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By P. Mengé

The covering of a hydraulically filled goethite pond is discussed from a geotechnical point of view. The characteristics of the goethite were defined in order to allow a detailed study of the procedure for the construction of the cover on top of the soft material and a verification of the stability of the cover and side slopes after construction. These characteristics and the main results of the studies are given, as well as the experiences and observations made during the execution of the work. Finally, the monitoring plan, during and after construction, is also discussed and some results are given. The 'Design and Construct' contract form was used to allow the contractor to choose the optimum and most economical method to realize the closing of the pond, based on his experience with similar projects. The works were carried out between mid 2003 and the end of 2004. The paper will, amongst others, discuss the special method of working that had to be developed to allow the covering of the whole pond in a relatively short time period, without soil improvement methods such as vertical drains or stabilization by in situ treatment. Fill material was used to establish a platform on top of the soft material so that the cover liner and finishing layer could be installed on top of the fill layer. The 'floating roof' principle was used; subsidences were allowed to occur during the installation of the impermeable top liner and soil cover.

Jan 1, 2006

By L. Haavanlammi

Iron is a significant component of all copper concentrates leached in the HydroCopperTM process. The metals in the concentrate are leached in a chloride solution by oxidation with cupric ions. Copper enters into the solution as a cuprous chloro¬complex. Iron dissolves at the same time in the ferrous form, but it is immediately oxidized to the ferric state. Oxidation is effected by sparging air or oxygen into the leaching reactors. Because the pH is 1 - 2.5, ferric ion precipitates as akaganeite (T<90°C) or hematite (T> 90°C). Arsenic, antimony and the main part of the bismuth co-precipitate with iron and report to the leach residue. Cupric leaching is faster than iron oxidation; thus, leaching of low-iron concentrates (secondary copper minerals) is quicker than leaching high iron concentrates (chalcopyrite). Pyrite does not dissolve during copper leaching, but is oxidized slowly at higher redox-potentials after the copper has been leached.

Jan 1, 2006

By S. K. Dimitrov

?Ellatzite Med? is one of the biggest mining companies in Bulgaria, processing about 12,000,000 t of ore per year. Waste materials left after extraction of copper concentrate are deposited in tailings dam ?Benkovski 2?. The hydraulic structure is built according to the downstream method, through hydrocyclonization where the downstream batter and the body of the wall are formed by the separated coarse sand particles of the separated tailings. In connection with the prolonged concession of Ellatzite Med and the enlarged capacity of Benkovski 2, the tailings dam has expanded on to the surrounding terrain. To guarantee a normal hydrocyclonization and build up of a tailings wall during waste deposition from the ore mill, the technological scheme of the hydraulic transport system of Benkovski 2 has been changed.

Aug 1, 2013

By H. Yoshida, H. Hatta, T. Suzuki

"The effect of the copper and magnesium contents and quenching rate during quenching on the age hardening behavior of 2000 series aluminum alloys was investigated. For the higher copper-containing specimens as conventional alloys, like AA2024, precipitation of the stable phases increased as the quenching rate decreased under the as-quenched conditions. The maximum hardness after the artificial aging of air cooled(AC) specimens was much lower than that of the water quenched(WQ)specimens. On the other hand, for the lower copper-containing specimens, coarse precipitation did not increase even in the case of the AC. The age hardening behaviors of the WQ and AC were very similar such that the maximum hardness and aging rate were almost the same. Many parts of the fine precipitates that increased the hardness were thought to be the GPB zone or fine S’ phase for the WQ and relatively coarse S’ phase for the AC. From the calculated CCT(continuous cooling transformation)diagrams, the lower copper-containing specimens could maintain the copper and magnesium in the solid solution state during the AC, so they could be quenched at a rather slower quenching rate like the AC.INTRODUCTIONThe 2000 series aluminum alloys, containing copper and magnesium as the major chemical components, are some of the well-known heat treatable aluminum alloys. These alloys have a high quenching sensitivity, thus the age hardening ability of these alloys decreases with as low quenching rate. To prevent the decrease of the age hardening ability, quenching is done by a method such as water quenching, which is not very efficient in an industrial situation, because the method requires such large equipment. For these alloys, reducing the quenching sensitivity helps them to be produced in a rather convenient way. For example, 6000 series alloys such as A6063 have low quenching sensitivity, thus they could be quenched by only air cooling just after extrusion and they do not need water quenching. Based on these reasons, investigations of these alloys with high copper and magnesium contents have been conducted in the past to find a way to lower the quenching sensitivity by adding transition elements such as manganese, chromium and zirconium (Kanno, Suzuki, & Itoh, 1986; Suzuki & Itoh, 1986; Kanno, Sakuma, Muromachi, & Watanabe, 1988). However, very few studies have focused on the quenching sensitivity of the lower copper and magnesium containing alloys because of their usage for structural components with high strength, and most of the past studies have used only the fast quenching method like water quenching. On the other hand, from our recent results, there is a possibility to lower the quenching sensitivity of 2000 series alloys with lower alloying elements. In this paper, the effect of the copper and magnesium contents with lower alloying elements and quenching rate, especially in case of slower quenching rate than conventional quenching method, on the age hardening behavior of the 2000 series alloys is investigated by the hardness measurement, structure observation and thermal analysis."

Jan 1, 2018

By M. Reda

Erosion corrosion is acceleration in the rate of corrosion attack in metal due to the relative motion of a corrosive fluid and a metal surface [1]. The increased turbulence caused by pitting on the internal surfaces of a tube can result in rapidly increasing erosion rates and eventually a leak [2]. Engineers and scientists in different disciplines have worked for many years on methods of complete protection from flow induced corrosion or partially reducing corrosion of this type, and they have proposed or applied different countermeasures [2]. The accident at the Surry-2 nuclear power plant (USA) and other similar incidents have once again disturbed the scientific-technical community. This has forced the plant operating personnel and the management to undertake wide-ranging measures in order to discover on time, assess, and monitor such cases. In these extreme cases, protective coating and even metallic bulk material coating (the substrate itself) may suffer considerably from mechanically induced damage [2]. At high velocities, the "leaching out" dissolution reaction of particular, for example, steel elements at the solid-liquid interface become the rate determining step. One practical example for the difference between erosion corrosion and flow induced corrosion is the famous steam eruption from a Japanese [3, 4] nuclear power plant cooling system at the pressurized water reactor (PWR), turbine and in the condenser-steam generator connecting pipe. The rupture occurred in the carbon steel pipe connecting the condenser and steam generator. The damage occurred in the easily eroded/corroded carbon steel at a vulnerable location downstream of an orifice plate, In general, when there is significant reduction in pipe thickness through erosion/corrosion, distinctive patterns are visible, but those patterns were not observed in this case, Thus one can speculate that another phenomenon is possibly controlling, Fluid flow within pipes reduces the pipe thickness leading to an eventual rupture, The thickness reduction mechanism is erosion/corrosion, One example is "cavitations corrosion", Erosion and corrosion occur at the same time, and it is difficult to determine which one is dominant, Therefore, the term, "erosion/corrosion," is used [5]. In the atomic energy field, the terms "Flow Accelerated Corrosion" and "Flow Induced Corrosion" are also used. It is the purpose here to show that during flow induced corrosion a different mechanism may possibly be operating and in some cases it can be different from the well known erosion corrosion. Another example is fretting failures in early Canadian nuclear steam generators which was thought to be due to excessive vibration caused by high.

Jan 1, 2010

By W. B. Agocs

"AbstractThe airborne magnetometer data of the Marmora iron ore deposit at Marmora, Ontario, have been used as an example to show the mapped results obtained by the use of line spacings of from 1 mile to 14 mile. The maps are illustrative of the results which could be obtained from such line spacings for any type of geophysical survey, and they show the probability of 'missing' a feature of economic value if the line spacing is too coarse.The probability equations are given for the crossing of randomly oriented features whose maximum dimension is less than the spacing of the control lines for circular, elongate, and rectangular outlines. The equations are P = D/S; P = 2L/S; P = 2(L+W)/,.S; P = A/,.S; P = (2L(S+T)-L2),.ST; and P (D(S+T-,.D)) ST, respectively; where P is the probability; D is the diameter; L is the length; W is the width; and S and T are line spacings.IntroductionTHE EFFECT of station spacing, and the effect of the distance between the plane of observation and the plane of the source of the potential field anomalies, have been studied by geophysicists in the past.The purpose of this paper, however, is to illustrate the effect of line spacing •on the resultant mapped magnetic anomaly for a known magnetite mass, and to present the elementary probability equations for determining the optimum control spacing for detecting a particular type of feature. The effect of line spacing which is illustrated by the magnetic maps presented herewith would be comparable to results which would be obtained by any geophysical survey, since the contours between lines are of necessity interpolated."

Jan 1, 1955

By Z. Huda

The effect of various percentages of cold-working and recrystallization on the microstructure and hardness of commercially-pure aluminum plate, has been studied. The &apos;A critical deformation for the aluminum, has been determined. Experimentation involved cold rolling and recrystallization processes followed by quantitative metallographic practice and the hardness measurements. The raw material chosen was a plate of commercial aluminum which was cold rolled to different percentage of cold-work and then recrystallized by heat treatment at 150°C. The critical deformation percentage of aluminum was computed to be around 30% of cold-worked.

Jan 1, 2007

By J. L. Jambor, E. J. Reardon, E. C. Appleyard, J. A. Cherry

Abstract- Since the 1957 initiation of deposition of mill tailings at the Heath Steele mine, New Brunswick, periodic detailed studies of the tailings geochemistry and mineralogy have been con­ ducted, thereby providing a unique opportunity to examine the geochernical evolution of a sulfide- rich mine-tailings impoundment. When deposited, the tailings contained about 85 wt% sulfide minerals, 1 wt% to 3 wt% carbonate minerals, and 12 wt% to 14 wt% aluminosilicate minerals. Mineralogical examination of samples of the tailings from deep in the impoundment indicates that little oxidation occurred prior to tailings deposition. The mill process-water deposited with the tailings was neutral to slightly basic and contained low concentrations of Cu, Pb, Zn and As. Sampling of the tailings five years after deposition indicated that sulfide-oxidation reactions, occurring near the tailings surface, had decreased the tailings-water pH and increased the concentrations of Fe, SOi-, Cu, Zn and Pb (up to 10 000 mg/L, 25 000 mg/L, 2.5 mg/L, 200 mg/L, and 4.5 mg/L, respectively) . In 1975, ten years after decommissioning, the tailings could be divided into three zones: an upper oxidation zone in which sulfide oxidation is actively occurring, a hardpan layer, 15 cm to 20 cm thick, composed of tailings cemented by secondary Fe minerals, and an underlying reduction zone in which the tailings are relatively tinoxidized (Boorman and Watson, 1976). Chemical analyses indicated the presence of low-pH waters containing very high concentrations of SO42- , Fe, and other metals (up to 63 600 mg/L SO42-, 28 600 mg/L Fe, 10 mg/L Pb, 600 mg/L Cu and 4000 mg/L Zn), suggesting that there was a period of intense sulfide oxidation between five and ten years after tailings deposition. More recent sampling, conducted some 20 years after the end of tailings deposition, indicates that relatively little change has occurred in the last ten years, thereby suggesting that the hardpan layer has provided an impediment to the downward movement of dissolved constituents . Analyses of the tailings solids show increased accumulations of many metals at or near the depth of the hardpan layer. Evaluations of the long-term evolution of the tailings can be enhanced by comparison of descriptions of the tailings with descriptions of the gossan that overlay the massive­ sulfide orebody prior to mining. At Heath Steele, this comparison suggests that many of the mechanisms controlling the distribution of metals in the tailings will probably persist over geologic time.

Jan 1, 1992

By Brian C. Asbury

Gold-bearing quartz veins with auriferou pyritic wall rock alteration haloes at the Komis deposit near Waddy Lake in northern Saskatchewan occur in fractured Archean intermediate volcanic rock flanking a plutonic felsic intrusion. Three ore zones totalling 1.5 million tonnes grading five g/t gold have resulted from a combination of patterns of high density of fracture-filling quartz veins created by contrasting competencies of four predominant rock types and preferential gold deposition in magnetitebearing andesite host rock. Pre-glacial surface weathering remobilized gold from a nearby pyritized intermediateto- felsic dyke to form the EP Zone with a wide variety of supergene accessory minerals. Much of the EP Zone wa eroded by glacial action to forn1 a highly anomalous gold-bearing till dispersion train which facilitated its di covery.

Jan 1, 1986

By A. Zarei-Hanzaki, S. M. Fatemi-Varzaneh, M. Haghshenas

The microstructure in modified semi-solid ALTHIX (A356) alloy consists of aAl phase with Al/Si eutectic structure. Silicon phase in eutectic structure is coral like with fine fibers. The lack of good ductility in this alloy is related to the presence of silicon fibers. Accordingly many investigations have been recently conducted to modify the Si morphology through Thermomechanical processing on this alloy. In the present work an ALTHIX (A356) alloy was deformed at 450°C, 500°C and 540°C through different strain rates. Consequently the silicon fibers were broken into small particles. The results indicated that the Si particles may coarsen according to Ostwald ripening mechanism at 540°C deformed by rate of0.0005 sec-1 & 0.0001 sec-1-

Jan 1, 2006

By L. X. Li

Coking coal producers often encounter variations in clean coal quality when mining multiseam deposits containing coals with different washability and coking properties. This paper describes how, for a single coal property, an initial clean coal specification with an ash content of 8.5% on an air-dried basis (ADB) and a free swelling index (FSI) of 5.5 can be improved to a specification with 7.5% ash content ADB and an FSI of 6. This is accomplished by sorting coal seams into two groups for processing and blending. A preliminary economic model demonstrates how this improvement enhances economic returns through a beneficial factor.

Jan 1, 2014

By X. L. Song, G. W. Zhang, F. Y. He, X. Xiao, L. L. Huang

This paper presents the design of a model and process simulation of a vertical mill based on a population balance model. The simulator, Simulink, which is a systematic modeling tool within MATLAB, was used for the simulation. The model will simulate the real time variation trend of each size fraction in the feed material to the vertical mill, as well as, the size distribution of the batch grinding products. Breakage distribution and selection functions are calculated based on batch grinding laboratory experiments using Back-calculation method. The simulated size distributions correspond with those in the actual mill operation having a relative error of less than 0.50%. This work lays the foundation for future research on modelling and simulation of a closed circuit grinding operation consisting of a vertical mill with hydrocyclone classifier.

Jan 1, 2016

By Junior Santos

Kinross Paracatu started the operation of the new gold processing plant in the end of 2008, being composed by one SAG mill and two ball mills. During the first year of operation the plant had several problems related to stability and throughput capacity, mainly due to low grinding efficiency of the ball mills. In this period many actions were taken to maximize the throughput rate. Among the actions are reducing the size of balls in the mills, increasing the ball charge in the SAG mill, changing cyclone configuration and return of circulating load to SAG mill. With better stability of the circuit, the second stage of improvements has begun with the objective of increasing throughput rate and also reducing operation costs. Among the actions are the optimization of ball charge in the mills and a better operational control of cyclone parts. After two years of operation was obtained a significant increase in plant capacity, but still requires the addition of a third ball mill in order to maximize the use of SAG mill, which has spare capacity.

Jan 1, 2012

By T. E. Wakefield

"Final Galloway (stage) designs for vertical drill and blast shaft sinking projects evolve from complex thought patterns which integrate operational processes, systems and methods of communication, power supply, drilling, blasting, ventilating, mucking, supporting, surveying, dewatering, sealing, concrete lining and shaft furnishing. Attention to ergonomic design detail at the shaftsman / structure interface is at the heart of safe and successful multi-deck working platforms. For economy the end product must have a low mass to reduce suspension rope end loads to be able to use smaller suspension hoists and have lighter headframe structures, be robust to withstand concussion damage, be easily constructible on site, be maintainable in the shaft barrel, and comply with safety and legislated standards. This paper’s ambition is to describe a systematic design framework and sequenced thought process that delivers a product that is engineered with excellence, illustrated by making use of two designs that evolved during recent Galloway projects, one destined for a large diameter man/material shaft, the other for a ventilation shaft. The stage engineering iterative process starts with mapping permanent and sinking hoisting layouts, followed by laying out horizontal deck plans, mostly constrained by the permanent shaft purpose and configuration, whilst maximizing openings to enable muck to be removed rapidly for the best sinking cycles. Concurrently the designer needs to understand the chosen sinking methodologies in conjunction with crewing to determine the number of decks and fix their spacing. Insufficient access to move and line up formwork, set reinforcing rods and pour concrete in the confined spaces of the stage is an inherent major risk to be mitigated. An iterative and integrative process follows for the primary configuration which delves into increasing design detail, accommodating all other methodology influences, resulting in 3D layouts for further risk assessment, review and fine tuning by seasoned shaftsmen. INTRODUCTION Documented colliery shaft sinking practice from the late 1800’s makes reference to purpose built walling (bricked lining) cribs with floors suspended in sinking shafts, thereby allowing shaft lining to proceed concurrently with the excavation. Improvements were made by Sir William Galloway who introduced two decks supported at the corners by angle irons. The sinking stage, or Galloway, has developed substantially over time to be the in-barrel heart of the sinking operation, with overwhelming complexity for those who have to design one for the first time."

Jan 1, 2019

By M. B. Mansur, A. S. Guimarães, A. J. M. Santanilla, D. C. R. Espinosa, J. A. S. Tenório, R. A. Pini

The separation of Ni and Co from sulphate medium containing Mn, Mg, Cu and Ca was carried out by solvent extraction. The object of this study was to investigate the synergistic effect using phosphinic acid (Cyanex 272) and carboxylic acid (Versatic 10) and their mixtures in kerosene. The extraction percent of each metal ion was found to increase with increasing pH and extractant concentration. Co was preferentially extracted over Ni under the same extraction conditions. The separation factors of Ni/Co increased with the use of the synergistic systems investigated.

Jan 1, 2014

By E. A. Roux

As the first mine-to-metal zinc operation utilising atmospheric leaching, solvent extraction and electrowinning, Skorpion Zinc faces unique challenges and opportunities. One of these challenges is found in the solvent extraction circuit, in which di-ethylhexyl phosphoric acid (D2EHPA) is used as the organic extractant. Although D2EHPA is an excellent extractant for zinc, it suffers from the co-extraction of ferric iron, which is produced during leaching and by the corrosion of the grinding media. This situation is partially mitigated by iron precipitation in the neutralisation step prior to solvent extraction. Unfortunately, some ferric iron still reports to the solvent extraction process. This leads to a slow build up of iron in the organic phase. Chemical stripping is used to maintain the Fe concentration at an acceptable level. In this paper, the efficiency of the iron removal process is discussed.

Jan 1, 2006

By H. Mindivan

In the present study, the feasibility of recycling AA6061 Al alloy chips by a combination of ciyomilling, cold compaction and hot extrusion processes was investigated. Furthermore, the effect of Al powder addition to the recycled Al alloys chips on the mechanical properties was investigated. The characterization of recycled Al alloys was made by structural examination and mechanical tests (hardness, compression and dry sliding wear tests). The results indicated that by increasing wt. % of Al powder added to the recycled Al alloy chips the studied properties (the density, hardness, compressive strength and wear resistance) increased due to reduction of porosity in the recycled Al alloys.

Jan 1, 2011

By Xiu-Xiang Tao

This study investigated bio-liquefaction of lignite and its model compounds of thymol, bezioc acid and quinoline by a fungus, Hypocrea lixii AH. It analyzed, during bio-liquefaction, enzyme activity of oxidase, LiP, Lac, MnP and polyphenol oxidase, and degradation products by UV-Vis, FTIR, 13C NMR and GC-MS. The results showed that the bio-liquefaction percentage (by mass) of lignite was up to 44.86 %. The bio-liquefaction products of lignite were mainly aniline, amide, ether, carboxylic acid ketone and ester. The aromatic ring number was 1-3 with an aromatic carbon ratio of 0.328, which indicated rings opening, bonds breaking and oxidation reaction. By considering with the enzyme activity analysis results, it showed that LiP and Lac catalyzed reactions to open aromatic cycles and to break bonds; esterase to break ester bond; and peroxidase in oxidation reaction.

Aug 1, 2013

By Deepak Bhadouriya, Saurabh Singh, Aditya Raj Suman

"An experimental study of chemically enhanced filtration and dewatering of fine coal slurry with and without additives was carried out. The experiment involved determination of effect of slurry concentration, additives (cationic, anionic and nonionic), filter area, filtration velocity, particle size and cake resistance on dewatering and filtration using vacuum filtration cell. Finally, the rate of filtration and dewatering and optimum amount of additives used were determined under suitable filtration condition. Overall, it was found that the filtration and dewatering characteristics were enhanced by increased slurry concentration, larger filter area and larger particle size. In addition of additives, the kerosene was found to be best for enhancing the filtration which yielded cake moisture reductions of approximately 17% by weight. At optimum dosages, the final cake moisture contents were reduced by 3.6% and 5.8% by weight using the appropriate surfactant and flocculent, respectively.INTRODUCTIONFor India, it is estimated that coal constitute a principal source of energy for the next several decades. It is majorly used at thermal power plants to generate electricity and also to a great extent in steel and cement industry. It has been observed that its consumption is increasing so as to meet the energy requirements of the country. It has been found that in a coal preparation plant; approximately 20-25 percent coal is of the mined coal of the range below minus 0.5 mm (28 meshes). Generally, this fine fraction is discarded due to its high cost of processing and further utilisatisation is very minimal. But with ongoing research and development for advanced clean coal technology, various new techniques have been evolved to maximize the utilization of available coal. In recent time technologies such as column flotation, cleaning of fine size coal to lower the ash content and low pyretic sulfur is feasible at high recovery value. But in various researches it is found that one of the biggest hurdles in utilization of fine coal cleaning technology by the coal industry is the economic dewatering of the fine clean coal product. Thus, until an economical and practical solution to dewatering of fine clean coal is achieved, the efforts devoted to developing fine clean coal technology will be wasted. In this paper an effort toward enhancing and developing the optimum technique of dewatering and filtration of fine coal slurry has been made."

Jan 1, 2016

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003