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By K. Avarmaa, P. Taskinen

"The solubilities of rhodium (Rh) in a molten silver alloy in doré-smelting conditions for treating copper refinery slime at temperatures of 1,000 to 1,300 °C were measured using a high-temperature equilibration-quenching technique and direct phase analysis by electron probe X-ray microanalysis. The results obtained indicate that the solubility of rhodium in molten silver is very limited: only 0.04 to 0.26 weight percent at 1,000 and 1,300 °C, respectively. The thermodynamic properties of rhodium in molten silver were estimated from the solubility data. The compositions of the solid rhodium alloys in equilibrium with molten silver-rich doré metal were also measured in this study. The excess rhodium in the doré alloy will precipitate during the refining as solid, greater than 99 weight percent Rh.IntroductionSilver refining is a core step of the processes of anode slime treatment and precious metals recovery in copper refineries (Hait, Jana and Sanyal, 2009; Ludvigsson and Larsson, 2003). It separates the oxidic materials, such as nickel oxide (NiO) and barium sulfate (BaSO4), from metallics after the de-coppering and de-selenation steps of the anode slime, and refines the silver bullion from the undesired elements present (Cooper, 1990; Hyvärinen, Lindroos and Yllö, 1989). Doré metal is a silver-rich alloy which after the smelting step will be refined electrolytically, and the remaining constituents of gold as well as the platinum group metals (PGM) will be subsequently recovered in their own processing stages.Because of low concentrations of PGMs in copper, they are typically soluble in the doré metal in anode slime treatment. This can be concluded from their binary phase diagram data with silver (Massalski et al., 2007). One exception is sometimes encountered in the anode slime smelting operations if the smelter feedstock is rich in rhodium, as may be the case if the raw materials contain secondary raw materials such as e-scrap. The solubility of rhodium in solid silver is less than 0.04 weight percent (Królas and Sternik, 1995), and its solubility in molten silver is highly uncertain. The only experimental information in the literature (Królas et al., 1993; Elliott, 1985) suggests that the silver-rhodium alloy system at 960 °C forms a eutectic, which locates less than 2 °C below the melting point of pure silver (Arblaster, 2015). Early observations (Rössler, 1900) propose that rhodium is insoluble in molten silver even if solid silver-rhodium solutions have been recently produced on a nanoscale (Kusada et al., 2010).The aim of this study is to measure experimentally the solubility of rhodium in molten silver at doré metal smelting and refining temperatures. The silver alloy used to mimic the doré alloy contained silver and about 1 weight percent of the alloying elements copper, gold, palladium, rhodium and tellurium. The experiments were carried out in metal-slag equilibria with nitrogen-oxygen mixtures as the atmosphere, employing an equilibration-quenching technique and using direct phase composition analysis by electron probe X-ray microanalysis (EPMA) (Jak, Hayes and Lee, 1995)."

Jan 1, 2017

By S. K. Kawatra

Many mineral oxide and multi-component oxide (basalt) specimens break down into powders upon expo-sure to sodium vapor at elevated temperatures for extended times. This paper examines several possible mechanisms of oxide breakage by sodium vapor, both experimentally and from a thermodynamic viewpoint. The oxides for which reduction by sodium was thermo-dynamically favorable all exhibited some degree of fragmentation. The oxides which were not favorable for reduction by sodium did not exhibit fragmentation, with the exception of rutile, a titanium oxide. The rutile fragmentation was caused by the reduction of iron that was in solid solution in the rutile crystal structure.

Jan 1, 1995

By Robert L. Zook

Coal refuse slurry impoundments are dams constructed of coarse coal refuse to impound fine refuse (slurry) and water (25-30% solids). Both products are waste from coal preparation plants. A number of these structures in West Virginia, Pennsylvania and Kentucky were investigated to determine embankment stability. During the investigation a variety of embankment designs were encountered. The investigation determined the soil and geological characteristics of the embankments and the sites. This was accomplished by a test drilling and monitor installation (observation wells and piezometers) program, geologic study, and large scale mapping which allowed sub-surface profiles of the embankments to be constructed. The laboratory testing program concentrated on textural classification of the coal refuse, permeability and determining strength parameters to be utilized in the stability analyses. For the stability analyses, the Modified Fellinius Slip Circle, Simplified Bishop Slip Circle and Analysis for Translational Failure -were utilized. In all stability analyses hydrostatic pressure and earthquake were considered. This investigation indicated that 62% of the embankments analyzed are in a stable condition. The coal seam mined, the type of roof rock, and the gradation of the refuse influence the degree of compaction obtainable and the permeability of refuse. The shear strength of coal refuse appears to be controlled by its composition, moisture content, degree of compaction, amount and grain size of fines present. This investigation demonstrated these em¬bankments should not be treated as pure state-of-the-art dams; consideration must be given to the particular properties of coal refuse and the total refuse disposal system. Refuse dim slurry impoundments generally lack the site se- lection phase that is standard practice with siting most other types of dams.

Jan 1, 1974

By Rebecca Mae Summer

Large scale surface mining has a major impact on land use. Without reclamation, abandoned mining sites are usually less productive than before mining. With increasing and completetive land use demands in the United States, it becomes increasingly evident that multiple land use should be considered for all areas that will be mined, with special emphasis on coal, sand, gravel, and stone. The mining of these commodities affects the largest land areas and the latter two are commonly mined near population centers where high land-use pressures justify serious consideration of multiple use. Typically, sequential use will mean restoration of the mined land or at least transformation of the land into a useable state. Determination of land reclamation capability is a viable approach to planning reclamation of surface mined land. The natural resource base--geology, soil, and water--controls the type and intensity of land-use practices which can be sustained following mining. Evaluating physical limitations can eliminate consideration of uses which would severely impair the environment or which are impractical. This approach provides for an environmentally and economically sound land use at very little cost. In addition, it can save or make money for the mining company and landowner. Sand and gravel is an especially significant resource because it is mined throughout the entire country and commonly extracted near cities. Increasing urban growth and industrial activity require increased supplies of sand and gravel. This translates into expanded surface mining and an increase of disrupted land. Oftentimes this land is within an urban area and has potential for real estate or water-based activities. Therefore, if reclamation is planned and carried out concurrently with mining, it is definitely feasible and

Jan 1, 1977

By Mohamed A. Younis, Robert J. F. Goodfellow

This paper investigates the design approaches taken and the philosophy employed during the construction of the Metropolitan Airport Commission (MAC) storm tunnels, part of the Phase 4 Segment of the MAC Trunk Storm Sewer Project at Minneapolis St.-Paul International Airport, located in Minneapolis, Minnesota. URS Corporation was retained to provide a design and Construction Management (CM)services for the MAC Trunk Storm Sewer Project. A case history of the design and construction challenges of the project is presented. The MAC storm tunnels consisted of the construction of twin 10-foot inside diameter (I.D.) tunnels within 7 feet of an existing 72-inch I.D. storm pipe at the base of a 70-foot high highway embankment. The analysis required during the design stage of the project is discussed. This analysis and our design approach provided a defensible framework and justification to make design decisions on relevant issues including: allowable spacing of new and existing structures; preferred order of construction; expected ground deformation behavior; response of lining types to adjacent construction; and effects of proposed changes to design at the submittal stage and during construction.

Jan 1, 2003

The 28th annual American Mining Hall of Fame Awards Banquet and fundraiser sponsored by the Mining Foundation of the Southwest will be held at the Marriott University Park Hotel, Tucson, AZ on Saturday, Dec. 4, 2010. The Mining Foundation of the Southwest is a nonprofit organization whose objectives are public education about the mineral industries, and recognition of outstanding accomplishments in and contributions to the fields of mineral and fuel resources. Funds are being raised to the support the foundation?s educational programs. Among these is the Educational Outreach Program operated jointly by the foundation and the Arizona Department of Mines and Mineral Resources.

Jan 1, 2010

By Shankar S. Hegde

In many areas of the United States much of the most readily minable coal is nearing depletion, while at the same time, increased national attention is being given to coal as a major alternate energy source. If some of the thinner, more erratic, deeper and lower quality coals, which comprise the great bulk of U.S. resources, are to be mined efficiently and economically, greater attention must be devoted to careful planning of mines and to preparation facilities. One of the cornerstones to careful and successful mine planning is precise knowledge of coal thickness and areal distribution, roof and floor quality, and seam quality. Data on which this knowledge is based are obtained from various borehole techniques and, in some cases, seismic methods. Despite the many technical innovations that have been made in acquiring subsurface data, little attention has been given to the problem of systematic storage and retrieval procedures of the data and assembling them in a form that can be used for various computer mapping programs now available. (See Bilter and Martin, 1977; Bryant and Zobrist, 1977 and Farrell and Wherry, 1978). The purpose of this paper is to describe a series of user oriented programs developed over the past five years which are specifically designed for precise logging of rock core, accurate storage and retrieval of this data, correlation of seams between logs, tagging seams, computer assisted data posting of maps and preparing maps and profile sections for report illustrations. The entire system stresses increased precision and speed for a series of operations which are now largely manual, time consuming and prone to error.

Jan 1, 1980

By Osvaldo Bascur, Barun Gorain, Jaco Steyn

"The last few decades have seen some remarkable advancement in information technology, but recently various digital technologies have resulted in several synergies to deliver innovation in diverse applications. The mining industry has been relatively slow in adopting these technologies compared to the other industries, but this scenario is changing fast.Challenges. Mining companies globally are going through a series of challenges such as declining ore grades with complex metallurgy, increasing depth of ore bodies, high capital and operating costs, lower productivity, shortage of technical resources, significant pressure from stake-holders to deliver, along with growing environmental and corporate social responsibility issues. Improvement in profitability would need significant improvements in operational performance.Consequently, over the last few years, there has been a major focus among some mining companies to imbibe operational excellence. This has been only possible because of the replacement of a silos-based approach by an integrated view of the organization. Such an integrated view is now possible via the evolving digital technologies. Even so, such a transformation calls for a change in culture, which, for most organizations is not trivial. Attempts in the past to integrate functions, such as through mine-to-mill initiatives in the mining industry, have demonstrated significant benefits to many operations (McKee, 2013). Still, sustaining these benefits has clearly been a challenge due to manpower turnover and lack of proper systems and structures that integrate information between business functions within an operation and between operations and the corporate level.Opportunities. The advent of digital technology has opened up opportunities to integrate interdepartmental information for a unified understanding across an entire organization. The advances in instrumentation, equipment control systems, supervisory control systems (SCADA/ Historian) and industrial networks have helped in the direction of enterprise- wide integration. The availability of real time information across an enterprise has given rise to numerous possibilities to improve organization performance. As suggested by Seshan and Gorain (2016), some of the potential opportunities are as follows:"

Jan 9, 2018

By Innocent John Arinze, Chidubem Okwudiri Emedo

This contribution presents the first multi-scale geophysical investigation conducted in the Abakaliki and Obubra mining districts (AOMD), southeastern Nigeria, for the exploration of shallowly emplaced (< 50 m) massive sulfide and barite mineral deposits. Raw airborne magnetic data covering the AOMD was acquired and subjected to diverse enhancement routines to facilitate the identification of areas of subtle magnetic anomalies for subsequent ground truthing. The mineralization is mainly made up of galena, sphalerite, and barite. The contrasting physical properties between these minerals and their host rocks make resistivity, induced polarization (IP), spontaneous potential (SP), and magnetic methods ideal to study and delineate the mineralization and possibly locate the ore bodies. Wenner DC resistivity and IP data acquired along the same parallel traverses are inverted using Res2dinv to produce 2D tomography models of resistivity and chargeability. The resistivity and IP models were successful in delineating zones of sulfide and barite mineralization. The ground SP data collected along the same traverses as the resistivity and IP data were interpreted as line graphs. The 1D SP models show a number of central negative anomalies that could be related to sulfide mineralization. These anomalies show fair-to-good spatial continuity and are in close agreement with the result obtained in the resistivity and chargeability model. This study suggests the presence of exploitable mineral deposits in the AOMD and demonstrates the superior interpretative ability of combined geophysical methods over a single geophysical approach.

Oct 20, 2020

By Theodore H. Eyde

In 1971, the Minerals Division of The Superior Oil Company acquired exploration rights to an unpatented claim group in the Superior (Pioneer), Arizona mining district, lying west of the Concentrator fault. This major post-mineral fault displaces the Magma vein-fault, which is mined in the Magma Mine at Superior, Arizona. The Magma vein-fault and the enclosing section of pre-mineral rocks consisting of Paleozoic and younger Precambrian sediments and diabase, is overlain by a thick section of post-mineral rocks, consisting of the Gila conglomerate, the Apache Leap dacite, and the Whitetail conglomerate. Geologic information on the thickness and attitudes of the rocks obtained from previous diamond drilling indicated that the section of post-mineral rocks might be from 3,000 to over 4,010 feet thick in the target area. (Figure 1) The Magma vein-fault is a steeply dipping vein which has produced nearly a billion dollars of copper, zinc, silver, and gold. It has been mined continuously for nearly 10,000 feet along the strike and nearly 5,000, feet vertically down the dip. It ranges from less than a foot to over 50 feet wide and contains sulfide mineralization con¬sisting of pyrite, chalcopyrite, bornite, and chalcocite.

Jan 1, 1973

By T. R. Kostecki, A. J. S. Spearing, G. S. Esterhuizen, K. V. Jessu

Discontinuities are geologic occurrences in rock and when present within a pillar, reduce the strength of the pillar. Empirical formulas that are commonly used to determine pillar strength do not explicitly take into account the presence of discontinuities and thus can overestimate the pillar strength. The effect of discontinuities on the strength of pillars has been investigated using numerical models, but in these models, the discontinuity strike was parallel with the pillar faces. In this study, fully three-dimensional hard rock pillars were simulated using numerical modeling to understand the effect of the discontinuity dip direction on square and rectangular hard rock pillars. Based on the results, recommendations to assess a pillar’s strength in the presence of a discontinuity are discussed.

Jan 1, 2018

By A. Gungor

Thermal treatment can significantly improve industrial comminution operations by reducing energy requirements and increasing mineral liberation. The assistance of thermal pretreatment prior to grinding by microwave heating is scrutinized in this study. For this purpose three copper ore samples with different chemical composition were used. To see the effect of microwave heating on ore; work index, breakage rate and breakage distribution functions of original and heat treated samples were examined. The results obtained in this study did not show significant improvement in the grindability characteristics of the studied ores with microwave heat treatment. The inadequate amount of microwave transparent matrix was the main reason for the absence of cracks and micro-fractures in the microwave heated copper samples.

Jan 1, 1999

By A. Khoshnevisan

Molybdenum resources around the world are mainly associated with porphyry copper ores. Molybdenite (MoS2) is the main Mo mineral that has rhenium in its crystal lattice. This paper investigates the recovery of rhenium and molybdenum from a molybdenite concentrate using a hydrometallurgical treatment method. The molybdenite concentrate is leached with nitric acid and subjected to solvent extraction to recover and separate rhenium and molybdenum from the leached liquor. The effects of pH and the chemicals? concentration on extraction characteristics of Mo and Re are investigated to define the best condition for selective extraction of these metals. The tested leached liquor contained of 8.2 g/L Mo, 1.5 g/L Fe, 0.5 g/L Cu and 60 ppm Re. A good extraction efficiency, up to 94%, was achieved for Re from the leached liquor, where the extraction of other metals, such as Fe and Cu, was negligible. In particular, at very low pH, rhenium is extracted selectively from solution, while the extraction of molybdenum is less than 10%. After removing rhenium, molybdenum was extracted with LIX984N. The selectivity of molybdenum extraction over other metals in solution was significant. Nearly 94% of molybdenum can be extracted from the solution at a pH value of -0.12, without any interference from other metal ions such as copper and iron.

By D. Zim

Mining activity in South America is a growing enterprise. One of difficulties found in many areas of the South American continent, especially in north Chile and south Peru, is the shortage of water supply. In order to overcome this difficulty some mining companies proposed to transport the water from Pacific Ocean up to the mountains. This can be accomplished by the use of stainless steel pipelines, but this is a cost prohibitive solution and is also subject to severe pitting corrosion in a saline environment. The use of mild steel may be a lower cost solution than stainless steel as the material of construction for pipelines but it is subject to corrosion anyway. The corrosion in this case can be internal or external corrosion although cathodic protection as well preventive maintenance usually is enough to mitigate external corrosion without the need to shut down the pipeline. The same is not true about the prevention of internal corrosion. It is not practical, sometimes not even possible, shutdown a pipeline to carry out an inspection and fix sections where potential failures are detected. It is possible avoid corrosion caused by sea water within the mild steel pipelines by applying a proper chemical program designed to virtually eliminate dissolved oxygen in the water commonly called deaeration.1 This type of treatment obviously involves additional capital investment since it requires the construction of one deaerator with the first pumping station and additional equipment at each point where the water can come into contact with oxygen. Deaerators will increase operational costs and subsequent injection of chemicals will be required in the case of multiple degasification facilities thus increasing the consumption of chemicals. grams based on oxygen scavengers, the objective of the present study is to develop a new water treatment capable of preventing mild steel corrosion in aerated sea water. The new treatment must be able to prevent both generalized and localized (pitting) corrosion and overcome the necessity to construct and operate deaerators.

Feb 23, 2014

By Praterm J. D.

The process parameters for effective utilization of nitric acid as an oxidant for copper-iron sulfides have been developed. Leaching variables found to be important were acid concentration, temperature, time, atmosphere, pressure, mineral type, particle size, and percent solids. Particular attention was devoted to analysis and control of fumes evolved during the oxidation. Responses recorded were metal extraction, elemental sulfur formation and oxidation, product gas composition and evolution rate, reagent consumption, and residue flotation response. The paper concludes by laboratory testing a flow sheet based on the above observations. Ninety-eight percent of the copper contained in a chalcopyrite-bornite concentrate was recovered, requiring 1. 6 pounds of nitric acid to be regenerated externally per pound of copper extracted. Iron remained in the leach residue as hydrogen jarosite and was ultimately rejected from the system by froth flotation. Sixty percent of the sulfur contained, in the heading concentrate reported in the elemental form; the remainder was oxidized to sulfate and eliminated with the hydrogen jarosite in the flotation tails or by neutralization of the solvent extraction raffinate with lime. Nitrogen was evolved primarily as NO and NO2; up to 3 percent N2O was also present. Gases containing sulfur were absent except when pyrrhotite was solubilized in the absence of soluble copper. In this case, H2S was evolved.

Jan 1, 1972

By D. J. Englund, R. A. Davis

"A three-dimensional CFD model of a straight grate furnace for indurating iron-oxide pellets was developed for exploring conditions of furnace operation for fluid flow, heat transfer and reactions. The model includes reactions for natural gas combustion in the gas phase and calcination and magnetite oxidation as well as drying in the pellet bed. The performance of the model was investigated with a series of pellet production rates that included adjustments to the fuel rates to achieve proper induration temperatures in the pellet bed. The model may be used to discover opportunities for process improvement.IntroductionIron oxide pellets are a feedstock to blast furnaces for iron making. Pellets require physical strength characteristics needed to maintain their integrity during storage, handling, transportation and smelting. Pellets are produced from iron ore in a series of mineral processing operations that form wet green balls from slurries of iron-ore concentrate with binders, such as bentonite, and possibly fluxing-agents such as limestone and dolomite. The green balls are dried, fired at high temperature, and then cooled in an induration furnace to achieve the strength and chemical composition required for efficient reduction and slag separation in blast furnaces. Induration furnaces are generally straight grates or grate-kilncooler configurations. These furnaces operate with pellet beds passing through a series of temperature zones to control drying and chemical reactions in the bed.Process air passes through the zones in an overall counter flow direction to the pellets for efficient heat transfer and energy recovery from the cooling stage. Consequently, the zone conditions and the overall furnace performance are highly coupled. Thus, it becomes challenging to predict how changes to any single zone may affect the rest of the furnace. To gain a better understanding of machine performance and coupling, a three-dimensional, steady-state model of a complete straight grate induration furnace was created using computational fluid dynamics (CFD)."

Jan 1, 2015

By Jessica M. Wempen, William G. Pariseau, Dallan J. Coons, Michael K. McCarter, Erik C. Westman

The abstract discusses the importance of proper pillar sizing in underground mining for safety and efficiency. It highlights the use of theoretical models, geotechnical measurements, and numerical modeling in predicting pillar behavior. The research focuses on using seismic tomography to image stress changes in a yield pillar at a longwall mine as the longwall face approaches. The study aims to compare the stress distribution imaged using tomography with theoretical models, geotechnical measurements, and numerical models.

Mar 18, 2022

By Yousef Ghorbani, Abolfazl Danesh, Fatemeh Kazemi, Ataallah Bahrami, Morteza Abdollahi

The abstract highlights the impact of flocculants used in the middle thickener of a copper-molybdenum plant on both process water quality and molybdenite floatability. The study investigates the effect of a starch-based flocculant (wheat starch) on the efficiency of the middle thickener and molybdenite flotation. The findings indicate that the presence of starch influences the settling behavior of particles with different shapes, and the dosage of starch affects both molybdenum recovery and the presence of copper minerals in the molybdenum concentrate.

Mar 7, 2022

By Angela Binder, Mareike Schubert, Yichen Jiang, Sandra Nowosad, Oliver Langefeld

GermanyINTRODUCTIONThe mining industry is currently characterized by various factors such as environmental impact, resource scarcity, social responsibility and geopolitical uncertainty. The production of minerals required to meet the demand for renewable energy is expected to increase by 500 % by 2050, particularly for critical minerals such as graphite, lithium and cobalt 1. Easily accessible deposits are often depleted, meaning that deeper and more complex deposits need to be developed. Furthermore, investors’ value systems have shifted towards more sustainable practices. Alternative approaches to solving this problem are therefore currently being developed, such as the Modular Mining Systems concept for scalable and adaptable mining projects 2. Many mining companies have also taken important steps to become more sustainable, implementing measures such as proactive closure strategies, restoration programs and the development of renewable energy projects. In the European Union, laws such as the Critical Raw Materials Act and the Net Zero Industry Act support the mining industry 3,4. They see it as important for the energy transition and promote more sustainable ways of working in the industry Particularly negative environmental impacts such as land degradation, scarcity of local water resources, water pollution and greenhouse gas emissions are ingrained in society’s memory. Despite these efforts, the public image has not yet changed. To change this perception, the industry must strive to better communicate its sustainable practices and the steps it is taking towards a more responsible and sustainable future, promote transparency and build trust.Digitalization, automation and electrification are driving the digital transformation in mining. However, their implementation can lead to higher capital expenditure, limiting their adoption across the industry. Furthermore, implementing new technologies can be a daunting task for any organization. Change management comes into play when introducing such disruptive technologies. It involves preparing an organization for change, potential resistance and establishing effective communication. This helps to ensure that the implementation is successful and the benefits of the new technology are maximized. Digital transformation requires well-trained, young mining, electrical, mechatronic and software engineers with a deep understanding of information systems. Unfortunately, the industry faces the enormous challenge of attracting this younger generation, who have little interest in the extraction of raw materials. The need for action is compounded by an aging active workforce heading into retirement and the forecast of increasing demand for critical minerals.In this challenging environment, the concept of Blue Mining with its constant further developments represents a promising approach. This implies a shift from a linear to a sustainably oriented circular economy. For the mining industry, this specifically means the introduction of innovative technologies, the increased recovery of materials from waste and the consistent questioning and application of circular principles along the entire life cycle of a mine. Such a change can not only reduce the environmental impact, but also contribute to economic resilience and increased social acceptance of mining.

Feb 1, 2025

By Sahin Furkan Sahiner, Onur Golbasi

Effective maintenance planning is vital for coal mining operations, where haul truck fleets directly determine production continuity. This study presents a discrete event simulation (DES) model for evaluating maintenance strategies under multiple failure modes and their interdependencies. The model integrates corrective, periodic preventive, and opportunistic maintenance, dynamically updating equipment lifetimes through probabilistic time-betweenfailure and time-to-repair distributions. Applied to a fivetruck coal haulage fleet over a one-year horizon, results show that periodic preventive maintenance delivers the highest availability (76%) under unconstrained conditions, slightly outperforming corrective-only maintenance (75%). Opportunistic and integrated approaches performed worse (68% and 69%), reflecting redundancy from overlapping interventions. These findings suggest that structured preventive programs provide the most reliable outcomes when costs and resources are not limiting. The DES framework serves as a baseline for future models incorporating cost, spare parts logistics, and workforce availability, supporting robust maintenance planning in coal mining operations.

Feb 22, 2026