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By C. L. Reichardt

Pressure exerted on gold producers by regulators, project financiers and civil society in the wake of the Baia Mare tailings spill in Romania during 2000 prompted most responsible gold companies to sign up to the International Cyanide Management Code for the Manufacture, Transport and Use of Cyanide in the Production of Gold (the Code). The Code stipulates a ?cradle to grave? approach more comprehensive than that applied to any other mining reagent and poses particular challenges for operators who use cyanide-bearing tailings for backfill. This paper examine some of the challenges for Code compliance facing deep underground gold mines that employ backfill technology, most particularly the requirement to demonstrate that the potential migration of cyanide (and its degradation products) from emplaced backfill will not have an unacceptable impact on worker health and safety or the receiving environment, either during mine life or after closure. Although the Code only contains a single reference to backfill, more careful consideration confirms that most sections of the Code that deal with tailings management are potentially applicable to mines where tailings material is used for backfill, as are certain principles pertaining to aspects of operations, worker safety, emergency response, training and dialogue with stakeholders. For gold mines of the Far West Rand, the most significant cyanide-related risks associated with backfill operations relate to worker exposure to cyanide-bearing seepage and HCN gas. There is potential for seepage of cyanide-bearing water from backfill to compromise the beneficial use of surface and groundwater, and thus impact on downstream users and ecosystems. However, the extreme depth of mining and the specific geological and hydrological controls on the Far West Rand suggest that the potential environmental risks associated with backfill are likely to be considerably less significant than the cyanide-related risks to the workforce.

May 1, 2007

By Kari Niiranen, Andreas Boehm

LKAB (Luossavaara-Kiirunavaara AB) is operating underground iron ore mine, with three beneficiation and pelletizing plants in Kiruna, Northern Sweden. The wet low intensity magnetic separation (WLIMS) is regarded as the crucial part of silicate mineral separation from the ore. The Kiirunavaara iron ore deposit shows a rather low content of silica (ca. 2.3 to 3.3 % SiO2) but the silica grade is expected to increase in the deeper parts of the deposit. This can be problematic in the case of DR pellet quality with an average silica grade under 0.75 % SiO2. A laboratory scale methodology was developed for the systematic characterization of the ore for mineral processing with the focus on silicates at the Institute of Mineral Processing, University of Leoben. This methodology is combining mineralogical, geochemical and process mineralogical characteristics. Automated mineralogy (QEMSCAN) was used to study the modal mineralogy, the distribution of silicate minerals in different particle size classes after comminution, the deportment of silicon (Si) between various silicates and degree of liberation and intergrowth of magnetite and silicates. Based on the mineralogical investigations, actinolite, phlogopite and even quartz and albite are the predominating SiO2 bearing minerals in the ore. The important result of the investigations was the discovery of two separate subtypes within the high silica ore type B2 based on their mineralogy and mineral processing characteristics. The crucial part of the investigations of intergrowths and liberation of magnetite results was the magnetic separation tests carried out with the Davis magnetic tube. The binary intergrowths of magnetite and the silicate minerals (mostly actinolite) are the most common type of mineral association discovered. The significant characteristics in the intergrowths of magnetite and actinolite are the fine-grained magnetite inclusions in actinolite which may end up increasing the SiO2 grade in the magnetite concentrate despite magnetic separation.

Jan 1, 2016

By Eiichiro Mizushima

Catalyst systems comprising (Ph3P)AuCH3 and acid co-catalysts were found to be highly efficient for hydration of alkynes to give ketones. Methanol was the best choice of solvents. Introduction Hydration of carbon-carbon unsaturated bonds is one of the environmentally benign routes to the carbon-oxygen bond formation. Hydration of alkynes forming carbonyl compounds, an important variation in this category, is a well known reaction which has been extensively studied. The reaction by acid-catalysis is the most conventional method, while it is applicable only to electron rich acetylenes to obtain satisfactory yields (1,2). The hydration of simple alkynes usually requires another catalyst (co-catalyst), typically a mercury(II) salt (3), which is inconsistent with the guiding principle of Green Chemistry (4).

Oct 1, 2003

By Georges Houlachi, Akram Alfantazi, Michael Mahon, Maysam Mohammadi

Corrosion resistance of the lead-based anodes directly influences the purity of the final product in the zinc electrowinning process. The anodic MnO2 layer that is electrodeposited on the anodes during this process can protect the anodes against corrosion. Sand-blasted anodes generate a uniform, adherent and shiny MnO2 layer, which gradually blisters and eventually sloughs off after several weeks. In this study, we attempted to develop a new method to stabilize the MnO2 protective layer on the anodes during the electrowinning process by providing suitable nucleation sites for electrodeposition of this layer. MnO2 particles (P80=40µm) were used as seed material for this purpose. Different techniques of galvanostatic and cyclic voltammetry polarizations, scanning electron microscopy (SEM) and atomic absorption spectroscopy (AAS) were employed to investigate the performances of the MnO2-seeded lead anodes. The experimental results showed that growth of the MnO2 layer is influenced by the MnO2 seed particles on the anode surface. The MnO2 layers electrodeposited on the MnO2-seeded lead anodes were uniform and strongly adherent to the substrate. This layer was more stable than those formed on the PbAg anode without MnO2 seeding. This could provide the anode with a higher level of corrosion protection. Moreover, formation of undesirable MnO2 mud in the electrolyte and the rate of manganese consumption were decreased when the MnO2-seeded lead anodes were polarized. These observations could be attributed to the different properties of the electrodeposited MnO2 layer on this anode in comparison with that formed on the PbAg anode.

Jan 1, 2016

By J. J. Gillman

"The coal deposits from Cape Perce on Cape Breton Island have been known to supply the coal requirements of the people living in or visiting the area for close to 300 years.A major block of coal has been identified off Cape Perce, which has several seams from which coal can be taken. The initial development by the Cape Breton Development Corporation will be in the Harbour Seam and constitutes the Donkin-Morien Development Project.The CBDC's confidence in this indicated resource is based on its knowledge of the Sydney Coal Field and from boreholes driven into the block during the summers of1977, 78 and 79. In 1980, further geological data were gathered from surface drilling and an intermediate-depth high-resolution seismic survey. The surface facilities for the Donkin-Morien Development Project will be located on the northern half of the cape, with access declines extending 3.9 km in a north-northeasterly direction to the Donkin block of coal reserves. The development has the potential of supplying all the coal needed f or the future electrical power generation requirements of Nova Scotia for many years to come.The planned mine, for which a project definition study has recently been completed, will have a production rate in excess of 3 million tonnes per year.IntroductionAt the Second CIM District 1 Meeting held in Halifax in October 1980, a background paper on Phase II of the Donkin-Morien Development Project was presented. The project involves a 3.2-million-tonne, saleable, underground coal mine. At that time, the chronological sequence of events had unfolded, starting with the initial boreholes through to the feasibility study, and on through site clearing and site preparation. This led to engineering design contracts for the portals and the two tunnels to be driven to intersect with the Harbour Seam close to 4 km from their entry point."

Jan 1, 1982

By R. Siwik, N. K. Davé

"The national reactive tailings (RATS) program is a co-operative industry-government effort to develop practical techniques for closure of reactive tailings areas. This paper summarizes the RATS program objectives and areas of research, and details the Noranda/CANMET project on the Waite Amulet tailings.Geophysical and biohydrogeochemical investigations were carried out at an inactive copper-zinc mine tailings site, Waite Amulet, in Noranda, Quebec. Geophysical investigations consisted of seismic, electromagnetic conductivity and electrical resistivity surveys to determine the thickness of the layers above bedrock and to map conductivity variations within the tailings and the immediate outlying area. Biohydrogeochemical investigations consisted of installing multilevel piezometer nests to determine groundwater flow patterns and porewater chemistry, obtaining solid core samples and characterizing for physical, chemical and mineralogical parameters, and iron oxidizing and sulphate reducing bacterial counts.The geophysical survey indicated a bedrock ridge extending under the tailings from the northeastern outcrop which may act as a porewater boundary layer. The survey also indicated a 2 to 20 m clay layer underlying the main tailings dam. Preliminary results of the saturated zone porewater chemistry have indicated three major zones of high electrical conductivity varying between 1,000 to 12,000 µs and pH between 3.4 to 8. Lower pH and high metal and sulphate concentrations were obtained in a shallow zone near the water table. With depth, the concentration of metal and sulphate ions decreased and pH increased below the water table. The underlying clay layer is relatively impervious -and most of the seepage from the tailings is probably exiting from the sides of the impoundment dam."

Jan 1, 1987

By O. Moselhi

Material can be seen as the fuel needed to execute the project from inception to completion. Material installed provides good indicators of progress achieved onsite vis-a-vis project schedule performance. It correlates well with the role of the schedule performance index (SPI) of the earned value method (EVM). Material is recognized to have a significant impact on achieved progress for physical completion of project activities. This paper presents a study on the development of material status index (MSI) in support of the EVM. Unlike the SPI, the newly developed index account for the criticality of project activities. This is carried out considering the total float of each activity, percent float (i.e. the ratio of float to activity duration) and the total float of the path on which the activity is located. MSI, can independently and jointly with SPI provide root causes behind problems encountered during project execution. In turn MSI can reveal material related factors behind the performance detected by joint interpretation of the two indices. MSI serves to provide added value in alerting management to take corrective actions. While SPI and MSI may have different values, they can jointly augment and enrich the captured project status based on EVM. To demonstrate the capabilities of the developed MSI method, it is implemented on a case study. The case encompasses the construction schedule of a hydro power station constructed in northern Quebec. Different scenarios are adapted from the real case to demonstrate a set of practical aspects of the developed index. The results generated from the analysis of the case study illustrate the useful features of MSI beyond those of the traditional SPI on two fronts; causation and the considerations of criticalities of actives.

Aug 1, 2013

By Ros Taplin

Realizing the potential of cutting greenhouse gases (GHGs) associated with mining, a variety of approaches has been proposed for their mitigation. The Clean Development Mechanism (CDM) under the Kyoto Protocol to the UN Framework Convention on Climate Change (UNFCCC) has been a key mechanism to assist in implementation of mitigation measures. The objectives of CDM are not only to assist Annex I countries in meeting their GHG emissions reduction targets with cost-effective reduction but also to achieve sustainable development in non-Annex I countries. However, apart from China, India, Brazil and Mexico, many developing countries are still in the stages of formulation or realizing CDM strategies. Projects associated with methane capture and flaring are the fourth most prevalent type of CDM project internationally. This research primarily has addressed emissions abatement and sustainable development aims and effectiveness of registered CDM projects associated with coal mining in China. The paper reviews 30 currently registered CDM projects in China on the UNFCCC database and six other non- Chinese projects. Systematic evaluation involving content analysis of documentary evidence regarding coal mining CDM projects is presented in relation to firstly, quantitative reduction of GHG emissions and secondly, sustainable development outcomes. The projects have been assessed via a set sustainability criteria. Overall it was found that sustainable development goals are only briefly referred to in Project Design Documents, Letter of Approvals and validation documents. Varying types of sustainability initiatives have been implemented with weak to strong indications of effectiveness. This has implications for the future effectiveness of CDM projects in the mining sector, the proposed new market mechanism under UNFCCC, and for assessment of projects under mechanisms established outside the UNFCCC.

Aug 1, 2013

By Brennan Lang

Why Seal Tunnels? ?Restore groundwater levels to pre-mining conditions. ?Saturate rock mass to reduce acid rock drainage. ?Reduce discharge flow to the environment. ?Reduce or regulate flows to a water treatment plant.

May 1, 2002

By DALE MacGREGOR, VERA TUREK

The Blue Mountain nepheline syenite deposit has been the subject of several detailed studies. It has been variously referred to as an intrusive stock, a metasomatic deposit, an intrusive sill and a metamorphic-metasomatic body. The body is divided into six mineralogical zones, the first five being based on the characterizing accessory mineral; muscovite, muscovitemagnetite, biotite-muscovite, biotite, hornblende and pink syenite. Mining currently takes place only in the biotite zone. Foliation is particularly prominent in the central (hornblende) zone and near the margins of the nepheline syenite. Majic bodies within the nepheline syenite may represent basic rocks that have been less altered by metasomatism, metamorphosed basic dykes or sloped blocks of metasediments. The most prominent structural features are the northeast-trending folds that have been modified by later north west-trending folds.

Jan 1, 1984

By Min-Sung Kang

Excavation and earthmoving equipment mostly operate in accident-prone areas. These areas normally have rollover, confinement, and fall or may be considered harmful work areas due to demolitions and sewage removals. It is inevitable that excavation and earthmoving systems should be developed to secure the safety of operators through unmanned and remote control systems. Therefore, this research proposes a system that enables excavators to be unmanned and remote controlled without any renovation, remodeling, change, or transformation by applying attachable and separable mechanism and modules. Moreover, this research proposes the sensor module to evaluate the dynamic status without processing remodeling or transformation the existing hydraulic drive excavation system by adopting the easy attachable and separable mechanism. The study verifies this proposal based on observed possibility and feasibility through the experiments.

Aug 1, 2013

By S. Sundararajan, J. Brousseau, P. Bocher, M. Galopin, N. Barka

This research is committed to the prediction of the hardness profile produced by induction heating, using a computer-modeling software. The paper presents the simulation of the induction hardening process to analyse the sensitivity of the induction parameters on the hardness profile of a low alloy steel specimen. The developed numerical model includes the coupling effect between electromagnetic and thermal fields, and takes into account the non linear behaviour of the material properties. The study applies an enlightened experimentation method to build the feasible domain of the process and to achieve predictive empirical modeling. The ultimate goal is to replace the trial and error method that is usually used for the development of new parts, by costless experiments with the numerical model. Further development of this approach will lead to the computation of the residual stresses and finally to the assessment of the mechanical properties of the part. The end result will be the ability to shorten the development time and to improve the quality of the hardened part.

Jan 1, 2006

By N. Torres, G. Melcher

"An alternative to building new copper smelters, because of either stringent environmental regulations or in order to expand current plant capacity, could be achieved through the retrofitting of old reverberatory furnaces by making use of tonnage oxygen. The CONTOP® technology offers unique advantages over other techniques for this purpose, especially regarding substantial reduction in bath, capital and operating costs. This is possible to achieve since the reverb throughput could be largely increased with no major structural modifications to the furnace.The following options are offered to the smelter operators: dirty concentrates can be treated in an adjacent Contop system, or the cyclones can be mounted on the reverb roof for either dual operation or full Contop operation. ln the tatter case the furnace will be used as a settling chamber and f or slag c1eaning by top blowing with reducing gases.By incorporating Contop technology, the furnace throughput can be increased, higher malle grade, fixation of sulphur from furnace off-gas and substantial savings in energy consumption are possible to attain.IntroductionCopper smelting has been revolutionized during the last quarter century to such an extent that the standard type of plants consisting o f roasters and reverb furnaces seem a thing of the past, or almost. Though the building of new, more energy efficient smelters is a very likely opportunity for a grassroots plant, it would be hardly justifiable to replace an old existing plant unless there are heavy environmental or economic constraints(1,2,3)."

Jan 1, 1984

By F. A. Charalambous

Brannerite is commonly referred to as a refractory uranium mineral as it is usually highly resistant to acid leaching. There is however widely varying literature data on brannerite leaching, with some studies reporting that brannerite leaching can be achieved under relatively mild conditions. The differences observed for brannerite leaching are most likely due to the high degree of variation in the composition and structure observed in natural brannerites. These aspects of brannerite chemistry however are not very well understood due to a lack of fundamental research. The aims of this study were to investigate and develop methods for synthesising brannerites of varying composition and to investigate the effects of composition on brannerite leaching in acidic conditions.

Aug 1, 2010

Slurry flow, including flow through the charge, through the discharge grates, along the pulp lifters and its discharge from the mill is an important contributor to the efficiency of the grinding process within a SAG mill. Poor transport of finer ground material can adversely affect grinding leading to excess energy consumption and over-grinding of fine material. This paper extends a 1-way coupled DEM-SPH method to three dimensions and applies it to a 1.8 m diameter by 0.6 m long AG/SAG pilot mill. This provides detailed information on the internal flow of slurry within a SAG mill, including the prediction of dry regions and of slurry pooling. Full 3D analysis also allows the pulp flow patterns into and out of the mill via pulp lifter chamber to be investigated.

Jan 1, 2012

By J. Dubinski

This paper describes the key circumstances of the underground coal gasification (UCG) process, which is planned to be carried out in the Polish hard coal mine ?Wieczorek?. The construction and field tests of a UCG pilot plant have key issues that need to be addressed to realize the research project goal: the elaboration of a highly effective technology of fuel and electricity production. The project will conduct several monthly tests of gasification in the pilot geo-reactor, which will be constructed based on the results of laboratory tests. The realization of the process requires numerous appropriately prepared actions adjusted to natural conditions in the hard coal deposit. Based on scientific principles, it is necessary to elaborate the procedures related to the location of the UCG installation (including its legal and safety aspects), and to perform a technical risk analysis. In addition, it is necessary to determine the required mining, geological, technical, economic and organizational circumstances, while at the same time considering the real but constantly changing process conditions.

Aug 1, 2013

By Roger Potvin

Abstract The demand for pure zirconium and titanium metals in Germany increased considerably during the war. Pure zirconium was used in flash bulbs, in vacuum tubes, and in time fuses for bombs, where it has a decided advantage because it gives no gas in burning. Under the form of alloy, it was used with other rare elements for making substitutes for platinum; it was also used as a scavenging agent in high-grade steels. Metallic titanium was mainly used in connection with the manufacturing of special alloys. The authors were sent to Germany by the Department of Reconstruction and have investigated the German process developed for producing these rare metals. They describe the procedure and special equipment used for their commercial production in Germany during the war. General Metallic zirconium and titanium were .produced on a commercial scale in Germany by the thermal reduction, with metallic sodium, of potassium fluozirconate and titanium chloride, respectively, using a mixed potassium and sodium chloride flux. According to the information gathered, the sole German producer of these rare metals in pure form was the Deutsche Gold und Silber Scheideanstalt (commonly called Degussa), at their Werk II, 215 Gutleutstrasse, Frankfurt/Main, which was visited by the authors on September 18th, 1945. As far back as 1934, Degussa was carrying on active research on the manufacture of zirconium, and nearly one ton of the pure metal had been produced before September, 1939. Concurrently, a quite similar process was worked out for the recovery of titanium and it was in commercial operation in the year 1938, during which the production totalled about half a ton (metric). The demand, especially for pure zirconium, increased considerably during the war, attaining a total of about 48 tons during the period October, 1939, to the end of 1944, and reaching a peak of more than 15 tons in 1943. In 1944, the plant was slowed down due to the frequent and disastrous bombing by the Allies, especially in March and September.

Jan 1, 1946

By P. J. Adams

Environmental regulations require means for controlling emissions of SO2 NOx and particulate when burning coal. The combustion of coal in limestone fluidized beds is one of the most promising techniques for the necessary reduction in emissions. Fluidized-bed firing, furthermore, offers potential economies in capital equipment. The world's largest steam generator applying fluidized-bed techniques was built under the sponsorship of ERDA and installed in Rivesville, West Virginia. This paper describes the design and discusses the start-up and development difficulties which were experienced during the period from initial operation to current readiness for commercial operation. Other developments leading to utility and industrial fluidized-bed steam generating equipment are reviewed. The future potential of this promising technique is discussed.

Jan 1, 1979

To produce high quality castings, one must monitor the melt quality by evaluating such parameters as the grain refinement and silicon inoculation and modification during the production of the commercial casting. Thermal analysis is a tool one can use for both monitoring and providing input to the process control of the operation. The current technique of performing thermal analysis in commercial foundries is to pour a relatively small quantity of the molten aluminum alloy into a sampling cup and to then acquire the cooling curve. This approach is somewhat simplistic in that one has limited control of the cooling rate and hence the solidification rate of the sample. Moreover, this process requires a fair amount of user intervention and effort. In the past, studies have been conducted in an attempt to develop a system for conducting thermal analysis in-situ. In a study at McGill University, an alkali based heat pipe system was developed for conducting thermal analysis in-situ. While the concept was deemed as very desirable, the complexity of the equipment and procedure was a substantial negative component. In order to improve the technique of accomplishing real-time thermal analysis with an in-situ probe, a new method that is based on McGill heat pipe technology was developed. In the new system, a controllable and flexible water based heat pipe probe is used to solidify a small quantity of metal while residing in the melt. The solidified aluminum is remelted after completing the thermal analysis. This is a key feature of the probe. It resides permanently in the melt yet it is able to both solidify a sample of the melt and then to subsequently remelt it. Various solidification rates encountered in commercial castings are attainable by adjusting the heat extraction rate of the unit.

Jan 1, 2004

By P. E. Walker, M. E. Reed, R. C. Sims, B. Snowdon, D. E. Fallas

An advanced Flash Furnace feed system is the key to improving furnace performance. Clyde-WorleyParsons has developed a revolutionary pulseless pneumatic injection feed system technology, capable of delivering a range of benefits to operators of Flash Furnaces. The solution was created by combining the pneumatic conveying and injection knowledge, expertise and technology of Clyde Materials Handling with WorleyParsons' flash furnace process and operating experience. Optimal furnace burner performance requires the feed material to be presented to the burner as a stable, pulseless and accurately controlled flow, distributed evenly around the burner tip circumference. These simple requirements appear obvious, but are extremely difficult to satisfy in industrial environments and are not achieved by conventional feed systems. Our analysis of existing operating furnaces has identified the link between pulses in concentrate feed rate caused by conventional drag chain conveyors and rapid fluctuations measured in the furnace pressure. These fluctuations occur at a timescale close to the reaction shaft residence time and lead to unwanted instability in the primary furnace reaction zone - the flame. Through the use of the solution created by Clyde-WorleyParsons, it is predicted that the much more accurate control of feed rates achieved can lead to substantial improvements in furnace output, increased oxygen efficiency and better control of the composition of furnace liquids, such as matte, blister or slag. All these improvements lead to significant increases in smelter output and efficiency, and deliver high economic value compared to the cost of the feed system. Clyde-WorleyParsons' solutions can be deployed on greenfield sites or retrofitted, and therefore, have the capability to improve feed control at both new and existing smelters. This paper will discuss the field test work undertaken to date, the impact of findings and the ongoing analysis of linkages between instabilities in the various components of conventional feed systems and furnace pressure stability.

Jan 1, 2007