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By J. Schick, V. Granger

Nowadays, all French former uranium mining sites are remediated and redeveloped. If needed, mining waters containing radium have to be treated before discharged into the environment. Classical radium treatment consists in a (Ba,Ra)SO4 salt precipitation and radium monitoring was carried out using a time-consuming analysis called emanometry. Three zeolite samples have been tested to remove 226Ra from mining water. In batch experiment, radium was totally (R=100%) and quickly removed after 2 minutes contact time. Continuous sorption experiments were carried out through a vertical column at lab scale. Chabazite is the most efficient zeolite with an 226Ra activity below 0.2 Bq/L until 60000 Bed Volume. Chabazite is always efficient although radium content in material reaches 150 Bq/g. 226Ra uptake was also tested at semi-industrial scale on a pilot plant. More than 3000 m3 were successfully treated with a radium content below 0.1 Bq/L. The environmental impact assessment of Ra-chabazite was characterized by using batch leaching tests made according to the NF EN 12457-2 standard as applied on all wastes. Ra-chabazite stability is excellent during this test: radium leaching is very low, less than 0.005%. A new 226Ra measurement method was developed by ICP-MS for a better analysis reactivity. This new method was carried out in a couple of minutes with a lower sample volume than emanometry. The validation was performed according to the French NF T90-210 standard for the calibration function definition, the limit of quantification, the accuracy and the interferences.

Jan 1, 2020

By J. W. Gregg, P. M. Dranchuk, D. L. Flock

"From preliminary investigations it has been observed that although evaporation losses may be estimated by comparing single values of certain physical properties of crude oils and their evaporation residues, such techniques possess little accuracy unless both the evaporation process and the variation of the property as a function of the process are completely known. The accuracy of estimation may be increased somewhat through the comparison of property mid-per-cent curves. Further increases in accuracy are possible if bottoms yield •curves rather than mid-percent curves are used. The use of both the mid-percent and bottoms yield curves however involves a prohibitive amount of effort in most cases. Examinations of distillation bottoms from Hempel type distillations carried to end points just short of the cracking point have indicated that these bottoms are not appreciably affected by the evaporation process. It was further observed that bottoms of identical API gravity, obtained from a crude oil and its evaporation residues behave as if they were pure components which were unaffected by evaporation. Based on these observations Hempel distillation bottoms of equal API gravity were obtained for a crude oil and its various evaporation residues from API gravity bottoms yield curves. The volume percent of these bottoms in the crude oil and its residues were used to calculate the evaporation losses suffered by the crude in order to yield the various residues. The results indicate that, although further refinements in technique are required, it is possible to calculate evaporation losses with an accept-able degree of accuracy through the use of this method."

Jan 1, 1960

By A. R. Laplante

Gold recovery early in the flowsheet, typically from the primary grinding circuit, has seen significant advances in the past three years. Some of the advances achieved under the auspices of the AMIRA P420B Gold Processing Technology project are reviewed. The areas covered are gravity-recoverable gold (GRG) characterization, GRG behaviour in classification, gravity recovery simulation and the link between gravity recovery and cyanidation.

Jan 1, 2005

By B. Stettner, J. Asante, S. Abraham

The levels of nitrogen in steel produced in various metallurgical vessels vary significantly. For example, the tap nitrogen levels in steel produced in the BOF are around 4Oppm, as compared to 70-100ppm in both DC and AC electric arc furnaces. Given the pressing need to reduce nitrogen levels in steel to satisfy customer demand, IPSCO Inc. has gained considerable experience in controlling nitrogen levels in steel over the course of the last three years. Hence, a cost effective process has been developed through an intensive nitrogen control program from steel melting in the EAF through to the continuous slab casting stage. This paper describes the practices employed at each stage of the steelmaking process that have enabled IPSCO Inc. to reduce and control nitrogen levels in steel.

Jan 1, 2004

By D. Michaud, C. Bazin, S. Lévesque, L. Pérez-Barnuevo, H. Longuepée

In recent years, with the emergence of Geometallurgy, a great effort has been made to characterize ore resources as early and accurately as possible, to allow better design and a more efficient operation of mineral processing circuits. In this context, core logging plays an important role, since drill cores provide the first insight into the ore characteristics. However, to satisfy geometallurgical requirements, traditional core logging does not suffice. New tools and methodologies need to be developed for the automation of core logging and the acquisition of mineralogical data better related to mineral processing performances. In this paper, a methodology for the geometallurgical characterization of drill cores is proposed, based on the drill core textural patterns. Textural pattern is defined here as the macroscopic spatial arrangement of minerals. The Mont-Wright iron ore deposit (Quebec, Canada) is used as a case study. The first part of this work aimed at analyzing the potential link between the iron ores textural patterns observed in drill cores and their response to ore processing, namely comminution and concentration. Preliminary results show similar performances in terms of energy consumption and heavy liquid separation for samples showing the same textural pattern. In the second part, this work seeks to develop a methodology for the automated identification of drill core textural patterns by the application of digital image analysis and discriminant function analysis. The results obtained show that this methodology is able to discriminate between the textural patterns identified at Mont-Wright with a good rate of success. Therefore, this work lays the foundation for the development of a new drill core characterization tool, which would allow for the early prediction of the iron ore behaviour during mineral processing through the identification of drill core textural patterns.

Jan 1, 2016

By L. Cáceres, G. Leinenweber, P. Bustamante

"Given the severe scarcity of fresh water sources in Northern Chile the use of seawater has become the only alternative to allow mining expansion. This option however poses several technological challenges as a result of the high concentration of natural salts that promote various forms of metal corrosion. Therefore the steel piping protection has been a constant challenge for design engineers responsible for solving the problems of corrosion. Known protection alternatives are varied and expensive, a few of them are rubber coatings, protection based centrifuged concrete, extra wall thickness of pipes in combination with corrosion inhibitors, extra wall thickness of pipes without using corrosion inhibitors, and the use of highly corrosion resistant steel materials.In this framework the aim was to study the corrosion kinetics of carbon steel pipe API 5L X70 under electrochemical and weight loss testing. The test conditions include a range of seawater velocities between 0.2 to 3.0 m/s.For electrochemical experiments the API 5L X70 steel specimen was a 4 mm diameter disk embedded in an 8 mm diameter Teflon rod and exposed to seawater. Duplicated coupons were placed in a standard test apparatus that was built according to the standard ASTM D 2688 – 94.The main results were: a) corrosion mechanism explained in terms of the counterparts partial processes which are the hydrogen evolution and oxygen reduction reaction; b) for the test specimen a corrosion band like feature that suggest a lateral dispersion of aggressive solutions from corrosion pits; c) a range of corrosion rates between 1 and 1.96 mm/year for flow rates between 0.2 and 3.0 m/s; and d) a convenient inhibitor dose between 20–25 mg/L for optimum inhibition efficiency to obtain a maximum value of 80% for corrosion efficiency."

Jan 1, 2016

By Q. H. Bui

The elastoplastic self-consistent model is one of the effective models to study the initial microstructure effect on the mechanical behavior of bulk materials. However, the use of this micromechanics-based model which takes into account only the Hall-Petch relationship at grain level for predicting the grain sized effects on the strength of the deformed materials is not accurate yet because of the fact that the dislocation density contributes also to the strengthening of this kind of materials. In this study, a modification made to the Hill-Hutchinson elastoplastic self-consistent model was proposed for investigating the microstructure dependence of the mechanical behavior of cold-drawn 6063 aluminium tubes. Because of the novel modification, an estimation procedure with two steps was required to identify the parameters of this micromechanical model. An acceptable agreement between experimental and theoretical stress-strain curves was achieved.

Jan 1, 2011

By P. M. Daignault

"Fording Coal Limited is one of Canada's largest producers of metallurgical coal for the export market. Medium- to highvolatile coals are mined at its Fording River operations in southeastern British Columbia. This paper discusses some of the mine design and production related problems encountered, and how they have been resolved. Other aspects of the operation such as geography, geology and standard mining methods employed are also covered.IntroductionFording Coal Limited was formed in 1968 to mine and market metallurgical coal resources held by the company in the East Kootenay region of southeastern British Columbia<1>. The company, at its Fording River operations, holds approximately 19,635 hectares of coal lands, having an estimated resource of 3.5 billion tonnes of metallurgical coal. Total reserves are approximately 520 million tonnes.Fording Coal is owned 600Jo by Canadian Pacific Enterprises Limited and 400Jo by Cominco Limited. Cominco itself is owned approximately 540Jo by Canadian Pacific Enterprises. The company, originally staffed and managed by Cominco, has been independent since January 1978, with its own board of directors, management, staff and employees. The head office is in Calgary, Alberta. The Fording River operations are located in British Columbia, approximately 70 km north of the Crowsnest Pass, near the Alberta/ British Columbia boundary, only 150 km by air and 320 km by road from Calgary.A contract was signed in 1969 with the Japanese steel mills to provide 45. 7 million tonnes of metallurgical coal over fifteen years, commencing in 1972, at an annual rate of 3 .05 million tonnes per year. The mine is presently expanding annual production capacity from the original 3.0 million long tons (3.05 million tonnes) to in excess of 5.0 million tonnes.Concurrent with this production expansion, a vigorous marketing effort has diversified Fording's customers to include additional countries in the Pacific Rim area. Three cleaned coal products are now marketed compared to the single ""standard blend"" product originally shipped to satisfy the Japanese contract. The product specifications are listed in Table I."

Jan 1, 1985

By X Dai

This paper investigated the loss of cyanide via oxidation in CIP or CIL processes by relating the cyanide oxidation to its major oxidation product, cyanate. The results showed that the oxidation of both free cyanide and copper cyanide complexes are substantially enhanced by the presence of carbon. The rate of cyanide oxidation was found to occur in the order: Cu(CN)32- > CN- > Cu(CN)2-. The cyanide oxidation rate in the presence of copper and carbon increased significantly with increasing dissolved oxygen concentration, typical of CIL vs. CIP conditions. Cyanide oxidation rate of iron, zinc or nickel cyanide complexes was minimal.

Jan 1, 2011

By G. Zárate, G. Tapia

Anglo American Chile has been doing copper concentrate leaching studies at the laboratory and small pilot plant scale since 1992. Among the processes evaluated are bacterial leaching and pressure leaching using Mantos Blancos, Salobo Project and Quellaveco Project concentrates. Late in the nineties, it was decided to focus the research on pressure leaching, either medium or total pressure oxidation. Preliminary scouting tests were run with Mantos Blancos concentrate samples during 2000, which were repeated during 2003 together with samples of Los Bronces and El Soldado concentrates, in order to define the most suitable concentrate for running a pilot plant campaign at AARL, which was carried out in two campaigns, a first one from November 2003 through January 2004 and a second one during April 2004. Mantos Blancos was the selected concentrate and the laboratory and pilot plant results are discussed in this paper together with some preliminary economic estimates.

Jan 1, 2004

By I. M. R. Duarte, J. A. Rodrigues-Carvalho, F. R. S. Rosa, A. B. Pinho

"This paper aims to contribute to the knowledge of the mechanical properties of the shales and greywackes which constitute the flysch-type deposits of the Baixo Alentejo Flysch Group, in the south of Portugal. These formations are flysch-type deposits constituted by sequences of usually thick greywacke beds alternating with thin shale beds, which include sometimes intercalations of conglomerate beds. All the sedimentation of these flysch formations was controlled by tectonics. At the same time, should have occurred along with the first Hercynian deformation phase, a low-grade metamorphic event (chlorite zone), that affected these flysch deposits. This study highlights the influence of anisotropy and heterogeneity of these flysch rocks on their physical and mechanical characteristics. The anisotropy verified in some physical properties and on mechanical properties, due to the foliation makes difficult the sample preparation for the laboratory tests. Besides, it induces a scattering of the properties values measured, as for example, the strength and the deformability. The heterogeneity is related to the main features of these geological formations, which are constituted mostly by thinly stratified greywackes and shale beds, which sometimes may affect the results of the laboratory tests making them less representative. The study is made by using both shales and greywackes that constitute these flysch-type deposits in order to evaluate their geotechnical properties, mainly of the shales. Samples of these two rock materials, are tested accordingly a laboratory testing programme, which includes which included mineralogical analysis (X-ray diffraction), physical tests (bulk density, porosity, and void index) and mechanical tests (uniaxial compression, and deformability tests). INTRODUCTIONOne of the factors that most influence the geomechanical behavior of rocks, as well as rock masses is the anisotropy. The word anisotropy comes from two Greek words ""anisos"" (meaning uneven) and ""tropos"" (meaning direction). A body or material is considered to be anisotropic, where the same property has different values depending in which direction it is measured, therefore, an anisotropic material is one whose magnitude of the properties depends on the direction in which these are studied or measured. Otherwise, it is about an isotropic material. However, the fully isotropic materials are quite rare in nature."

Jan 1, 2015

By Su-Ping Peng

Three dimensional (3D) seismic exploration has been carried out since the 1980s in the mining district of China, where it has been playing an indispensable role in the high yield and efficiency of coal mining. Unlike oil exploration, this technique uses high density seismic acquisition technology. In recent years, it has focused on wide azimuth 3D seismic acquisition. Evaluation of geometry moved away from depending on folds, azimuth and offset, toward being based upon a focus-ray beam. Conventionally, coalfield 3D seismic interpretation focused on time domain and was based on kinematics information, which is only suitable for less complex geological conditions. To achieve high-resolution processing for the complex topography and structure in coalfields, data processing shifted from poststack to prestack. The means to improve the accuracy of interpretation for complex geological conditions are 1) integration of multiple attributes and multiple disciplines, 2) combination of seismic and geological data, and 3) comprehensive combination of time domain and depth domain data. With the demand for lithological exploration, high-resolution data processing must also take into account the requirements of preserving amplitude in seismic data. Seismic attributes technology, seismic inversion technology, and dynamic tracking interpretation are key techniques in 3D seismic exploration. They greatly improve interpretation accuracy, produce better results in the goaf space description of the coal-bearing strata and coal seam structure, and effectively reduce exploration costs under complicated geological conditions. Therefore, these techniques will be the primary means employed in the future to deal with coalfield complex structure and lithological exploration.

Aug 1, 2013

By J. Lu, J. B. Wiskel, D. G. Ivey, E. Niemi, H. Henein

Simulated TMCP using a Gleeble was undertaken to evaluate the effect of the austenite to ferrite cooling rate, coiling temperatures of either 400°C or 500°C and the magnitude of plastic deformation at the coiling temperature on the hardness of a Grade 483 (X70) steel. For comparable apparent cooling rates and deformation conditions, the hardness of the samples were independent of coiling temperature The application of a minimum compressive deformation > 8% was required to increase hardness at both simulated coiling temperatures of 400°C and 500°C. An increase in hardness was also observed with increased cooling times between 800°C and 500°C (i.e., slower cooling rates).

Jan 1, 2005

By E. J. Marcotte

"INCO LIMITED'S Shebandowan Mine and Mill is located in a scenic tourist and cottage area near the western tip of Lower Shebandowan Lake, approximately 90 Km west of Thunder Bay, Ontario. This nicely designed complex is a positive indication that mining operations can co-exist in harmony within the natural environment.The Shebandowan complex processed nickel-copper ore from 1973 to 1985, inclusive, after which operations were shut down.In late 1988, INCO LIMITED decided to place the Shebandowan complex back into operation, under contract, to mine and mill the remainder of the ore body, according to their specifications. MaclSAAC'S EXPLORATIONS was the successful bidder for the project. Following preliminary rehabilitation, operations were re-activated in late March, 1989. The ore mined to date is of a moderately lower nickel grade than the majority of previous years. However, a higher tonnage rate, combined with improved nickel recoveries, has contributed to a viable operation.A series of mill operating and equipment modifications has enabled MaclSAAC EXPLORATIONS to achieve the quality and grade of nickel-copper concentrates specified, and at the same time, expand mill tonnage throughput while attaining increased nickel recovenes."

Jan 1, 1992

By W. Holdsworth

The flotation mill of Dentonia Mines, Limited, at Greenwood, B.C., went into operation on April 20th, 1934, and by October 11th a total of 15,000 tons of ore had been treated. It is intended in this paper to describe briefly the operation and to give some of the operating data which have been gathered. The metallic minerals in the Dentonia ore are pyrite, chalcopyrite, galena, and, occasionally, native gold, and the gangue includes chloritic material, vein quartz, and calcite. Pyrite makes up about 90 per cent of the metallic content of the ore, in which it is disseminated as irregular grains and well-formed cubes. An average analysis of the ore is: gold, 0.27 oz. per ton; silver, 1.73 oz. per ton; copper, 0.12 per cent; lead, 0.31 per cent; and zinc, trace. From the mine ore-bin, situated near the portal of the tunnel at the mine, the ore is hauled by motor truck to the mill, a distance of three-quarters of a mile, and there dumped into the receiving bin, which has a capacity of fifty tons. The hauling is done during one eight-hour shift, commencing at 7 a.m. The maximum size of the ore fed to the mill-bin is ten inches. Lumps larger than this are broken by sledge hammer to pass through grizzly bars, spaced ten inches apart, installed above the bin. The ore is drawn from the bin by a 30-inch, 6-ply conveyor belt, 18 feet 6 inches long. In the near future, when the cross-cut tunnel is completed, the ore will be trammed to the receiving bin. This will effect a considerable saving in cost. At the same time, the bin will be set back several feet, so that the length of the conveyor belt may be doubled. This will make efficient ore-sorting possible, and so ensure a minimum of waste rock in the mill feed.

Jan 1, 1935

By W. G. Hubler

History The Aldermac mine is situated on the Nipissing Central railway near the &apos; centre of the township of Boischatel, Quebec, and is about ten miles west of Noranda. Aldermac Mines, Limited, is a subsidiary company of Towagamac Exploration Company. The property was staked by Messrs. Alderson and MacKay and McMartin, during the winter of 1922-23. During October, 1925, a copper discovery was made by K. W. Fritzsche, who was in charge of exploration work at that time, the first trench on this discovery averaging 8 per cent copper over a width of ten feet. This led to the discovery of another body 200 feet to the north, with an average of 3 per cent copper over fifteen feet in width. A magnetic survey was then carried out which led to the location of the large pyrite ore-bodies which have been developed in the past few years. Development work was carried on to a depth of 1,125 feet, and approximately three million tons of massive pyrite ore was indicated. Extensive metallurgical tests were conducted in the laboratories of the Mines Branch of the Department of Mines at Ottawa to determine the proper metallurgical treatment and the economic possibilities of the ore. Owing to the comparatively low copper content, and the uncertainty of the copper market, it was doubtful if the mine could be profitably operated for the production of copper alone. Messrs. Alderson & MacKay, however, realized the possibility of utilizing the large tonnage of pyrite as a substitute for native sulphur, &apos;which in past years has been imported into .Canada for the manufacture of acid and sulphate pulp in paper mills. They therefore organized the Sulphite Research Corporation with the object of developing an economical process of utilizing the pyrite.

Jan 1, 1932

By D. H. Ryan, B. Abdul, M. Pernechele, E. Asselin

Hydrometallurgical processing of sulphide concentrates at medium temperature (150°C) produces residues, which contain valuable metals (Cu, Ni) as well as sulphur and iron bearing minerals and phases. The low solubility of iron during the medium temperature processing of sulphide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. A better understanding of the formation and structure of these iron precipitates may elucidate key factors that would ultimately result in lower valuable metal losses and more stable leach residues. Residues from two medium temperature leach processes were characterized by Mössbauer Spectroscopy. Some portions of the Mössbauer Spectrum were suspected to be linked to jarosite but could not be positively identified as such. There was a broad range of disorder and substitution present in the material and solely attributing it to jarosite proved difficult. Various synthetic jarosites with Cu substitution were precipitated for Mössbauer analysis. These were then characterized by Quantitative X-Ray Diffraction (QXRD), Scanning Electron Microscopy (SEM), Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) and Mössbauer Spectroscopy. The Mössbauer Spectra of the synthetic jarosites is compared with that of the residues from medium temperature (150°C) sulphide concentrate leaching.

Jan 1, 2014

By N. Golchinfar

Tunnels in deep mines are subjected to high stresses. Fracture and failure of the rock mass around an opening can occur when mining-induced stresses are high. In burst-prone grounds, mining-induced seismicity can cause additional dynamic loading which can further increase the stress around the tunnels. When the dynamic stress reaches the rock mass strength, fracturing can occur and rockburst may happen (depending on loading stiffness around the failed rock mass). Rock support installed in the tunnel must be capable of dissipating dynamic energy and holding the failed rocks. Hence, it is important to estimate the depth of failure for rock support design. This paper focuses on how to model depth of failure under dynamic loading. In the modeling, two scenarios of rock failure are considered. In the first scenario, rock failure occurs under static loading and subsequent dynamic loading further increases the depth of failure. In the second scenario, no failure occurs under static loading but in the subsequent dynamic loading, failure around the tunnel is created.

Aug 1, 2013

By D. Stone, N. J. Aslin, W. Webb

In today&apos;s modem copper electro-refineries, increasingly higher average current densities are being employed. With these increases many refineries are approaching their limiting current density. The nearness of the average operating current density to the limiting current density has placed increasing emphasis on the need to maintain an even current distribution. This paper explores the importance of maintaining even current density and discusses the factors, processes and practices that are necessary to achieve and maintain high quality production at high operational intensity.

Jan 1, 2005

CSIRO Minerals, in association with the AJ Parker CRC for Hydrometallurgy, has an active program of hydrometallurgical research in which physical and computational modelling are used to better understand and improve a range of different unit operations. The modelling is based on flow simulation (Computational Fluid Dynamics or CFD), but incorporates other physical and chemical phenomena of importance, such as droplet break-up and coalescence, species transport and reaction. This paper reviews some of the major projects that have been undertaken at CSIRO Minerals and will illustrate the critical importance of hydrodynamics to the performance of unit operations and the improvements that can be made to performance using such modelling techniques. Unit operations that are discussed include solvent-extraction, gravity thickeners, flotation cells, bio-heap leaching and stirred tanks.

Jan 1, 2005