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By Holger Cordes

X-ray diffraction has long been used for qualitative and quantitative mineral analysis but Rietveld data analysis is still an under utilized method for mineral exploration and processing applications. In this full-profile approach the structural parameters of each mineral phase, together with experimental parameters, are refined by least-squares methods to minimize the difference between observed and calculated diffraction patterns. The result is a standard-less, quantitative analysis of the mineral abundance in the sample that is more accurate and considerably faster compared to traditional methods. The TOPAS software package combines a user-friendly interface with a unique approach to resolve overlapping peaks. Automated analysis options are also available and significantly reduce analysis time for routine samples. Several examples on a wide range of naturally occurring rock types are shown that illustrate the capabilities and limitations of the method. The examples include several options for the quantification of amorphous constituents like volcanic glasses.

Jan 1, 2006

By N. E. Idenyi

The effects of compositions and firing temperatures on the physico-mechanical properties of blended Nsu fireclay and Nkalaha redbrick clay have been investigated. The clay samples were compounded according to the following ratios: 10:90, 20:80, 30:70, 40:60 50:50, 60:40, 70:30, 80:20 and 90:10 in the order Nsu: Nkalaha respectively, and test samples made and fired at 9000C, 10000C 11000C and 12000C. The properties tested for were the modulus of rupture, porosity, shrinkage, apparent density, water absorption and bulk density. From the results obtained, it is inferred that the blends have a maximum service temperature of 11000C, with the 30: 70 blend presenting the best characteristics. A conclusion is drawn to the effect that the blend could be adapted for the production of ceramic earthenware, electrical porcelain pin insulators, cement manufacture and for refractory linings where temperature requirements are less severe.

Jan 1, 2006

By Muammer Kaya

The purpose of this review is to raise awareness about e-waste problem in the World. Whether generated at our home or our office, e-waste is most rapidly growing waste problem in the world. Even though there are conventional disposal methods (such as landfill and incineration) for e-waste, these methods have both economic and environmental disadvantages; recycling is a new waste management option which diverts end-of-life (EOL) electrical and electronic equipment (EEE) from landfill and incineration [1, 2]. Successful diversion strategy must be based on economic sustainability, technical feasibility and social support [3]. Recycling infrastructure includes transportation, collection, recovery and resale establishments. The first part of this paper describes the e-waste facts, how big is the e-waste problem and existing recycling programmes and collecting methods in the USA and EU; second part, describes various methods available to recover valuable materials (glass, plastic and metals (Pb, Cu, Al, Steel, Ni, Au, Pd, Cu etc)) in e-waste for a safe and environmental friendly disposal

Jan 1, 2009

By Vincent Menard

The purpose of the present work is to demonstrate the removal of manganese from a neutral leach zinc-rich solution ([Zn] =150 g/L) at 80°C by oxidative precipitation using a gas mixture of sulphur dioxide (SO2) and oxygen (O2). In order to determine the optimum conditions for manganese removal, several bench-scale semi-batch experiments were performed, where the effects of ORP and gas mixing were investigated. These tests showed that SO2/O2 is a fast and effective oxidant for removing manganese down to ppm level as long as the appropriate ORP is attained/maintained and gas transfer kinetics are optimized.

Jan 1, 2006

By Eun-young Kim

Electrogenerated chlorine leaching of waste printed circuit boards was investigated in hydrochloric acid solutions. The pulverized printed circuit board contained about 37.6% of metal component, in which copper was about 83.6%. The leaching rate of copper was greatly affected by current density and agitation speed. The leaching of copper up to 98% was achieved at 20 mA/cm2, 50?, 180 minutes, and 600 rpm in 1M HCl solution. Increasing agitation and lowering current density enhanced utilization efficiency of electrogenerated chlorine. Leaching of copper was suppressed at initial stage, while the minor metal elements, such as aluminum, lead, and tin, were dominantly leached out.

Jan 1, 2006

By Esher Hsu

In Taiwan, around 8,000 tons of batteries are consumed per year but only 17% of which were collected and transported to oversea for recovery. The dumping used batteries have become a potential environment problem. How to increase the collection efficiency of used batteries is an important issue for EPA in Taiwan. Besides, some treatment plants are on process to get permission for recovering used batteries. The objective of this study is to estimate the recycling cost of spent consumer battery and explore the feasibility of recovering used consumer batteries in Taiwan based upon the principle of cost-efficiency. The recycling cost including collection cost and recovery is estimated based on a survey. Results would provide some suggestions to Taiwan EPA regarding feasibility of recovering used batteries in Taiwan.

Jan 1, 2006

By Jian Yang

The mechanism of resulfurization in the desulfurization process with magnesium vapor produced in situ by aluminothermic reduction of magnesium oxide was clarified in the present work. The influences of various operating parameters on the resulfurization were studied and the methods that could prevent resulfurization were proposed. There are two kinds of mechanisms of resulfurization in the desulfurization process with magnesium. One is decomposition of the desulfurization product of MgS under the inert atmosphere. The other is oxidation of MgS under the oxidative atmosphere. Under the present experimental conditions, lowering operating temperature and oxygen partial pressure in the atmosphere could effectively prevent the resulfurization. Adding CaO onto the melt surface was an effective method for preventing the resulfurization due to transformation of the desulfurization product of MgS into the more stable compound of CaS. Since addition of the activated charcoal powders greatly decreased the transfer rate of oxygen in the atmosphere to the melt surface, it also reduced the resulfurization remarkably.

Jan 1, 2006

By He De-wen

The municipal solid waste is a by-product of the daily life of urban residents. The quantity and ingredients of municipal solid waste has exceeded the current management and disposal ability, which has done a great harm to municipal environment and sanitation quality and threatened people?s health. On the basic of analysis on the amounts and main elements of municipal solid waste of Changsha City, the sanitation landfill, incineration, composting, reclamation and utilization technology of household waste were compared specifically in this paper. Based on the concrete conditions of Changsha City, the paper has proposed a disposal proposal combined with reclamation and landfill of municipal solid waste of Changsha City, and the environmental benefit, social benefit and economical benefit of the prepared processing routes were also analyzed in the paper.

Jan 1, 2009

By Tang Chaoho

Laboratory research on the reducing and matte smelting of Jamesonite concentrate has been carried out. The influence of the process conditions such as the smelting temperature, the amount of pyrite cinder (the agent of fixed sulfur) and the amount of additives on the smelting process have been studied. Under the optimum condition the direct recovery ratios of antimony and lead are 83.26% and 68.50% respectively. The ratio of fixed sulfur is 98.97% but more than 15% lead and 30% silver remained in the ferrous matte. The key problem to be solved of this new process is how economical and effective is the recovery of silver and lead in ferrous matte.

Jan 1, 2003

By Tang Chaoho

Laboratory research on the reducing and matte smelting of Jamesonite concentrate has been carried out. The influence of the process conditions such as the smelting temperature, the amount of pyrite cinder (the agent of fixed sulfur) and the amount of additives on the smelting process have been studied. Under the optimum condition the direct recovery ratios of antimony and lead are 83.26% and 68.50% respectively. The ratio of fixed sulfur is 98.97% but more than 15% lead and 30% silver remained in the ferrous matte. The key problem to be solved of this new process is how economical and effective is the recovery of silver and lead in ferrous matte.

Jan 1, 2003

By Zhigang Liang

A carbon free precast block was prepared by using high-alumina fused corundum as aggregate and fused magnesia, and ultra-fine Al2O3 and ultra-fine SiO2 powders as matrix materials. A small linear expansion for the precast block was achieved through spinel formation from the reaction of MgO with Al2O3. The precast block showed a lower apparent porosity, higher hot modulus of rupture and better slag corrosion resistance compared to the traditional Al2O3-MgO-C brick. Moreover, the practical application of the precast block to the ladle lining proved it to possess a better thermal insulation which could effectively prevent the temperature drop of molten steel during the refining process. It can be predicted that the carbon free precast block could possibly be accepted as a new type of ladle lining material for the production of low-carbon and ultra-low-carbon steel.

Jan 1, 2009

By Javier Enrique Basurco Cayllahua

In this work, a gram-positive bacteria was used as biosorbent to elucidate the aluminum load capacity under different conditions related to metallurgical and chemical plants. The sorption data followed the Langmuir, Freundlich, Dubinin-Radushkevich isotherms. In order to determine the best isotherm fit, three error analysis methods were used to assess the data: correlation coefficient (R2), residual root mean square error (RMSE) and Chi-square test. The error analysis established that the Dubinin-Radushkevich model fits better the aluminum biosorption data. The maximum sorption capacity was found to be 41.59 mg.g-1. The maximum removal of aluminum was 95% at pH around 5. The experimental kinetics data was evaluated considering two models (pseudo-second order and pseudo-first order). This study indicated that the R. opacus is an environmental friendly biosorbent.

Jan 1, 2009

By Peng Lv, Shiqian Liu, Bin Xu, Qian Li, Yongbin Yang, Tao Jiang

The treatment process of a low-grade refractory gold ore containing sulfide minerals and carbonaceous matters was studied in this work. The gold extraction of this ore by all-sliming cyanidation was only 11.75%. Hence, a pretreatment was necessary. In this paper, a flotation-preoxidation-cyanide leaching process was developed. The concentrate from the flotation procedure was processed using different preoxidation methods. A concentrate containing 34.08g/t of gold with the gold recovery ratio of 81.20% was obtained by flotation. After roasting, microwave heating or alkaline pressure oxidation, the gold cyanidation ratio reached 82.37%, 81.26% and 71.09% respectively. Roasting was an effective, reliable and mature technique to oxidize sulfide minerals and carbonaceous matters. Roasting and microwave heating both produced dangerous environmental pollutants while alkaline pressure oxidation was eco-friendly.

Jan 1, 2015

By He De-wen

Based on the principle of life cycle assessment (LCA), municipal solid waste management (MSWM) was analyzed by life cycle inventory method. According to the system expansion and substitution method, the content and frame of life cycle analysis is summarized and applied to municipal solid waste. On the basic of feasibility research of life cycle analysis on MSWM, the paper put forwards complete and concrete ?three changes? measures under life cycle analysis on MSWM. Some aims of MSWM can be achieved under above conditions of LCA on MSWM: to improve the current system efficiency of MSWM; to enhance the serve quality of MSWM, to increase recycle garbage from MSW; to reduce waste amount and reach minimization and innocuity aim of MSWM; to help the departments of MSWM to get over all difficulties to realize their ideal goals.

Jan 1, 2009

By Jay S. Gunasekera

Since great emphasis is being placed on the manufacturing science and processing science programs in the Department of Defence and other government research agencies and industries; currently, extensive research on computer aided design(CAD)/ computer aided manufacturing (CAM)/ and computer aided engineering (CAE) is being conducted at Ohio University (OU) . OU has invested over a million dollars in CAD/CAM hardware and software. Design and analysis packages like ALPID, NIKE, STREAM, SHEAR, POLY_FLON, RINGROLL have been developed or modified at OUusing finite element method, finite difference techniques or enhanced slab analysis. Packages like ABAQUS, FLUENT, and NASTRAN have been extensively used.

Jan 1, 1990

Lime-enhanced carbothermic reduction may provide an alternative process for treating low grade chalcopyrite concentrates. To date, most research on lime-enhanced reduction has been on pure, synthetic sulfides. In this study, preliminary experiments were carried out on natural chalcopyrite using a thermal analysis system to assess the rate and extent of reaction at several temperatures and identify the major solid and gaseous reaction products. Calculations were performed to establish the thermodynamic limits of the reactions in the temperature range of interest in order to identify the potential conditions for processing chalcopyrite concentrate. The study found that finely ground chalcopyrite can be reduced carbothermically in the presence of lime at moderate temperatures and in a reasonable time to form metallic copper, with the sulphur reporting virtually entirely to calcium sulfide. At temperatures below about 750?770ºC calcium ferrite is the stable form of iron whereas at higher temperatures metallic iron is stable. Further work is required to demonstrate the reaction on a scale to obtain sufficient sample for evaluation of subsequent processing steps to remove the gangue material and iron products from the copper.

Jan 1, 2009

By W. J. Mitchell

During the months of April and May 1992, the Phelps Dodge Hidalgo smelter underwent a major turnaround. This was the third such turnaround in the life of the facility which was commissioned in 1976. During the third furnace campaign, the smelter processed 5.2 million tons of concentrate producing 2.6 billion pounds of anode copper over a 7.5 year period. The critical path on the fifty-nine (59) day turnaround schedule was the reconstruction of the Outokumpo flash furnace which integrated some modifications with standard rebuild practices. Modifications included incorporation of horizontal cooling jackets throughout the furnace settler as well as the installation of castable refractory in the reaction and uptake shafts.

Jan 1, 1993

By Xiaowen Liu

The thermal decomposition of diaspore was investigated by thermogravimetry (TG),differential scanning calorimetry (DSC), X-ray power diffraction(XRD),infrared (IR)spectrain this paper. The thermal decomposition mechanism of diaspore was discussed according to Coat-Redfer equation. It was found that the decomposition of diaspore was carried out at 500?,and the peak temperature was 530?. The electrovalent balance of diaspore was destroyed. The previous crystal structure was changed. a- Al2O3 was obtained after thermal decomposition. The activation energy is 287KJ/mol.

Jan 1, 2006

By Xinli Wang, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng, Byoung-Gon Kim

"The microwave reflection loss (RL) of ferric oxide is studied in the temperature range from 297 to approximately 1400 Kat frequencies of 915 and 2450 MHz. It is shown that the maximum microwave absorption with RL of -38.46 and -35.97 dB can be obtained for ferric oxide having thicknesses of 0.03 and 0.01 m at 915 and 2450 MHz, respectively. The maximum absorption peak with RL below -10 dB is in a 250 K temperature range from 723 to 973 Kat 915 MHz, which shifts to the range between 823 and 1073 K at 2450 MHz. This migration is in good agreement with the variation of the dielectric loss tangent of ferric oxide.IntroductionMicrowave irradiation has distinguishing characteristics such as volumetric and selective heating compared with conventional methods, leading to extremely broad applications in materials heating and processing [1-5].The efficiency of microwave heating was found to be dependent on various factors, such as microwave power [6], frequency [7,8], radiation time [8], applicator geometry [8], sample microwave absorption properties and position as well as dimension [9-11 ], etc. Among these parameters, sample dimension plays an important role but is usually neglected by researchers in microwave processing of materials. In fact, although numerous studies have been directed toward the utilization of microwave energy to assist materials heating and processing, few reports were released on the effect of sample dimension [12,13].This is because all aforementioned factors influencing microwave heating generally exert interactive effects to each other during the heating process, making clarification of the effect of sample dimension difficult. Therefore, it is necessary to propose a parameter or concept for quantifying the effect of absorber dimension on microwave heating, increasing heating efficiency."

Jan 1, 2013

By He De-wen

The influence of wastewater containing benzene from chemical industry by technology combined blow-off with Fenton reagent oxidation was experimentally studied. The present results suggest that the technology combined blow-off with Fenton reagent oxidation can effectively remove benzene pollutant in wastewater. The main factors that influence the removal benzene such as temperature and blowing time and volume, pH and reagent dosage of H2O2 and Fe2+ are studied and the optimal experimental conditions are as follows: time 20min, temperature 40i, air-blowing volume 0.4L/min, pH value 5, and H2O2 and Fe2+ dosage 2mL/L and 200mg/L respectively. Under the above conditions, benzene pollutant can be removed up to 97%. Compared to other removal ways of wastewater containing benzene, the technology combined blow-off with Fenton reagent oxidation is more effective and has the advantage of high speed.

Jan 1, 2009