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By N. Sacks, N. B. S. Magagula, I. Botef

"Low-pressure cold gas dynamic spraying was used to deposit WC-4wt%Ni and WC-4wt%Ni-1wt%Mo coatings onto mild steel. Dense coatings with very low porosities were produced. No decarburization occurred during deposition and no deleterious phases were formed. The coatings were subjected to standardized material characterization tests, as well as slurry abrasion testing to assess their wear behaviour. The wear tests were conducted in synthetic minewater-silica slurries, while distilled watersilica slurries were used as a control. The hardness of the coatings, 512HV0.3 and 458HV0.3 for WC-4wt%Ni and WC-4wt%Ni-1wt%Mo respectively, are comparable to those achieved using high-temperature coating processes. The abrasion wear rates for both coatings were less than 5 mg/min and 10 mg/min in the distilled water-silica and synthetic mine water-silica slurries respectively. The approximately 50% increase in wear rate in the synthetic minewater slurry is attributed to a synergistic corrosive wear mechanism. The predominant wear mechanisms were identified as binder smearing and delamination, with carbide grain fracture and pull-out. IntroductionSlurry abrasion is a common phenomenon in mining operations, particularly in pipelines transporting, for example, sand-water slurries. This type of wear can cause pipeline fracture, shortened operational lifetimes, and impede pipeline efficiency. To reduce or limit abrasion, thermally sprayed tungsten-carbide-based coatings are often used as pipe linings (Kanchan et al., 2010). This is due to their attractive mechanical properties, which include high wear resistance, stiffness, hardness, compressive strength, and tensile strength. These properties are provided by the coating microstructure and composition, which is a blend of hard, wear-resistant tungsten carbide (WC) particles embedded in a fracture-tough metallic binder phase (Brookes, 1997). Cobalt (Co) is the most commonly used binder due to its excellent wetting of the WC phase and moderate mechanical properties; however, its application is limited to non-corrosive environments as it has a low corrosion and oxidation resistance (Andren, 2001). Nickel (Ni) may also be used as a binder, and has been shown to have superior oxidation and corrosion resistance, but in some applications may not have the required mechanical properties (Kim et al., 2006)."

Jan 1, 2016

By Y. Qin, L. Han, P. Gao, Y. Han, Y. Lia

In the present study, an innovative comminution technology of high-voltage pulse discharge was proposed for galena to weaken the mechanical property. The results of pre-treatment experiments indicated that the optimal operating conditions of spherical gap spacing 25 mm, pulse numbers 120, and loading voltage 25 kV were obtained, where the relative grindability of pretreated products was improved significantly, although with the prolonging of grinding time, the superiority of high-voltage electric pulses was gradually weakened. The galena ores were subjected to a high-voltage pulse discharge, and then the crack generating along the boundary between galena and gangue was observed under an optical microscope, and the surface burning which appeared in the ores. The scanning electron microscope (SEM) results indicated that the pretreated products were in a state of melting and then condensation, accompanied by some pore formation. Pulsed discharge pre-treatment not only produced more micro-cracks and cracks in the sample but also extended the original crack. Keywords: High-voltage pulse discharge; galena; relative grindability; micro-crack

Jan 1, 2020

By S. Langea, H. Lieberwirth

Impact crushers are common machines in comminution plants. Their high size-reduction ratio and relatively simple design, make them a preferred tool even when subjected to harsh wear, and producing a large quantity of fines in some applications. Until now the alignment of the operational parameters was an operator’s responsibility. Due to the random process characteristic this is mostly done based on empirical values and sensor data, such as power consumption. This paper describes a new approach for online process monitoring of the horizontal-shaft-impact crusher. The application of robust, low-cost acceleration sensors enables the permanent observation of the process characteristics. The operational and evaluation methods are determined on the basis of experiments. Subsequently the recorded measurements are analysed in regards of throughput, rotational speed and product particle size distribution. Occurring signal characteristics are described based on physical and technical principles. The measured data of the acceleration sensors at varying operation conditions provide insight in the course of process. The accurate utilisation yields the determination of the preferential process conditions providing the best balance between the pros and cons of an impact crusher. Both the experimental method and the data processing is discussed from a scientific perspective, displaying a completely new approach for the operation of impact crushers. Keywords: Impact crusher, acceleration sensors, data processing, particle size

Jan 1, 2020

By N. Madani, S. Abulkhair

In multivariate geostatistics, it is common to have different types of complexities between variables of interest. In this context, an inequality constraint is an example of complex bivariate relationships. Unfortunately, traditional co-kriging and co-simulation algorithms cannot reproduce this type of bivariate complexity, leading to the overestimation of disturbing elements. This paper proposes a new algorithm based on a hierarchical sequential Gaussian co-simulation framework, integrated with inverse transform sampling, to model inequality constraints between variables. First, the proposed methodology's validity was evaluated by applying it to a real case study from an iron deposit, with an inequality constraint between iron and aluminum oxide. Then the simulated results were compared with a conventional hierarchical co-simulation algorithm to investigate the effect of inverse transform sampling on the quality of the co-simulation. The results showed that the proposed algorithm can reproduce an inequality constraint between variables.

Sep 1, 2021

By E. Marè, D. R. Groot, R. Engelbrecht, T. Coetsee

Hydrogen peroxide is often used as an oxidising agent in experimental waste electronic equipment (WEE) leaching work. However, the high cost of peroxide is a negative factor in its consideration in further process development. A few studies have reported on the efficient application of peroxide addition schedules to ensure optimum reagent consumption. Large quantities of unleached substrate material contained in WEE feed material result in a large dead volume of material in the leaching reactor. This factor necessitates fast reaction rates to enable the use of a high feed material throughput reactor to enhance overall project viability via hydrometallurgical processing. In this study the effects of hydrogen peroxide addition schedules on base metal leaching efficiency and solution temperatures were tested at laboratory scale. The results showed that overall peroxide consumption can be optimised to lower levels by matching peroxide additions to the particular feed material’s leaching behaviour. A simplified integrated model for peroxide decomposition is used to explain its effect on solution temperatures and leaching rates. Keywords: Peroxide consumption, waste electronic equipment, copper leaching, integrated model

Jan 1, 2020

By T. M. Chagwedera, A. E. Lewis, J. Chivavava

Eutectic freeze crystallisation is a novel separation technique that can be applied to treat brine solutions such as reverse osmosis retentates, which are often a mixture of different inorganic salts. The treatment of calcium sulphate-rich brine solutions through eutectic freeze crystallisation has resulted in gypsum scale formation on the walls of the crystallisers and ancillary equipment. In order to prevent gypsum scaling on equipment surfaces, it is essential to understand the mechanism of gypsum scaling on cold surfaces. This paper focused on the interaction between gypsum crystallisation in the bulk solution and scaling on the crystalliser walls in the presence of gypsum seeds. A cooled, U-shaped stainless-steel tube suspended in the saturated solution was employed as the scaling surface. Preliminary results showed that the scale layer was predominantly composed of needle-type and hexagonal prismatic crystals. The rate of scale deposition was highest during the first 24 hours, thereafter it decreased. A thin scale layer was observed to have coated the tube within the first hour of the experiment. Seeding, using reagent grade gypsum crystals, was effective in reducing scale layer formation through providing a surface for growth. The highest scale reduction, 81%, was realised at a seed loading of 0.50 g/L. At a high seed loading of 4.01 g/L, the seed material adhered to the tube. Keywords: Gypsum, eutectic freeze crystallization, seeding, scaling, cooling crystallisation

Jan 1, 2020

By M. Ericsson

?Rare earths ?will not be bargaining instruments?? was stated in a headline in China Daily of 29 October 2010. The Chinese government is trying to fend off the persistent accusations from Japan, the USA, and Europe that it is manipulating the supply of these so called ?critical? metals to gain political and economic advantages. The critics maintain that China has taken the rest of the world hostage by controlling 97% of the resources of rare earths. These elements are crucial in a number of high-tech applications. They are not impossible to substitute, but difficult to do so effectively. The name ?rare earth? is a misnomer, as even the least abundant is 200 times more common in the Earth?s crust than gold. They are, however, difficult to find in economic concentrations. The Chinese near-monopoly over the rare earths, together with China?s scramble for other resources in Australia, Africa, and elsewhere around the world, is seen as an example of a Chinese strategy to take control of vital metal resources. The Chinese are also accused of using unfair and sometimes illegal business practices in this fight for resources. Practices which, critics claim, put the Chinese interests above the interests of the host countries, in particular in Africa.

Jan 1, 2011

By G. M. Evans, S. Mitra, A. V. Nguyen

As an alternative to the conventional flotation method, there has been continual research in an effort to enhance base metal ores and combustibles recovery using ultrasonics. These studies however were largely limited to the pre-treatment of ores for the removal of surface contaminants while the effect of ultrasonics on the bubble and pulp-phase interactions remained somewhat unexplored. Noting this deficiency, this study aimed to investigate the mechanistic effect of an ultrasonic field in an impeller less flotation cell specifically focusing on the bubble-particle interaction dynamics. A lab-scale flotation cell (capacity 1 litre) was designed, involving a vertically oriented ultrasonic probe (20 kHz, rated at 1.2 kW) and operated in the output power range from 1 to 20% with continuous liquid recirculation. Particle suspension was achieved by the combined action of recirculation and ultrasonic pulses. Interactions of coarse size glass ballotini particles (D32 = 314 μm) with bubbles (< 1 mm diameter) in the presence of a surfactant were studied, using high-speed imaging. Application of an ultrasonic pulse in the aqueous medium resulted in the generation of numerous microbubbles which increased with increasing input power and duration of the ultrasonic pulse time. Such periodic pulses introduced at a high level of turbulence in the pulp phase facilitated adequate bubble-particle contacts. Microbubbles played a key role in forming particle clusters which were observed to be floatable even in the absence of any carrier bubbles. When carrier bubbles were introduced, some of these particle clusters attached to the bubble surface and conveniently floated. It was noted that a favourable state of bubble-particle interaction was achievable to produce stable bubble-particles aggregates by suitably controlling the input power and period of the applied ultrasonic pulse. Keywords: Flotation, bubble-particle interactions, collision, attachment, detachment, ultrasonic pulse

Jan 1, 2020

By J. Engelbrecht

Understanding the deportment of minerals in size fractions has already led to improvements in the flow sheets for platinum minerals beneficiation. There are, however, more potential changes in the flow sheets that may improve the recovery of platinum group metals or reduce the costs of beneficiation before refining. Based on known technology of pre-concentration, milling, gravity concentration, flotation, and magnetic separation a number of potential alterations or additions can be considered and motivated based on the mineral deportment in size fractions.

Jan 1, 2012

By M. Royker

Gold has been demonstrated as a possible catalyst for oxidation reactions. Some evidence for a possible promotion effect of platinum has also been recorded. The influence of platinum as promoter for Au/?-Al2O3 prepared via anionic ion-exchange for the oxidation of glycerol was investigated in a batch reactor at 60°C. It is inferred that the addition of platinum reduces the catalytic activity and the rate of deactivation, resulting in an overall higher final conversion of glycerol with increasing platinum loading. The addition of platinum to the catalyst favours the formation of the desired product, glyceric acid.

Jan 1, 2012

By G. Sánchez, S. Seiler, B. Klein, T. Cebeci, P. Bradshaw

The Decar Nickel District is a greenfield discovery by FPX Nickel Corp., of nickel mineralisation located in central British Columbia (BC), Canada. The Baptiste deposit is part of the Decar Nickel District and is a unique deposit containing a nickel-iron alloy mineral called awaruite, with over 2-billion tonnes of inferred resource grading 0.12% Davis Tube Recoverable (DTR) nickel. This deposit represents a significant nickel resource. Awaruite is a high density and ferromagnetic mineral, which could be recovered, along with magnetite that is also present in the samples, using magnetic separation. However, there is still a lack of understanding of the properties of the awaruite and its metallurgical response. This information is imperative for the set-up of the variables involved in its concentration. The aim of this paper is to show and discuss the effect of magnetic field strength for the recovery of nickel from Baptiste deposit samples. Magnetic separation at bench and pilot scale with different magnetic field strengths is evaluated as a concentration method for awaruite. Mineralogical information is provided to support the results and also to briefly assess the variability of DTR nickel within the deposit. The Baptiste deposit is unique and will benefit from a sound scientific understanding of the process solution as well as other ongoing work. If successful, the outcome will lead to the development of a mine. With greater than 2-billion tonnes of inferred resource, the mine would represent a significant new source of nickel globally. Keywords: Nickel ore processing, magnetic separation , awaruite, magnetite

Jan 1, 2020

By Z. L. Xue, J. L. Li, X. Y. Wang

"In low-carbon energy-efficient basic oxygen furnace (BOF) steelmaking processes, limestone partly or completely replaces the active lime. The effects of limestone calcination temperature (1200–1500°C) and time (5–15 minutes) on lime reactivity and CaO grain size were investigated. The reactivity was evaluated by titration with hydrochloric acid, and the CaO grain size was analysed using scanning electron microscopy. The results revealed that for calcination temperatures higher than 1300°C, the reactivity reached a maximum and then decreased . The higher the temperature, the earlier the peak of reactivity appears. The CaO grains grow with increasing temperature and time, which leads to the decrease of reactivity. Notably, the effects of temperature on CaO grain size and reactivity are more marked than that of time. To obtain active lime calcined at ultra-high temperature by flash heating, the calcination conditions should be 1300–1400°C for 10–15 minutes, or 1400–1500°C for 8–10 minutes. IntroductionLime is one of the most important slag-making materials for dephosphorization and desulphurization in the basic oxygen furnace (BOF) steelmaking process. The reactivity of lime is a measure of its capability to take part in slag-making. Lime having a reactivity of more than 300.0 mL (4 N HCl), determined by hydrochloric acid titration is generally referred to as active lime (Rusjan et al., 2007; Zeman, 2008). At present, the active lime used for BOF processes comes primarily from a kiln or shaft kiln, where limestone is preheated at 700– 900°C, and then calcined at 1050–1200°C (Drenhaus et al., 2010; Oates, 2007)."

Jan 1, 2016

By S. Liaghat, J. Rosenkranz, P. Semsari Parapari, S. Chehreh Chelgani, A. Tohry

It is commonly accepted that the energy consumption for comminution within mineral processing is responsible for around 3% of the global electrical energy usage. However, it was clearly noted that inside mills, less than 1% of this energy efficiency is actually consumed for particle size reduction. Therefore, monitoring of grinding parameters and modelling of product particle size distribution (e.g. characterised by the 80% passing size P80) play an essential role in operating costs of a mineral processing plant. Several empirical models have been introduced for the prediction of the P80. Since in the industrial scale usually a few numbers of grinding variables are monitored, these models cannot identically be used in plants. In addition, these empirical models do not always indicate the magnitude of correlations between milling variables. This study proposes to introduce the Hilbert-Schmidt independence criterion (HSIC) as an intelligent model for exploring linear and nonlinear relationships between grinding variables and P80 for an industrial scale data assessment. HSIC can rank variables based on their importance and help to select the most effective one for the generation of predictive models. HSIC modelling through various monitored grinding variables (ball charge, feed input rate, F80, power draw and work index) of an industrial plant indicated that F80 as a feed property has the highest effect on P80 of the ball mill products. Modelling results highlighted that the P80 can be accurately predicted, based on effective variables by using a HSIC model. These outcomes showed that HSIC as a powerful modelling tool can assess the relationships between monitored grinding parameters, select the most effective grinding parameters and satisfactorily predict the P80. Keywords: Product particle size, variable importance measurement, Hilbert-Schmidt independence criterion, mill charge

Jan 1, 2020

By K. Barani, F. Moradpouri, M. Godarzi

A sampling campaign carried out on the lead flotation circuit at Lakan lead-zinc processing plant demonstrated that the Pb recovery was only about 68-69%. Characterization of the Pb flotation tailing showed that 61.4% of the Pb is in the –37 μm size fraction, which is difficult to recover by flotation. Batch flotation experiments were carried out on a plant sample of the lead flotation feed and high-intensity conditioning (HIC) was used to improve flotation recovery. The results showed that increasing the collector conditioning time from 1 to 3 minutes significantly increases the Pb recovery from 42.5% to 57.3%. Further increases in conditioning time to 5 to 7 minutes decreased the Pb recovery. With a collector conditioning time of more than 3 minutes, due to the surface cleaning effect, increasing collector and frother dosage improved the flotation selectivity and recovery, even at higher collector dosages. The Pb recovery increased from 69.1% to 79.8% with increasing impeller speed from 600 to 1250 r/min. HIC increases the flotation kinetics and greatly improves the flotation recovery and concentrate grade.

Apr 2, 2022

By G. J. McTeer, D. J. Rioux

Teck Metals Ltd operates an integrated zinc-lead complex at Trail, British Columbia, Canada. Since 1997, KIVCETTM flash smelting technology has been utilized for the treatment of zinc plant residues and lead concentrates. Trail Operations’ furnace uses four water-cooled jackets for bullion tapping. This paper provides an overview of KIVCET bullion tapping for the past 16 years, and discusses successes and challenges encountered with respect to operations, training, and monitoring.

Jan 1, 2014

By K. H. Zhang, Y. P. Gao, J. Q. Zhao, Q. Li, J. C. Ma

Compared with sinusoidal oscillation, non-sinusoidal oscillation enhances the ability to control waveform and meets different oscillation requirements by adding an independent parameter, which is the key technology for high-efficiency continuous casting. A new waveform of mould non-sinusoidal oscillation is proposed in this paper, that is, a velocity waveform that is composed only of straight lines and parabolas, which not only has good dynamic characteristics, but also further enhances the feature of non-sinusoidal oscillation. Compared with sinusoidal oscillation, the negative strip time is reduced by 15.9%, the maximum negative strip velocity difference is increased by 38.3%, and the maximum positive strip velocity difference is decreased by 27.8%. The formulas of oscillation process parameters can be clearly deduced, and the isoplethic curves of oscillation process parameters when multi-parameter simultaneously changes are drawn. The negative strip time decreases as the modification ratio, frequency, and casting speed increase, but increases as stroke increases. In order to maintain the stability of negative strip time, an oscillation synchronous control model for optimising oscillation basic parameters was developed. Through practical application, the mean oscillation mark depths decreased by 10.1 μm and the flux consumption is increased from 0.37 kg/t to 0.45 kg/t in the non-sinusoidal oscillation model, which meets the requirements of normal production.

Oct 24, 2025

By K. Esmeli, A. Ozkan

The enhancement of shear flocculation of a galena suspension by ultrasound in the presence of sodium isopropyl xanthate and potassium ethyl xanthate was investigated by studying the effects of surfactant concentration on flocculation efficiency, contact angle, and zeta potential. Strong flocculation was obtained under alkaline conditions (pH > 9) and a high ultrasound power level (150 W). Although the ultrasonic treatment increased the negativity of the zeta potential of the galena particles, this did not decrease the flocculation efficiency, thereby showing that the hydrophobic interactions between the particle were stronger than the electrical double-layer repulsion resulting from xanthate adsorption. The findings indicate that the ultrasonic treatment promoted the adsorption of surfactants onto the mineral surfaces.

Jul 5, 2023

By M. R. L. Blackwell

Over the period 1964 to 1969 Conzinc Riotinto of Australia undertook and completed an evaluation of a large low-grade copper orebody on Bougainville Island in the Territory of Papua and New Guinea. From the outset it was clear that the geographic, climatic and topographic characteristics of the area would necessitate a heavy capital outlay on production and support facilities. Both the physical problems and the magnitude of the investment amplified the need for a thorough and rigorous evaluation of the various strategies for exploiting the orebody. In view of the number of independent and inter-related variables and the flow of new data, a computer-based evaluation process extended the scope and depth of the analysis considerably. The system used permitted an iterative assessment and re-assessment of the various strategies with the results becoming increasingly refined with time. This process encompassed the modelling of the orebody, the simulation of alternative operating strategies and the determination of the financial profitability of the project,

Jan 1, 2014

By G. Mucsi, F. Kristály, R. Szabó

Kaolin is one of the most important ingredients in porcelain manufacturing. Its main phase is clay mineral containing aluminum hydrosilicate, namely kaolinite. Beside kaolinite it also contains quartz, illite and feldspars, which impair its applicability. Kaolin is a non-reactive material, but metakaolin can be produced by heat treatment (calcination) of kaolin, which is also used by the cement and concrete industry due to its latent hydraulic (pozzolanic) properties. Beside thermal activation, reactive materials can also be produced by mechanochemical activation in general. This paper deals with the mechanochemical activation of kaolin. The raw material was classified into various size fractions, then ground in a batch stirred media mill under varying circumstances (residence time, circumferential velocity). After grinding, the structural changes of the products were investigated by X-ray diffractometry (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). In addition, the particle size distribution of the ground material was determined by laser scattering. As a result of the grinding experiments and analytical measurements of the products, it can be clearly seen that reactivity of kaolin can be improved significantly by mechanical activation in a stirred media mill, but due to its high energy density the circumstances were optimised carefully to avoid aggregation. Keywords: Kaolin, grinding, stirred media mill, mechanical activation, material structure

Jan 1, 2020

By P. L. Moolman

An approach to the design of a tailings disposal system is presented using an example from a platinum project on the eastern limb of the Bushveld Complex as a base case. The design is driven by two inputs: namely, maximizing water recovery and minimizing power cost, expressed as cubic metres and kilowatts per ton of solids deposited on the tailings storage facility respectively. The approach considers low-, medium-, and high-density platinum tailings and uses material-specific aspects such as thickening and rheology to determine the most economical option. An analysis based on direct capital and operating cost (water and electricity) shows that the medium-density scenario results in the lowest total cost per ton of tailings deposited, even though this system results in the highest electricity consumption per ton of tailings deposited. As the cost of water and electricity is likely to increase in the future, the higher-density tailings disposal options become more economical, with the paste option the preferred option.

Jan 1, 2012