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By Xin Tan

In this paper, two types of low-grade complex zinc oxide ores (sandstone and limestone ores) from Yunnan province, China were investigated. A large number of argillaceous and alkaline gangue makes it infeasible to treat the ores with heap leaching. Although wet metallurgy can be considered, the lower efficiency of liquid-solid separation, the high cost, and low revenue limit this technology to be put into practice in large-scale. In order to solve this problem, a new technology combining mineral processing method with metallurgy technique is studied to process this refractory ore that consists of sandstone ore with 5.84 per centZn and limestone ore with 6.50 per centZn. The results of the tests showed that zinc can effectively be recovered from two types of the ores by using the new technology, and the acid consumption can be remarkably reduced. For sandstone sample, 82.96 per cent Zn was recovered by flotation and final Zn recovery by flotation+ hydro-metallurgy can be up to 78.17 per cent from the ore. In addition, for sandstone, acid consumption can be reduced from 270kg/t by direct acid, leaching to 76.92kg/t by flotation + hydrometallurgy combination. For limestone sample, 85.90 per centZn was recovered by flotation and totally 80.95 per cent Zn can be recovered by new technology which is a combination of mineral processing and metallurgy. Besides, H2SO4 consumption can be reduced from 450kg/t for sandstone originally to113.79kg/t after using new technology. One merit of this new process technology is that the zinc sulfides and oxides can be recovered without desliming in the flotation cells at the different stage and make sure the concentrate products as a good feed for hydrometallurgical technology. This study provided pretty good technical support for tapping low-grade refractory zinc oxide ores. Keywords: low-grade zinc oxide ores, limonite, non-desliming beneficiation, flotation + hydrometallurgy combination

Sep 1, 2012

The objective of the paper is to develop a material balance calculation procedure for a production unit involving two plants separated by a pipeline. The case study is taken from the oil sands industry. The raw sands are first mixed with water in a conditioning plant, then transported through a pipeline to an oil extraction plant. The combination of pipeline dimensions and nominal throughput creates a significant variable time lag between the two plants. As usual, mass balance calculations required for the evaluation of plant performance indicators, such as bitumen recovery, are inaccurate due to measurement errors. In addition, in the present case study, the time lag of the pipe creates an additional source of uncertainty, which may lead to misinterpretations and wrong decisions. Raw data are usually reconciled through steady-state mass balancing, to correct for measurement errors. However, because of the significant pipeline dynamic lag, standard steady-state daily mass balance may fail at giving an appropriate picture of the operations. The proposed solution to the data reconciliation problem includes the use of a pipeline plug-flow model in the mass balance calculation. To fulfil the industrial constraint that current data reconciliation must not modify past reconciled values, while still satisfying dynamic constraints, a daily one-step method, i.e. a unitary filter-ing horizon, is recommended. The method is illustrated with simulation data, and the results com-pared to those of standard data reconciliation methods.

Jan 1, 2014

By Guanghua Ai, Xiong Huang, Huashan Yan, Ting Li, Tingsheng Qiu

"Cyanide tailings of gold and silver concentrates contain considerable quantities of copper-lead-zinc sulfide minerals that can be recovered. However, the strong inhibition effect of cyanide often makes it difficult to recover these sulfide minerals effectively. In this research, a sample of cyanide tailings was investigated based on the principles of process mineralogy; activating flotation tests were carried out for the target minerals in the tailings, and the activation mechanism of the activator and its influence on the target minerals were investigated by Fourier transform infrared spectroscopy (FTIR). Mixed flotation of copper and zinc was carried out using QJ-01, a combined agent containing sulfite, as the activator of copper and zinc minerals, and ammonium dibutyl dithiophosphate (ADD) and butyl xanthate (BX) as the combined collector. Copper concentrate was obtained from the mixed concentrate by using a combined inhibitor of sodium sulfide and zinc sulfate to inhibit the zinc mineral. Zinc concentrate was extracted from the copper tailings by using copper sulfate as the activator and BX as the collector. The flotation test yielded copper concentrate with a grade of 22.56% and recovery of 76.96%, and zinc concentrate with a grade of 42.56% and recovery of 82.29%, which shows that comprehensive recovery of the sulfide minerals – copper and zinc –from the cyanide tailings was realized. The FTIR analysis showed that CN- was chemisorbed on the surface of chalcopyrite and sphalerite following cyanide treatment, while the combined activator QJ-01 containing sulfite reduced CN- into SCN- and weakened the complexing ability of CN- with metal ions on the mineral surface, thus achieving a good activation effect on chalcopyrite and sphalerite. The results of this study can provide practical guidance in increasing the resource utilization ratio of cyanide tailings in gold mines, and thus contribute to alleviating environmental problems caused by stockpiling cyanide tailings. INTRODUCTION Cyanidation, the most widely used technology for extraction of gold, has several advantages such as high recovery, process maturity, low cost, etc. According to available data, the annual discharge of cyanide tailings from China's gold mines exceeds 20 million tons (Li et al., 2011). Lower grades of exploitable gold ore entail increased discharge of cyanide tailings. Huge quantities of cyanide tailings are regarded as waste and stored, resulting in significant wastage of land resources. Moreover, residual beneficiation reagents, cyanide ions, and heavy metal ions in cyanide tailings cause severe pollution of water and land (Laitos et al., 2013; Donato et al., 2007; Mudder and Botz, 2004). In addition, cyanide tailings often contain valuable elements such as gold, silver, copper, lead, zinc, sulfur, and iron, which, if not recycled, would result in considerable wastage of resources. Hence, it is imperative to study the reduction and safety of cyanide tailings, and the mineral resources present in them."

Jan 1, 2018

By Sunil K. Tripathy

Particle characteristics such as size, density, liberation and magnetic susceptibility play vital role in magnetic separation technique. To understand the performance of magnetic separation process for chromite beneficiation industry, particle characteristics need to be analysed. However, to date, this has been an expensive and time consuming task, thus only minimal amounts of this type of data are available in the literature. Several new methods are being developed, that will produce the required mineralogical and liberation data to provide processing information rapidly and inexpensively. Among these, QEMSCAN is a unique and advanced characterisation equipment used for liberation analysis for different ore whereas S.G. Franz Isodynamic Separator for determining the magnetic susceptibility. In Indian chromite deposits, the content of iron bearing minerals in the ore is typical which controls the Cr:Fe ratio in the product while treating in gravity based beneficiation plant. In the present investigation, detailed characterisation of two distinct chromite ore samples from Sukinda chromite deposit, India, was investigated which includes advanced mineral characterisation using QEMSCANand magnetic susceptibility measurement by using Frantz Isodynamic separator, etc.. Presence of haematite and gibbsite along with chromite mineral were identified as major gangue minerals in the high grade ore from XRD pattern whereas Goethite, Quartz, Haematite, Kaolinite, Ringwoodite identified in the low grade ore. The mass magnetic susceptibility of low grade ore is very high 5.2 cm3/g compared to 2.7 cm3/g for high grade ore, due to the presence of abundant quantity of iron bearing minerals. Subsequently, these two types of ore were subjected for magnetic separation for improving Cr:Fe ratio by using different magnetic separators viz. induced roll magnetic separator, wet high intensity magnetic separator, rare earth roll magnetic separator, rare earth drum magnetic separator. The results of magnetic separation studies indicated that, Cr: Fe ratio of the chromite ores can be improved to 3.99 and 1.97 from the feed assaying 3.09 and 1.29 respectively. Studies on rare earth roll magnetic separator indicated that both the ores were upgraded to a maximum Cr:Fe ratio level at optimised condition. Keywords: characterization, QEMSCAN, magnetic separation, rare earth roll magnetic separator, industrial mineral, chromite

Sep 1, 2012

By V. A. Chanturiya

The results study the minerals oxidation were obtained by us during the methods of microscopic, FT-IR spectroscopic, XRD and chemical analyses of sulphides in tailings of copper-nickel wastes in Kola peninsula. Sulphide minerals begin to oxidize already at the stage of stockpiling and initial stages of storing. The proportion of non-ferrous metals and magnesium oxide increases with time, calcium partially precipitating in the form of gypsum. Comparison of heavy metal contents in pore solutions in cur-rent and stale copper-nickel ore concentration tailings has revealed a significant difference in practically all the parameters. The lower metal contents in current tailing pore solutions (by 5~30 times) are probably due to the presence of float reagent residues blocking oxidation. Much lower concentrations of magnesium and calcium can be accounted for by the difference in kinetics: the rate of sulphide oxidation at this stage is much higher than that of solution interaction with non-metallic minerals as the result of which the solid phase ? solution equilibrium is not achieved. It is generally believed worldwide that it the mining wastes with acidic pore solutions that pose the greatest hazard for the environment. Our findings suggest that although the solution pH in all the samples is higher than 7.8, the contain heavy metal concentrations by far exceeding permissible values. The direct determination of the total and silicate Ni contents in the tailings from current production and in storage tailings has shown that both sulphide and silicate Ni forms occur in tailings. However, the role of silicate Ni is much larger in the storage tailings. The average silicate Ni content accounts for 10% of the bulk Ni content in the current tailings and it increases to 40% in the storage tailings. Thus, the storage tailings are marked not only by sulphide oxidation and the removal of water-soluble sulfates, but also by the interaction of sulfates with the silicate matrix. Although complete equilibrium is not achieved even within 30 yr under polar-region conditions, the major part of the Ni in fine-grained fractions passes into silicate form. The probability of Ni transition to the silicate form directly correlates with the dispersion of the material and the amount of chemically reactive serpentine and hydrochlorite. The migration of Ni as sulfates and its precipitation by chemically active silicates distorts the distribution of this component in the coarse- and fine-grained fractions that are typical of tailings from the current production of copper-nickel ores. On the one hand, the variation of the mode of Ni occurrence in storage tailings lowers the value of technogenic raw materials as a source of this metal.

Jan 1, 2014

By L. S. Bbosa

Single particle impact breakage experiments provide essential data to aid in understanding of rock fracture in comminution. Such experiments, conducted using devices such as the drop weight tester, split Hopkinson bars and more recently the rotary breakage tester, have been successfully used to characterize ore breakage properties in relation to measured fracture energies. The work presented in this paper highlights the techniques behind the calculation of impact breakage properties from each of these three devices. The breakage parameters that can be calculated from experimental data from each of these are to be described. Drop weight tests are used to calculate A and b hardness parameters using the standard JK breakage model. Split Hopkinson pressure bars are used to establish the ultimate compressive stress of particles through single impact breakage tests and the fraction of impact energy utilized to cause particle fracture. Low energy breakage tests using the rotary breakage tester are shown to be used in calculating particle breakage probability. Methods to calculate parameters related to particle breakage probabilities such as E0 and Ecrit are also discussed.

Jan 1, 2014

By Y. G. Sun

This paper mainly reported separation manganese silver oxidized ores process by amylum de-gradation reduction and its influencing factors. When dosage is given according to nMn : nH2SO4 : n(C6H10O5)n : nH2O=1:k21.8: k116.66:30, the amount of up to 95.93% Mn leach rate and less than 2% silver loss can be obtained. Cyanidation process was used to extracted silver from leaching Mn residues. Silver leach rate could reach 94.15% at consumed amount of 1kg/t NaCN for 1h. Silver leach recovery rate was more than 92.27% by leaching Mn and cyanidation two-step processes so manganese and silver were separated effectively.

Jan 1, 2014

By B. Rai

Aluminum is produced by the Hall-Héroult process, which involves passing a current through a molten mixture of alumina dissolved in cryolite (Na3AlF6) to reduce the alumina to aluminum. This process occurs in an electrolytic cell comprising a steel shell lined with a carbon cathode and refractory bricks. After a certain period of operation, the carbon cathode deteriorates and is removed from the cell along with the refractory bricks. These removed materials are referred to as spent pot lining or ?SPL?. Typically, 30 Kg of SPL waste is generated for every ton of Aluminum produced. Globally aluminum smelters produce more than 500,000 tons of SPL each year. Even though SPL has a high fuel value (8000 to 9000 BTU/lb) and contains valuable metals, it is classified as a hazardous material due to its cyanide content and leachable fluorides. Various disposal/recycle techniques have been developed over the years for SPL but none of them is satisfactory. Thus, large quantities of SPL are still being dumped in landfills. In some countries, even the land filling of SPL is not permitted. The safe disposal of SPL thus remains a challenging problem to the aluminum industry and the search continues to find methods of converting SPL into a non-hazardous waste and/or recovering the valuable materials contained in the SPL. We have developed a process to produce hydraulic setting cements (eco-cement) containing a novel fluoride rich cementitious phase, from SPL by an energy efficient, low temperature clinkering route. A raw mix blend of SPL, lime/limestone, calcium sulfate and tailings sands based on a set of design criteria developed by us, is clinkered in a two stage process; 2 hours soak at 800 °C followed by clinkering at 1000 °C for another 2 hours, to produce a soft clinker. The SPL eco-cement is made by grinding the clinker to a fineness of 5000 cm2/g Blaine with 1% by weight borax as a set retarder. A good quality cement having as high as 20 % by weight of SPL in the raw mix (28 % by weight in the cement clinker) is thus produced. The physical properties of the SPL cements are found to be comparable to the Indian standard (IS) specifications for Ordinary Portland Cements (OPC). We have produced the cement in a few Kg batches and tested the reproducibility of results from batch to batch for further scale up. Once commercialized, this process has a potential of converting SPL into value-added cement products. Keywords: cement, spent pot lining, clinkering, fluoride, aluminum, ordinary portland cements

Sep 1, 2012

By J. Qiu

By means of natural sedimentation, two different bentonite samples from Shandong province were purified, this paper studies the Hydro-properties of the two purified montmorillonite samples. Firstly, the layer charge of two purified montmorillonite samples were calculated by crystal structure formula reckon method and general hydro-properties were also measured. The research results showed that the layer charge of montmorillonite correlated well with its hydro-properties: mont-morillonite with lower layer charge had better hydro-properties, such as Mont-1, which had higher swelling volume and gelling value with lower CEC; while, montmorillonite with higher layer charge had worse hydro-properties, such as Mont-2, which had lower swell volume and gelling value with higher CEC; it proves that the hydro-properties of montmorillonite depends on its layer charge characteristics, layer charge characteristic is the inherent factors deciding the hydro-properties of montmorillonite, montmorillonite with lower layer charge has better hydro-properties than the one with higher layer charge. In this paper, the relation between the medium condition and colloid performance of Mont-1 are also studied. The results show that the hydro-properties of Mont-1 could be changed by changing slurry concentration (w/w) and shear rate or adding certain amounts of inorganic cation electrolytes, dispersants and surfactants. The viscosity of montmorillonite slurry could be enhanced by increasing slurry concentration,adding univalentcation electrolytes (less than 4% w/w) or proper amounts of dispersants and surfactants (less than critical micelle concentration); The slurry viscosity could be reduced by decreasing slurry concentration, increasing shear rate, adding proper bivalent (more than 4% w/w) cation electrolytes or proper quantities of dispersants and surfactants (more than critical micelle concentration).

Jan 1, 2014

By D. P. Chakraborty

Joda East Iron Mine, one of the captive iron ore sources of Tata steel, located in the state of Odisha in eastern India caters to approximately 45% of the iron ore requirement of the Jamshedpur Steel Plant. The iron ore occurring in the mine having high in iron content along with high in alumina. Clay and gibbsite are the predominant mineral phases present as surface coating, fracture filling and/or free occurring and are responsible for alumina content higher. Alumina in iron ore impacts the techno-economic performance of a steel plant by impacting sintering and blast furnace productivity. The impact is even higher when it comes to fine ore used in the blast furnaces in the form of sinter as it constitutes a major portion of the blast furnace burden. Therefore, it is beneficial to upgrade iron ore in the mine head and to reduce alumina before it is subjected to agglomeration. Mineralogical test works reveal, that alumina in iron fines is mainly associated with the clay attached to the hematite particles, either free or interlocked to a very fine size. The paper describes the efforts made to reduce alumina in the iron fines in Joda East processing plant, without much of capital investment for a very sophisticated fines beneficiation circuit. In this process, a suitable dispersant was added in the plant that dispersed the masked slime coating over the iron ore fines, thereby making a better quality iron ore fines with reduced alumina content. The alumina in fines improved by 0.2 units? means from a label of 2.4-2.6 % reduced to 2.2-2.4 %. With this initiative, not only the primary objective of alumina reduction is met but also it has given substantial benefit in reduction of silica and as well as moisture in product. This moisture reduction also has given bottom line impact by reducing idle freight and royalty.

Sep 1, 2012

By Heramb M. Bal

This paper will underpin the future development of intellectuals having greater understanding of patent law and legislation, IP rights, and innovation. To understand this idea, I present a case study of China?s progress in the last 31 years in the rare earth research, innovation, and simultaneously patents area. Rare earth elements (REE) are at the centre of high technology and are the next wave of world innovation. Much of modern society depends on rare earth elements through their use in computers, lasers, telecommunications, iPods, medical technology, military applications, and so on (Long et al, 2010). The rare earth research, a large research body is being provided by Chinese sources. China devoted three or four university centers to the study of rare earths (Lifton, 2009). These measures are all designed to keep China at the forefront of REE production, materials, technology, and innovation. As a result in the last fifteen years there has been a shift from a US-dominated REE industry patents to Chinese patents. The world must identify strategic areas of rare earth innovation and provide funding to firms and universities that conduct such research. Not only research and innovation is vital but filing patents and preserving IP rights for research and innovation is even more important. We (rest of the world) need a comprehensive strategy to guide the development of patent and IP rights for research and innovation. To achieve this, the development of intellectuals with superior knowledge of patents and IP rights are the future need of minerals industry. Keywords: innovation, rare earth, patent, IP rights

Sep 1, 2012

By Kevin Galvin, James Dickinson

"The Reflux Flotation Cell (RFC) consists of an inverted fluidized bubbly bed, located above a system of parallel inclined channels. This novel arrangement enhances the hydrodynamics of flotation in a number of ways. Firstly, the free-surface of the flotation cell is enclosed via a fluidized bed distributor, ensuring uniform application of wash water to promote desliming. Secondly, foams can be variable in their stability and lack permeability. Hence this system is preferably operated in the absence of foam, instead opting for a bubbly zone of high bubble volume fraction through the use of a very high gas flux and/or wash water flux. Discharge of the product proceeds upwards through a central port of narrow cross-sectional area. Thirdly, the system of inclined channels increases the segregation between the bubbles and the water, ensuring the bubbly zone remains contained within the upper vertical zone, and the liquid flux reporting to the overflow is low. The expanded operating regime of the RFC was investigated by covering a very broad range of gas fluxes, up to 5.5 cm/s, and wash water fluxes, over 2 cm/s. Both laboratory and pilot plant performances were quantified by the recovery of hydrophobic particles and rejection of the hydrophilic particles, using model and industrial coal feeds. The new system hydrodynamics was found to offer significant advantages in flotation kinetics, desliming, and particle recovery across a broad particle size range. Bubble interfacial flux reached as high as 600 m2/m-2s-1. The upper system consists entirely of a high volume fraction of bubbles, which provides a "safety-net" to protect against the detachment of coarse particles, and a highly permeable zone for counter-current washing of the flotation product. Under relatively extreme conditions selective stripping of the product is observed, resulting in grade recovery values beyond those achievable using the tree flotation method."

Jan 1, 2014

By Yi Ran Zhang, Nawoong Yoon, Brent Hilscher, Maria Holuszko

"Ore sorting technology has been rapidly advancing in recent years. Improving expected mill feed grade has a significant benefit to project returns, and can no longer be ignored. When there is an increase in the mill feed grade while maintaining the same throughput, the mine will be able to process much more metal and improve the floatation recovery. There are many more factors that contribute toward the economics of the project by implementing sensor-based sorting technologies covered in this paper. This paper reviews the economic impact on an underground copper-silver deposit with references to the concept of ""profit recovery,"" which is the measurement of recovery based on rock profitability rather than just metal content. The economic impact of sensor-based sorting is discussed in detail throughout the paper. The preliminary economic evaluation of the project compares the mine's base case design versus a design incorporating sensor-based sorting. The paper's primary focus is on economic impacts rather than the explanation of the sensor based sorting results. The sorting data is presented on a scoping level and using a sensor-based sorting study where the best possible results are used for obtaining the grade recovery curves. Also, the breakdown and analysis of the project economics are based on the operating cost available from the particular operation. Any assumptions taken into consideration are also outlined and discussed. INTRODUCTION The mining industry has been adopting Sensor-based ore sorting technology fairly rapidly in the recent years. The ability to increase mill feed grade by rejecting waste grade rocks early in the processing stage is proving to be revolutionary for some operations. These potential outcomes should not be overlooked by both producing operations and prospective projects, thus leading to a wide range of studies on ore sorting. The answer to this is the creation of a new term and concept - Profit Recovery™."

Jan 1, 2018

By I. Nishkov, I. Grigorova, N. Valkanov, M. Ranchev

The processing of sulphide ores with variable and complex mineral composition and physical properties, such as those processed by two-stage selective flotation scheme in “Erma reka” concentrator, Minstroy Holding JSC, requires excellent selectivity in order to achieve acceptable concentrate grades. The lead-zinc ores from the hydrothermal lead-zinc deposits mainly contain galena (PbS), sphalerite (ZnS), pyrite (FeS) and chalcopyrite (CuFeS2), as well as non-metal minerals such as quartz, carbonates and clinopyroxenes skarns. One of the main impurities present in sphalerite is iron, which is known to be detrimental to the rate of sphalerite flotation and its recovery. The results from the conducted laboratory and industrial tests, presented in the previous study, showed that it is possible to depress the iron rich sphalerite by adding MINFIT® (modified sulfur-oxy depressant) at the pH of approximately 9.5 in rougher lead flotation circuit, leading to reduction of zinc sulphate consumption and complete elimination of cyanides from the flotation process. Furthermore, the consumption of copper sulphate, which reactivates the surface of the zinc minerals, was significantly reduced. Consequently, the optimisation of the reagent regime in the Erma reka concentrator, led to notably improved qualitative (grade, recovery) properties of the final lead and zinc concentrates. Moreover, when comparing the reagents consumption for 2014 and 2016 – when the processing plant have been applying the new optimized reagents regime, comprises the use of MINFIT as the primary depressant, the following results have been achieved: ZnSO4 decreased by 30%; CuSO4 consumption decreased four times and full rejection of cyanides from the process. Finally, this paper provides a state-of-the-art review of the obtained results during the period of application of the new flotation reagents regime in the Erma reka concentrator, Minstroy Holding JSC.

Jan 1, 2018

The ultimate goal of a mineral processing plant is to recover as much of the target mineral(s) as possible from the ore being treated to achieve the best economics. Selection of the mineral processing techniques is the most important step in achieving this goal. However, due to the complexity of the ore, the recoveries of valuable minerals may be not satisfactory even when the mineral processing technique(s) are well chosen. In other words, minerals of interest can be lost to the tailings for mineralogical reasons. For example, gold is mainly extracted from the ore by gravity, flotation, cyanidation, or a combination of these processes, and high recovery (>90%) can be achieved when gold occurs as coarse grains. However, when a refractory ore is being processed, gold extraction will be challenged by mineralogical factors, which often cause gold losses to various tailings. Mineralogical factors affecting gold recovery mainly include grain size, shape, surface coatings and rimmings, presence of cyanicides, oxygen consumers and preg-robbers, presence of slow-dissolving gold minerals and the refractory nature of submicroscopic gold. Among these factors, locking in sulphide, silicate and other minerals as fine-grained gold inclusions and/or as invisible submicroscopic gold is by far the most common factor leading to poor gold recovery encountered in gold ore processing. Processing of PGE ores faces the same challenges as gold. Small grain size and locking of PGM in sulphide and non-sulphide minerals often cause PGM losses. When silver ore contains significant amounts of pyrargyrite, proustite and stephanite, silver recovery by cyanidation can be very low because of the slow dissolving kinetics of these minerals. In the processing of base metal ores, high content of pyrite, intergrowth of chalcopyrite with sphalerite and presence of clay miner-als may cause problems in recovering Cu-, Pb- and Zn- bearing minerals. Process mineralogy helps address all issues and problems related to mineral processing with predicting and trouble-shooting being two major objectives. It provides useful information on process selection, flowsheet development, recovery improvement and reagent consumption optimization. The information acquired from a process mineralogical study can be used as a guide for a metallurgical testwork program for process design or optimization.

Jan 1, 2014

By A. Vilinska

Microorganisms have a tremendous influence on their environment through the transfer of energy, charge, and materials across a complex biotic mineral-solution interface. Recent developments in biotechnology have not only aided hydrometallurgical leaching operations but also shown great promise in mineral beneficiation processes. The adhesion of bacteria on minerals alters the surface properties relevant to flotation and flocculation of minerals. The biomodification of mineral surfaces occurs through the attachment of microbial cells, oxidation reactions and adsorption or chemical reaction with the metabolite products. Several types of heterotrophic and chemolithotrophic bacteria have been successfully applied in flotation and flocculation processes for the last two decades. Al-though the potential of microorganisms in minerals beneficiation has been realised by several re-searchers from their laboratory investigations, the studies were mostly confined to pure mineral systems and there is hardly any sincere effort to apply the methodologies on ores. This paper presents a brief summary of the literature in bioflotation and bioflocculation, and attempts to outline new dimensions of research for a practicable application of this technology in mineral industry.

Jan 1, 2014

This article takes the OMRON C200HE PLC for example introducing its application in mica-paper production equipment, including style selection, address assignment of I/O point, and programming for different function. In the transformation process of simulated data and digit data, the corresponding relations between two data and so on are also discussed.

Jan 1, 2014

By Y. S. Song

Flotation separation of galena, sphalerite with pyrrhotite in ethanoic acid + sodium acetate sys-tem was studied in this paper. The flotation tests show that galena and sphalerite can float but pyr-rhotite can hardly float in the pH range of 3.6 to 5.6 in ethanoic acid + sodium acetate system. The flotation tests also show that galena can be separated efficiently from pyrrhotite and sphalerite can be separated on the whole from pyrrhotite, but the separation efficiency of the former is much better than the latter. The flotation results have been investigated by ultraviolet spectrum and XPS analysis, and explained by theory of hard and soft acid and base (HSAB), hydrogen bond and galvanic coupling.

Jan 1, 2014

By Chandra Sekhar Gahan

The present study aimed to investigate the depyritization of coal using iron oxidizing and sulphur oxidizing acidophilic chemolithotrophic microorganisms in an iron free 9K growth medium at varying pulp densities. Three different coal samples used in the shake flask study from three different countries such as domestic anthracite (Korean), Indonesian and Chinese lignite. Experiments were carried out in batch at a controlled temperature of 35 °C and varied pulp densities of 8%, 10% and 12% (w/v) with a working volume of 100 ml containing 10 ml of microbial inoculum and 90 ml of the iron free 9K growth medium. Coal samples were crushed and ground to fine size fractions <100 microns by attrition mill wet grinding. The progress in the experiments were followed by the regular measurements of pH, redox potential, viable planktonic cell count, residual Fe2+ ion concentration, amount of acid addition and amount of slaked lime addition. The pyritic sulfur removal percentage varied between 90-95% with highest sulfur removal with China coal (95%) followed by Korean Coal (93-94%) and slightly lower level for Indonesia coal (90%). However the pyrite oxidation was highest for Korean coal ranging between 78-80% followed by a similar level of pyrite oxidation of 50-61% for the Chinese and Indonesian coal. It was found that 10-12% pulp density would be fairly feasible for all the different coals tested leading to an economical process. Another benefit from this study is the iron free 9K growth medium, which will reduce the operation cost and overall it?s an environment friendly process.

Sep 1, 2012

By Sravya Kosaraju, Christian Ekberg, Stefan Allard

Li-ion batteries are now used in electric vehicles (EVs), plug-in hybrid vehicles (PHEVs) and, hybrid electric vehicles (HEVs). Nanostructured Li(NiyMnzCo1-y-z)O2 is one of the more popular cathode chemistries for automotive Li-ion battery, due to its enhanced properties such as large surface area, short diffusion length, enhanced ionic and electronic conductivity, improved mechanical strength and structural integrity [Pan et al, 2013]. Recycling of Li-ion batteries helps to mitigate environmental effects of virgin metal extractions along with improper disposal of end of life batteries. To fulfill these objectives of the recycling, recovery of pure streams of the involved metals should be considered. In this study, the batteries were first discharged and dismantled in an inert atmosphere (Ar). The electrodes were then heat treated in a box furnace. This was done in order to break the chains of the adhesive (PVDF) and consequently separate the metallic substrates Cu and Al from the electrochemically active compound. This heat-treatment also helped to simplify the dissolution of the metal constituents in the electrochemically active compound from the cathode in the acid leaching process. Solvent extraction was chosen to achieve separation and recovery of metals with higher purity from these leachates. In the scope of the present work, a complete process from the point of dismantling to separation of constituent metals using solvent extraction was studied.

Jan 1, 2014