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By D. B. Dow

The presence of sulphur compounds in petroleum and its products is, generally speaking, undesirable, and the problems involved in removing such compounds are of great importance to the petroleum refiner and to the manufacturer of gasoline. There are several types of these compounds which are dissimilar in physical and chemical characteristics, as evidenced by different objectionable features which they exhibit, and special treatments have been developed to meet conditions existing in various products. This paper deals with the treatment of natural-gas gasoline for the removal of certain sulphur compounds which, if not removed, impart on objectionable odor and in addition badly discolor the product. The presence of this particular type of sulphur compounds is detected by the "doctor" test.* In some instances natural-gas gasoline is purchased on "doctor" test specifications, and the ordinary purchaser, while not buying on "doctor" specifications, is insistent in his demand for a water white product. Gasoline which fails to meet the "doctor" test, if not received by the buyer within a few weeks after time Of manufacture, may be "off color" enough to warrant a deduction from the market price.

Jan 1, 1923

By Robert P. Vinson

This report describes three coal mine ventilation studies by the Bureau of Mines in which sulfur hexafluoride (SF6) was used as a tracer gas. One of these studies was conducted to determine air movement and leakage in a sealed area. Another was run to determine the ventilation efficiency of a bleeder system. Finally, a study was made of air leakage across permanent stoppings of parallel intake airways. These studies proved sulfur hexafluoride to be a useful addition to the equipment commonly used in coal mine ventilation analysis.

Jan 1, 1976

By C. I. Pierce

This report describes and presents results of a phase of a laboratory study conducted at the Morgantown Petroleum Research Laboratory, Federal Bureau of Mines, Morgantown, W. Va., to determine the response of shielded electrodes of different dimensions in thin, noninvaded beds and to stimulate interest in the use of focused-type logging devices in the Appalachian oilfields. A blotter model was used to obtain plots of the potential field in the vicinity of a model shielded electrode. Three plots are presented. The difference in curvature of equipotential lines and the variation in measured resistance values for different blotter-model conditions suggest that the shielded electrode will give resistivities higher than normal when measurements are taken in a thin conductive bed located between resistive beds, and resistivities lower than normal when measurements are taken in a thin resistive bed located between conductive beds.

Jan 1, 1961

By R. Hogg

"Some basic features of the science and technology of particle systems are reviewed in the context of agglomeration processes. Emphasis is placed on the force of interaction among particles and with their environment and on their dependence on particle characteristics and interfacial phenomena. The complex role these forces play in the various stages of agglomerate formation, growth, consolidation and structure development, and their influence on final product properties is discussed.INTRODUCTION Agglomeration is an example of a process where the technology has generally preceded the science. Process development• has very often been by trial-and-error albeit with an eye on some basic principles. Nevertheless there is' a scientific basis to the process and a better understanding of the fundamentals can surely lead to improvements in process design and control.Successful processes for the agglomeration of fine particles depend on proper control of the adhesional forces between particles, to encourage agglomerate formation and growth and to provide adequate mechanical strength in the product. At the same time the rheology of the particulate system can be critical to the rearrangement of particles necessary to permit densification of the agglomerate and the development of an agglomerate structure appropriate to the end-use requirements.AGGLOMERATION SYSTEMSUltimately, the performance, of any agglomeration process depends on the• characteristics of the particles and their environment. The specific effects, however, are often complex and may be very difficult to pinpoint by simple observation of the process. A typical agglomeration process involves a number of concurrent or consecutive steps - adhesion, growth, compaction, etc., - each of which is affected by the characteristics of the system, but not necessarily in the same way. The effect of particle size, say on agglomerate growth may be quite different from its effect on compaction and its optimum value may differ widely from one stage to the other. Obviously there.is a general need for compromise in the design and operation, of agglomeration systems. Furtnermore, an understanding of the details of the process and their complexities can be critical to process optimization and improved product quality control."

Jan 1, 1989

By Joseph Cervik

Gas occurs in coalbeds in an adsorbed and a free gas state, Adsorbed gas is stored in the micropore structure and its transport is governed by Fick's law. The free gas occurs in the. fracture system and flows according to Darcy's law. These two modes of mass transport are interdependent. Production decline curves of coal-gas wells are of the constant percentage decline type and, thus, show no indications of flow characteristics peculiar to coal-gas reservoirs. The effectiveness of surface boreholes as a degasification scheme depends upon both good fracture permeability and a high fracture density. Conventional methods of reservoir engineering analysis are not applicable to coalbeds.

Jan 1, 1969

By William C. Larson

A study was conducted by the Bureau of Mines to provide quarry operators with information regarding (1) the effects of jointing and bedding on rock fragmentation when bench blasting in two small-scale (2.5-ft) limestone benches, and (2) the successful use of inexpensive equipment and field techniques to determine the orientation and spacing of joints and bedding separations within the quarry. Using inexpensive equipment, such as a pocket transit and steel and paper tapes, joint and bedding separations were mapped and their frequencies measured. Results from two small-scale bench blasts in the Stewartville member of the Galena limestone formation showed that when the row of vertical blast-holes was oblique to the vertical joint orientations, the backface expression was outlined by two relatively large triangular protrusions (joint surfaces). In this blast, part of the rock burden was unbroken. When the line of vertical blastholes paralleled a predominant joint set, all of the rock burden was broken and displaced. The thickness of fragments that had been displaced by a blast correlated with the observed bedding thickness in the bench.

Jan 1, 1974

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT's) of the dried coal-additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT's of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988

By Sumner M. Anderson

ATHOUGH scattered signs of increased activity in the mining industry accompanied an incipient improvement in the overall economic situation during the latter months of 1963, production levels for the year as a whole responded to the general 1962-63 business recession with a 4.2 percent decline. The petroleum industry, active since 1907, did not become a dynamic force in the economy until exploration and drilling contracts were concluded with private companies in 1958 and 1959; on November 15, 1963, having virtually achieved self-sufficiency in petroleum in the preceding year, those contracts were unilaterally annulled. In the field of metallics, the only approach to internal sufficiency-aside from the iron and steel industry that has depended heavily on the importing of basic raw materials-has been in mining, smelting, and refining lead and zinc although iron ore, silver, beryllium, tantalite, and tungsten have been mine production items of economic significance. Reserves of lead, zinc, silver, bismuth, vanadium, and low-grade and metallurgically difficult iron ore-as well as those of beryllium, tantalite, and tungsten which are produced primarily for export-appear to be fairly abundant. The exploration of deposits of copper, cobalt, tin, lithium, gold, manganese and uranium has been undertaken on a relatively small scale, and little precise information is available on the extent of reserves. Argentina is dependent on foreign sources for part of its required iron and steel and, except for lead and zinc, most of its nonferrous metals. Nonmetallies and solid fuels present an exceptionally varied array of production items among which cement had the second largest 1963 output in South America. Borates, bentonite, common clay, diatomite, fluorite, granite, lime, limestone, obsidian, onyx, rhodochrosite, salt, and spodumene ordinarily are produced for export either exclusively or in excess of domestic consumption requirements. Barite, cement, chalk, gypsum, marble, and mica are both exported and imported. Argentina depends entirely or partly on imports for coal and coke, certain special types of clay, mineral abrasives, graphite, magnesite, mineral fertilizers, sulfur, talc, and minerals for construction, the last group being chiefly attributable to convenience of river transport from Uruguay.

Jan 1, 1964

By John R. Bitler

A computerized napping system was developed by the Bureau of Mines to provides procedures for the rapid and inexpensive display of coal reserve data. Mapping system output consists of two types of maps, point distribution and contour (isopleth), which can be produced for data (coal analyses) associated with a point location (outcrop, drill core, or mine samples). These locations can be in the form of latitude and longitude or Universal Transverse Mercator (UTM) grid coordinates. The mapping area can range in extent from as small as a single county to as large as a multistate region. The mapping system utilizes programs developed at Harvard University, in addition to several modifications developed by the authors. The primary advantage of this system is that it enables the display of a rapidly changing data base and computerized map generation without the intermediate steps of digitizing and overlaying to produce base maps. The mapping system is applicable to any regional mineral reserve or resource study for which point location data are available. Included are example maps of the distribution of data points and contouring for sulfur content of the Upper Freeport coalbed in this western Pennsylvania demonstration area.

Jan 1, 1977

By D. K. Dysinger

In this U.S. Bureau of Mines study, neodymium metal of 99.8 pct purity was prepared by electrolysis of Nd203 salts dissolved in a molten fluoride electrolyte. The metal was electrowon in a molten state at current efficiencies of 50 to 60 pct. Oxygen and carbon were the major impurities detected in the product. During operation of the small-scale laboratory cell, a number of technical problems including anode effect, low oxide solubility in the electrolyte, high neodymium metal solubility, reactivity of the metal with the cell materials, and back reaction of the metal with the anode gases were encountered. Approaches to improve cell operation and prospects for commercial adoption of the electrolytic production of neodymium metal are discussed.

Jan 1, 2010

By R. V. Ramani, K. Bode

"IntroductionIn part 1 of this paper, the results of the experimental work in a wind tunnel under controlled conditions were presented. To understand the spatial and temporal behaviour of airborne dust under mine conditions, experiments were performed in the Lake Lynn Experimental Mine of the US Bureau of Mines. The mine airway experiments were designed to study the variations of ambient concentrations along the length of an airway, and the deposition rates and deposition velocities in an airway cross section. Other objectives of the study were to investigate the spatial and temporal behaviour of airborne dust with regard to air velocity and particle density, the size distribution of the airborne dust cloud as it travels in the airway, and the size distribution of the dust particles deposited along the airway. Other objectives of the study were to compare wind tunnel results with In-Mine results, whenever appropriate.Experimental ProcedureLocationA complete description of the Lake Lynn Laboratory Mine of the US Bureau of Mines (USBM) can be found in the US Bureau of Mines Information Circular 8911 (Mattes et al., 1983). This mine provides excellent facilities for dust experiments. The airway dimensions are similar to those of a coal mine airway. The mine has a drift (D Drift, see Figure 1) that extends almost 500 meters without interconnecting airways, stoppings, or bends. The D drift measures approximately 6m in width and 2,25m in height.The Lake Lynn Laboratory Mine· is ventilated by a variable speed, 75 kW (100 hp), 28,3 m3/s (60 000 cfm) blower fan installed on the top of the ventilation shaft. Air velocities of 1, 1,3 and 1,8 m/s, respectively, could be obtained in the D Drift. However, the temperature changes at the surface can cause small variations in air quantities and velocities underground. The low background dust level in the mine reduces the problem of sample contamination from other sources of dust. Extended periods of uninterrupted data collection can also be scheduled. Mine airway parameters which are important for the analysis include the dimensions of the airway and the ventilation data such as the air velocity, and the pressure loss in the drift. All these data were acquired during altimeter surveys which were conducted prior to each of the experiments."

Dec 1, 1995

Acid pollution from abandoned mines causes serious contamination of major streams in coal mining areas. In Pennsylvania alone it is estimated that 3000 miles of streams are devoid of fish and plant life because of coal mine effluent.1 The pollution arises because water and oxygen react with iron sulfide in the mine cavity to produce sulfuric acid and iron sulfate, which later find their way back into surface streams. Two general approaches to the problem are possible: (1) prevent the acid-forming reaction from taking place, (2) treat the acid mine water after it is formed so that it will not be harmful to the ecology when discharged into streams and other surface waters. The work described in this report belongs in the first category - it was based on the assumption that acid formation in the mine cavity can be prevented by keeping water (one of the reactants) out of the mine. This was to be accomplished by-forming a waterproof seal over the mine cavity which would prevent the seepage of surface water into the mine. It was planned to form such a seal at or near the surface of the ground by applying latex to the soil. Ideally a dilute latex would be applied to the soil and would penetrate to a depth of two to three feet below the surface where it would be coagulated by reacting with a constituent of the soil or by other means., A seal below the surface of the soil would have several advantages over a surface seal - it would not be subject to destruction by traffic, frost or vegetation and, more important, it would allow the use of the top soil for many agricultural purposes. A preliminary feasibility experiment was performed prior to application for the present grant. It showed that it was indeed possible to form a sub-surface seal by means of latex. A core of soil was obtained locally (Wayne, N. J.) by driving a 6.5 cm inside diameter steel pipe about 100 cm long into subsoil for a distance of 71 cm. The soil was retained within the pipe for this experiment. A part of the free space above the soil in the pipe was charged with water, and the seepage rate of the soil after it had become saturated was 15 ml/min under a total head (wet soil plus supernatant column of water) of 92 cm. After the supernatant water had drained completely, 100 ml of 5% rubber latex was added and allowed to seep into the soil. This was followed by additional water and the seepage rate was found to be 2 ml/min under the same head. This seepage rate remained unchanged when remeasured on the following day. Since there was no visible evidence of the latex in the collected drain water it is presumed to have been retained by the soil.

Jan 1, 1972

By Jan M. Mutmansky, Christopher J. Rise

"One of the most serious long term health problems associated with underground,mining is Coal Workers Pneumoconiosis (CWI'), more commonly known as Black Lung Disease. It occurs in some coal workers, normally after 15 or more years of exposure to coal mine dust, and leads to a variety of respiratory problems. Two types of pneumoconiosis are recognized simple CWP, which has been estimated to affect 6.9 percent of miners and is a condition that does not impair the miner's ability to work nor reduce life expectancy; and a more severe form of black lung (called progressive massive fibrosis) that occurs in about one percent of the cases and results in severe lung damage.Although the relationship between coal dust and CWP has long been recognized, detailed knowledge of the relationship is insufficient for setting up authoritative guidelines to reduce the health risks for those employed in dusty,underground environments. CWP is not only a health problem for workers that causes considerable distress, it is also a very expensive problem the total annual costs associated with CWP approach two billion dollars.As part of its efforts to combat CWP, the U.S. Bureau of Mines in 1983 established a Generic Mineral Technology Center to carry out basic research into all aspects of respirable coal dust:— control of dust generation — the behavior of dust in the mine — characterization of dust particles interaction of dust and lung— the relationships among dust generation and mobility and the mine environment, geology, and seam characteristics,Penn State, West Virginia University, the University of Minnesota, and the Massachusetts Institute of Technology are involved in this research, which is administered from the Department of Mineral Engineering at Penn State.Our work is one of the seven projects to be conducted at Penn Slate. We are concerned particularly with the characterization of dust and its relationships with the mine environment, and our main goal is to establish standard procedures for describing and measuring these variables.Coal DustCoal dust is a very complex material that varies greatly in chemical and mineralogical properties. Moreover, it is not the only constituent of respirable dust in the mine. When a coal seam is mined, it is inevitable that rock particles other than coal are included in the material. This rock comes from the mine roof, the floor, and the partings and inclusions within the coal scams. Since the roof and floor strata, the partings and inclusions are often stronger than the coal, mining them frequently causes more dust than mining the coal itself. One of the objectives of our research is to find the relationships between a specific coal's characteristics before it is mined and the respirable dust characteristics after it is mined. We are particularly interested in the size distribution of particles, the chemical properties, and the mineralogical properties."

Jun 1, 1988

By W. W. Weller

Heat-capacity measurements of sodium dimolybdate (Na2Mo207) and sodium ditungstate (Na2W207) were conducted over the temperature range from 51° to 298° K. The entropies of the two compounds at 298.15° K were calculated from the heat-capacity values and were used, in conjunction with other entropy data, to evaluate the entropies of formation of the compounds from their constituent elements and oxides.

Jan 1, 1963

By Robert J. Willard

This chapter includes tables for 1982 that were not available in time for publication of the 1982 Minerals Yearbook, but does not include corresponding tables for 1983. The value of raw nonfuel minerals produced in the United States during 1988 was estimated at $21.1 billion, an increase of $1.5 billion over the value for 1982. This is a reversal of last year's downturn in value from that of 1981, which was the only decrease noted since 1971; hence, an overall trend of increasing values has been maintained for 12 years, except for 1982. Although the reversal is a basis for cautious economic optimism, it is tempered by continued problems in the domestic mining industry: inadequate funds for capital investment and competition with other countries that have lower production costs. Output of metal commodities in 1983 increased for 8 out of 21 metals, and metal values, in general, increased for 9 of the metals. Output of nonmetal commodities was mixed, with 24 nonmetals showing increases, 20 showing decreases, and 2 unchanged. Nonmetal values were also mixed in 1982: 25 showed increases, 20 declined, and 1 was unchanged. Improvements in the international metals market have not been forthcoming because of the continued depressed prices for major metals. Governments in foreign producing countries have been concerned with maintaining employment and continuing foreign exchange flows through mineral exports. Consequently, the excess of supply in the face of shrinking demand brought downward pressure on metal prices in general, except for the precious metals. On the domestic front, this situation means U.S. mining companies must become even more cost efficient. The major trend in the mining industry in 1983 was to cut costs further, reduce or stabilize total production, reduce outlays for major capital equipment, modify existing systems and equipment, and streamline operations. Most of the accomplishments reported herein reflect this trend.

Jan 1, 1984

New Continuous Personal Dust Monitors (CPDM) submitted to NIOSH for approval to sample coal mine dust must accurately measure respirable coal mine dust in mine environments. There are two steps in the process which may be done in any order. The manufacturer is required to submit the results of a comparative underground coal mine dust sampling study, where the candidate CPDM is compared to an approved coal mine dust sampling device (currently the Coal Mine Dust Personal Sampling Unit (CMDPSU)). This testing shall follow the guidelines outlined below and shall demonstrate through weighted regression analysis that the mean coefficient of variation with bias correction is equal to or less than 12.8%. The other step involves laboratory testing to determine the electronic and environmental stability. This testing must be conducted by a private, commercial, academic or other laboratory approved by NIOSH.

Jan 1, 2009

By J. A. Organiscak

Enclosed cabs are a primary means of reducing the silica dust exposure of equipment operators at surface mines. The National Institute for Occupational Safety and Health (NIOSH) has investigated various factor effects on enclosed cab air filtration system performance. Factors experimen­tally investigated were intake filter efficiency, intake air leakage, intake filter loading (filter flow resistance), recirculation filter use and wind velocity effects on cab penetra­tion (inside to outside cab concentration ratio). Adding an intake pressurizer fan to the filtration system was also investigated. Results indicate that the intake filter efficiency and recirculation filter were the two most influential factors on cab penetration. Use of a recirculation filter significantly reduced cab penetration over the intake air filter by itself due to the multiplicable filtration of the cab interior air. Cab penetration was also affected to a lesser extent by intake filter loading and air leakage. Adding an intake pressurizer fan notably increased intake airflow and cab pressure while providing only minor changes to cab penetration.

Jan 1, 2008

By John M. Gomes

Two methods for electrowinning tungsten from wolframite [(Fe,Mn)W04] were investigated. The first method, direct electrowinning from wolframite concentrate dissolved in molten salt mixtures composed essentially of various combinations of sodium phosphates, sodium borates, and sodium halides, yielded impure products. The second method was electrowinning from a halide-tungstate melt that was obtained from a high-temperature, two-phase extraction of tungstic oxide (W03) from wolframite. Electrolysis in electrolytes prepared from addition of sodium metaphosphate (NaPO3) and boric oxide (B2O3) to the halide-tungstate melt produced tungsten metal of 99.9 percent purity. Tungsten carbide (WC) was electrodeposited from the halide-tungstate melt when the melt was adjusted to contain 82 mole-percent NaCI and 6.0 mole-percent each of W03, sodium metaborate (Na2B204), and caustic soda (NaOH).

Jan 1, 1970

By Fred N. Kissell, Jay F. Colinet

The two major lung diseases of miners are "blacklung" and silicosis. Blacklung, or pneumoconiosis, was first recognized as a disease of British coal miners in the 1600s. However, investigations into the cause of blacklung disease did not begin until the 1900s. The causative agent of pneumoconiosis in coal miners was thought to be silica until studies in the United Kingdom provided evidence that expo- sure to coal dust containing minimal silica could also cause pneumoconiosis. In the Federal Coal Mine Health and Safety Act of 1969, coal workers pneumoconiosis (CWP) was defined as "a chronic dust disease of the lung arising out of employment in an underground coal mine." Diagnosis of CWP is generally based on chest x-ray findings and a patient's history of working in coal mines, usually for 10 or more years. In its early stages, CWP is called "simple CWP." Miners with simple CWP are at increased risk of developing an advanced stage of the disease, called "progressive massive fibrosis" pMF) or "complicated CWP." PMF (complicated CWP) is associated with significant decreases in lung function and oxygen- diffusing capacity. PMF is also associated with breathlessness, chronic bronchitis, recurrent chest illness, and episodes of heart failure. Coal miners with silicotic lesions or PMF have an increased risk of tuberculosis and other mycobacterial infections. PMF may progress even in the absence of further dust exposure. This disease is also associated with increased mortality (National Institute of Occupational Safety and Health [NIOSH] 1995). The most recent study to determine the prevalence of CWP in coal workers was in the mid- 1990s. The average prevalence of CWP was 2.8%, but for those with 30 or more years in the industry it was 14%. For the 10-year period from 1987 to 1996, 18,245 deaths were attributed to CWP. The most frequently recorded occupation on the death certificate (70%) was mining machine operator (NIOSH 1999). Silicosis may develop when inhaled respirable crystalline silica (quartz) is deposited in the lungs. The clinical diagnosis of silicosis is based on (1) recognition by the physician that the level of silica exposure is adequate to cause the disease, (2) the presence of chest radiographic abnormalities consistent with silicosis, and (3) the absence of other illnesses (e.g., tuberculosis or pulmonary fungal infection) that may mimic silicosis. The radiographic patterns are often the same for CWP and silicosis; thus, these diseases are sometimes distinguishable only by work history or pathological examination. Chronic silicosis commonly involves 15 or more years of exposure to silica. The characteristic microscopic feature is the silicotic nodule. Chronic silicosis is often asymptomatic and may manifest itself as a radiographic abnormality with small, rounded opacities of less than 10 mm in diameter, predominantly in the upper lobes. Lung function may be normal or show mild restriction. Chronic silicosis is also associated with a predisposition to tuberculosis and other mycobacterial infections and with progression to complicated silicosis.

By W. R. Wrzensinski

This report presents the findings from a l-yr Bureau of Mines program in which sulfur concrete reinforcing materials were tested and evaluated to determine their resistance to corrosion. It also summarizes the permeation characteristics of sulfur concrete and the exemplary performance of precast, reinforced sulfur concrete structures in various industrial environments. The Bureau is furthering the development of sulfur concrete technology as part of a larger effort to find uses for the Nation's plentiful sulfur resources in construction materials. Sulfur concrete is a corrosion-resistant material that can be used in acid and salt environ-ments where conventional materials fail. Penetration of corrosion-inducing agents is minimized because of the low permeation characteristics of sulfur concrete.

Jan 1, 1988