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By Ram Song, Yohei Harada, Shinji Kumai, Kazuho Otsuka

"Recently, vertical-type high-speed twin-roll casting (HSTRC) has been developed. The HSTRC shows extremely high cooling rates over 1,000 K/s even at the mid-thickness area. The fabricated strip has many metallurgical characteristics; super-saturation of alloying elements, fine solidified structure, and homogeneous distribution of fine constituent particles. In Al-Mn based alloys, the Mn alloying element can be supersaturated in the a-Al matrix and also form Mn-containing constituent particles during solidification. The Mn supersaturation and the distribution of primary/secondary particles in cast products affect the metallurgical behavior in the down-stream processing and can improve mechanical properties of the final products. In this study, Al-Mn based alloy strips were fabricated by HSTRC with various Mn contents. The solidified microstructure, constituent particles and its distribution, and Mn solubility were investigated in the as-cast condition. Due to the high cooling rate of HSTRC, fine constituent particles were homogeneously distributed, and coarse intermetallics were not observed. Mn solid solubility was estimated by electrical conductivity. The estimated Mn solubility was equivalent between strip surface and mid-thickness area.INTRODUCTION Al-Mn based alloys, as non-heat treatable wrought aluminum alloys, are widely used in packaging and heat exchanger for automobile industry. Besides Mn, Al-Mn based alloys often contain Fe and/or Si as alloying elements or natural impurities. During solidification, Mn can be super-saturated in the Al matrix, and also form Mn-containing constituent particles. Additionally, in the subsequent thermal-mechanical processes such as homogenization, rolling, and intermediate annealing, Mn in solid solution precipitates out of the Al matrix as secondary particles. The size, distribution, type, and the amount of dispersoids including constituent particles affect to texture evolution, recrystallization behavior, and final mechanical properties of wrought Al-Mn based alloys (Huang et al., 2016; Huang & Marthinsen, 2015; Engler et al., 1995; Muggerud et al., 2013). Therefore, controlling the initial level of Mn super-saturation and the distribution of constituent particles are important in the cast Al-Mn based alloys."

Jan 1, 2018

By Richard K. Komarek, Antonios Zavaliangos, Roman T. Dec

Current industrial compacting and briquetting practices are largely based on trial-and¬error techniques. This paper introduces a two dimensional finite element model of compacting/briquetting process in the roller press. Compared with other modeling techniques used in the past, finite element method offers the most versatile approach because it incorporates adequate information about powder behavior, geometry and frictional conditions and offers predictions for the density distribution, velocity field, stress distribution, roll force, roll torque and other important process variables. More over, when the model includes elasticity, it offers predictions on the internal stress state in the briquet after its exit from the pressing zone. This enables to perform realistic computer experiments which are helpful for establishing the pressing system design, forming cavity geometry and process conditions necessary to produce compacted or briquetted product with the desired properties.

Jan 1, 2004

By M. Kataoka, Y. Obara

It is known that compressive strength and tensile strength of rocks vary significantly with specimen size. Rocks are composed of crystals and grains in a fabric that includes flaws such as microcracks, grain boundaries and pores. As the likelihood of including severer flaws becomes greater for a larger specimen, the strengths are small. On the other hand, the size effect in the fracture toughness of rocks has not been made clear until now because there are few studies focused on it. In this paper, Semi- Circular Bend (SCB) test was performed using Kimachi sandstone with various specimen sizes. A shape of the specimen is a semi-circular disc with an artificial notch. The specimens were prepared with various thickness t and radius r as the following two groups; t was changed from 10 to 37.5 mm with r = 37.5 mm in the specimen of group (a), and r was changed from 12.5 to 150 mm with t/r = 0.8 in the specimen of group (b). As a result, there was no significant change in the fracture toughness with different t. On the other hand, the fracture toughness increased with increasing r and converged on a certain constant value in a range larger than approximately 70 mm of r. Consequently it was clear that the size effect in the fracture toughness of the sandstone exists.

Jan 1, 2015

By L. S. Almeida, U. A. Courbassier, C. T. Guimãaraes, M. N. Souza, V. L. Silva, H. P. Dias, G. A. Bicalho, B. S. Rocha, P. N. Rodrigues, A. Carnevale

During primary aluminum production the anode changing is a very important task. So improvements on it will be essential to avoid disturbance and have a better operational control. After anode changing a good current distribution will be guaranteed using a cavity cleaner and precise anode setting. Albras switching a manually anode setting to an automatic one solved the setting problems. In this paper it will be shown some pot line results and the improvements on workers ergonomic and safety conditions. The device was developed in a partnership between Albras and Pesto.

Jan 1, 2006

By Z. Tang

A collaborative project was performed between NRC Institute for Fuel Cell Innovation and MagPower Systems Inc, to develop a cost effective fabrication process to manufacture the anode for magnesium-air fuel cell with improved performance. A novel fabrication process was developed, which resulted in a porous microstructure with increased surface area, instead of the traditional solid structure. This porous anode greatly increased power density in the magnesium-air power source. This fabrication process is very simple and cost effective. Especially, this process makes it convenient to incorporate different alloying additions, as well as hydrogen inhibitor and electrolyte management additive into the anode. The anode composition was designed so that micro galvanic cells were formed as current is drawn out of the fuel cell, and resulting increased dissolution rate of Mg. It is feasible to incorporate hydrogen inhibitor and electrolyte management additive into the porous anode, and the anode with some kinds of inhibitors exhibited improved electrochemical performance. This paper describes the microstructure and electrochemical performance of anodes with designated porous structure and alloying additions. Furthermore, quantitative kinetics analysis of the obtained I-V curves and electrochemical impedance spectroscopy were carried out to clarify the mechanism.

Jan 1, 2005

By L. Jiang

This report investigated the dynamic recrystallization (DRX) phenomenon in magnesium alloy AZ31 billets to understand the deformation mechanisms and microstructure evolution during extrusion and other metal forming processes, Compression tests of coarse-grained as-cast magnesium alloy billets containing lamellar Mg17Al12 eutectic phase and (Al, Mn) particles suggest that temperatures higher than 300°C, strains greater than 0,25 and strain rates above 0,l/s lead to the formation of fine DRX grains in the deformed samples. Microstructural observations also indicate particle-stimulated DRX nucleation (PSN) during hot deformation of the AZ31 alloy, facilitated by the presence of Mg17Al12 and (Al, Mn) particles, While the Mg17Al12 is dissolved into the matrix at about 350°C, (Al, Mn) particles may remain effective for PSN at temperatures up to at least 400°C, This study suggests that alloy design with a proper distribution of second-phase particles can provide the desired microstructure for improved properties and formability in wrought magnesium alloys.

Jan 1, 2004

By Ch. Enkhbold

Underground mining of minerals is becoming an increasingly complicated technological and ecological problem. It can be explained both by worsening of geological conditions of mining and by a specific character of mining industry, which, in contrast to processing branches of industry, intrudes into one of principal components of the nature ? the Earth's interior. At a traditional organization of mining industry, the entire volume of the produced rock mass is brought to the Earth's surface, where valuable components are extracted. This entails not only power over expenditure for long-distance transfer (especially in the vertical direction) of the waste rock forming a part of the original mineral, but also the formation of huge volumes of worked-out spaces. The latter leads (nature cannot stand emptiness!) to an irreversible development of geomechanical processes of shifting of overlying rock masses resulting in an irreparable damage of all surface structures located on the territory undermined by deep mining. Owing to their high productivity combined with low power consumption and instrumental compactness, novel bifunctional technological processes of minerals dressing successfully solve the problem of rock mass processing in underground conditions with subsequent operative disposal of final tailings of such underground dressing in the worked-out space. Besides, an integration of two processes into one is achieved, for example, a decrease in the rock mass coarseness with a simultaneous precise separation of valuable and waste components.

Aug 1, 2013

By W. R. Richmond, T. S. Li, D. Ilievski

The reactive precipitation of ferrihydrite was studied in a laboratory semi-batch precipitator, where a highly concentrated sodium hydroxide solution was fed into an iron nitrate solution. Instantaneous hydrolysis of iron[III] takes place when the two reagents are mixed generating supersaturation, and leading to immediate precipitation of ferrihydrite via a primary nucleation mechanism then followed by limited crystallite growth to 3 to 7nm. A mathematical model of the semi-batch laboratory precipitator was used to simulate the pH responses during the precipitation of ferrihydrite at different reagent feed rates. The model comprised of interconnected compartments of averaged hydrodynamic conditions, incorporating physically meaningful turbulent mixing time constants. The precipitation process is described by the solute concentration conservation equation incorporating a postulated ferrihydrite primary nucleation model. It was found that the semi-batch precipitator model predicted the experimental pH response reasonably well. The experimental results demonstrated that the reagent feed rate has a critical effect on the course of the precipitation of ferrihydrite, i.e. it is a rate determining step given the fast hydrolysis and precipitation kinetics.

Jan 1, 2005

By François Baillargeon

Two types of ore deposit provide the bulk of the world nickel production. They are the hypogene magmatic massive sulfide deposits and the supergene lateritic deposits. Platinum group elements (PGE) are also extracted from magmatic sulfide deposits. Recent sky-rocketing price of palladium has prompted the mineral industry to seek alternative resources. In such a manner has emerged the Lac-des-Iles type of target, a very low sulfide-bearing bulk tonnage type of deposit. Furthermore, unconventional (e.g. non-magmatic) types of deposit are now sought more intensively (Wilde et al., 2003). Considering both this trend of the PGE Industry, and that only a few magmatic deposits account significantly for the world nickel production, someone may wonder if a diversification of the hypogene nickel resources base would not be needed in the near future. Laterites are residual deposits developed on ultramafic rock under wet tropical climate. Are all ultramafic protoliths equal to generate high-grade lateritic deposit? Are some preweathering processes important to generate favourable ultramafic protoliths? The mineralogical heterogeneity of some ?dry? lateritic nickel deposits renders their ore beneficiation difficult. Is the type of nickel-bearing mineral found in the protolith a significant factor influencing the laterite heterogeneity? To contribute to answer all these questions, we have undertaken a research project on the nickel occurrences of the southern Quebec serpentinite belts. Why choosing this specific region for such a project? First because, due to continuous mining of asbestos ore since 1870, the serpentinite belts of this region are among the best exposed and studied in the world. Secondly, this region host a complete spectrum of nickel deposits that have been described before in the scientific literature. Furthermore, this region is slightly to moderately metamorphosed which make it perfectly suited to study the departure from magmatic nickeliferous paragenesis through various metamorphic conditions. As a matter of fact two orogenic events affected this region, the Taconian, in Ordovician time, and the Acadian during the Devonian. The magnitude and the timing of these dynamo-metamorphic events vary considerably through the region (Gauthier et al., 1994). These variations are now well constrained due to precise age dating.

May 1, 2003

By M. Mirzazadeh

Air cooled crackable and conventional forged steel specimens were tested under reversed push-pull conditions to examine the effect of shot-peening on their high cycle fatigue behaviour (-106 cycles). The steels were tested in the normalized as well as shot-peened conditions. The results showed that shot-peening smooth specimens had little effect on the fatigue limit of the air cooled forged steels and the detrimental effect of the rougher peened surface was not apparent. Microhardness profiles indicated that the shot peening produced a gradient of compressive residual stresses that was greater than that of the loading stresses, suppressing the anticipated beneficial effect on fatigue life. Crack initiation was more likely to occur below the surface. The results indicate that the surface roughness was not a significant factor in controlling the fatigue lives, since they were essentially the same for the non shot-peened and shot-peened steels.

Jan 1, 2010

By ManhKha Trinh, Neal Pyke

Dofasco was the first company to adopt oxygen steelmaking in North America in 1954, two years after the first LD vessel installed and operated successfully in Linz, Austria. Since then, Dofasco has investigated and implemented several strategies to maximize hot metal usage and minimize overall cost. Some key strategies -low hot metal silicon, combined blowing conversion, vacuum degassing tank upgrade and BOF slag carryover control - are discussed. Post combustion, scrap preheat, carbon injection trials along with current operating philosophies are described.

Jan 1, 2004

By John D. Godfrey

Precambrian Shield rocks, exposed in the extreme northeast corner of Alberta, provide the only possibility for a granitic building stone development in the province. Among a wide variety of granitoid rocks in the Shield, the Chipewyan Red Granite is one of the most favourable prospects. Geological mapping and exploration has revealed two prospective sites within a major pluton situated close to navigable water. Cleaned outcrop surfaces show clearly the pattern of joints and lithologic variations within the granite at prospective quarry sites. Other features include: basic dykes, quartz veins, and sheeting fracture zanes. Systematic orthogonally arranged fracture sets and the sheeting zanes are auributed to a tectonic origin. onsystematic irregular fractures are related to surface and nearsurface processes, such as decompression through unloading .

Jan 1, 1984

By Kazutoshi Haga, Batnasan Altansukh, Yasushi Takasaki, Mohd Yazid Bin Abdul Razak, Atsushi Shibayama

"In this study, the volatilization behaviour of arsenic (As) and antimony (Sb) from arsenicantimony bearing minerals such as tennantite (Cu12As4S13)/tetrahedrite (Cu12Sb4S13) in copper ore was investigated using a roasting process. Specifically, the thermal decomposition of tennantite and the arsenic volatilization were investigated under nitrogen and air atmosphere. The roasting experiments were performed at temperatures ranging from 500 to 1,200oC and different retention times using a laboratory electric furnace. The results indicated that over 95% volatilization was achieved at 700oC. On the other hand, when the temperature increased to 1,200oC, volatilization rate of Sb reached to 90%. Therefore, volatilization of Sb requires high temperature compared to As. It suggests that As and Sb can be separated using temperature difference. Selective removal of As is possible at 700oC, subsequently Sb can be recovered as a volatilized product by increasing the temperature to 1,200oC. Meanwhile, volatilization of Cu and Fe was not observed on these conditions. The content of As and Sb in the residues obtained from roasting at 700 and 1,200oC was less than 0.3 and 0.75 mass%, respectively. The Cu content in solid residue at 1,200oC increased to 34 mass%. The clean copper concentrate with lower amounts of arsenic and antimony was obtained from the process. INTRODUCTIONRecently, arsenic (As) and antimony (Sb) contents in copper (Cu) concentrates are increasing year by year. Arsenic and antimony are present with Cu minerals such as enargite (Cu3AsS4), tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that associate with copper sulfides [chalcopyrite (CuFeS2) and bornite (Cu5FeS4)]. They are normally concentrated by flotation and treated in copper smelters. However, treatment of copper concentrates containing high amounts of arsenic and antimony by a smelting process is difficult due to environmental implications of toxic arsenic and antimony. As demand for copper continues to grow, the need to source copper from several types of resources including those that contain high levels of As/Sb becomes necessary. Therefore, a novel processes for the treatment of As/Sb bearing Cu concentrates are required. Reviews on copper resources such as enargite, tennantite and tetrahedrite containing high amounts of arsenic and antimony are covered widely in literatures by many researchers (Padilla et al., 1998; Welham, 2001; Vinals et al., 2003; Guo & Yen, 2005; Balaž & Achimovicova, 2006a; Filippou et al., 2007; Mihajlovic et al., 2007; Lattanzi et al., 2008)."

Jan 1, 2016

By J. E. Armstrong

THE Pinchi Lake mercury belt is in central British Columbia, about fifty miles north of the Prince Rupert branch of the Canadian National railway (Figure 1). Until 1936 little was known about the geology of this area. Jn 19~6 and 1937, J. G. Gray and the writer mapped the Fort Fraser area (G.S.C. maps 630A and 631A) for the Geological Survey of Canada. During the field season of 1937, cinnabar was discovered by J. G. Gray in the Permian limestones on the north shore of Pinchi lake on what have since proved to be the main showings of the Pinchi Lake mercury mine. Claims were staked in the spring of 1938 and later that year were optioned to the Consolidated Mining and Smelting Company. Development work revealed cinnabar deposits of commercial size and grade, and a small reduction plant was erected, production of mercury commencing in June, 1940. Since 1940, this plant has been enlarged by additional units. The ore treated is reported to contain between 0.5 and 0.75 per cent mercury. The production of mercury from this deposit is now far in excess of Canadian requirements and this country is able to supply the United Kingdom with part of its needs. In 1940 and 1941, several other occurrences of cinnabar were found northwest of Pinchi lake. During 1941, the writer made a geological investigation of the known cinnabar occurrences and of the belt of country in which they are located. The present paper summarizes the results of this work. The writer is indebted to officials of the Consolidated Mining and Smelting Company, and to Mr. E. Bronlund of the Pinchi Lake mine in particular, for their generous co-operation in the work.

Jan 1, 1942

In order to avoid impurity problem and enhance absorption/desorption kinetics of Mg-based compounds, nanostructured Mg-based compounds were synthesized from Mg, Ni and other elemental nanoparticles produced by hydrogen plasma-metal reaction. XRD and TEM results demonstrate that homogeneous nanostructured Mg-based compounds with less impurity were successfully synthesized by this method. DSC in hydrogen atmosphere, pressure-composition isotherm and the kinetics of hydrogen adsorption/desorption were investigated at different temperatures. The results show that the nanostructured Mg-based compounds can absorb hydrogen in a high speed at a low temperature.

Jan 1, 2005

By R. Salimi

Tricalcium aluminate hexahydrate (TCA) is used as filter-aid for security filtration in the Bayer alumina process. TCA is typically produced on-site by mixing Bayer liquor with slaked lime. Specific properties are required from the TCA to ensure adequate filter throughput, lifetime and importantly effective reduction of solid/colloidal impurities from the solution. The effect of reaction time on morphology and particle size distribution of tricalcium aluminate was studied for a batch experiment at simulated process conditions. It was found that reaction time plays a critical role on the morphology, crystal structure (diameter and crystallinity) and particle size distribution. In the early stages of the reaction, nucleation dominates the crystallization process followed by growth dominated by agglomeration up to a mean particle size of 10 µm. The particle morphology shifted from an irregular shape to more spherical throughout the course of the reaction.

Jan 1, 2014

By E. G. Baltuch

Natural Ventilation in mining and metallurgical processing applications is key to proper operation function. There are number of ventilator designs available to a project team or design engineers, the selection of which will affect both the type of building structure required, project costs and design performance which is difficult to rectify or re-engineer once implemented. Research and applied results, such as that performed by Air-Therm Inc., demonstrates that computational fluid dynamic simulation allows for 5 dimensional observation, analysis and optimization at significantly lowered cost than previously possible. These results have been fully implemented on a number of mining and metallurgical applications and the company continues to study, optimize and innovate as new tools become available to provide the best possible engineered solutions for particular applications.

Aug 1, 2013

By P. W. A Severin

"The Sturgeon Lake deposit, a partly eroded lens of massive sulphides with an underlying sulphide stringer zone, is one of five orebodies that occur in the Sturgeon Lake area of northwestern Ontario within volcaniclastic rocks of the Archean Wabigoon Subprovince in the Superior Province of the Canadian Shield.The Sturgeon Lake Cu-Zn-Pb-A g-Au deposit was discovered in October 1970 as a result of an I.P. survey. Production from this open-pit mine began in March 1974 and continued until the ore was exhausted in March 1980.The Sturgeon Lake property is underlain by basaltic volcanics, minor amounts of mafic lapilli tuff and rhyolite volcaniclastics. A quartz crystal-bearing rhyolite occurs at the top of the felsic volcaniclastics and is ""capped"" by the Sturgeon Lake massive sulphide deposit. The felsic volcanics have been intruded by a crudely layered sill-like, carbonatized mafic intrusion. Recent work suggests that the felsic rocks that underlie the Sturgeon Lake deposit are lateral equivalents of those in the vicinity of the Mattabi Mine and are not correlative with the dacitic volcaniclastics that underlie the Lyon Lake and Creek Zone deposits. Hydrothermal processes that resulted in the formation of the Sturgeon Lake orebody have resulted in a depletion of Na2O, CaO and FeO and an increase in MgO, K2O, copper and zinc. In the vicinity of the sulphide stringer zone, the rhyolites are ""bleached"" due to silicification and sericitization. The rocks lying immediately below the massive sulphides are locally strongly chloritic.The Sturgeon Lake deposit may have formed on a top ographic high which prevented mafic flows and dacitic volcaniclastics that underlie the Lyon Lake and Creek Zone deposits from inundating the Sturgeon Lake fumarolic vent from the west. Continued or resurgent activity from the Sturgeon Lake fumarole may have resulted in the formation of the Lyon Lake and Creek Zones as more ""distal "" deposits in topographic lows. The Sturgeon Lake, Lyon Lake and Creek Zone deposits were subsequently overlain by mafic tuffs and flows."

Jan 1, 1982

By James R. Hunter, Sandra K. Zacharias, Ursula M. Franklin

Archaeometallurgical remains can be a valuable source of information about past technological activities and, by inference, the societies that undertook them. Material traces of former metal-producing or metal-working centres can include raw materials, products, or metallurgical installations such as mines, furnaces or forges. Of these remains, the most common is slag, often left undisturbed since its original production. Physical and chemical analyses of archaeological slag and metal can often reveal the processes and materials involved in their formation. Mineral composition and softening temperature of a slag, for instance, can indicate the conditions of the metallurgical operation, such as temperature and atmosphere and, thus, help identify metallurgical processes which took place at a site(1). The present report illustrates the value of such analysis. Metal-working remains from Sainte-Marie among the Hurons, near Midland, Ontario, on the south side of Georgian Bay have been analyzed in order to determine the techniques and processes used by the 17th-century blacksmith who worked at the mission headquarters from 1642 to 1649. Samples were selected from a very large collection of blacksmith refuse which was excavated from the site by archaeologist Kenneth Kidd in 1941-42(2).

Jan 1, 1999

By S. J. Cook

Outstanding advances among the metals, marked the mineral production records for Canada during the first half of 1925. Production of metals and non-metals reached a total value of $90,347,698. as compared with $84,307,385. in the first half of 1924, an increase of 7.16 per cent. Metals and non-metals produced during the calendar year 1924 were valued at $17 4,202,537.; production during the first half of 1925 showed a sum equal to 51.86 per cent of this total. Advances among the metals were general. Gold rose to a new record. Lead advanced 62.41 per cent over the high mark attained in the first half of 1924. Nickel production was well maintained. Copper was up a million pounds. Silver showed increased values. Zinc followed the trend in lead to almost double the output recorded in the first half of 1924. Cobalt production continued to improve. Despite the loss due to the protracted strike in the Nova Scotia coal mines which reduced the output of coal in that province; during the six months ending June, to less than half the tonnage reported in the first six months of 1924, improved conditions throughout the rest of the non-metal mining field resulted in the production of non-metals during the half-year reaching a total value of $31,199,233. as compared with $36,844,286. in the first half of 1924; the loss in the value of coal output al one amounted to $5,723,873, while the decrease in the aggregate value of non-metals amounted to only $5,645,053.

Jan 1, 1925