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By M. F. He

There are three polymorphic modifications in pyrrhotite (monoclinic, hexagonal and orthorhombic), with monoclinic and hexagonal polymorph being more abundant. The floatability of different crystalline structures of pyrrhotite (monoclinic and hexagonal) is studied in this paper. It is shown that the floatability difference of monoclinic and hexagonal is obvious and that the flotation recovery of monoclinic pyrrhotite is greater than that of hexagonal pyrrhotite using different collectors . Using butyl dithiophosphate as collector, the flotation recovery of pyrrhotite is higher than when sodium diethyl dithiocarbamate and sodium butyl xanthate are used as the collectors. Monoclinic and hexagonal pyrrhotites are more easily activated by Cu2+ in acidic conditions than in alkaline conditions, while Cu2+ can not activate hexagonal pyrrhotite when sodium diethyldithiocarbamate was used as the collector. By the measurement of contact angle, it is indicated that monoclinic and hex-agonal pyrrhotite float well and are easily activated by Cu2+when dithiophosphate was used as the collector. Using sodium diethyl dithiocarbamate as a collector, the flotation behavior of pyrrhotite was investigated. The relationship between potential and pH range for pyrrhotite flotation was established. The results show that the flotation of pyrrhotite is dependent on pulp potential at certain pH values.

Jan 1, 2014

By G. Unland

The sizing of crushers depends on the expected crushing forces. However, the crushing forces develop differently with every individual rock while it is compressed by the working surfaces of the crusher. For sizing, this compression process has to be characterized by the maximum crushing force. The maximum crushing force depends on the strength, shape and size of the rock, the amount and velocity of the imposed displacement of the working surfaces of the crusher on the rock and the conditions of the contact surfaces. From experience it is known that the strength of the material and, therefore, the crushing forces depend on the size of the specimen. This dependence is the so called size effect. The determination is based on compression tests. The force development is recorded during the compression of the specimen and for every individual test the maximum force is determined. The occurring maximum crushing forces of several rocks with the same diameter comminuted under the same conditions can be assessed by a mean value and a variance. The relationship between the mean values of the cross section related maximum crushing forces FAmax and the corresponding sizes d of the specimens can then be described by mathematical functions. They are derived from different approaches (phenomenological, statistical and statistical-physical methods). The phenomenological methods are subjective and yield functions depending on the assumptions of a person, whereas the statistical and statistical-physical methods are based on an evaluated function and the optimization of the parameters.

Jan 1, 2014

By Yuexin Han

The wet preconcentration of haematite, comminuted by high-pressure grinding roller was studied, using the cylindrical ferromagnetic medium. The effects of various factors including rod diameter, rod gap and background magnetic field intensity (BMFI) on the performances of preconcentration for different size fractions and the force analysis of single mineral particles with different diameter in the separation zone were emphatically investigated. The results showed that as the rod diameter increased, the rod gap decreased, and the BMFI increased the tailings grade and the tailings yield reduced while the concentrates recovery raised that was regardless of variations in feed size distribution. For the -3.2+0.18mm size fraction preconcentration, the magnetic medium with a rod diameter of 4 mm and a rod gap of 7 mm at BMFI of 454kA/m is used to get a higher performance. For -0.18mm size fraction preconcentration, the magnetic medium with a rod diameter of 4 mm and a rod gap of 4 mm at BMFI of 263kA/m is used to get a higher performance. After the classifying preconcentration, at the optimum condition, the overall concentrate grade increases by 9.56 percentage points and the concentrate recovery is up to the 82.67% with a tailing grade of 10.68% and a tailing yield of 40.31%. The magnetic force, exerted on weekly magnetic minerals was proportional, to the specific susceptibility and square of BMFI. For the same BMFI, the magnetic capturing force on coarse particles increased, and that on fine particles decreased with the increasing of rod diameter. For the lean locked-particles, considering the gravity and viscous resistance of particles, rods with a big diameter were beneficial to the capture of coarse particles and had no influence on the capture of fine particles, while rods with a small diameter were good for the capture of fine particles and not suitable for the capture of coarse particles of lean locked-particles. Keywords: low grade haematite, high-pressure grinding roller, high intensity magnetic separation, pre-concentration

Sep 1, 2012

By H. Sarvamangala

Selective separation of alumina, silica, calcite and apatite from hematite was achieved through microbiologically induced flotation and flocculation in presence of bacteria (B.subtilis) and that of hematite from apatite after interaction with yeast (Saccharomyces cerevisiae). Bacterial and yeast metabolites containing extracellular proteins were characterized from mineral-grown cell free extract. Bacteria and yeast can adhere to mineral surfaces and influence subsequent separation of the minerals. Bacteria functioned as a stronger depressant for hematite, while yeast cells depressed apatite at neutral pH. Selective affinity of the bacterial and yeast cells towards the mineral surface was observed through adsorption studies. Extracellular proteins (EP) were isolated from B.subtilis and yeast. The protein profile of the EP of bacterial and yeast cells grown in presence and absence of minerals was studied. This study has demonstrated the utility and amenability of microbially-induced mineral beneficiation of iron ores through bacterial and yeast cells and their metabolic by products.

Sep 1, 2012

By Jan Svoboda, Toyohisa Fujita

The current status and history of innovation in magnetic methods of material treatment are reviewed. The milestones and key drivers of innovation in magnetic separation are identified, advantages of this technology in comparison to other physical methods of material manipulation are discussed and reasons for its failure to live up to its potential and expectations are indicated. Derailers that were responsible for the implementation failures are identified. The future focus in such diverse areas as mineral processing, waste treatment, recycling and biosciences is discussed and the research and development needs are outlined.

Jan 1, 2003

By Shailin Lalloo, Allan B. Nesbitt

A fluidised bed was exposed to high gravities by placing it in a centrifuge. The bed expansions were measured and compared with the bed expansions predicted by the Richardson-Zaki model (1954). The Richardson-Zaki model was found to predict effectively the fluidisation behaviour of defined particles in this increased gravity environment.

Jan 1, 2003

By P. Spolaore

In the frame of Bioshale FP6 project, the bioprocessing of a polymetallic and polymineral concentrate produced in an industrial operation in Lubin, Poland, was assessed. Following successful batch culture tests, processing in continuous conditions was tested to determine the main specifications for the application of the stirred-tank technology to this sulphide concentrate from black shale ores. The experimental work was carried out in a laboratory-scale unit consisting of 3 stirred tanks (50L or 20L) using an acidophilic and moderate thermophilic bacterial population. Different configurations of the unit and key operating parameters were tested (nutrient medium composition, solids concentration, rates of agitation and aeration). Scientific and technical approaches, such as bacterial community structure and mineralogical analysis were implemented in order to better understand the chemical and biochemical reactions occurring in the system. Using the data produced during the continuous operation, downstream processing assessment for both copper and silver recovery was also carried out. The best copper recovery obtained in the continuous operation was 92% and a hot brine leaching of the bioleach residue (PLINT process) allowed to recover 92% of the silver. A preliminary tech-no-economic evaluation of Lubin concentrate bioprocessing including bioleaching, copper and silver recoveries demonstrated the potential economic feasibility. Recovery of silver plays an important role in the economy of the process. This study presents promising values to further investigate this bioprocessing option.

Jan 1, 2014

The value creation with kaolin clays depends on removing the colored impurities which manifests in to higher brightnessone of the most sought after properties on applications such as paper coating, paint and others. The processes for removing impurities include magnetic separation, froth flotation and selective flocculation. While the flotation and selective flocculation processes exploit the physico-chemical differences between the surface properties, the magnetic separation uses the bulk magnetic susceptibility differences between the diamagnetic clay and ferro- and para-magnetic nature of the impurities. The major advantage with magnetic separation remains high yield and no or low reagent usage. However, the magnetic separation technology suffers from low separation efficacy when finer colored impurities (<1 µm) are encountered in the feed. Use of stronger magnetic intensities during magnetic separation showed limited success; nonetheless the adverse effect due to finer size range remains a dominant effect even at 5 Tesla magnetic field. Furthermore, the presence of diamagnetic colored impurities irrespective of their sizes can not be removed. Cytec Industries has recently developed a ?bolt-on? chemical enhancement technology for magnetic separation that essentially embraces the best product performance attributes of flotation and selective flocculation while keeping the chemical usage to a minimum level and using the readily available magnetic separation equipment. The paper will outline the technology and illustrate optimization work at pilot plant magnet on a wide variety of crude accommodating the process needs and plant limitations. The major advantages of chemical enhancement technology to magnetic separation include: 1) simple extension to existing magnetic separation technology, 2) ability to produce comparable product in quality with cost effectiveness compared to flotation and selective flocculation, 3) removal of impurity minerals over wide size range, 4) removing non-magnetic impurities, 5) providing robust process with high process yield and 6) operation-friendly nature. Furthermore, chemical enhancement technology for magnetic separation has also emerged as a platform for re-moving impurities at low levels in other mineral systems as well.

Jan 1, 2014

By H. M. Yang

Structural alteration of pyrophyllite during mechanical activation in a planetary mill was investigated by X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) techniques. Mechanochemical effect markedly promotes the decrease in reflection intensities with increasing the grinding time. Prolonged grinding causes the pyrophyllite to become the amorphous structure. It can be indicated that pyrophyllite is very susceptible to alteration by grinding. Crystal size (d006) of pyrophyllite appears to be a limit after 2h grinding. IR spectroscopy analysis shows a little alteration in the bands of pyrophyllite after mechanical activation. The results indicate that the ordered structure of pyrophyllite is destroyed and lattice deformation occurs. Porous silica was then successfully prepared via leaching the mechanically activated pyrophyllite. Pyrophyllite was first ground for 6 h. Ground samples were subsequently leached with 4 M hy-drochloric acid at 80 °C for 2 h to produce porous silica with specific surface area of 188.1 m2/g, total pore volume of 0.18 mL/g and average pore size of 3.9 nm from N2 adsorption analysis. Otherwise, the porous silica obtained from direct leaching of the original pyrophyllite only has a specific surface area of 4.3 m adsorption analysis. 2/g and total pore volume of 0.03 mL/g. It is inferred that grinding is favorable for the formation of microstructure pores. It offers a simple and convenient route for the preparation of porous materials from natural minerals.

Jan 1, 2014

By F. A. V. Guimarães, A. M. Costa

"The moisture in sintering is a very important parameter for the performance of the process. It allows that the granulation takes pace in an efficient way making the water bridges between the bigger particles used as nucleus and the finer particles that perform the coating of those coarse particles. The formation of the micro pellets is extremely important to prevent loss in permeability of the bed in the sintering grate, avoiding excessive fuel consumption and producing a quality sinter. The aim of this project is to use some of the methodologies for determine the saturation degree on ores and coal to determine the optimal moisture for sintering. In the sinter pot grate series, 3 to 4 assays in a series of 10 are required to determine the optimal moisture for the process. The saturation degree curve test has shown that is really viable to use this technique to skip those tests and go directly to the series to determine productivity and the coke / anthracite consumption. In an industrial scale can be used to adjust the water addition in the conventional mixing methods used in the sintering plants to increase productivity in the process.INTRODUCTION Sintering Sintering is a high temperature agglomeration process in which iron ore fines are partially melted and bonded together using fluxes and a source of fuel, usually coke breeze. The agglomerated product, sinter, has improved metallurgical properties making it an ideal ferrous burden that enable the passage of hot gases in the iron-making blast furnace. The sintering process is normally carried out over three basic stages: granulation, ignition/sintering, and product sizing. In the granulation stage, iron ore fines (usually a blend of selected ores), sinter return fines, fluxes and fuel, and are mixed with water and micro-pelletised in a drum or disc before being introduced in the main granulation circuit. (Wang, Teng, & Wang, 2017)."

Jan 1, 2018

By Richard K. Komarek, Antonios Zavaliangos, Roman T. Dec

Roller presses are widely utilized in mineral industry for fine milling and compaction. Recently used models are providing only limited information about the material behavior in the roll bite. This paper introduces a 2-dimensional finite element model for analyzing those two basic processes. A pressure-dependent plasticity model with linear elasticity was used as a constitutive model for the particular material. Coulomb friction law was used to describe phenomena on the material/roller surface interface. Two basic roller geometries are considered: smooth (used for milling and compaction) and with cavities, commonly used for briquetting. Comparison of the results obtained from the model with experiment indicates that they are following the general trends of experimental values recorded with laboratory roller presses. It is shown, that the model is suitable to analyze material behavior through all stages of the rolling process: feeding zone, nip region, neutral plane and release section. It can predict pressure, shear stress, slip of the material over the roller surface, material velocity field, failure of the compact during release and the course of other important process variables. This allows the process engineer to gain an improved understanding, leading to a better process and equipment design and control.

Jan 1, 2003

By Jihoe Kwon, Daeyang Lee, Mario Fujimura-Kashiwagui, Heechan Cho

"Calcium carbonate is one of the most widely used mineral in today&apos;s industries such as plastic, paper and pigment. There are many essential physicochemical properties required by each industry field but the most common requisite is size. One way to achieve appropriate size is grinding. Grinding is typically an energy intensive process, consuming about 40% of total energy cost in mineral process. Due to that reason, optimization of grinding process is a critical element to achieve price competitiveness. Two different type of grinding apparatus were hired to find out optimum condition in terms of energy efficiency. Utilizing samples containing 10, 20, 30 and 40% solids concentrations, a 1l batch type attrition mill was operated as the first grinding step at various operating speed with 1? to 5? grinding media in order to study the optimum operating conditions to reach submicron particles. Next, a 0.15l vertical beads mill was tested as next step with 100? to 500? grinding media to study the optimum conditions in the submicron range. Net energy and the specific energy input was measured to reach stated size ranges. Also, using a back-calculation based on the population balance model further operating conditions were studied. There were several competitive combinations which showed significant energy efficiency improvement when compared with the single step grinding."

Jan 1, 2014

By T. Laxmi

This paper details the optimization of rougher Wet High Intensity Magnetic Separator (WHIMS) using response surface methodology. The optimization is in parametric form and takes account of the major operating variables in WHIMS operation such as current in ampere and grid gap, in inch. The objective is to recover ilmenite mineral from red sediment deposits of Srikakulam, India by optimizing the rougher WHIMS. We predict mineral recoveries as a function of current and grid gap. Combination of these predictions with assay data provides predictions of mineral grades and recoveries. The optimized response was validated against data derived from laboratory-scale rougher WHIMS test work, comprising (i) mineral grade, (ii) mineral recovery, and (iii) separation efficiency of the process. We observed close match between the experimental and the predicted data over most of the operational range. This paper describes how the optimization was carried out using the response surface methodology along with MATLAB. The response surface was used to closely investigate the separation of ilmenite mineral by varying ampere and grid gap. The results show that under optimum conditions, such as 3.5 amp current (0.53 Tesla) and 2 inch grid gap, the mineral grade could reach, as high as 87.9% in the concentrate with 74.3 % recovery and 74.4% yield. Keywords: red sediment, wet high intensity magnetic separator, optimization, ilmenite, placer heavy minerals

Sep 1, 2012

By P. A. Bepswa

A numerical study done to test the efficacy of heuristics developed for the design of measurement networks for high precision metallurgical accounting is presented in this paper. The heuristics considered were designed to maximise variance reduction of terminal stream measurements through data reconciliation for observable linear flow systems. A complex metallurgical process flow sheet from the mineral sands industry was used as a case study. Monte Carlo type simulations coupled with a non-linear programming based steady state data reconciliation algorithm were used as tools to investigate the heuristics. The results obtained suggested a close correlation between magnitudes of measured variances and the respective levels of variance reduction obtained through data reconciliation for both internal and terminal streams. It was observed that variance reduction through data reconciliation was maximised for terminal stream measurements in networks characterised by high precision measurement of internal streams and/or in flow sheets characterised by high ?stream to node ratios?. Terminal streams attached to highly interconnected parent nodes were observed to experience higher reductions in variance compared to terminal streams attached to less interconnected parent nodes. The results generally highlight the additional benefits of highly interconnected flow sheets and high precision internal stream measurement regimes on the maximisation of variance reduction of terminal stream measurements through data reconciliation. These findings are significant to metallurgical accounting and to process accounting applications in general in that they provide a conceptual basis for design decision making regarding the construction of measurement networks aimed at maximising variance reduction of targeted streams through data reconciliation.

Jan 1, 2014

By Kr. J. Dedelyanova

Selective flocculation of iron minerals could improve the economics of high intensity magnetic separation as concomitant process. When the minerals are finely disseminated is necessary a finer grinding to be applied which generates a lot of slimes. The HIMS is not enough efficient for particles below 20 microns ? territory where the selective flocculation is already well known industrial practice, so the combination of these two methods of beneficiation can bring a higher grade at high recovery to be achieved. The dynamics and selectivity of the precipitation process is studied in batch tests with flocculant starch and dispersants sodium silicate and sodium hexametaphosphate. The influence of preliminary conditioning with nitrogen acid at pH 2 before flocculation is also investigated. Flowsheet including these two methods is tested and the distribution of iron is shown.

Jan 1, 2014

Electrochemical behaviors of synthetic and natural enargite in buffer solutions have been investigated using open circuit potential, stationary polarization and cyclic voltammetry as functions of solution pH, scan direction, scan range, scan rate and dissolved O2. The results indicate that the electrochemical behaviors of synthetic and natural enargite are very similar; solution pH, scan direction, scan range and scan rate have remarkable effects on the electrochemical behavior of enargite while dissolved O2 has little effect on the electrochemical behavior of enargite. The potential range in which enargite possesses the ability of passivation is from ?0.9 V to + 0.83 V vs. SCE. Enargite is most stable in neutral and alkaline solution around potential ?0.2 V vs. SCE. The main oxidation products on enargite surface in alkaline solution are Cu(OH)2 while the potential imposed on it is within the range of ?0.2 V to 0.33 V vs. SCE and Cu(OH)2 + S0while the potential applied is higher than 0.52 V vs. SCE.

Jan 1, 2014

By X. M. Wang

Magnetic floatation column (MFC) is a new equipment used for increasing content of iron, in which magnetite is separated in open gradient magnetic field. Simulation study was performed to investigate the separation characteristics of the separation method by analyzing the dynamic motion of magnetic particles. In this paper we compare two magnetic fields created by different magnets. The obtained simulation results give perspective in industrial design of MFC as the basis stage.

Jan 1, 2014

By Ahmad Amini, Hadi Abdollahi, Pouya Karimi

Due to detrimental effects of cyanidation process on the environment in gold industry, application of cyanide alternatives such as thiourea are being highly considered in recent projects. In this study, the extraction of gold from poly metal ore, using thiourea was precisely investigated. The representative sample contained 2.5 ppm Au and 160 ppm Ag. The sample was categorized as oxide gold ore, because the main part of its pyrite was changed to iron oxide and hydroxide such as goethite and lepidocrosite. According to mineralogy, the main gangue mineral was quartz. It shows that gold grains are free and interlocked with quartz matrix. Also, the presence of a high amount of silver in free and sulfide forms and also the low content of other sulfide minerals such as base metal sulfides is a remarkable point of these studies. In the gold extraction process with thiourea, there are several parameters that affect the rate of gold dissolution such as concentrations of thiourea as a gold lixiviant and ferric sulfate as an oxidant, pH and size fraction of feed and leaching time. The influence of these parameters on the gold dissolution rate were investigated and optimized. The results showed that the concentration of thiourea is the most influential parameter which could increase the gold recovery to 71% (at 10 g/kg sample). The optimal amount of ferric sulfate was determined as 6 g/kg sample. Also, the optimal levels of size fraction of feed and pH of solution were 88% under 75 micron and 2 as acidity; respectively. Leaching time was 6 hrs. In addition, this sample was leached with cyanide and the optimized values of size fraction of d88=75 microns, pH=10.45, 2500 ppm of sodium cyanide with time leaching of 24 hours were concluded for maximum recovery of gold in solution. Finally, the results of cyanidation tests were compared to the thiourea dissolution after optimizing all affected parameters in cyanidation process.

Jan 1, 2018

By P. Condori

In spite of the importance of the slurry transport and discharge in autogenous and semiautogen-ous (AG/SAG) mills, it is evident that a more comprehensive and useful model is still required. Semi-empirical models used up to now have many limitations and cannot be used beyond the ranges in which they were developed. The breakage of particles as they are transported along a mill com-plicates the experimental analysis and the modelling of the transport process within the mill. The interaction of the grate discharge and the pulp lifters, with the added issue of backflow from the pulp chamber into the mill, makes the discharge modelling process difficult. In order to overcome these difficulties, a mechanistic approach has been applied. The general transport and discharge model was subdivided into four independent models: Flow through the charge, flow through the grate, flow in the pulp lifter, and flow-back. This paper gives an overall description of the modelling approach and discusses in particular the modelling of transport of fluids through the charge. In order to evaluate and calibrate the model, experimental work was carried out. To evaluate the gradient pressure under different conditions of charge packing and flow rate, a specialised experimental rig with a highly sensitive pressure gauge was used. Preliminary results identify the differences of the charge and grate on the restriction of flow. The existence of a dynamic voidage in our particular system was more evident and as a result, a semi-empirical correlation for the voidage was developed. In general, results show that the me-chanistic model derived from Ergun?s equation for flow through a packed bed can be satisfactorily adapted.

Jan 1, 2014

By Y. X. Yang

Bottom ash is a solid waste stream in a Waste-to-Energy (WTE) processing plant during the combustion of the municipal solid waste (MSW). In the Netherlands, bottom ash contains typically about 18% metals originated from the MSW, and current industrial practice could recover about 10% metals through magnetic and eddy current separators. The remaining 8% as the finer particles is difficult to recover through current physical separation technology. Among various alternatives, vitrification is one of the promising options to immobilize the ash and recover the remaining metals. During vitrification a homogeneous glassy slag and a Fe-Cu based alloy were obtained. In the cur-rent study, the metal alloy recovered from the bottom ash originated from a Dutch Waste-to-Energy plant contains about 82 wt% Fe, 12 wt% Cu and 6 wt% other alloying elements and impurities such as C, S, P, Ni etc. The generated alloy does not have direct commercial applications, and separation of copper from iron-based alloy is critical to obtain the market value of both copper and ferrous constituents. To find a suitable processing route of this metal alloy, various alternative approaches have been considered for an efficient removal of copper from the alloy, and the focus in the present study was on the sulphide treatment at elevated temperatures of 1400 ~ 1500oC. The tested sulphide systems include pure FeS, FeS containing sulphide mixture (such as Na2S and Al2S3), pyrite (FeS2) mineral, ZnS containing sludge as an industrial waste. It was found that the carbon saturation of the alloy is proved to be an essential condition for a proper phase separation. The results showed that FeS mixed with Na2S, ZnS containing sludge and pyrite are effective sulphide systems for copper removal with a removal efficiency of 92% by using pyrite and 95% by zinc sludge at a S/Cu ratio of around 7 times of the stoichiometry. The copper content drops from 12 wt% to about 2 wt%. However, it is still difficult to remove copper completely from the alloy in a single step, and a multi-step operation is needed. The present research is expected to contribute both to the utilization of the metal recovered from bottom ash, and to the general recycling of steel scrap where copper removal from the steel scrap is a critical issue.

Jan 1, 2014