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By D. H. Baker

This report, one of a series prepared by the Federal Bureau of Mines on the technology of titanium, describes the development of an electrorefining cell from which cathode deposits up to 30 inches long can be produced. Data show individual deposits to be homogeneous, comparable from top to bottom, and not varied in quantity or quality of metal over the entire length of the deposit. Investigations concerned with various diameter cathodes showed that cathode current efficiencies were materially reduced with cathodes less than 2 inches in diameter. Deposits produced on 1/2-inch-diameter cathodes showed cathode current efficiencies of 19 percent and on 1-inch cathodes, just over 22 percent, whereas deposits produced on 2- and 4-inch-diameter cathodes showed about 70-percent current efficiencies. A series of 20 deposits on 4-inch-diameter cathodes was produced under simulated production operation. The average current efficiency, based upon a divalent ion, was 72 percent with 11 1/2 pounds of metal produced per cycle of operation - 98.8 percent of which had a Brinell hardness number (B.h.n.) of 80 or less.

Jan 1, 1959

Provide reliable, early-warning fire detection instruments, telemetry, and control systems for noncoal underground mines. Approach Industrial-grade fire detection instruments and signal telemetry equipment were modified for long-term exposure to harsh underground mine conditions, then were installed in four mines to evaluate long-term performance and reliability. How It Works The elapsed time between the onset of a fire and its detection is critical because fires tend to grow in size and intensity with time. Early fire detection and warning permit the initiation of a mine's emergency plan (evacuation, fire fighting, etc.) while the fire is still small, or ideally, while it is still in the incipient stage. Fire detection and warning systems, utilizing sensitive heat, flame, smoke, and gas analyzers, provide the most rapid and reliable indication of a developing fire.

Jan 1, 1987

By Daniel W. H. Su, Gregory J. Hasenfus

This paper demonstrates that finite-element modeling can be used to predict in situ coal pillar strength, especially under non ideal conditions where interface friction and roof and floor deformation are the primary controlling factors. Despite their differences in approach, empirical, analytical, and numerical pillar design methods have apparently converged on fundamentally similar concepts of coal pillar mechanics. The finite-element model results, however, are not intended to suggest a new pillar design criterion. Rather, they illustrate the site-specific and complex nature of coal pillar design and the value of using modeling procedures to account for such complex site-specific conditions. Because of the site-specific nature of coal pillar design, no single pillar design formula or model can apply in all instances. Understanding and accounting for the site-specific parameters are very important for successful coal pillar design. More work remains before the century-old problems related to pillar design are finally solved. Future research should focus on the cross-linkage of empirical, analytical, and numerical pillar design methods.

Jan 5, 1999

By J. L. Ellenberger

The National Institute for Occupational Safety and Health (NIOSH) has continued the research role of the former US Bureau of Mines (USBM) to engineer techniques that will reduce the hazards in the mining workplace associated with coal bumps. Recent research focused on a longwall coal mine in Utah with overburden greater than 750 m (2,500 ft) containing several massive sandstone units. The primary field instrumentation at the site was three-dimensional, full waveform, autonomous microseismic arrays placed underground and on the surface in order to surround the active multi-panel longwall district. The purpose of these arrays was to help investigate the strata mechanics associated with the redistribution of stress and the associated gob formation of the longwall. Specifically, the seismic arrays were used to determine the timing and location of the failure in the strata surrounding the active mining. Overall 13,000 seismic events were detected and located with on-site processing during the five months the panel was being mined, including a magnitude (ML) 4.2 event. Of these, a smaller subset of 5,000 well-located events was selected during post-processing to form a consistent data set for analysis in this paper. From this data set, it was observed that the seismic events generally occurred in advance of the longwall face, both above and below the panel, consistent with failure of the strata in the forward stress abutment zone. Also, the occurrence of the ML 4.2 seismic event within 150-180 m (500-600 ft) of a deep cover longwall face with no associated bump caused a re-evaluation of the nature of the connection between seismic activity and coal bumps.

Jan 1, 2002

To provide a means for rapidly evaluating proposed mine layouts in order to avoid potential hazards while minimizing loss of coal. The Approach: Development of a computer program that will compute many possible mine layouts by changing the mine plan until the arrangement giving minimal hazards with optimum extraction is found. How It Works: The Hazard Evasion Program for Mine Planning, developed by the Bureau's Denver (Colo.) Mining Research Center, tests hundreds of possible solutions to a mining layout, and by sorting out the 10 best (based on the criteria of maximum safety for workers with minimum abandoned coal), limits the number of choices that need to be considered and appraised for applicability to a given mine scheme. The program is applicable for room and pillar or longwall mining, for oil and gas well hazards, and for other hazards that can be described mathematically such as channel sands, potential bad roof areas, faulting, voids, or water pockets.

Jan 1, 1974

Water pollution has been an integral part of most mining operations in the past. Most mine planners had designed their mining operations with little or no regard for prevention of water pollution. The main planning element was always the economics of mineral recovery. Quite often the cheapest means of mineral recovery resulted in the largest water pollution problems. Recent water pollution laws have introduced a new economic element - water pollution control costs - to be considered in mine planning. Water pollution control costs can be extremely high. Foresighted planning can minimize these costs and provide better water pollution control. Effective pollution control preplanning can eliminate pollution from active mines and minimize pollution that may occur after completion of mining. Presently available technology can practically eliminate water pollution by treatment of the mine water. Use of water treatment during mining has no effect on the levels of water pollution after treatment ceases and the mine is abandoned. Therefore, this section of the report deals with preplanning to reduce water pollution, both present and future, by using at-source control techniques. Proper planning of mining and pollution control techniques should follow the concept of a complete, comprehensive reclamation plan. This plan should have control measures designed for all phases of mining from initiation through completion. Preplanning involves acquiring complete information concerning the future mine site, defining the reasons why mining could cause pollution from the site, and determination of available techniques to prevent or minimize formation or transportation of pollutants. Location of haulage and access roads and other mine related facilities should be included in preplanning for water pollution control. Mine site planning is the primary step in establishing any new mining area and is the key to a successful, non-polluting and economical

Jan 1, 1973

To reduce the possibility of injury to operators and damage to equipment caused by collision of mining vehicles during coal loading. Approach An energy-absorbing bumper was developed and tested underground on a continuous miner. How It Works The bumper, a long box-like weldment backed by five energy absorbers, is attached to a continuous mining machine by a hinge behind the cab. See Figure 1. When a shuttle car collides with the bumper, or when it is otherwise struck, the energy absorbers are compressed. This absorbs and dissipates part of the kinetic energy of the colliding vehicle, thereby reducing or eliminating its destructive effects. Each energy absorber consists of two chambers separated by a freely-moving piston. One chamber (Figure 2) contains hydraulic fluid. The second chamber contains a gas. When a collision causes the absorber to compress, the hydraulic fluid in the first chamber is forced past a metering pin and through an orifice. The hydraulic fluid then pushes against the piston, compressing the gas in the second chamber.

Jan 1, 1978

By D. N. Nilsen

The Bureau of Mines is developing a method to recover Ni, Co, and Cu from laterites containing less than 1.2 pct Ni and 0.25 pct Co. The method consists of the following basic unit operations: (1) reduction roasting, (2) leaching, (3) solvent extraction, and (4) electrowinning. The method reflects three Bureau of Mines objectives: (1) recovery of critical minerals that are domestically in short supply from low-grade domestic laterites, (2) lower processing energy requirements, and (3) solution recycling. This report deals with the extraction of cobalt and the preparation of a suitable cobalt electrolyte by solvent extraction from liquor produced by this method. Nickel and copper are coextracted with LIX64N from an ammoniacal ammonium sulfate leach liquor containing about 1.00 g/l Ni, 0.30 g/l Co, 0.03 g/l Cu, and 0.02 g/l Zn. Cobalt (III) in the nickel-copper barren raffinate is reduced to cobalt (II) with cobalt metal. Reduction of cobalt (III) to cobalt (II) greatly aids subsequent extraction. Commercially available XI-51 extracts about 94 pct of the cobalt from the treated raffinate in one stage in a laboratory mixer-settler continuous circuit. Ammonia loaded on the solvent is removed in two washing steps. About 94 pct of the cobalt then is stripped from the XI-51 in one stage with spent cobalt electrolyte containing about 77 g/l Co and 18 g/l sulfuric acid (H2S04), Electrolytes containing less H2S04 also may be used. Preliminary data indicate that coextracted zinc may be removed from pregnant cobalt eletrolyte containing 3 g/l or less H2S04 with di-(2 ethylhexyl) phosphoric acid (D2EHPA).

Jan 1, 1980

By Thomas V. Falkie, R. Venkataramani

Anderson, L. B., 1963, "Multiple Regression Techniques Correlate Experimental Data," Chemical Engineering, V. 70, N. 12, pp. 223-228. Aubert, E. J., Lund, I. A., and Thomasell, A. J., 1959, "Some Objective Six-Hour Predictions Prepared by Statistical Methods," Journal of Meteorology, V. 16, pp. 436-46. Barrett, A. L., 1958, "Alternating Current in Continuous Mining," Mechanization, V. 22, N. 9, pp. 83-86. Bower, A. B., Jr., 1970, "Bit Design: Key to Coal Cutting," Coal Age, V. 75, N. 7, pp. 70-72. Bower, A. B., Jr., 1971, Personal Communication dated April 29, 1971; General Electric Company, Mining and Metallurgical Products Department, Detroit, Michigan. Burt, C., 1950, "Group Factor Analysis", British Journal of Statistical Psychology, V. 3, pp. 40-75. Cady, L., Gertler, M., Gottsch, L., and Woodbury, M., 1961, "The Factor Structure of Variables Concerned with Coronary Artery Disease", Behavioral Science, V. 6, pp. 37-41. Cattell, R. B., 1965, "Factor Analysis: An Introduction to Essentials I. The Purpose and Underlying Models," Biometrics, V. 21, N. 1, pp. 190-215. Christensen, R. W., Heins, R. W., Babcock, W., and Tonn, R., 1971, "The Effect of Material Properties on Materials Handling Processes," Six Month Technical Report, (August 1971) to Advanced Research Projects Agency, U. S. Department of Defense; The University of Wisconsin. Collins, G., 1961, "Factor Analysis," Journal of Advertising Research, V. 1, N. 5, pp. 28-37. Cooley, W. W., and Lohnes, P. R., 1962, Multivariate Procedures for the Behavioral Sciences, New York: John Wiley and Sons, Inc. Cree, J. 0., 1956, "Power for Continuous Mining," Mining Congress Journal, V. 42, N. 10, pp. 49-52. Draper, N. R., and Smith, H., 1966, Applied Regression Analysis, New York, John Wiley & Sons, Inc. Griffiths, J. C., 1966, "A Genetic Model for the Interpretive Petrology of Detrital Sediments," The Journal of Geology, V. 74, N. 5, pp. 655-672.

Jan 1, 1972

By G. H. Schnakenberg

In response to the underground mining industry's growing concern with the exposure of workers to the diesel particulate matter (DPM) component of diesel exhaust, a method was developed to estimate the average workplace concentration of DPM that could be expected from using the new lower DPMemitting engines now being approved by the US Mine Safety and Health Administration (MSHA) when these new engines are equipped with state-of-the-art exhaust-control, technology for filtering and combusting DPM. The resulting estimate uses the MSHA-reported particulate index for these engines, the prevailing rule-of-thumb ventilation rate of 150 cfm/hp and the available diesel-exhaust filter technology that has been shown to be at least 80% effective in reducing tailpipe DPM. In the estimate calculation, every engine used in an underground mine is assumed to be equipped with this control technology. Under the stated reasonable conditions, an average DPM level of 90 µg/m3 (mass) is predicted as technically feasible.

By T. N. McVay

The Bureau of Mines has developed a field test for detecting the presence of columbium in a variety of minerals containing the clement. The test consists of fusing the mineral or rock powder with potassium pyrosulfate in a porcelain crucible, digesting the melt with hot dilute hydrochloric acid to release the columbium oxide (Cb205), and subsequently reducing the columbium oxide to a lower oxide by adding tin, which gives a blue color to the contents of the crucible. The method will detect 1 percent of contained columbium oxide (Cb205) in a mineral sample provided no tungsten is present. If a mineral containing appreciable titanium is test,-!d in the same manner, the solution in the crucible becomes violet. In the presence of columbium, titanium at first causes a violet coloration of the solution, which after a few minutes is masked by the stronger blue of the reduced columbium oxide. Although tantalum oxide (Ta205) does not interfere with the columbium test, tungsten gives a blue color that is indistinguishable from the color obtained with columbium. A simple method is available to detect the presence of columbium in the absence of tungsten, but when the presence of tungsten is suspected, the sample must be subjected to somewhat more elaborate chemical tests to determine the presence or absence of columbium. Although these latter tests can be made in the field, several steps are involved that arc best performed in the laboratory with simple equipment.

Jan 1, 1962

To determine the relative permeability of the soil a series of percolation tests were performed at the three locations of interest at Lanse, i.e., 3C, 03A and strip bank, and KA and KB at Kato. Soil cores were removed to 2, 8, 16, 24 and 32 inch depths with the thin wall sampler tube, each core separated from the next by about fifteen feet. Then two-foot-long thin-wall tubes were inserted into the 2, 8, and 16 inch deep holes and three-foot long tubes were inserted into the 24 and 36 inch deep holes. Each tube was tamped down about one inch further to assure a bottom seal; the tubes were filled with water and the rate of fall was measured. The test is similar to those done for septic tank percolation studies 6; but is not quantitatively related to Darcy's coefficient of hydraulic conductivity because the water can flow in three dimensions from the bottom of the tube. The measurements are dependent on the length of test, since the rate of fall is a function of the head. Therefore, it should be noted that the 24 and 32 inch deep tubes should give faster percolation rates because of the one foot greater head. At locations 03A and 3C the data show a sharp decrease in percolation at increasing depth, Table XV. However, the percolation at 03A and 32 inch depth is much higher than at 3C (0.2 vs. 0.01 inches/hour); the fragipan layer must be deeper at the 3C location since this area does experience a perched water table. On the strip bank the rates of falling head are randomly variable, appearing to be as much dependent on the particular location of insertion as on depth of placement. For example, water drained from the 16 inch tube as fast as it was added, probably into a sub-surface cavity or crevice. At Kato the tubes were more difficult to place because of interference of tree roots. For this reason 2 inch deep tubes were not inserted. These short tests at Kato were inconclusive, varying extensively when the tubes were moved. Field permeability tests were also performed in two (previously described) eight-inch diameter permeater tubes at Lanse and one at Kato. Because the soil is confined inside the tube, hydraulic conductivity can be calculated according to Darcy's flow equation. The high values reported in Table XVI experienced when the tubes were rewetted from a dry surface condition, enable us to conclude that infiltration is faster than the saturated permeability of the soil. In contrast to the falling head percolation tests, these permeability results do not show a high variation between locations.

Jan 1, 1972

By Willard L. Hunter

The separation of tantalum and columbium by solvent extraction was under-taken as part of the Bureau of Mines research program to improve methods for extracting, separating, and reducing these elements to metal. The diethyl ketone aqueous HCl-HF system was one of several systems studied to determine the effect of metal and acid concentrations in aqueous solutions upon the transfer of tantalum and columbium into selected ketones. The tantalum-columbium oxide mixture used in this investigation was obtained by chemical extraction from Geomines slag. The investigation showed that tantalum 99.4 percent pure and columbium 97.2 percent pure can be produced by the selective transfer of tantalum into diethyl ketone from a solution of 2-N HF and 1-N HC1. The relatively low acid concentration necessary for tantalum transfer and the excellent selectivity of the system recommend its use for the separation of tantalum and columbium.

Jan 1, 1961

The current procedure for measuring the concentration of respirable coal mine dust is as follows. Each filter is preweighed by the filter manufacturer to ±0.1 mg. Following sampling with the Coal Mine Dust Personal Sample Unit (CPSU) at 2.0 L/min, the filter with coal mine dust is sent to MSHA for weighing. The current MSHA procedure for weighing respirable dust samples uses a Mettler Model AE163 analytical balance in conjunction with an automatic weighing system with a precision of ±0.02 mg [Tomb 19901. Each balance is calibrated twice per day. Quality control for the automatic weighing system includes the systematic weighing of one in eight filters on a second Mettler AE163 balance. Tolerance is set at ±0.1 mg between the two weighings of the same sample. Weights are truncated at the 0.1 mg level (e.g., 3.457 mg is truncated to 3.4 mg) [Bowman et al. 19851. The difference of the two truncated weights is then recorded as the weight of coal dust deposited. The respirable concentration (mg/m3) is computed by multiplying by a correction equal to 1.38 and dividing by the volume of air sampled (2.0 L/min x sampling time [min]).

Jan 1, 1997

Develop new technology to encourage domestic processing of automobile catalytic converters for recovering platinum -group metals. Background Automobile catalytic converters are used to convert pollutants in automobile exhaust into water vapor, carbon dioxide, and nitrogen, About 1 million troy ounces of platinum-group metals arc used each year in the. United Slates to manufacture catalytic converters. It has been estimated that about 60 pct of the used catalytic converters arc being collected. Most of these used catalytic converters were not processed in the United States but were exported to Japan or Europe for processing. In 1991, about 250,000 troy ounces of platinum-group metals were recovered from scrap catalytic converters collected in the United States. Each short ton of decanned catalyst may contain 30 troy ounces of platinum-group metals valued at over $15,000. Development of an economic process for the recovery of platinum-group metals that can be operated on a small or large scale may increase, the percentage of catalytic converters collected and encourage domestic processing to recover a platinum-group metal concentrate. This would significantly decrease the dependence of the United States on imports for these critical and strategic metals.

Jan 1, 1992

By W. K. Sawyer

In this Bureau of Mines investigation, one-and two-dimensional gas reservoir simulators were combined in such a manner that pressure distributions both in an induced vertical fracture and in the surrounding formation, could be determined as a function of time for any specified well production rate. The technique used consisted basically of the alternate ust of one-and two-dimensional algorithms for obtaining new pressure distributions in the fracture and in the reservoir, respectively. The pressures at adjacent reservoir and fracture nodes were used to calculate flow rates from the formation into the fracture, which provided source terms for both algorithms. The combination model developed provides the only known means of simultaneously simulating transient gas flow in a vertical fracture and the surrounding formation. Thus, the technique developed would be useful in locating wells in a gas storage field in that the effects of both fracture length and conductivity could be considered prior to drilling and fracturing operations. In addition, it will be helpful in analyzing pressure drawdown tests in a vertically fractured gas well since the entire test can be readily simulated for a wide range of reservoir and fracture properties.

Jan 1, 1974

To devise an economical, environmentally acceptable method for recycling scrap lead-acid batteries. Approach A combination electrorefining-electrowinning method for recycling lead metal and sludge from scrap batteries was devised which produces a 99.99 + percent pure lead product and eliminates the lead and sulfur oxide emissions that are the normal by-products of high-temperature smelting processes. How the Method Works Lead metal grids and lugs are separated from the battery sludge by washing and screening, and are melted and cast into anodes for electrorefining by the Betts process. The electrolyte used is fluosilicic acid, a large volume waste product generated during the production of phosphate fertilizer. During the electrorefining process, impurities in the anode are trapped and held in an adherent slime blanket on the surface as the anode dissolves while pure metallic lead is deposited on a lead cathode. The major problem in the past has been to recover the lead from the battery sludge which consists of approximately 60 percent lead sulfate, 21 percent lead, and 19 per-cent lead dioxide. In the flow sheet developed by the Bureau

Jan 1, 1983

Improve the accuracy of commonly-used mine air velocity measurement techniques. Approach The Bureau of Mines, through a contract with Ketron, Inc., conducted a detailed study to establish appropriate, generalized correction factors for commonly-used air velocity measurement techniques. The techniques used were centerline readings, continuous traverse and split traverse vane anemometer readings, and smoke cloud readings (see Bureau of Mines Bulletion 589 for details on the proper use of these techniques). The various measurement techniques were used at different mine test sites to measure different air velocities. The data collected from the test sites were used in a statistical analysis which determined a generalized correction factor for each measurement technique. The correction factor multiplied by the measured velocity was used to provide the true velocity.

Jan 1, 1984

The National Institute for Occupational Safety and Health (NIOSH) recommends that occupational exposures to respirable coal mine dust and respirable crystalline silica* be controlled by complying with the provisions presented in this document. These recommendations are designed to protect the health and provide for the safety of workers exposed to respirable coal mine dust and respirable crystalline silica for up to 10 hr/day during a 40-hr workweek over a working lifetime. The information presented in this document demonstrates that underground and surface coal miners are at risk of developing simple coal workers' pneumoconiosis (CWP), progressive massive fibrosis (PMF), silicosis, and chronic obstructive pulmonary disease (COPD). Adherence to the recommendations in this document should prevent or greatly reduce the risk of adverse health effects in workers exposed to respirable coal mine dust and respirable crystalline silica. NIOSH recommends that preventive efforts be focused primarily on reducing worker exposures. Effective health and hazard surveillance and medical screening are also useful components of a comprehensive prevention effort.

Jan 1, 1997

By R. H. Grau, S. B. Robertson, R. B. Krog, T. P. Mucho

Stone mines represent the highest percentage of operating underground nonmetal mines in the United States. With the introduction of stricter Diesel Particular Matter (DPM) regulations, large-opening underground room-and-pillar stone mine operators are faced with implementing one or more alternative methods to reduce concentration levels including: install and maintain an effective ventilation system; install lower DPM emission diesel engines; the adding of DPM filters. The National Institute for Occupational Safety and Health (NIOSH) is actively researching various aspects of fan and stopping designs in an effort to improve the ventilation of these mines. NIOSH has identified and further developed three alternative ventilation methods for use in large-opening underground mines: split-mine, perimeter, and unit-ventilation. This paper describes the implementation of the three methods with respect to their use in mines of various levels of development.