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By Manfred Krutein

Ocean mining has a number of problems which are critical to its development: ? Political hurdles on national and international stages ? The worldwide economic situation, with the possibliity of a recession ? Financial difficulties in funding further work ? Technical problems for the development of ocean mining and transport subsystems ? Demands for technology transfer This paper touches the last two points and provides some thoughts for discussion and creative objectification. The many technical problems of ocean mining will be identified and some proposed solutions will be investigated relative to the state-of-the-art technology of ocean mining and nodule transport. An outlook into the future attempts identification of the steps necessary to eventually develop components for workable systems that are not only technically but also economically feasible.

Jan 1, 1978

By Isobel Yeo, Florent Szitkar, Sven Petersen, Sebastian Graber, Nico Augustin, Marcel Rothenbeck, John Jamieson

"INTRODUCTIONSeafloor massive sulfides (SMS) along mid-ocean ridges are often seen as a possible future contribution to a secure metal supply for global human needs. A growing interest over the past few years resulted in six national exploration licenses and one application pending, covering 10,000 km2 each, that have been brought before the UN International Seabed Authority (ISA) since 2011. Each contractor has to explore these 10,000 km2 within the 15-year runtime of the contract. However, the need to define areas that are not economically interesting is more pressing, as 50% of the 100 license blocks have to be returned to ISA after only eight years - hopefully areas that do not contain large and economically interesting SMS deposits. Current geochemical prospecting technologies, however, have mainly been developed for the search for active hydrothermal systems (e.g. hydrothermal vents and associated black smokers) that can easily be traced through physical and chemical anomalies in the water column (temperature, chemical variations of elements such as Mn, Fe, redox potential, and/or the particle concentration in the water column). Such plume surveys have been a primary tool for exploration of SMS systems, but they only identify active, and therefore mostly young and small hydrothermal systems. In a recent high-resolution AUV survey performed within the EU-FP7 funded project “Blue Mining”, we covered 47 km2 along the TAG segment of the Mid-Atlantic Ridge to test exploration methodology for fast and reliable exploration of larger areas of the seafloor for inactive seafloor massive sulfide occurrences using the autonomous underwater vehicle (AUV) “Abyss”."

Jan 1, 2017

By J. W. Jamieson

INTRODUCTION Hydrothermal vents that form seafloor massive sulfide (SMS) deposits represent unique biodiversity hotspots that host many species that are found only at these sites. The destruction of these habitats remains one of the greatest environmental risks associated with proposed mining of SMS deposits. For this reason, there is a growing movement to protect active vent sites from direct and indirect effects of seafloor mining (Van Dover et al., 2018). Mitigating the adverse effects of mining on these ecosystems may prove to be one of the greatest challenges facing the marine minerals industry. At the same time, there is increasing evidence that inactive or extinct hydrothermal systems, which do not host the density or diversity of animals typical of active vents, may constitute a significant proportion of the SMS resource potential on the seafloor. Mining inactive SMS deposits may therefore present an extractive opportunity that does not necessitate the disturbance or destruction of active vent habitats. However, if mining of SMS deposits is to take place only at inactive vent sites in order to protect active vent ecosystems, a clear definition of what defines a site as active or inactive is necessary. ACTIVE AND INACTIVE SEAFLOOR MASSIVE SULFIDE DEPOSITS Our understanding of the number of inactive deposits, their size and grades, and how they are preserved on the seafloor remains limited, largely due to the challenges associated with finding these deposits. Over 90% of all hydrothermal vent fields discovered so far are hydrothermally-active. Almost all of these sites were discovered through the detection of chemical anomalies associated with active hydrothermal venting via water column surveys. Inactive sites have no associated hydrothermal plume, and thus the well- established plume survey exploration method is not effective. As a result, very few truly inactive sites inactive sites have been discovered. Alternative exploration methods, such as spontaneous potential (SP) surveys, magnetic surveys, and high-resolution mapping are required (Cherkashev et al., 2013; Jamieson et al., 2014; Tivey and Johnson, 2002). As methods for locating inactive deposits continue to develop, our understanding of the distribution and resource potential of these deposits will increase, and the focus of resource exploration will shift from active to inactive vent sites. However, for now, most exploration and deposit development activities remain focused on active vent fields.

Jan 1, 2018

By J. Bruce Gemmell

ODP Leg 158 drilled seventeen holes into the active TAG hydrothermal mound and underlying stockwork, 26°N, Mid-Atlantic Ridge. Drilling in five different areas, including a high-temperature black smoker complex and a lower-temperature white smoker vent field, revealed the multi-stage depositional history and character of sub-seafloor mineralization and alteration. The upper portion of the mound consist of massive pyrite and pyrite breccias which are underlain by pyrite-anhydrite breccias and then by quartz-pyrite breccias. Quartz-pyrite breccias grade down into silicified wallrock breccias. Chloritised basalt breccias occur at depths greater than 100 m. Several stages of quartz-pyrite±chalcopyrite veins occur in the stockwork zone and lower portions of the mound, whereas anhydrite±pyrite±chalcopyrite veins occur within the upper parts of the mound. Recovery of unaltered basalt near the edges of the mound has constrained the extent of the stockwork zone to a pipe-like feature 80 meters in diameter. A detailed sulfur isotope investigation of sulfides and sulfates within mound and the underlying stockwork zone has revealed the overall range of sulfide d34S analyses to be 0.35% to 10.27%. Anhydrite has a tight range of d34S values 20.55% to 21.56%. There are distinct differences in d34S values between the different textural types of pyrite (massive sulfide, breccia clasts, disseminations associated with alteration, and veins). The massive sulfide and breccia clasts have a similar distribution of d34S values (6%-8%), however the d34S values of the disseminated pyrite associated with the alteration are distinctly heavier (8%-10%). Vein sulfides have the lightest d34S values (5%-7%). Sulphur-isotope values at TAG are, in general, the heaviest reported for unsedimented mid-ocean ridge deposits.

Jan 1, 1998

By Jelena Milinovic, Sofia Martins, Anna Lichtschlag, Sven Petersen, Fernando J. A. S. Barriga, Bramley Murton, Adeline Dutrieux

"The active TAG hydrothermal mound is one of the largest and better studied. Due to its size (one of the largest, known so far, in the Atlantic Ocean) and concentration of specific economic valuable elements, it might be considered for future exploitation due the increasing demand for raw materials. However, the discovery of several large inactive sulfide mounds, some partially buried under sediments may relieve this pressure. Exploration for such occurrences can, together with geophysical exploration tools, be accomplished by mineralogical and geochemical studies of those sediments.INTRODUCTION AND GEOLOGICAL SETTINGThis study reports the results from sediment samples collected during the Meteor M127 cruise on the TAG hydrothermal area in 2016. The Trans-Atlantic Geotraverse (TAG) hydrothermal field (Mid-Atlantic Ridge, 26°08’N) is located 2.4 km east of the main rift valley at depths of about 3650 m. The TAG hydrothermal field stands as an example of a massive sulfide deposit on a low-spreading ridge associated with an active detachment fault (Humphris et al., 2015).Associated with the TAG hydrothermal field are metalliferous sediments/deposits that can reach several meters in thickness (Metz et al., 1988). These sediments/deposits can be formed by hydrothermal plume fall out (buoyant and nonbuoyant), massive wasting of hydrothermal edifices (sulfide mounds and chimneys) and authigenic mineralization (Gurvich, 2006). By studying the grain size, mineralogy and geochemistry of the sediments it is possible to identify each type of sediments and find their proximal or distal distribution. The location of the gravity cores studied here is distributed along sediment ponds near inactive hydrothermal mounds [Three mounds area (B)], actively venting low-temperature mound [Shimmering mound (A) and Mir zone (D)] and an area of sediment accumulation [Central area (C)] (Rona et al., 1993) (see Figure 1)."

Jan 1, 2017

By Carl L. Kaiser

This abstract discusses selected recent technology developments at the Deep Submergence Lab at the Woods Hole Oceanographic Institution aimed at fundamentally changing the nature and scope of AUV operations in the deep ocean. The Autonomous Underwater Vehicle (AUV) Sentry is described in its current configuration with discussion of emerging capabilities. Telepresence enhanced AUV operations are discussed including moving both operations and data processing personnel off the vessel. Autonomous Surface Vessel (ASV) aided AUV operations are discussed including recent experiments where an ASV provided both navigational aiding and a satellite based relay for acoustic communication of telemetery and mission redirection. New flexible communications strategies to perform intervention and manipulation tasks from an untethered vehicle are discussed. The abstract concludes with a brief discussion of industrial collaborations, including the newly launched Center for Marine Robotics.

Sep 14, 2011

By G. Cherkashov

A new hydrothermal field with massive sulfide deposits was discovered in 2004 at 16º 38.4?N, 46º 28.5?W on the Mid-Atlantic Ridge. Hydrothermal signals had already been recorded from bottom waters and sediments in this area during cruise 19 of R/V Professor Logatchev in 2000. This site was revisited during the 24th cruise of R/V Professor Logatchev in February 2004 when samples of massive sulfides were recovered and video records of the deposits made. The basalt hosted hydrothermal field is situated at a depth of 3700-3750 m, 600 m above the inner floor on the eastern slope of the rift valley. Structurally, the new field is located at the intersection of a deep along-axis marginal fault and a transverse sub-latitudinal dislocation. Six sulfide mounds as well as associated metalliferous sediments were mapped (sampled and/or recorded by video profiling) within the hydrothermal site. The largest ore body, 500 x 225 m, in the southern part of the field consists of small blocky talus and relics of sulfide chimneys partly covered by iron oxyhydroxides. The chimneys are 1-5 m high. The southern and western boundaries of the massive sulfide deposit have not yet been delineated. More than 1,100 kg of massive sulfides and stockwork mineralization were sampled at 7 sites by dredge and TV-grab. Everywhere, iron sulfides were the principal minerals present. Pyrite in association with lesser amounts of chalcopyrite occurs in both massive sulfides and stockwork mineralization. Of particular interest is the chalcopyrite-siliceous stockwork where silicified and chalcopyritized basalts are intruded by a network of chalcopyrite veinlets. These zones could be fairly thick and enriched in base metals. Sphalerite was very rare.

Jan 1, 2004

By Jeremy Spearman, Mark Lee, Jon Taylor, Neil Crossouard, Bramley Murton

"SUMMARYThis paper describes challenges faced when executing a programme of monitoring to measure the dynamics of currents and sediment plumes at a seamount and the solutions identified to deliver the measurements. The study site was the Tropic Seamount, which extends some 3300m above the surrounding seabed and is found at the southern limit of the Canary Island Seamount Province. The purpose of the study, which forms part of the Marine E-tech project, was to provide information on the interaction of flows with the seamount and to assess the behaviour of sediment plumes that could be generated from potential seabed mining operations targeting the recovery of ferromanganese crusts. Since the crest of the seamount is submerged to a depth of 1000m, much of the work was undertaken using remotely operated and autonomous vehicles supported by measurements from the surface vessel. Despite only limited information on currents being available for planning purposes, the combination of short term forecasting using a 3-dimesional hydrodynamic model of the study area coupled with the collection and analysis of reconnaissance data collected during the first phase of measurement activities made it possible to plan and execute a number of detailed hydrodynamic experiments on the seamount crest. The results of these experiments have advanced the understanding of the behaviour of sediment plumes in the deep ocean and will ultimately improve our ability to manage the impacts which may arise from deep sea mining operations."

Jan 1, 2017

By K. Vanstaen, K. M. Cooper, S. Ware, S. L. Boyd

Remediation and restoration of offshore marine habitats is a relatively new concept with attempts in European regions largely being instigated by requirements of various strategic directives including Article 2 of the Habitats Directive (1992), the EC Water Framework Directive (2000, Article 2 of the OSPAR Convention (1992) and the developing European Marine Strategy Directive. A field experiment to establish the practicality of various options for rehabilitating the seabed on the cessation of dredging has been successfully set up. The purpose of this experiment is to investigate the practicality and effectiveness of gravel seeding as a potential restorative method that can be applied at marine aggregate extraction sites following cessation of dredging. Zone 2, within Area 408 (offshore Humber) was chosen as the experimental site as there is some evidence for persistence of sand which may have resulted from screening operations at this site.

By K. Vanstaen, K. M. Cooper, S. Ware, S. L. Boyd

Remediation and restoration of offshore marine habitats is a relatively new concept with attempts in European regions largely being instigated by requirements of various strategic directives including Article 2 of the Habitats Directive (1992), the EC Water Framework Directive (2000, Article 2 of the OSPAR Convention (1992) and the developing European Marine Strategy Directive. A field experiment to establish the practicality of various options for rehabilitating the seabed on the cessation of dredging has been successfully set-up. The purpose of this experiment is to investigate the practicality and effectiveness of gravel seeding as a potential restorative method which could be applied at marine aggregate extraction sites following cessation of dredging. Zone 2, within Area 408 (offshore Humber) was chosen as the experimental site as there is some evidence for persistence of sand which may have resulted from screening operations at this site.

Aug 24, 2006

By Sofia Martins, Anna Lichtschlag, Sven Petersen, Fernando Barriga, Bramley Murton, Adeline Dutrieux

"Sediments in the vicinity of the hydrothermal seafloor massive sulphide (SMS) mounds are characterized by high concentration of metallic particles. They result from a long process of weathering of the primary mineral deposits and have been accumulated in depressions by mass wasting and hydrothermal plume fall-out. We present here the first results obtained on pore waters analyses of such sediments in distinct geological seafloor environments (in low-temperature hydrothermally active zones, on extinct hydrothermal mounds and in a remote depositional channel). Vertical concentration profiles suggest that the pore fluid composition is affected more by seawater circulation compared with hydrothermal fluid flow in all environments. The composition of pore fluids is affected by diagenesis and redox processes in the distal depositional channel where Mn2+ is released at depth with Cu2+.IntroductionMarine hydrothermal fields, hosting seafloor massive sulphides, are potential resources for future deep-sea mining and might become economic reserves for the industries. They are widespread at mid-oceanic ridges, arcs and back-arc spreading centers (Hannington et al., 2011; German et al., 2016). Sediments in the vicinity of these fields can contain unusually high concentration of Fe, Mn, Zn and Cu among other metal elements (Shearme et al., 1983). These hydrothermal, or metalliferous, sediments result from a combination of processes such as collapsing and weathering of chimney material, filling of the channels by turbidite-like mass wasting, in situ authigenic mineralization and hydrothermal plume fall-out (Goulding et al., 1998; German et al., 1990). The sediments contain important indicators reflecting the development of the hydrothermal systems. Because of their widespread distribution and metal content, they themselves can be considered potential mineral resources. Circulation of seawater through these deposits, however, often modifies the sediment composition by oxidizing the sulphides into oxyhydroxides and clays causing mobilization of the metals. To address the importance of alteration and diagenesis of these hydrothermal sediments, including the result of seawater circulation, we investigated the post-depositional processes occurring in the hydrothermal sediments at the TAG Hydrothermal Field (Mid-Atlantic Ridge, 26°N), focusing on the mobility of metallic cations in a number of different seafloor environments."

Jan 1, 2017

By Sup Hong

A pilot mining robot, named MineRo-II, has been developed by KIOST during 2011-2012. The pilot scale was defined as 1/5 of the commercial mining capacity, 1.5 million dry-tons of nodules per year. The development purpose of MineRo-II is to use for the pilot mining test planned in 2015. MineRo-II was designed to be self-propelled by electric-hydraulic power and remotely operated in real-time from aboard. The main operational functions are crawling on seafloor, pick-up and crushing of nodules, discharging nodules out to buffer. Prior to MineRo-II, a test miner (MineRo-I) was developed in scale of 1/20th in 2007, and performed two times sea trials in 2009 and 2010. The results of performance tests were evaluated and utilized for the concept of MineRo-II. The design concept aimed at the expandability of the mining capacity based on modularity of configuration, maintenance simplicity and multiplicity of backup solution. The pilot-scale mining capacity is achieved by four pick-up modules of each 1m wide, which are moving forward with robot vehicle and sweep the nodules entering below the pick-up heads. Principally, by adding the pickup modules in lateral dimension the mining capacity may increase linearly. MineRo-II was designed and constructed in unit-module wise. The robot consists of two unit-modules having an identical mechanical and hydraulic configuration. Each unitmodule has two tracks, two pick-up devices with attitude control devices, two crushers, one discharge pump, and one hydraulic system. Two unit-modules are connected by one loading frame and integrated by electric-electronic system. Two thrusters for control of the

Sep 14, 2011

By Steinar L. Ellefmo, Thomas Kuhn

The deep-sea ocean floor offers a great potential for mineral resources. The evaluation of these resources is both time consuming and costly and require as any resource evaluation data; geodata. The collection of hard data, physical samples, is of course preferred because the associated uncertainty is low. However, the collection of soft data or image derived data can offer a valuable supplement. In this paper image derived nodule uncertain abundance data from an area in the Pacific is utilized. Implementing these uncertain data improves the estimation when the quality of the estimation is measured using the classification indicators like the kriging standard deviation, the relative prediction error, the slope of regression and the weight of the mean. It is concluded that uncertain data is better than no data. INTRODUCTION The deep-sea offers vast mineral resources (Cathles (2011), Hannington et al. (2011), Hannington (2013), Singer (2014)). A mineral resource can according to increasing geological confidence be classified as an inferred, an indicated or a measured resource. The classification is performed by a competent- or qualified person and is dependent on the amount, quality and characteristic of available geodata. The competent person must have at least five years of experience relevant to both the style of mineralisation, the type of deposit and the performed task. Typical examples of a “task” is for example resource estimation and classification or planning- and execution of exploration activities and presentations of the results. The competent person must also be a member or a fellow of a professional organisation and thereby be bound by reporting code (-s) that defines minimum standards, recommendations and guidelines for public reporting.

Jan 1, 2018

By Jonguk Kim

Submarine hydrothermal activity and mineralization related to island arc volcanism along the Tonga arc were explored during two research cruises in October 2009 (KODOS 09H) and February 2010 (KODOS 10H), respectively. In KODOS 09H cruise, geophysical survey, including multi-beam bathymetry, marine seismic and magnetic investigations, was performed on 10 volcanoes to find out possible structural discontinuity that can act as fluid pathway for formation of hydrothermal deposits at submarine caldera system. The result provided acoustic and seismic image maps and magnetic anomaly maps of targeted volcanoes. Then, detailed seafloor observation and sampling as well as deep tow side scan sonar survey were performed in KODOS 10H cruise on 5 volcanoes which are selected as targeted areas from the previous cruise. Among 5 targeted volcanoes, TA26 shows most extensive hydrothermal activity. Hydrothermal vents and alteration zone were observed on western caldera and summit of eastern cone of the TA26. Although only weak hydrothermal alteration was observed on eastern cone, mineralized fragments of chimney and mound were sampled from western wall of central caldera on TA25 volcano. On TA12 volcano, strong hydrothermal plume and alteration zone was detected during video tows operated between SW scoria cone and small ridge. However, only small amount of hydrothermal altered rocks were collected from TA12. Although hydrothermal activity and mineralization might be formed, supported by plume detection and result of geophysical survey, only weak alteration zones were observed on other two volcanoes (TA19 and TA22). The exploration area generally show shallow depth up to several tens of meters on summit where subsurface boiling of hydrothermal fluid might occur due to low hydraulic pressure, which can affect on styles of hydrothermal venting and mineralization process observed on Tonga submarine arc volcanoes.

Jan 1, 2010

By Matthew Kowalczyk, Steve Bloomer, Peter Kowalczyk

"Mineral deposits found near seafloor hydrothermal venting are of great economic interest. Valuable metals such as gold, copper, zinc, and other polymetallic sulfides are found in appreciable grades in seafloor massive sulfide (SMS) deposits associated with these vents. For mapping these deposits, electromagnetic prospecting is one geophysical method that is very useful because copper/gold rich deposits are highly conductive.Ocean Floor Geophysics (OFG) in 2008 developed the first EM system to successfully map the limits of conductive mineralization in a survey at the Solwara 1 deposit (Kowalczyk, 2008). Since then, towed coincident loop time domain systems have been developed by Waseda University (Nakayama and Saito, 2016) and have successfully detected known mineralization buried at 30m depth. Using a deep tow controlled source electromagnetic (CSEM) array, very clear anomalies have been measured (Murton, 2017) over known mineralization at the TAG field on the mid-Atlantic ridge.In 2014 and 2015, OFG partnered with Fukada Salvage and Marine Co. Ltd. and the Scripps Institution of Oceanography to map methane hydrate deposits off the coast of Japan using a towed controlled source electromagnetic (CSEM) system developed by Scripps. These hydrate deposits are resistive targets, and the Scripps system successfully mapped subsurface electrical resistivity distributions to depths of several 100 metres below the seafloor. OFG is attempting to extend the Scripps CSEM technology to map subsurface conductive SMS deposits to a similar range of depths below the seafloor."

Jan 1, 2017

By Timothy F. McConachy

Between April 2000 and April 2002, the Commonwealth Scientific and Industrial Research Organization (CSIRO) Division of Exploration and Mining has led 6 research expeditions totalling 160 days ship time in waters of Papua New Guinea, Vanuatu, Solomon Islands, Indonesia and Australia. Five expeditions were undertaken aboard the Australian research vessel Franklin following successful competitive research proposals, and the sixth used the Indonesian vessel Baruna Jaya VIII (see Table 1). In addition, two CSIRO participants joined JOIDES Resolution for the Ocean Drilling Program Leg 193 in the Manus Basin of PNG. The major scientific objective underpinning these expeditions was to locate and study present-day seafloor and sub-seafloor hydrothermal ore-forming activity in order to develop improved methods of exploring for ancient mineral deposits on land that originally formed by similar processes. The research has been supported financially by a number of Australian-based mineral companies, by Australian international aid agencies, and by appropriation funds from CSIRO, and was conducted in collaboration with researchers from Australia, Indonesia, Portugal, New Zealand, United States of America, South Korea, and the host nations. Building upon earlier successes in the 1986-1997 PACLARK-PACMANUS programs in the Woodlark and Manus Basins of PNG, we have sought to examine a wider range of geological settings in which ancient orebodies are inferred to have formed, including both volcanic and sediment-hosted environments. We have now visited volcanic arcs, fore-arc and triple-junction related submarine volcanoes, and back arc basins associated with convergent plate margins in the SW Pacific and SE Asia, as well as conceptual Mississippi-Valley-type targets associated with warm seeps at passive margins in the Great Australian Bight (see Figure 1). Surveys ranged from northern Sulawesi via far western Bismarck volcanic arc near PNG-Indonesia border, through the eastern Manus Basin and the Tabar-Lihir-Tanga-Feni chain in PNG, the western Solomon Islands festoon, the San Cristobal arc, parts of the Vitiaz arc, to the northern and southern New Hebrides arc in the Solomons and Vanuatu.

Jan 1, 2002

By Sven Petersen, Berit Lehrmann, Bramley J. Murton, Paul A. J. Lusty

"INTRODUCTIONToday’s metal mining focusses on land based ore deposits which only consider one third of the Earth’s surface. Through an increasing global demand of strategic metals used in the electronic and green industry (Zepf et al. 2014), ‘uneconomic’ sites of lower grade in more technical challenging grounds such as greater depth and/or more remote areas are developed by the mining industry often resulting in higher environmental impact. However, considering the steady growth of the Earth population a shortage of certain metals may occur (Krausmann et al. 2009). In 2010, the United Nations allowed commercial exploration for seafloor massive sulphides (SMS) in international waters with currently six contractor licenses being granted.Although the number of discovered vent sites has steadily increased since the first discovery of hydrothermal venting at the Galapagos Rift in 1977 (Corliss et al. 1979) with more than 600 sites being known today, their economic potential is poorly constrained. So far Nautilus Minerals Inc., a Canadian mining company, is the only company having conducted a NI 43-101 resource estimate for the Solwara site, located in the territorial waters of Papua New Guinea. Other studies using bulk geochemical data from 95 sites published in literature do exist (Hannington et al. 2011, Monecke et al. 2016) suggesting a global resource potential for today’s known SMS deposits of 600 million tons with a median grade of 3 wt.-% copper, 9 wt.-% zinc, 2 g/t gold and 100 g/t silver. However, the geochemical data being used originated mainly from easily recoverable, mainly non insitu surface grab-samples and are under current mineral resource classification schemes such as JORC code or NI 43-101 not even accepted for resource estimations. Furthermore surface samples such as high-temperature sulphide chimney and talus material are not representative for the entire deposits with information regards thickness and continuity of individual sulphide layers obtained through drilling being scarce. In addition, it remains unknown what geological processes occur once hydrothermal activity ceases and whether metal tenor becomes enriched, depleted or disappears."

Jan 1, 2017

By Ian J. Graham

Brothers volcano, in the southern Kermadec Arc, is host to two hydrothermal vent fields with very different geology, permeability, vent fluid compositions and mineralogy (see de Ronde et al. and Ditchburn et al. this volume). The NW caldera site contains mineral deposits (sulfide chimneys and crusts), which are either Cu-rich (?magmatic?) or, more commonly, Zn-rich (?epithermal?). The lower cone site, in contrast, is characterized by native sulfur mounds and spires. It has been proposed (see de Ronde et al. this volume) that the metals, especially Cu and possibly also Au, enter the hydrothermal system via injection and degassing of magma and/or the dissolution of metal-rich glasses. They are then transported rapidly upwards via magmatic volatiles along long (c. 2.5 km), narrow (c. 300 m diameter) pipes, consistent with evidence of vent fluids forming at higher than hydrostatic pressures, at relatively shallow depths. The NW caldera and cone sites may represent stages along a continuum between magmatic-hydrothermal and water/rock-dominated end-members. In this context, investigation of melt inclusions in conjunction with other geochemical and petrological research was carried out to ascertain the metal transporting conditions that may have led to mineral deposition and ore formation. Sixteen melt inclusions in plagioclase were analyzed for their chemical compositions from a typical cone dacite sample using LA-ICPMS at the University of Tasmania. The inclusions are typically glassy and commonly occur with other inclusions such as apatite, clinopyroxene, zircon, magnetite, sulfides and/or low-density fluids (Fig. 1). Major (XRF) and trace element (ICPMS) analyses were performed on whole rock samples collected during the 2005 Shinkai 6500 expedition. Haase et al., (2006) has also reported EPMA glass analyses from cone dacites, which may be used for comparison (Table 1). [ ]

Jan 1, 2010

By Natalia Konstantinova, Kira Mizell, James R. Hein, Georgy Cherkashov, Amy Gartman, Pavel Mikhailik

INTRODUCTION Ferromanganese (FeMn) crusts from Mendeleev Ridge, Chukchi Borderland, and Alpha Ridge, in the Amerasia Basin, Arctic Ocean, are similar based on morphology and chemical composition. The crusts are characterized by two- to four-layered stratigraphy. The chemical composition of the Arctic crusts differs significantly from hydrogenetic crusts from the North Pacific Prime Zone (PCZ; Hein et al., 2013), such as a high mean Fe/Mn ratio (2.6 versus 1.3) and low Si/Al ratio (1.8 versus 4.0), with lower Mn, Ca, Ti, P, Ba, Co, Cu, Ni, Pb, Sr, and Zn and higher Si, Al, Mg, As, Li, V, Sc, and Th. Based on Arctic FeMn crust mineralogy, chemical composition, and growth rates, crust formation was dominated by three processes: Precipitation of Fe-Mn (oxyhydr)oxides from ambient ocean water, sorption of metals by the Fe and Mn phases, and fluctuating but large inputs of terrigenous debris (Konstantinova et al., 2017; Hein et al., 2017). The Mn and Fe phases are hydrogenous and reflect bottom ocean-water chemistry and the aluminosilicate phase contains stable detrital minerals such as quartz, feldspars, zircon, monazite, and clay minerals. A precise method of studying the distribution of elements in FeMn crust phases is sequential leaching that dissolves four mineral phases of different stability step-by-step, in the following order: easily leachable phase, mostly bio-calcite; manganese oxides; iron oxyhydroxides; and residual aluminosilicate minerals (Koschinsky and Halbach, 1995). Twelve bulk crusts and crust layer samples obtained from six hydrogenous FeMn crusts were studied. Those crusts were collected during Russian (Arktika 2012) and USA (HLY0805, HLY0905, and HLY1202) research cruises from different parts of the Amerasia Basin (Mendeleev and Alpha Ridges, Chukchi Borderland). Samples were chosen for the sequential leaching experiments based on their morphology, location, and water depth. Hydrogenetic crust (D07-33) from the Tuvalu EEZ, central-west Pacific Ocean, was included in the experiment for comparison. Recovery during the four-step sequential leaching, with respect to the bulk analyses, was between 80% and 120%.

Jan 1, 2018

By Stephan K. Schwank

In mid 1993, Bauer Spezialtiefbau GmbH, based in Germany got the order to develop a sampling tool capable of penetrating all different types of seabed sediments including cobbles and boulders and into bedrock. BHP and their partners Benguela Concessions Ltd., had been convinced by the Bauer Trench Cutter Technology and a large scale test in Germany that this system will be the right one to fulfill their expectations for sampling the diamond area off the coast of Namibia. The technique of the tool is based on Bauer's standard cutter technology, which is widely used for the installation of cut-off and diaphragm walls all around the world. The two counterrotating cutter wheels with 12.1 tom torque each cut an area of 3 x 1.2 m (up to 3 x 3 m are possible). The material mixed with seawater was then pumped to the separation plant on board the vessel Geomaster with a capacity of approximately 700 m3/h. Cutter wheels and mud pump were mounted on a special cutter frame and connected by wire ropes and hydraulic hoses to the vessel. An outer frame with four telescopic legs supported the cutter vertically on the uneven seabed and allowed a controlled penetration of the tool up to 6 m into the diamond bearing ground. The tool required a total power installed of approximately 800 kW. All hoses, the 6-inch mud hoses as well as the hydraulic hoses, were stored and compensated on drums on board suitable for a water depth of up to 200 m. Launch and recovery of the tool was effected through the moon pool of the vessel and the 25 m high, special designed drill tower. The 65? to sampling tool had been commissioned in early 1994 in Cape Town. After intensive testing the sampling programme of more than 4000 holes could be successfully completed by January 1995.

Jan 1, 1998