annual Meeting of the American Institute of Mining, Metallurgical and Petroleum Engineers, New York, New York, February 18-22, 1962. Permission is hereby given to publish with appropriate acknowledgments, excerpts or summaries not to exceed one-fourth of the entire text of the paper. Permission to print in more extended form subsequent to publication by the Institute must be obtained from the Secretary of the Institute. If and when this paper is published by the Institute, it may embody certain changes made by agreement between the Technical Publications Committee and the author, so that the form in which it appears here is not necessarily that in which it may be published later.

Jan 1, 1962

By David J. Akers

In past years, water drainage control in coal mines has been primarily directed on the basis of water quantity rather than quality. Due to the recent intense interest in total ecology and environment, emphasis has shifted to the point where the water exiting from a mining operation may be of better quality than when it enters. In most operations this has meant the use of treatment methods (neutralization) while the technology for the prevention of acid drainage is being developed or refined. To date, underground abatement of acid formation has generally been less expensive but also less effective than surface treatment of the mine water. It seems probable that total mine water pollution control will have to include both underground abatement and surface treatment methods. The general acid producing reaction involving the oxidation of pyrite - 2FeS2 (pyrite) + 702 + 2H20 ? 2Fe2S04 + 2H2SO4 - is well known, even though the individual steps are not clearly understood. The major implication of this reaction, that acid production can be eliminated by not allowing the contact of pyrite with free oxygen or water, has been well substantiated both in the laboratory (1,2) and in practice. (3) Underground abatement or control processes can be generally classified into two types: (1) the effective control or elimination of acid causing reactions within the mine, and/or (2) the reduction or prevention of water flow into and out of the mine. Recognizing the fact that these two types may be directly inter-related, this paper will, for the purposes of clarity and simplification, discuss each separately.

Jan 1, 1973

By C. Ayora

The Iberian Pyrite Belt (SW Spain and Portugal) contains one of the largest reserves of pyrite in the world with mining activities dating back to prehistoric times. About one hundred abandoned mine wastes and galleries release a huge acidity and metal load to the Tinto and Odiel rivers. Once the mining activity is over, polluting discharges can persists for decades or even centuries with no specific responsible entity. In-situ passive remediation technologies are especially suitable for these orphan sites. The concept is to insert a reactive porous material in the natural flow path of contaminated surface and ground waters, and it is implemented through infiltration ponds and reactive barriers, respectively. Calcium carbonate pea-size gravel is the common alkalinity supplier to neutralize acidity and precipitate metals. These remediation systems have been traditionally implemented in coal mines. However, the acid drainages from the Iberian Pyrite Belt contain metal concentrations one to two orders of magnitude higher than those from coal mines and require special designs to avoid quick clogging or passivation (coating) of the grains of reactive material. To overcome these problems, a Dispersed Alkaline Substrate (DAS) mixed from fine-grained limestone sand and a coarse inert matrix (e.g. wood chips) was developed. The small grains provide a large reactive surface and dissolve almost completely before the growing layer of precipitates passivates the substrate. The high porosity and the dispersion of nuclei for precipitation on the inert surfaces retard clogging. However, limestone dissolution only raises pH to values around 6.5, which is sufficient to precipitate the hydroxides of trivalent metals (Al, Fe), but it is not alkaline enough to remove divalent metals. Magnesium oxide, which hydrates to Mg hydroxide upon contact with water, buffers the solution pH between 8.5 and 10. A DAS system replacing limestone with caustic magnesium oxide has been tested to be very efficient to remove divalent metals (Zn, Cd, Mn, Cu, Co, Ni, Pb) from drainage previously treated with limestone.

Aug 1, 2013

By N. Kuyucak

"Acid mine drainage (AMD) is one of the most significant environmental challenges facing the mining industry worldwide. It occurs as a result of natural oxidation of sulphide minerals contained in mining wastes at operating and closed/decommissioned mine sites. AMD may adversely impact the surface water and groundwater quality and land use due to its typical low pH, high acidity and elevated concentrations of metals and sulphate content. Once it develops at a mine, its control can be difficult and expensive. If generation of AMD cannot be prevented, it must be collected and treated. Treatment of AMD usually costs more than control of AMD and may be required for many years after mining activities have ceased. Therefore, application of appropriate control methods to the site at the early stage of the mining would be beneficial.Although prevention of AMD is the most desirable option, a cost-effective prevention method is not yet available. The most effective method of control is to minimize penetration of air and water through the waste pile using a cover, either wet (water) or dry (soil), which is placed over the waste pile. Despite their high cost, these covers cannot always completely stop the oxidation process and generation of AMD. Application of more than one option might be required.Early diagnosis of the problem, identification of appropriate prevention/control measures and implementation of these methods to the site would reduce the potential risk of AMD generation. AMD prevention/control measures broadly include use of covers, control of the source, migration of AMD, and treatment. This paper provides an overview of AMD prevention and control options applicable for developing, operating and decommissioned mines."

Jan 1, 2002

By Vincent T. Ricca, Kurtis Chow

When dealing with acid mine drainage as to treatment levels, costs, and evaluation of abatement schemes, predictions of the quantity and quality of the discharges are needed. An acid mine-drainage model is presented in this paper. In essence, the model is a hybrid of computer programs for stream flow simulation and acid mine drainage. Two major aspects of the model are discussed: mine-water generation and acid-load production. The former is based on hydrologic concepts and the latter on pyrite oxidation kinetics and oxidation product removal. The total model is programmed for the high-speed digital computer. The major inputs are: climatological, basin characteristics, and mine characteristics data. By the use o f the hydrologic model the amount of water that flows through the pyritic system is determined. From this information, acid loads removed by leaching, inundation, and gravity diffusion are then predicted. The outputs from the total model are: average daily mine-water discharge, the associated acid concentration or load, plus the average daily flow in the receiving streams or at basin outlets. The capabilities of the separate models have been tested individually and the joint model has been applied to a small drift mine in southeastern Ohio.

Jan 1, 1975

By Vincent T. Ricca

Acid mine drainage is a serious water pollution problem, for its contaminants will eventually effect the quality of the receiving streams. According to the Appalachian Regional Commission (1969)1, 10, 500 miles of streams have been polluted by mine drainage, and 70 percent of this acid pollution is accounted for by underground mines. Due to the severe damage to aquatic life, to recreational and industrial use, and to domestic water supply, more stringent mining and anti-pollution laws have been legislated and coal mine operators are required to treat the mine water discharges to meet the minimum standards. For years now, abatement and treatment methods have been extensively studied. Progress reports presented in the Fourth Symposium on Coal Mine Drainage Research, 1972 1 suggest that a thorough investigation and understanding of the basin discharge is necessary in order to cope with the mine drainage problem. The extent of mine water discharge contamination can be considered as a function of the basin streamflow and acid generation load.' A conservative treatment cost estimation these days is $0.40 per 1, 000 gallons for water with 100 ppm iron, 500 ppm acidity. These figures need not include collection and pumping costs nor the cost of dispersing of chemical waste by-products. To achieve optimal abatement and treatment of mine drainage, predictions of the quantity and quality of mine water discharges are needed. Basin discharge is a continuous process and it can be considered as a. macro-system. This system can be subdivided into micro-systems to describe the various mine discharge .types in the basin. The mining activities could produce acid water discharges from deep mines, stripmines, or associated gob piles. A total study entitled ?Resource Allocation to Optimize Mining Pollution Abatement Programs?* will consider all of these sources. However, this paper will discuss only one micro-system, the drift (deep) mine type. We will look at a single mine and its watershed. The total research project considers a multiple mining complex in an extensive stream basin.

Jan 1, 1973

By Q. Xiao, R. Naidu, W. Li, S. Song

Acid mine drainage (AMD) derives from the oxidation of sulfide minerals, primarily pyrite (FeS2), and is the most severe environmental issue facing the minerals industry. The most common short-term approach to AMD treatment is migration control, such as acid neutralization and metal/metalloid and sulfate removal, through the addition of alkaline materials, including lime (Ca (OH)2), limestone (Ca CO3), gangue minerals and industrial wastes. This requires the continuous input of materials and may result in the production of a vast amount of secondary sludge requiring further treatment and disposal. Addition of chemicals is usually more important in metal/metalloid removal than in sulfate removal unless the sulfate is present in very high concentrations. A more promising long-term strategy for AMD prevention is source control through the complete removal of pyritic minerals and encapsulation of potential risk minerals by coating with impermeable surface layers. This is regarded as the most cost-effective approach, although the mechanisms underpinning this and the implementation procedures are yet to be fully elucidated. It is likely that long- and short-term practices can be combined to optimize the remediation of contaminated mining sites. Some factors such as differing geological and mineralogical characteristics and transportation costs must also be considered for the successful implementation of AMD prevention and remediation strategies. This review also considers some implications for AMD remediation, but the promising bioremediation of AMD is not discussed as it has been extensively reviewed.

By E. A. Zawadzki

The problem of pollution of water by mine drainage is at least as old as the mining industry itself. However, research on the formation, composition, treatment, and abatement of mine water is a relatively recent historical event. At Bituminous Coal Research, Inc., acid mine drainage control has been an important area of work since 1944, at which time BCR began sponsorship of research at West Virginia University. The work at West Virginia University involved a detailed study of the acid mine drainage problem and led to the identification of iron oxidizing bacteria as important factors in the formation of acid mine water. The results of this research were summarized in 1954 by Temple and Koehler (1) who concluded that "no practical solution for the problem" of controlling acid mine drainage is yet known.?

Jan 1, 1967

By M. P. Filion, K. Ferguson, L. L. Sirois

Acidic drainage is the largest single environmental problem facing the Canadian mining industry today. Technologies to prevent acidic drainage from occurring in wasterock piles and tailings sites, and on the walls of open pits and underground mines, need to be developed and demonstrated. There are two groups in Canada which have accepted this challenge: the national Mine Environment Neutral Drainage (MEND) program and the British Columbia Acid Mine Drainage (BCAMD) Task Force. This paper summarizes the activities of these two organizations.

Jan 1, 1990

By M Watts, P Lindsay

Herbert Stream, a tributary of the Waimangaroa River on the Stockton Plateau, has elevated metal concentrations and low pH characteristic of acid mine drainage (AMD). Dissolved aluminium concentrations average 8.3 ppm, iron 1.4 ppm, manganese 0.69 ppm, and zinc 0.12 ppm and pH ranges from 2.8 to 3.2. Flow rates range from 2.3 to 26.6 L/s with an average of 5.3 L/s. To determine the effectiveness of different treatment strategies, a small amount of the AMD was diverted through three small-scale passive AMD remediation systems over an eight month period. These included a reducing and alkalinity producing system (RAPS), a limestone leaching bed (LLB), and an open limestone channel (OLC). Both the RAPS and the LLB performed well, effectively removing metals and restoring pH. The RAPS lowered aluminium concentrations by up to 99%, iron 97%, manganese 95%, and zinc 80% and the LLB lowered aluminium concentrations by up to 99%, iron 99%, manganese 92%, and zinc 91%. The pH was restored to between 6.4 and 7.4 by the RAPS and to between 7.3 and 7.9 by the LLB. The OLC performed well as long as the residence time was similar to that of the other treatment systems. OLC removal rates for aluminium was up to 99%, iron 94%, and manganese 21%, and the pH was restored up to 5.6. Due to its simplicity and effectiveness, it is proposed the LLB be constructed to fullscale size to treat the entire Herbert Stream.

Jan 1, 2007

Neutralisation, normally using lime, is the most widely used method for treating high flows of acid mine drainage (AMD). Lime costs can be very high however. If carbonate sources could be used to achieve pH values above six, costs could be greatly reduced. For example, use of locally quarried limestone at Mt Lyell could potentially reduce alkali costs from about $A 3.5 to $A 1 million/year. Methods for enhancing the effectiveness of limestone and magnesite for neutralising Mt Lyell and Savage River AMD respectively have been examined through a series of investigations. Small-scale testwork found that the maximum pH economically achievable with ground limestone was about five, due to slow dissolution rates and surface armouring. The problems of surface armouring were greatly reduced by the use of crushed limestone or magnesite at high pulp densities (75 per cent solids w/w), enabling pH values >6 to be achieved in a practical time frame. The use of particle sizes in the range 6 mm and finer also reduces costs by avoiding the need for grinding, and reduces the problems of solid-liquid separation and solid recycling that arise if large additions of ground carbonate are used. Pilot scale tests were carried out using tumbling drum reactors with limestone and Mt Lyell AMD and a pulsed-bed static reactor with magnesite and Savage River AMD. pH values averaging 6.2 and 6.4 were achieved with Mt Lyell and Savage River AMD respectively. Approximately 80 per cent of feed acidity was neutralised. A preliminary engineering design and cost estimate has been completed on the pulsed-bed reactor and shows that the concept is technically feasible and, if results are confirmed, economically attractive. Further pilot testing is planned.

Jan 1, 2002

By Richard F. Hammen

Mineral extraction from sulfide ore deposits usually leads to the combined action of oxygen and water on the newly exposed ore. The result is acid mine drainage, a low pH solution of various metal sulfate salts and sulfuric acid. Paradoxically, the valuable metals dissolved in acid mine water are a liability because they are too toxic for discharge but too dilute to recover economically. The expense of compliance with water quality release standards has reduced the profitability of many mining operations. Solid phase extraction (SPE) columns have been developed to extract metals from acid mine water. These columns are designed to remove the toxic elements from water and recover the metals as purified fractions. This article describes the results of a Phase 1 bench-scale project to test the performance of the SPE columns. The tests were conducted with water collected from the abandoned Berkeley Pit copper mine in Butte, MT.

Jan 1, 1993