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By G. Szilvay, P. Kinnunen, J. Salminen, V. Miettinen, O. Salmi, J. Mäkinen

This paper demonstrates experimental studies on bioprocessing of different waste streams. In Part I of this paper three tailings from mining industry were bioleached with mixed acidophilic culture in order to solubilize valuable metals, like copper, nickel, zinc and manganese to leaching liquor. Bioleaching resulted in > 70 %, > 85 %, 100 % and > 70 % leaching yields for Cu, Ni, Zn and Mn, respectively. However, contaminants like arsenic and chromium were not leached efficiently and they will cause challenges in residual solids and sometimes also in metal recovery from leaching liquor. Bioleaching resulted in 99 % leaching yield for copper. Part II demonstrates mine water treatment and also gold recovery from process liquids with biosorption method. The novelty of biosorption was finding that certain fungal species were able to be cultivated to self-immobilized systems, which are easier to operate than traditional suspended biomass methods. Biosorption resulted in more than 90 % removal for all contaminants, but was also seen to be gold selective.

Jan 1, 2014

The mining industry has generally been slow to apply ion exchange processes to hydrometallurgical applications even if ion exchange offers an ideal solution for a particular problem. Two notable exceptions are in gold and uranium recovery. The largest application of ion exchange in the metals processing industry has been the use of resin-in-pulp (RIP) for gold recovery as an alternative to activated carbon. Iron is a ubiquitous impurity in hydrometallurgical solutions. In many cases, bulk removal of iron from the process solutions is accomplished by precipitation. However, precipitation for iron control is often accompanied by losses of base metals by co-precipitation. Increasingly, the option of ion exchange for removal of smaller amounts of iron from process solutions has been favoured. A number of applications have been developed and proven at the commercial scale for the removal/control of iron from a range of metal processing solutions. This paper provides an overview of the application of ion exchange for iron removal from a range of metal processing operations, including Cu, Ni and Co solutions. A number of case studies are provided which review operational and resin regeneration strategies and the impact upon the commercial operation of metal processing with improved iron control.

Jan 1, 2006

By d&apos, F. Elia

Hot cracking of magnesium (Mg) alloys during welding creates a barrier to enhancing the use of these alloys in automotive applications. As a result, it is imperative to understand the mechanisms responsible for hot cracking of Mg alloy welds in order to develop means of eliminating this problem. In this study, the hot cracking susceptibility of AZ91E and AE42 magnesium alloys were assessed using the moving torch Varestraint test method. Plates of 3 mm thickness were extracted from AZ91E and AE42 ingots and subsequently tested. Quantitative cracking data in terms of maximum crack length (MCL) was used for evaluating the cracking susceptibility. Scanning electron microscopy was carried out. The results suggest that AE42 showed a higher resistance to hot cracking in comparison to the AZ91E alloy. This was attributed to the difference in microstructure between the two alloys. In the fusion zone and HAZ of AE42, the brittle needle-like A1IIRE3 phase was seen to decompose to the more ductile particle-like Al2RE phase, thereby increasing the alloy's resistance to hot cracking. In contrast, SEM fractography revealed that brittle A16Mn and Mg17A112 intermetallic particles segregated to grain boundaries and triggered hot cracking in AZ91E.

Jan 1, 2011

By J .. Carignan, Y. Dembele, J .. Guha, A. Fowler, A. Gobeil

The Barlow Lake stratigraphic section comprises the top of the Gilman Formation, the Blondeau Formation and the three sills of the Cummings Complex. Representative samples were analysed to allow characterization of the chemo-stratigraphic profile and geochemical affinity of the six rock facies found in the section. All the mineralized horizons are associated with sedimentary units. Geochemical signatures associated with the mineralizations are either very weak or very localized and shown by increases in K20 around the mineralizations and Fe203 near them. The mineralizations are stratiform, synvolcanic but resedimented and remobilized by regional metamorphism and possibly by hydrothermal activity initiated by the intrusion of the Cummings Complex. The evolution of the sedimentary basin with the decrease of its depth is confirmed by the chemo-stratigraphic profiles. Stratigraphic position in the section is important in order that the chemo-stratigraphy may serve as a guide for mining exploration in the distal facies of the Blondeau Formation.

Jan 1, 1984

By M. P. Filion, K. Ferguson, L. L. Sirois

Acidic drainage is the largest single environmental problem facing the Canadian mining industry today. Technologies to prevent acidic drainage from occurring in wasterock piles and tailings sites, and on the walls of open pits and underground mines, need to be developed and demonstrated. There are two groups in Canada which have accepted this challenge: the national Mine Environment Neutral Drainage (MEND) program and the British Columbia Acid Mine Drainage (BCAMD) Task Force. This paper summarizes the activities of these two organizations.

Jan 1, 1990

By M. Lytle

"The Corbin area of southeastern British Columbia has been a coal mining area since 1908. Byron Creek Collieries Ltd. Has operated its Coal Mountain Mine in this area from 1974 until the present. In February 1981, this company was purchased by Esso Resources Canada Ltd.Coal Mountain is structurally complex and standard computer algorithms are not applicable to model the overturned synclinal structures and faulted bedding surfaces. This paper discusses two approaches used by Esso Resources staff to model the geology of Coal Mountain.The first approach projects digitized cross-section data along trend to develop a large data base which correctly approximates the shape of the structure. The spatial orientation of the structure is corrected by merging the generated data set with drill-hole data. The second approach uses digitized cross-section and bench-plan geology to generate a block model of the coal reserve.HistoryThe Coal Mountain Mine, also known as the Corbin Mine of Byron Creek Collieries Ltd. is located 24 kilometres south of Highway 3 in southeastern B.C.In 1905, two American businessmen recognized the coal potential of the area during a horseback tour. The two businessmen, D.C. Corbin and E.J. Roberts, formed the Corbin Coal and Coke Co. to mine and market coal from their newly acquired 6075 hectares of coal licenses. By 1908, the town of Corbin was under construction, a 22.4-km rail spur was constructed from the mine to the main CPR line and the first underground mine began to produce coal. An open-pit operation was also developed at the 1828-metre elevation using a steam shovel loading into rail cars. The company operated continuously until 1935, when a lengthy strike forced suspension of operations.In 1943, the Consolidated Mining and Smelting Company Ltd. (now known as Cominco Ltd.) operated two surface mines to produce coal for its smelters at Kimberley and Trail, B.C. This operation ceased in 1948."

Jan 1, 1982

By A. Allaire

The Goldex operation of Agnico-Eagle Mines (AEM) commenced operations in the spring of 2008. Following some months of initial operation, the grinding circuit capacity was under-performing according to the original design throughput. BBA Inc. (BBA) was commissioned, in February 2009, to study the different options and recommend the quickest and most cost-effective solution to increase the grinding circuit throughput rate. The mandate was to increase the throughput of the grinding circuit to beyond the original design of 7,000 tpd to 8,000 tpd or greater, while retaining the existing SAG and ball mills. The circuit was modelled using JKSimMet software to evaluate the different options, each with a number of different operating parameters. The option of secondary crushing of the SAG mill feed was retained. Comparison of the different options and simulation outcomes, design of the secondary crushing circuit, operating conditions, and initial adjustments in the design and operating results of the new grinding circuit are discussed in this paper.

Jan 1, 2012

By S. S. Rahman, A. Gholami, M. A. Aghighi

"This paper provides a foundation for studying the growth of fractures in presence of other discontinuities and different anisotropies of low permeable hydrocarbon formations and helps to improve the design strategies for multistage fracturing.The multistage fracturing technology has recently been used to exploit low permeable hydrocarbon reservoirs. However, the mechanism of hydraulic fractures interaction and the impact of local heterogeneities on ultimate trajectory of the growing hydraulic fractures are not yet understood in depth. A fully coupled poroelastic Finite Element based model is developed to investigate the mixed mode propagation behaviour of growing hydraulic fractures. This model takes advantage of an explicit representation of the fracture which enables us to take the effects of rock and fluid related parameters into account. Moreover, impact of fracture geometry and leak-off phenomenon is investigated. The refined mesh around the crack provides the added advantage of more detailed stress distribution, pore pressure change and back stress in the vicinity of the fracture and in particular at the fracture tip. The potential deviation propensity of the fractures is evaluated based on the fundamental rule that fractures propagate perpendicular to the direction of the minimum horizontal stress.This study shows that pressurization of transverse hydraulic fractures results in the reorientation of local principal stresses, particularly in vicinity of fracture tips. Variation of flow patterns clearly influences the evolution of shear stress around the fracture tips which will potentially lead to mixed-mode I and II fracturing and consequently, fracture deviation. The presence of local heterogeneities such as preexisting fissures and/or fractures is a main source of such pore pressure induced stress redistribution and reorientation and potential deviation of hydraulic fractures.Most existing models ignore or simplify the effect of pore pressure/stress coupling as well as the fracture geometry and fluid flow within the fracture. Also, the fluid leak-off from the hydraulic fracture into the formation, which is a controlling factor in fracture growth, is often considered using analytical models. Taking advantage of a fully coupled porelastic model along with an explicitly discretized fracture, this study provides a more realistic insight into the complex fracture propagation processes of multistage fracturing operations particularly in presence of reservoir geo-mechanical complexities."

Jan 1, 2015

By Per-Lennart Nystedt

"The Boliden Lead Kaldo Plant for the treatment of lead bearing flue-dust from the Copper Smelter and the Slag Fuming Plant has been in operation at the Ronnskar Works of Boliden Metall since the middle of 1976. At the present stage, the plant can treat lead-bearing dust of different kinds and compositions. The process allows good separation of arsenic and halogens from lead.The flue dust from the Copper Smelter and the Slag Fuming Plant is very complex and, apart from lead, also contains zinc, copper, tin, bismuth, cadmium, antimony, arsenic, sulphur, silver, chlorine and fluorine. The metallurgical process has been developed by Boliden Metall and has been tested on a pilot scale at the Foundation for Metallurgical Research (MEFOS) in Lulea, Sweden.The pelletized dust is smelted in the converter, where the heat is generated by an oil oxygen burner. The second step consists of reduction with coke. A lead bullion and slag are obtained. The slag, transported in liquid form, is treated in the Slag Fuming Plant for the recovery of zinc. The third step is the elimination of arsenic from the bullion. This is achieved by treating the lead with iron (turnings or pellets). The result is a crude lead and speiss. The lead contains silver, tin, antimony and bismuth, and is suitable for the final refining stages in normal plant equipment for refined lead.For process control, we use the rapid analysis centre, which is pneumatically and electronically linked to 'all major plant sections and allows for a quick turn-around between delivery of the sample and feedback of results. All three steps in the process are performed in the same converter.Since the starting up of the plant, the original process has been subjected to some modifications. Initial problems related to equipment, maintenance and environment have been solved step by step. Examples are quoted. Recent operating particulars are presented."

Jan 1, 1980

By Lionel C. Kilburn

"This geological engineering method is based on jour main characteristics of mineral properties, viz; location: inclusion of valuable mineralization; inclusion of geophysical and/or geochemical targets; and inclusion of geological targets. These are subdivided into a total of 19 subcategories, which are used to determine the value of the property.The nineteen subcategories are prioritized and assigned relative value factors from 1.3 to 10. Value of each mineral claim unit is determined by applying the appropriate subcategory factors to a base value of $400per 16.2 hectare unit. Property value is calculated by totalling the values of such individual claim-units.The boundary between ore grade and sub-ore grade must be estimated for each property under valuation, thereby making the method sensitive to mineral commodity prices.A clear and disciplined sequence of decisions based on personal experience forms the basis of this method. The method utilizes all factors normally used to value a mineral property.IntroductionIt is generally accepted in the exploration industry that valuation of exploration properties is a subjective rather than objective process (Roscoe, 1986; Lawrence, 1988; Lawrence, 1989; Woodcock, 1985), and that it is greatly influenced by the experience and qualifications of the person who is doing the valuation. However, the significantly low degree of objectivity in mineral property valuation at this point in time invites effort to achieve a more quantitative engineering basis.Value of a mineral property depends basically upon metal prices, recoverable grades, mining and metallurgical practices, commodity supply and demand , and political-economic conditions, all of which vary with time. Therefore, any valuation is valid for only that point in time when it is made. Mineral deposits can decrease as well as increase in technical value with time."

Jan 1, 1990

By P. C. Sui

Numerical investigation and parametric simulations of the coupled electrical conduction and mass diffusion in the GDL of a PEMFC are reported. The coupled transport is solved using a 2D, "under-the-rib" computational domain for the cathode GDL. The current density on the GDL/catalyst layer interface, which constitutes one of the boundary conditions for the GDL domain and reflects the activation overpotential in the catalyst layer and the ohmic loss in the membrane, is solved iteratively using a novel numerical algorithm. A parametric study is performed to investigate the effects on current density distribution of various operating conditions such as oxygen concentration and membrane resistance, and of design factors such as GDL geometry, anisotropic transport properties, and deformation under the land area. The results show that the current density distribution under the land area can be dominated by either electron transport or mass transport, depending on the operating regime.

Jan 1, 2005

By Peter S. Jack

"IntroductionTHE ORES treated at the concentrator of the Britannia Mining and Smelting Company, Limited, Britannia Beach, B.C., have always contained some lead, but it was not until 1950 that the combination of lead headings and lead price was such that recovery of this metal at Britannia became worthwhile. In that year, with the mining of a new orebody, the lead in the mill feed was raised from 0.07 per cent to 0.15 per cent. Chalcopyrite, sphalerite, and pyrite concentrates are produced by flotation at Britannia, •and 95 per cent of the lead in the mill feed reports with the chalcopyrite concentrate, so that the rise in lead headings was reflected almost wholly in the lead content of the copper concentrate. In 1950, investigation was started to determine if some of this lead could be recovered economically."

Jan 1, 1953

By J. M. Skeaff

"The main solution, ore and residue pulp streams in the Rio Algom Quirke I uranium mill at Elliot Lake have been sampled and analyzed for radium-226. Analysis of the ore and leached residues indicates that Ra-226 dissolves and precipitates within the first pachuca tank. A maximum of approximately 0.2% of the Ra-226 in the ore remains in solution during leaching.IntroductionConcern over the acid drainage and radionuclide dissolution problems associated with uranium tailings disposal sites in Canada has prompted investigation into methods for improving current uranium processing practice.Present commercial practice usually involves leaching of the uranium ore with sulphuric acid, ion-exchange separation of the uranyl sulphate complex from the leach liquor and"" precipitation of the uranium as yellowcake. Daughter products of U-238, such as Th-230, Pb-21O and Ra-226 remain with the tailings and undergo long-term dissolution.Table I summarizes the probable behaviour of the radionuclides during milling. The concern here is with Ra-226, because it will deposit in the bones if ingested and is ""thus considered a serious health hazard(1), Similarly, Po-218 and Bi-214, which are daughter products of Rn-222, can be retained in the lungs and are considered to be the principal sources of radiation dosage(2) arising from the inhalation of Rn-222. Previous investigations(3-9l indicate or imply that Ra-226 undergoes redistribution during milling. However, detailed published information on the behaviour of Ra-226 in the uranium milling process appears to be lacking. A knowledge of the behaviour of Ra-226 in uranium mills, particularly during leaching, could lead to improved methods for its control.This paper reports the occurrence of Ra-226 in the Rio Algom mill. The main objectives of the study were to determine (1) the distribution of Ra-226 within the solids, (2) at what point, and how rapidly, redistribution occurs and (3) whether there are high concentrations of Ra-226 in solution."

Jan 1, 1981

By Kenta Suzuki, Toshiya Anami, Daisuke Shimosaka

"In an Al-Mn alloy heat exchanger fin stock, the effect of annealing conditions for as-cast and 0.1%Zr addition on recrystallization behavior is investigated using metallurgical analysis. Refinement of post-brazed recrystallized grains in fin stocks with Zr addition are suppressed for long-time annealing. In 0.1%Zr fin stocks, there was a decrease in the number of fine a-Al(Mn,Fe)Si dispersoids for pinning of sub grain and grain boundary. In addition, relatively homogeneous distribution of Al3Zr dispersoids was observed with increasing annealing time in as-cast. Homogeneous distribution of Al3Zr dispersoids can have a major effect on pinning of sub grain and grain boundary during brazing heat treatment. The homogenous distribution of fine dispersoids prior to brazing heat treatment is effective in causing the suppression of refinement of post-brazed recrystallized grain structure in aluminum alloy fin stocks.INTRODUCTIONAl-Mn based alloys are widely used as fin stocks in automotive heat exchangers because of their superior mechanical properties, braze ability, sagging and so on. In particular, coarsening of recrystallized grain structure is beneficial to avoid erosion, and achieve excellent sagging resistance (Lee, Yoon, Kim & Jung, 2002). For resisting grain coarsening, the alloys should contain a dense and homogeneous distribution of fine dispersoids to retarder crystallization (Humphyreys& Hatherly, 2004). It has been demonstrated that addition of Zr to Al-Mn alloys can shift recrystallization to higher temperatures because of the distribution of fine Al3Zr dispersoids in matrix(Pokoba, Cieslar& Lacaze,2012). According to Tohma, Asanoand Takeuchi (1987), coarsely recrystallized grain structure was obtained in 3003alloy with Zr addition after heat treatment. However, fine Al3Zr dispersoids are usually heterogeneously distributed because of segregation during casting and low diffusion rate of Zr in aluminum. Therefore, a homogeneous distribution of Al3Zr dispersoids can be achieved through long-time precipitation annealing(Jia, Hu, Forbord& Solberg, 2008)."

Jan 1, 2018

By H. Utsunomiya

Most magnesium alloy sheets show low deformability in rolling. Edge cracks and transverse fractures are common difficulties. In addition, rolled sheets show well-developed basal texture <0001>//ND. The texture causes high anisotropy in mechanical properties and low formability in subsequent metal forming. Differential-speed rolling, where the upper and the lower rolls rotate at different speeds, introduces shear deformation through the thickness. Not rolling texture but shear texture evolves in the sheet so that the asymmetric rolling can be a method of texture control. However the primary slip system of the hcp alloy, is basal, the shear texture should be also basal. Differences between the two basal textures, i.e., the rolling texture and the shear texture, have not been understood completely. In this study, conventional (same-speed) rolling and differential-speed rolling have been applied to commercial AZ31B sheets at 623K. Microstructures, textures and mechanical properties of the rolled sheets before/after annealing are compared. It is found that the basal texture is more pronounced by the asymmetric rolling. On the other hand, the asymmetric rolling is effective to decrease the grain size and the planar anisotropy.

Jan 1, 2006

By Robert B. Parsons

"The Canadian Exploration Incentive Program (CEIP), which was announced by the federal government on May 3, 1988, promises to maintain the viability of flow-through shares as a financing mechanism which has proven to be so crucial to the health of the junior exploration sector. This month, Tax Notes examines, the main features of CEIP, which will come into play on January J, 1989. IntroductionOn May 3,1988, the Honourable Marcel Masse, Minister of Energy Mines & Resources, and the Honourable Gerald Merrithew, Minister of State (Forestry and Mines) announced the Canadian Exploration Incentive Program (CEIP). Under CEIP, the federal government will make cash payments to eligible applicants equal to 30% of eligible exploration expenses. CEIP payments will be available with respect to both mineral, and oil and gas, exploration. In essence, the program will replace the ""mining exploration depletion allowance"" (MEDA) presently applicable to mineral exploration, and the Canadian Exploration and Development Incentive Program (CEDIP) which is presently available to the oil and gas exploration sector.This paper discusses briefly the main features of CEIP insofar as the program will affect mineral exploration. The comments herein are based on the Canadian Exploration Incentive Program Act which received Royal Assent on July 21, 1988, and on a discussion paper which was released by EM&R in May 1988. The bulk of the rules relating to the program will be in the form of regulations which have yet to be finalized. It is understood that EM&R would like to have the regulations in force by October I, 1988, when the oil and gas portion of CEIP becomes effective. (The rules relating to mineral exploration will become effective January I, 1989)."

Jan 1, 1988

By S. A. Kenzap

This paper provides an overview and discussion of key aspects of operating risk valuation in underground metal mining systems, with impact on project economics, using stochastic computer modelling in Discounted Cash Flow (DCF) analysis. Mine operating risk classification and assessment for ground, equipment and scheduling aspects are presented with an overview of available risk valuation tools that have been developed in engineering disciplines. The classification is organized by keeping in perspective the mine design needs and constraints, as well as the potential economic impact that operating problems can have on an underground development and production system. These sources of cost, revenue and time delays are tabulated to enable the hierarchization of potentially hazardous unplanned events occurring during the mining project life cycle. In complex technological systems, like the underground mining systems, the decision-making process involve a wide range of uncertainties, and often this is based on subjective and qualitative expert evaluations. Whether a qualitative or quantitative analysis is conducted, it is often the case that the probability of a certain project parameter value needs to be estimated. This requires use of methods and techniques to handle subjective, qualitative measures and to combine them with quantitative stochastic modelling in order to evaluate mine operations-related issues on DCF economic performance measure parameters. Links are established between decision making and the risk-based mine planning process for evaluation of design alternatives, with emphasis on the need of introducing flexibility in mine design. Finally, challenges of risk-based mine planning and design implementations are discussed and the call for an integrated risk-based real options systems valuation (ROV) ?in? projects analysis is made.

Aug 1, 2013

By Jan Drzymala, Przemyslaw B. Kowalczuk

Froth flotation is widely used for upgrading of ores and other materials. Efficiency of flotation depends on many parameters, including type, chemical structure and dose of flotation reagents. Selection of a proper frother in flotation depends on the material used, necessary dose of frother and its selectivity. The selectivity of flotation can be characterized by proper separation factors and indices. In this paper separation selectivity and power of frothers were evaluated basing on separation data for a given material and frother, plotted as the recovery of the useful component in the concentrate versus the recovery of the remaining components in the tailing. Such a plot is called the Fuerstenau upgrading curve. The selectivity was defined as the location of the whole upgrading curve in relation to no and ideal separation lines, expressed on the scale from 50 (no separation) to 100% (ideal separation). In turn, the flotation power was defined as the dose of frother to reach a certain upgrading level at which recoveries of the useful and unwanted components are equal. The power and selectivity of frothers were determined for the Kupferschiefer stratiform copper ore floated in the presence of a fixed amount of xanthate and varying doses of frothers using a laboratory flotation machine. Basing on the separation results for different poly(propylene glycol) (CnH2n+1O(C3H6O)mH, CnPm) and poly(ethylene glycol) (CnH2n+1O(C2H4O)mH, CnEm) alkyl ethers, it was found that the concentrate yield and recovery of copper as the useful component in the concentrate were greatly influenced by the type and dose of frother. However, the same results plotted in the form of the Fuerstenau upgrading curve clearly indicated that the selectivity of frothers was similar, while their power was different. It proves that both selectivity and power of frothers are useful parameters for characterizing flotation systems.

Jan 1, 2016

By Yuki Tsunazawa, Sho Fukui, Chiharu Tokoro

"A milling process is one of the important unit processes in mineral processing. In the milling process, the control of particle size distribution is necessary for the later physical separation process. Since the milling process is strongly affected by the equipment designs, operation conditions and raw materials, the control for particle size distribution of milling products is mainly based on empirical rules. Recently, the discrete element method (DEM) has been widely used as an effective tool to investigate the behavior of grinding media. Although the behavior of grinding media can be accurately simulated, it is not well-established the way to predict particle size distribution after milling by the DEM simulation.The objective of this study was to develop a new method to predict particle size distribution in ball milling using the DEM simulation. To predict particle size reduction, a correlation between experiments and the simulation was investigated in various operation conditions, that is, wide range of the rotation speed and the filling ratio of grinding media. In experiments, after lime stone was ground, the average and variance of particle size distribution were evaluated using some kinds of distribution equations. In the DEM simulation, direct simulation of particle disintegration in milling process is generally very difficult because of huge computational load. Therefore, collision energy between grinding media balls orgrinding media ball and wall was used as a factor of particle disintegration.As a result, a good correlation between experiments and simulation was obtained. In addition, the particle size distribution in ball milling could be predicted using this correlation. Therefore, these results indicated that the use of the correlation between experiments and the DEM simulation was an effective approach of predicting the particle size distribution in milling process."

Jan 1, 2016

By J. Baumbach, H. Bombach, M. Stelter

"Today technical electro-refining processes for copper exclusively use sulfuric acid, for silver refining nitric acid electrolytes are used. Sulfuric acid is characterized by very good chemical and electrochemical stability, good conductivity and low cost. The disadvantages of sulfuric acid are the precipitation of fine-grained cathodes with smooth surfaces only by using additives like glue, thiourea and chloride. In case of silver the electrolyte is electrochemical unstable and bears the risk of the formation of toxic NOx when pH is too low. A second disadvantage is the form of electrodeposition of silver as dendrites with their removal from the bottom of the Möbius cells.This paper reports the results concerning the application of an alternative electrolyte in copper and silver electro-refining. At first the electrolyte was characterized by the determination of current density potential curves. Electrolysis experiments were performed in laboratory scale using technical anodes for copper and synthetic anodes for silver. During the copper tests the solubility of contaminations from the anodes and the amount and chemical composition of the anode slimes were determined. Moreover the influence of current density, electrolyte temperature and the effect of several additives on the precipitation and chemical purity of the cathodes were investigated. In all experiments cell voltage as well as anodic and cathodic polarization was measured and current efficiency and specific energy consumption were calculated. A comparison with the results with those of tests using conventional sulfuric acid electrolyte shows the advantages and disadvantages of both systems, additionally the technical application chances and limitations for the new electrolyte. This electrolyte enables the precipitation of smooth copper cathodes with low silver and sulfur concentrations even at lower temperatures without any additive. For silver refining the electrodeposition of compact silver sheets is possible, that can be stripped comparable to those in copper electro-refining."

Jan 1, 2016