Search Documents

By R. Hans

Removal of toxic anions from aqueous solution was studied using a Magnetic Ion Exchange (MIEX) resin which is a polyacrylic, strong base resin. Gravity based settling is made more efficient due to the magnetic nature of the resin which is advantageous over conventional ion exchange resins. In addition, the magnetic microspheres of MIEX have larger surface area in comparison to conventional ion exchange resins. Over the years MIEX has been successfully used and has gained significant popularity for efficiently removing dissolved organic matter from wastewater and groundwater. In the present study the efficiency of the MIEX resin was tested for the removal of chromium(VI), molybdenium(VI), vanadium(V) and arsenic(V) anions. Effects of pH (2-10) and temperature (25oC-55oC) were examined. In general, low solution pH values were favorable for anion uptake by MIEX. Except for chromium(VI), the metal ion uptake was significantly increased by the increase in solution temperature. The adsorption data were analysed on the basis of chemical speciation and heterogeneous kinetic models.

Jan 1, 2014

By C. Guo, R. J. Chalaturnyk, M. MacKinnon, J. D. Scott

The Mildred Lake Settling Basin (MLSB) is the largest disposal site for mature fine tailings (MFT) at the Syncrude Canada Ltd. oil sands plant. Over the past years (since 1996), there has been a marked change in the densification behaviour of MFT in the MLSB. Methane-producing microorganisms, known as methanogens, have become very active, and large amounts of biogas (mainly methane) have been produced. Continued field monitoring of the MLSB has provided convincing evidence of the rapid densification process (rapid water drainage from the tailings) at the area with intense microbial activity. This rapid densification has caused pumping challenges in the transfer of fine tailings from the Mildred Lake Settling Basin for the creation of composite tailings. It may also have potential positive effects in accelerating the reclamation of the oil sands fine tailings. A field and laboratory research program was carried out to study the mechanism leading to the rapid densification phenomenon. A review and discussion of the research program is given and some results from the field investigations and small-scale column tests are presented in this paper.

Jan 1, 2007

By C. Cutts, K. Wheatley

The Dragon Lake Zone (uranium prospect) comprises a N160º trending vein that is approximately 110 m long, up to 5 m wide and from 1 to 40 m high. The zone is mostly within altered sandstone of the Fair Point Formation, the basal unit of the Paleoproterozoic Athabasca Group, but it also extends downward (up to 3.5 m) into basement rocks that occupy the northerly trending Maybelle River Shear Zone (MRSZ). This subvertical shear zone separates graphitic paragneiss and weakly deformed granitoid rocks to the east from non-graphitic paragneiss and foliated granitoid rocks to the west. The Dragon Lake Zone cuts across both the MRSZ and N060º-N070º-trending cross-faults that offset the shear zone but not the mineralized vein, which contains values up to 54.5% U over 50 cm core length. Strong chloritization occurs in graphitic paragneiss and sandstone adjacent to mineralization. Silica was depleted from the basement rocks and redeposited at the borders of the 5-15-m-wide alteration zone, as well as within overlying sandstone of the Manitou Falls Formation. There are minimal alteration effects in the overlying Lazenby Lake Formation. Geochemistry shows that the alteration zone in the Fair Point Formation is highly anomalous in metals, most notably in Ni, As, U, Pb, Co, and B. Clay within this zone is illitic and Fe-rich chlorite is also present. Brittle deformation is not as widespread or as well developed in the Fair Point Formation as it is in the overlying Manitou Falls Formation, which is extensively brecciated and contains some anomalous metal values.

Jan 1, 2013

By R. F. Favreau, L. C. Lang

"In modern blasting technology blasts are designed and analysed on an energy-mass-time relationship. The energy of the explosive is derived by computer analysis and the work potential of the available energy is expressed in numerical values. The mass involved in the blast is determined by the geometry of the blast and by the rock density. Time is also a relevant parameter, because time is required to complete the three basic stages of the breakage process.For successful application of the blasting parameters the basic mechanism of the breakage process must be understood.The physical-mechanical properties of the rock, local structural geology and the thermodynamic properties of the explosives can be brought together to create a computer model of a blast with which it is possible to predict separately the results of each parameter and to express the predicted degree of change in any parameter by actual numbers.A long-range project has started to create a ""bank"" of rock properties for as many Canadian and foreign mines as possible. A computer model has been successfully applied to predicting the effect of varying the ratio of spacing to burden at constant rock volume and significantly improved results are achieved, as the S/B ratio is increased up to about 2 to 2.5.High-speed photography has been applied to determine the time that has elapsed between zero time and the beginning of movement of the mass. The results assist in determining minimum and optimum delay time required for multiple-row blasting.The approach as described in the paper is now well proven and is clearly superior to previous methods based on powder factors and human assessment."

Jan 1, 1972

By D. Mas Ivars, K. Suzuki, J. A. Vallejos

"A comprehensive geotechnical characterization has been undertaken at the El Teniente mine to describe and determine the rock mass behaviour strength properties of the primary copper ore. The Synthetic Rock Mass (SRM) modelling approach is used to simulate the mechanical behaviour of this heavily and unfractured rock mass. The micro-parameters of the model have been calibrated against mechanical properties and scaling laws for intact rock and veins, in order to represent virtual samples of four different geotechnical units. Results can be used to predict the rock mass scale effects, anisotropy, and brittleness properties that cannot be obtained using empirical methods.INTRODUCTIONThe primary copper ore at the El Teniente mine is described as very competent and massive, given that it exhibits a brittle behaviour (Rojas, Cavieres, Dunlop, & Gaete, 2000). This description is coherent with the geological description of the rock mass, which does not have discontinuities match as the definition provided by International Society of Rock Mechanics (ISRM, 1981). Only faults can be classified as discontinuities, but they are widely spaced. The primary copper ore has a high frequency of veins, where the cooper mineralization is hosted, these vein network structures are known as stockwork. Soft veins containing weak minerals as infill (chalcopyrite and anhydrite) control the disassembling of the rock mass during caving (Brzovic & Villaescusa, 2007).Presently, there are mainly two traditional methods used to estimate the strength of the rock mass: 1) determination of the strength envelope of the rock mass using scaling parameters from laboratory tests and 2) using numerical modelling based on back analysis of previous experiences of failure observed and measured in mining or civil excavations. The primary copper ore of El Teniente mine has no fractures; therefore, it is difficult to determine a rating that would enable to scale laboratory data, such as, RMR (Laubscher, 1977) or GSI (Hoek, 1994). This is the reason why the first option is not valid unless the entry data is manipulated or adjusted in order to obtain reasonable results. The second option requires, in general, a good characterization of a previous failure event in the rock mass, which is not always available. In recent years, new techniques of numerical modeling have been developed (PFC3D, ELFEN, Abaqus). Those methodologies are the third way to estimate the strength of the rock mass, but they are still in development. Particularly, the concept of SRM developed by Itasca is implemented in this study (Pierce, Mas Ivars, Cundall, & Potyondy, 2007; Mas Ivars et al., 2011), aiming to capture the real behaviour of the rock mass."

Jan 1, 2015

By Dan Currie, Tom Lamb, J. Coady Marsh, Gary Landry

"This paper describes the Cape Breton Development Corporation's experience with the Lovat M-300 tunnel-boring machine at the Donkin-Morien Mine. Between January 3 and December 21, 1984, the 7.6 m (25 It) diameter TBM advanced 3350 m (10 990 ft) . The authors will describe experiences with the machine and highlight the implications of tunnelling machines to underground coal mine development in Canada. IntroductionThe Cape Breton Development Corporation (CBDC) has recently completed the drivage of a 7.6 m (25 ft) diameter tunnel, 3.5 km (2.2 miles) in length , to access the Harbour Coal Seam at the Donkin-Morien Project. The tunnel was successfully driven with the first Canadian rock tunnel-boring machine (RTBM or TBM), designed and built by Lovat Tunnel Equipment, Inc. The initial mine development consists of the drivage of two tunnels to the first major coal seam. Future plans are proposed for the development of a 4 million tonne-per-year mine (Marsh et al., 1983, Gillman, 1982), which will require the drivage of a further two tunnels and could access up to four coal seams. The tunnel cross-sectional areas were designed to provide sufficient ventilation area and access for a production of 4 million tonnes per year."

Jan 1, 1986

By J. A. Bos, Z. Dai, P. Quinn, A. Lee

A flowsheet is being developed for processing Thompson ultramafic low-grade nickel ores. This type of ore is characterized by high content of serpentinized magnesium silicates which generate slimes during comminution. Flotation of this type of ore proves difficult due to problems associated with the slimes. The flowsheet, based on extensive laboratory and miniplant flotation tests, consists of two key components: desliming by hydrocyclones prior to flotation and using soda ash for pH control in flotation. Satisfactory metallurgical results have consistently been achieved in laboratory full circuit simulation and miniplant tests.

Jan 1, 2009

By G. Rong, W. Du

Stability of some potential unstable blocks in the left bank slope of Baihetan hydropower station is evaluated in this paper using the three-dimensional (3D) limit equilibrium method. The Baihetan hydropower station is in the downstream of Jinshajiang River, China. The geological condition in the river valley is complex, and many large discontinuities are detected in the slope of the two banks. As a result, much attention should be paid to the stability of the slope in the feasibility study stage. Because the left bank slope is an oblique consequent one, we mainly focus on the slope stability analysis in the left bank. Comprehensive geological exploration is conducted in the studied area and the detected discontinuities are well researched. By building a 3D geological model of the left bank slope, three potential unstable blocks which are close to the dam site are detected. An irregular wedge analysis method is then used to calculate safety factors of the three blocks under three conditions, which are natural condition, rainfall condition, and seismic condition, respectively. It is found that the safety factors of the block 1# and the block 2# are quite low when compared to the suggested values. Extra care must be exercised when excavating the slope near the block 1# and the block 2#. A preliminary reinforcement is also suggested.

Jan 1, 2015

By J. R. Porter, C. Panaou

"A significant effort is expended on preparation of the capital estimate for feasibility studies. The development of the operating cost estimate is usually allocated a significantly smaller budget and less emphasis is placed on ensuring the accuracy of the operating cost. This paper presents a comparison of capital and operating costs of hydrometallurgy processing plants in order to demonstrate the importance that variations in operating costs have on the overall life-of-mine costs. The analysis is supported by a case study on the operating costs of a water treatment plant at an existing Australian hydrometallurgy facility at the feasibility design level. INTRODUCTIONDetermination of the economic validity of a minerals processing project is a critical outcome of a feasibility study. In many cases, the financial results of the feasibility study will determine if the project should proceed to execution. Ensuring that these results are reliable and built upon sound engineering practices allows companies to make informed decisions on resource opportunities and the selected technology.The methodology for developing a capital cost estimate at the feasibility level is well established. Specialist engineering estimators use budget quotations, first principle estimation and rules-of-thumb to develop an estimate with an accuracy of typically -10% to +15%. Cost reporting software packages are used to methodically build up the estimate from design information supplied by the engineering disciplines. Risk analysis and capital expense workshops are carried out to identify potential deficiencies in the estimate. It is widely recognized that in order to successfully produce a feasibility level capital estimate with an appropriate level of accuracy, a rigorous development process is necessary.The development of the operating cost estimate is typically less rigorous than the capital cost estimate. The operating cost is normally derived by the process engineering discipline and rarely are specialist estimators used to support the development. The allocated budget for producing an operating cost is usually smaller and less emphasis is placed on ensuring the accuracy and contingency reflect the most likely operating cost scenario."

Jan 1, 2012

By L. C. So, S. Faucher, S. Mostaghel, A. Triwahyuono, D. Sauter, S. -Y. Oh, S. K. Lee, K. Aswin

"Molten hauling and water granulation are the commonly used slag treatment methods in the production of nickel. Water is present in these processes either to accelerate cooling of the dumped slag or in the granulation itself which creates an inherent safety risk of explosions. Even good design and operation are not sufficient to prevent explosions or injuries from occurring. Several dry methods to treat slags have been intensely studied. However, most of these technologies have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple Dry Atomization process, which eliminates water and allows for heat recovery. As part of the development towards other sectors, laboratory-scale and pilot-scale trials have been completed in a number of base metals and PGM facilities. Recently, Dry Atomization of a nickel laterite slag was successfully demonstrated at the laboratory-scale. The current paper introduces the technology and reports the test results obtained from atomization of the nickel slag.INTRODUCTION The processing of nickel laterites produces vast amounts of slag with over 90% of the feed to the furnace reporting as slag. Slag handing is therefore of critical importance to a laterite smelter. Traditionally there are two ways in which the slag is handled (1) Molten hauling, dumping, cooling and quarrying (2) Water granulation, dewatering, stockpiling. There are inherent disadvantages of both methods that will be outlined in this paper. An alternate route of Dry Atomization provides distinct advantages over the two conventional routes that are of particular interest to the nickel producer such as elimination of molten hauling, dumping and quarrying, elimination of water and improved safety. There is also the potential to convert the slag, which is typically regarded as a waste product, into a value added product and the continuous nature of slag tapping makes it amenable to heat recovery. Hatch has recently conducted laboratory-scale test work on laterite slag to demonstrate its viability for Dry Atomization. Results of this work are presented."

Jan 1, 2017

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By M. J. Collins, B. Parekh, A. Hasenbank, B. Hewitt

Newcrest Mining Limited, originally as Lihir Gold, has operated a pressure oxidation plant for the recovery of gold from refractory ore since 1997. The mine and gold plant are located on Lihir Island in Papua New Guinea. Design of the original pressure oxidation circuit was based on the results of pilot plant tests conducted by Sherritt in Fort Saskatchewan. Following a decision to expand the plant in 2008, Lihir Gold contracted Sherritt to design a new autoclave. The design exercise utilized the original pilot plant test results, commercial process results at Lihir, and an understanding of advances in autoclave technology since the original plant was built. The new Lihir autoclave will be the largest horizontal, multiple-compartment autoclave in the world. The design process for the pressure oxidation expansion is described in this paper.

Jan 1, 2011

By B. K. Gorain

"The Air-Metabisulfite (AMBS) process has been developed to treat complex copper, molybdenum and precious metals (gold, silver) bearing ores using brackish and sea water. This process was able to produce significantly better copper concentrate grades and higher recovery than possible using conventional lime and/or cyanide based processes for certain complex ores with high sulphide gangue minerals. The AMBS technology in now used commercially following a rigorous evaluation process emanating from laboratory curiosity to plant applications. In addition, many projects have embraced this technology at a feasibility level involving various complex ore bodies.This paper presents a summary of the findings from testing the AMBS technology on various ores types. Experiences gained from this successful development from bench to piloting and then to plant applications are also presented in this paper.INTRODUCTIONProcessing of sulphide copper, molybdenum and precious metal ores typically involves flotation of copper bearing minerals while depressing non-sulphide and other non-copper sulphide minerals such as pyrite, pyrrhotite and sometimes arsenopyrite. Though in many precious metal ores, the values are in these sulphide minerals as well. The conventional method employed in the industry to produce a saleable copper concentrate requires depression of these non-copper sulphide minerals using an alkaline pH above 9.5, though 10.5 to 11.5 is more common. Alkalinity is controlled by the addition of a pH modifier. Lime is normally employed as a pH modifier due to its relatively low cost; however, the costs associated with adding lime can be significant and the effectiveness of lime as a depressant could be drastically reduced when the process water supplied to the flotation circuit contains high level of dissolved salts. In some cases, a small amount of cyanide is used along with lime to depress non-copper sulphide minerals especially when its proportion to copper sulphide minerals in the ore is higher than three."

Jan 1, 2016

By George E. Cole

Introduction In view of the fact that, during the past year, two Manitoba mines-Flin Fion and Sherritt Gordon-have entered the list of producers and have materially increased that Province's contribution to the metal production of the Dominion, it would seem appropriate at this time to review the progress of the industry in the Province, with particular reference to the out-standing metal-mining developments of the past decade. That these two mines have been able to continue their operations in spite of the low prices of copper and zinc adds a touch of brightness to the industrial life of the Province. Depression in metal prices is not encouraging to the mining industry, but it does stimulate efficiency in methods and costs of production. As two thriving towns have grown around the two mines, the will of the management to carry-on is of great consequence to Manitoba, this year so hard hit by the .agricultural depression. And, much as it is a pleasant feature in the mining situation that these mines have been able to continue operations, nevertheless it must be noted, in reviewing the mining developments of the past few years in Manitoba, that the Province was fortunate enough to profit by good times, in that an industry was established which gives evidence of permanency. In the metallic field, the section of Manitoba that first received attention from prospectors was the boundary district, west of the Lake of the Woods. Several claims were staked here at the time of the gold boom in the neighbouring Ontario area. But the first real interest in metalliferous deposits dates from the discovery of gold in March, 1911, in quartz veins on the shores of Rice lake, some twenty miles east of lake Winnipeg. Systematic and organized prospecting of the pre-Cambrian areas of the Province may be said to have commenced with that discovery. The first gold discovery in northern Manitoba was made at Wekusko (Herb) lake in 1914. This was followed by the discovery of the Flin Flan and Mandy copper ore-bodies in 1915 on Flin Fion and Schist lakes, respectively.

Jan 1, 1932

By Belinda Campbell

Tools for Consistency 1. GIS Web Site 2. National Project Management System 3. Site Grouping Approach (721 PIDs) 4. Mine Reclamation Standing Offer Agreements ?Contracting tool 5. Remedial Objectives Guidance Document Background ?CBDC (now ECBC) is a Federal Crown Corporation and falls under federal jurisdiction. ?When it stopped mining coal, CBDC turned its attention to cleaning up and closing out its industrial sites. ?Public Works and Government Services Canada is common service provider to the GoC. ?Expertise in environmental, engineering, IT, project management, communications, GIS, real property management.

May 1, 2011

By T. Gonzales, S. Thakurdin

The conducting of risk reviews is an essential activity in ensuring safe operating conditions, both during project design phases and for existing facilities. The following paper presents a structured approach to the conducting of risk reviews for existing operations, including descriptions of supporting documentation and guidelines for on-site review activities. The conducting of regular site risk reviews and safety audits is crucial in ensuring the continued safe operation of existing facilities, particularly in the copper industry where numerous processes and unit operations can present catastrophic risks, both in terms of loss of life and financial liability. The structured approach presented aims to provide a logical and comprehensive analysis of risks to align safety-related facilities and procedures with current industry best practice and ensure consistency across multiple client operations. INTRODUCTION The production of copper, whether by pyrometallurgical or hydrometallurgical process routes, carries significant inherent safety risks. Production volumes are relatively large, often requiring complex processing routes, multiple production trains and a variety of supporting ancillary facilities. Furthermore, considering the relatively large size of ore reserves, copper production plants can have operational lives well beyond the typical design duration of 20 years. In this context, the conducting of regular risk reviews is essential in ensuring safe operating conditions and aligning facilities with current industry best practices. Risk reviews and safety audits can take various forms and have various areas of focus. The methodologies and approaches described below relate specifically to catastrophic risks, defined broadly as risks that carry the potential for multiple fatalities and significant financial losses. Focus is given to existing facilities and does not consider the risk-related activities such as hazard and operability (HAZOP) studies conducted during plant design. The structured approach presented aims to provide a guide for effective site- based audits and a logical analysis of risks identified. RISK CLASSIFICATION Table 1 provides a typical summary of the classification of risk types and the associated consequence categories and descriptions. It illustrates the descriptions of a catastrophic risk in terms of the broad categories of Health & Safety, Environment, Financial, Image & Reputation and Legal & Compliance. In terms of the Financial category, numeric costs ranges are often prescribed depending on the financial characteristics of the specific operation and the associated parent company.

Jan 1, 2019

By E. Ghali, W. Zhang, G. Gabra, N. Sorour, G. Houlachi

The additives polyacrylamide, 1-Butyl-3-methylimidazolium chloride, Tetra-butylammonium bromide, Benzalkonium chloride and chitin are evaluated during zinc electrolysis from synthetic acidic sulphate electrolyte containing Mn2+ ions, in absence and in presence of 0.0055 mg dm-3 of Sb3+ ions. Galvanostatic polarization tests for 2 hours at 50 mA cm-2 and 38oC were carried out to determine the cathodic and anodic potentials, and current efficiency of the deposited zinc. Potentiodynamic polarization and cyclic voltammetry tests have also been employed to study the electrochemical behavior of each additive on the zinc deposit on aluminum electrode. Results showed that, in presence of Sb3+, adding 1 to 3 mg of 1-Butyl-3-methylimidazolium chloride increases the cell voltage by ˜0-7 mV. Current efficiency is increased by ˜4.90-6.40%; power consumption is reduced by ˜147-173 kWh t-1 by adding 1-3 mg, respectively. However, in absence of Sb3+, cell voltage is decreased by ˜7-28 mV, current efficiency is increased by ˜0.70-1.50%; power consumption is reduced by ˜41-47 kWh t-1 by adding 1-3 mg. The effect of the other additives on cell voltage, current efficiency, lead content and morphology of zinc deposit has also been examined. Surface morphology and crystallographic orientation of the deposit was studied using scanning electron microscopic (SEM) and X-ray diffraction (XRD), respectively. The content of lead in the deposit has also been measured using inductively coupled plasma spectroscopy (ICP).

Jan 1, 2015

By Taisuke Sakakibara, Shinya Suzuki, Tatsuya Kato, Chiharu Tokoro, Kenichi Muto

Surface complexation using a diffuse layer model were constructed for arsenic (As(V)), zinc (Zn(II)) and silicate (Si(IV)) for aluminum hydroxide in the co-precipitation process. From experimental investigations using isotherms, zeta potential measurement and XRD analysis, it was confirmed that co-precipitation involved not only surface complexation but also surface precipitation. However, surface complexation was major mechanism for As(V), Zn(II) and Si(IV) removal under the target removal level of the Japanese effluent standard. In surface complexation modeling, exchange capacity of aluminum hydroxide was determined from specific surface area obtained from experimental measurement and site density obtained from reference. Surface complexation coefficients were determined by fitting the removal property and sorption isotherm obtained from co-precipitation experiments. These parameters were in agreement with the numerical parameters found by Karamalidis and Dzombak (2010) who reported a database of adsorption equilibrium constants for gibbsite. The surface complexation models constructed in this study were applied to neutralization process of an actual AMD treatment. Our model could successfully represent the pH edges for As(V), Zn(II) and Si(IV) in the neutralization of AMD.

Jan 1, 2015

By J. M. Paxton, R. L. Roscoe, G. A. McCreary, W. W. Muir, T. J. Drown, D. A. Barr, T. W. Law

"This paper reviews the complete cycle of a small mining operation in a remote section of northern British Columbia, including discovery, exploration, development and production. The discovery of high-grade epithermal gold-silver mineralization occurred in 1969 following a regional geochemical reconnaissance program designed to search for porphyry copper mineralization in the Cassiar-Omineca Mountains. Exploration and development from 1971 to 1979 included geological, geochemical and geophysical surveys; trenching, almost 30 000 feet of surface and underground drilling in about 100 holes and cross-cutting, drifting and raising on the principal goldsilver- bearing vein. This led to the delineation of 100000 tons at an estimated grade of0.9 oz gold per ton and 18 oz silver per [on to an average depth of 120 feet below surface. of a 100-ton per day mining operation employing about 50 personnel with all supporting infrastructure transported to the site by a Hercules aircraft. The operation was subsequently supported by its own Twin Otter aircraft with periodic Hercules campaigns supplying major items including fuel.The mining operation included both open-pit and cut-and-fill methods. The milling operation employed conventional cyanide leach process with cyanide destruction initially by alkali chlorination and subsequently by the Inco SOl /Air process.The fly-in operation, initially structured on a 21-day-in and 7-day-out basis was modified to al-t-day-in and Z-day-out basis with no loss in efficiency and with a significant increase in employee satisfaction. The operation, which earned the B.C. Small Mines Safety A ward in two consecutive years in its Ll-month operating history, emphasized safety and process hazard awareness. Wildlife studies in the environmentally sensitive mine area also showed that industry and wildlife can coexist in harmony.Most importantly, the paper compares the feasibility assumptions with actual operating experience."

Jan 1, 1986

By W. E. Newton

THE following notes are offered primarily to show that industrial minerals or their products have a much more important place in the metallurgical industry than is perhaps generally realized, and with the hope also that some statement by the metallurgical consumer of the relative merits of various materials for particular requirements or services will l;>e of value to the industrial mineral producer. These notes are not in any way presented as complete. Also, some of the statements made may be debatable. The grouping adopted is as follows: (1) Refractories; (2) Fluxes; (3) Construction materials; and ( 4) Miscellaneous applications. Fuels are not dealt with in the present paper. REFRACTORIES GENERAL: Refractories are materials which will withstand high temperatures with-out melting or becoming markedly soft or pasty. While their primary function is to withstand heat, they are usually called upon to resist one or more of the following destructive influences: abrasion, pressure, corrosion by slags or fluxes, and rapid changes in temperature. Refractory materials may be conveniently divided into three classes: (1) Acid refractories-consisting of silica, or containing silica as their chief constituent. They combine more or less readily with metallic oxides, forming silicates, and are hence termed 'acid'. The most important of these are quartz, quartzite, siliceous sand, tripoli, Dinas rock, and ganister. Most fire-clays, although generally considered neutral sub-stances, contain relatively small amounts of free silica and are, to that extent, acid. (2) Neutral refractories-the term is merely relative in most cases, since, at high temperature, many of the refractories that are classed as neutral will react chemically with a strong base, functioning as a weak acid; or, conversely, with a strong acid, functioning as a weak base. Chrome and graphite are the most nearly neutral of all the commonly used refractory materials.

Jan 1, 1936