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By Yongjun Peng, Yufan Mu, Rolf A. Lauten

"Chalcopyrite, a major source of copper, is commonly found associated with iron sulfides, particularly pyrite. The separation of chalcopyrite and pyrite by flotation is difficult due to the galvanic interactions between pyrite and chalcopyrite during grinding and flotation. Galvanic interactions may cause oxidation and dissolution of chalcopyrite, copper activation of pyrite and the formation of hydrophilic iron hydroxide coating. The overall effect may change the floatability of the components and lead to the misplacement of pyrite into chalcopyrite concentrate. The objective of this study was to investigate the effect of lignosulfonate-based biopolymers on the depression of pyrite in the flotation of chalcopyrite with xanthate as collector and the mechanism responsible for the selective depression of pyrite. The flotation results showed that biopolymers depressed the flotation of both copper-activated pyrite and chalcopyrite in single mineral flotation although to different extents. In the flotation of mixed mineral systems, biopolymers significantly depressed pyrite flotation but had a less influence on chalcopyrite flotation. The selective depression of pyrite by biopolymers was due to the preferential adsorption of biopolymers on copper-activated pyrite surface. Galvanic interactions between pyrite and chalcopyrite surfaces promoted copper activation on pyrite. Presence of cuprous ions on pyrite surface favored biopolymer adsorption by the formation of a complex between the cuprous ions and biopolymer molecules. The same galvanic interactions also facilitated chalcopyrite oxidation leading to the formation of hydrophobic polysulfide that enhanced the hydrophobicity on chalcopyrite surface. The biopolymer structure controlled the depression effect. The results showed that the biodegradable biopolymers are promising depressants for pyrite.INTRODUCTIONCopper sulfide minerals, such as chalcopyrite (CuFeS2), bornite (Cu5FeS4), chalcocite (Cu2S) and covellite (CuS), are the major mineral source for copper. They are often found finely interlocked with iron sulfides, especially pyrite (FeS2) (Owusu, Brito e Abreu, Skinner, Addai-Mensah, & Zanin, 2014). Pyrite, as the most abundant sulfide mineral, is perceived as gangue in most cases and should be removed from the associated sulfides to minimize its contamination of the copper concentrate (Owusu, Addai-Mensah, Fornasiero, & Zanin, 2013; Wang & Forssberg, 1991). The commonly used strategy to remove pyrite is flotation (Wang & Forssberg, 1991)."

Jan 1, 2016

By B. Voyzelle

The deterioration of highway and bridge infrastructure has received considerable attention in recent years because of the billions of dollars needed for repair and rehabilitation. A major factor contributing to this problem is the corrosion of steel reinforcement. Reinforcing steels with good corrosion resistance and relatively low price are therefore essential for maintenance, cost reduction and service-life extension of the steel-reinforced structures. This article describes the development of low-alloying steels that offers good corrosion resistance with reasonably low cost. Topics include steel microstructures, mechanical properties, corrosion performance, industrial applications and economic aspects.

Jan 1, 2005

By T. H. Janes

THE POSSIBILITY of producing pig iron from iron ores of British Columbia for a west coast primary iron and steel industry has been investigated by the provincial government and by commercial interests on sever.al -occasions. The latest study is that currently under way by The Consolidated Mining and Smelting Company of Canada, Limited. The Company is studying the possibility of making pig iron from the oxide calcine resulting from the roasting of pyrrhotite. tailings used in making sulphuric acid for fertilizer production at Kimberley. A comprehensive report on the subject .of establishing a primary iron and steel works in the Province, based on local iron ores, was prepared by Arthur G. Mc-Kee and Company of Cleveland, Ohio, in 1942 for the B.C. Minister of Mines and is available to interested parties. A detailed survey on the subject was also pre-pared in 1954 by Dr. G. P. Con-tractor, then .of the British Columbia Research Council. Considerable information is there-fore available on most aspects of an integrated primary iron and steel industry in British Columbia to supply the needs of the western provinces. To date, however, no basic iron industry has been established despite the .occurrence of high-grade iron ore deposits on the offshore islands and the high freight charges on iron and steel products brought into the area from Eastern Canada and overseas producers. The chief deterrent has always been the relatively small and highly diversified market available to a local steel producer. Other major fact-ors have been the lack of sufficient proven reserves of iron ore, and the difficulty of making pig iron, suit-able for steel manufacture, economically on a small scale. Technical and economic conditions have changed considerably since World War II and the establishment of a primary industry based on electric furnace production of pig iron or on one of the direct reduction processes, coupled with electric furnace steel production, may now be economically feasible.

Jan 1, 1958

By William M. Luff

This paper outlines the regional geology and history of the area, and summarizes the stratigraphy, structure and geology of the Brunswick No. 12 mine area. The Brunswick No. 12 deposit is a stratiform massive sulphide body. It occurs in rocks of the Tetagouche Group, which is believed to range in age from Lower to Middle Ordovician. The stratigraphic sequence, including the stratiform orebody, in ascending order consists of older metasedimentary rocks, augen schist, metasediments, augen. schist, footwall metasediments, the -massive sulphide body, iron formation, hanging-wall metasediments, siliceous tuff, basic volcanic rocks , basic iron formation and a porphyry dyke. This sequence is similar to that at some other deposits in the area. Four phases of structural deformation are known to be present in the Brunswick No. 12 mine area. The first deformation folds (F1 ) and associated faulting are the most important factors in determining the distribution of the massive sulphides. This deformation has resulted in the massive sulphides being separated into four zones: the Main Zone, the West Zone, the East Zone and the V-2 Zone. Brunswick Mining and Smelting Corporation Limited is actively mining, developing and exploring the deposit.

Jan 1, 1977

By Olli Haavisto, Lauri Koresaar, Navid Khajehzadeh

In recent times sustainable minerals processing is an important topic in research. Sustainable mining is linked with efficient use of energy and human resource in all process stages including beneficiation of the ore. Controlling and optimizing the recovery while preserving the grade of the concentrate is extremely important in flotation plants. This development requires new technological solutions and has given rise to the multitude of application areas for lasers. X-ray Fluorescence (XRF) and Laser-Induced Breakdown Spectroscopy (LIBS) are currently two of the predominant non-contact and direct analysing methods in industry. LIBS and XRF measurement techniques both have high capabilities for measuring elements. LIBS has a very simple and easy-to-implement spectroscopic setup, wider range of elements can be detected with online LIBS and measuring light elements is simpler by LIBS compared with XRF. It is of great interest to extract mineralogical information from the elemental results with no modification on the measurement setup. In order to achieve this, more advanced interpretation of the elemental peaks of LIBS spectra is required. Therefore, the major focus of this research is about measuring mineral concentrations from the elemental lines of LIBS spectra using advanced statistical methods. This accomplishment provides knowledge about mineral concentrations from the real-time assay data of the slurry LIBS analyzer. Consequently, this paper first discusses an analytical method called partial least squares regression leading to rapid mineral identification from the elemental contents of the LIBS technique. Then the technique is employed to analyze the mineral contents quantitatively through the information acquired from an on-stream LIBS slurry analyser. This can lead to many benefits such as rapid control of concentrate quality, enhanced recovery, saving time, energy and manpower.

Jan 1, 2016

By G G. Suffel

T HESE remarks on the occurrence of strata-bound massive sulphide deposits are submitted be-cause the writer recently visited the principal Cyprus deposits (in January, 1965) and has also a back-ground of many years spent largely in detailed observation and map-ping of the Horne and Amulet ore-bodies, now largely inaccessible. They are particularly related to the Symposium papers (September Bulletin) by Hutchinson and by Roscoe. Some comments are offered on the cupriferous pyrite deposits of Cyprus. As the writer is currently reviewing the published literature on the related deposits in Turkey, a brief account of some characteristic Anatolian sulphide occurrences is given. The discussion is closed with some thoughts on the relationship between these Mediterranean sulphide deposits and those of northwestern Quebec and the Superior province in general. The geology of Cyprus, as it relates to the sulphide deposits, is well summarized by Hutchinson (1965). After visiting Mavrovouni, Skouriotissa and Limni and after much thought on the possible ge-nesis of these ores, it seems quite logical to me that he is right. They are indeed closely related to late-stage submarine volcanism.

Jan 1, 1965

By D. Roy Eccles

A multi-element geochemical response, with contrasts of up to 29 times background, was obtained in soil above the Mountain Lake Diatreme, northwestern Alberta. The overall geochemical signature is indicative of an ultramafic source; geochemical responses contain elevated concentrations of Co, Cr,O, Cu and Ni with the presence of high Ba, Ga, HI, PO,, Rb, Ta, Ti and light rare earth elements suggestive ofa kimberlite or lamproite body. The shape, or morphology, of the enzyme leach-based geochemical signature over the Mountain Lake Diatreme combines moderately strong to strong oxidation halos, or a rabbit's- ear geochemical profile, with a sharply-defined apical geochemical profile. Because some Alberta diatremes discovered to date form positive topographic highs, the resultant geochemical signature may express the soil development profile that forms directly on top of kimberlitic and lamproitic bodies. The enzyme leach technique, which has proven to be a useful tool in base metal, precious metal and petroleum exploration, may have a significant impact on exploration for kimberlite, lamproite and related rocks in Alberta by providing industry with a useful and cost effective tool to probe blind and/or buried anomalies identified by airborne and ground magnetic surveys in areas of glacial overburden.

Jan 1, 2001

By J. Defreyne

CESL has developed a proprietary hydrometallurgical process for base metal concentrates, notably those of copper and nickel. The process is based on pressure oxidation (PO) of the sulphide minerals, which is done at elevated temperatures in mixed sulphate-chloride liquor at about pH 2 ? 3. The process achieves maximum oxidation of the metals whilst minimizing sulphur oxidation to sulphate. Almost all base metal sulphide minerals are efficiently treated under these conditions. In the case of copper minerals, pressure oxidation does not generally put the copper into solution, because of the relatively high pH prevailing in this process. Therefore, PO is followed by an acidic leaching stage, which specifically aims at maximum copper dissolution with minimal leaching of iron. The overall copper recovery is largely determined by the efficiency of this stage. The process has low capital and operating costs, partly because there is minimal use of acid or neutralizing agents for iron dissolution or precipitation, respectively; this is achieved by minimizing iron leaching during both the oxidation and leaching stages. Iron sulphides in the feed concentrate deport almost entirely to the solid leach residue as hematite, which has superior handling characteristics for filtering and washing. Iron minerals play a key role in the process, with pyrrhotite and pyrite having very different responses to the oxidation process. Acid management for the whole process is affected by the iron mineralogy, and the flowsheet is therefore tuned to the specific concentrate.

Jan 1, 2006

By Jing Li, Weiqiang Lai, Joe Zhou, Jiezhen Ma, Shuibo Chen, Ashele Copper Company, Feng Gao, Guofu Feng

"Copper-zinc ores often contain gold and silver, which can be recovered into copper concentrate by flotation as by-product. The challenges for operations that produce copper, zinc, gold and silver are the separation of copper and zinc and the low grade of precious metals. Ashele copper-zinc ore in north China contains 2.38% Cu, 0.69% Zn, 0.21 g/t Au and 18.10 g/t Ag and the plant produces copper and zinc concentrates, with gold and silver being recovered into copper concentrate. Copper occurs mainly as chalcopyrite and Zn occurs as sphalerite. Copper is well recovered with a recovery of over 94%. However, the recovery of Zn is substantially low (around 50%) due to fine grain size of sphalerite. In addition, gold recovery is much lower than expected and only 33% of gold in the flotation feed was recovered. The grade of gold in copper concentrate is also lower than the required payable grade (1.0 g/t). To determine the cause for lower Zn and Au recoveries, a plant survey program was conducted on the operation. The information acquired shows that the loss of Zn was mainly in the copper concentrates (accounting for approximately 38% of the head assay); of which, 24% was liberated, 8.5% was associated with chalcopyrite and 4.6% was associated with pyrite, indicating that the separation of copper and zinc was the main cause for the Zn loss, with liberation being the second cause for Zn loss. Future effort in improving Zn recovery should be focused on the separation of zinc from copper. Gold in the ore occurs as both microscopic gold and submicroscopic gold, accounting for 36% and 64% of the head assay, respectively. Microscopic gold occurs mainly as native gold and electrum; it is relatively coarse with a grain size of 10 to 240 µm and a large portion can be recovered by gravity. Submicroscopic gold was mainly carried by pyrite (accounting for 38%), and to a less extent, by tennantite (15%) and chalcopyrite (10%). Gold in sphalerite is nominal (1%). It is suggested that more coarse gold and tennantite be recovered and a gold recovery increase can then be achieved to obtain a copper concentrate with over 1.0 g/t Au through flowsheet optimization. Gravity concentration should be investigated and may be worth added into the existing flowsheet to maximum the gold recovery and grade.INTRODUCTIONCopper-zinc ores containing gold and silver is a subtype of polymetallic sulphide ores. Unlike porphyry copper sulphide ores and iron-oxide copper-gold ores, this type of ores often contains substantial amounts of zinc and lead. Polymetallic sulphide ores are mainly distributed in Canada, such as at the LaRonde and Horne deposits. Other examples include Mt. Morgan in Australia and Boliden in Sweden. Globally, production and reserves from gold-rich VMS deposits account for 1370 t gold. This is equivalent to 1% of the world production and reserves, whereas the Canadian total for gold-rich VMS deposits is 870 t, representing close to 10 % of Canadian production and reserves (Gosselin & Dube, 2005a, 2005b). Flotation is the principal process for processing the copper-zinc sulphides ores, for subsequent smelting, roasting, or hydrometallurgical treatment. Oxidized copper-zinc ores can also be processed using leaching technology. For example, at LaRonde operation (a Cu-Zn-Pb ore containing 3-4 g/t Au and 60-100 g/t Ag) the flowsheet consists mainly of a copper flotation circuit and a zinc flotation circuit followed by a cyanidation process of flotation tails. The precious metals are recovered with copper concentrate, zinc concentrate and cyanidation of zinc tails via Merrill Crowe precipitation (Zhou et al., 2005)."

Jan 1, 2016

By A. Alwasel

Musculoskeletal disorders (MSDs) threaten the wellbeing and livelihood of a large number of construction workers incurring a significant cost to society. We present a new method to monitor and diagnose MSD risks in the workplace. The sensing unit of the system is an optical encoder encompassed within a non-intrusive exoskeleton to measure the joint angle of interest. This sensor can be applied to ball-and-socket and hinge-type joints of the human body, such as the shoulder, elbow, and knee joints. The system is contactless and does not require markers or cameras. Angle measurements are acquired directly without mathematical post-processing, thereby avoiding numerical noise and drift challenges. The system is a simple, robust, and deployable, but it currently lacks resolution of parallel degrees of freedom.

Aug 1, 2013

By B. M. Monaghan

"The developments of the 1950s and 1960s have seen Canada become an international source of iron ore, trading in all geographical areas and hemispheres. Canada's production will significantly increase in the next decade. However, although the outlook is bright, iron ore producers cannot be complacent. Instead, we must weigh the factors that have brought about the development of the Canadian iron ore industry and examine the probable changes for the next decade that will affect its growth.Looking ahead in the 1970s, competition will be severe. Pressure on prices will continue as new sources of supply bid for long-term contracts and as steel producers continue to develop mines around the world. Rising costs will make these pressures more severe. We must balance the growth of the world's steel makers with the emergence of new supplies of iron ore. The iron ore industry is now part of a new era in which demand and supply are intermeshed, and the developments around the world are acting on the Canadian iron ore industry's future."

Jan 1, 1971

By R. B. Sudderth, A. Quiroz G., M. Torres M., C. Salgado Q., J. Fernández O., H. Bravo P., M. Torres B.

SNF FloMin, Inc. has introduced a complete line of extractants for recovery of various metals. Among them are the CuPRO MEX™ Brand of copper extractants that are based on the well- known 2- hydroxy 5-nonylsalicylaldoxime and 2-hydroxy acetophenoneoxime. This paper presents the laboratory and pilot plant trial results for SNF FloMin’s CuPRO MEX™ 3302 reagent, the equivalent to the wellknown ACORGA® M5640 extractant, and the composition of these reagents are described. Some examples of SNF FloMin’s CuPRO-Sim™ Advanced solvent extraction simulator are presented.

Jan 1, 2014

RÉSUMÉ Cet article traite d’une analyse technique et économique du concept du triage optique en vue d’améliorer la rentabilité des opérations minières. Le principe du tri optique et les principaux systèmes et modules servant au fonctionnement de l’appareil de triage sont décrits. un modèle a été développé pour analyser l’intérêt économique d’une opération de triage optique. L’étude est basée sur des données provenant d’une halde de minerai à faible teneur en or, déposé à la surface, et de minerai extrait des opérations souterraines courantes de la mine Beaufor au Québec. Les résultats de cette analyse indiquent que l’opération de triage optique permet d’améliorer grandement la performance économique; l’opération devient alors rentable pour des teneurs en or relativement petites.

Jan 1, 2010

By A. D. Hunt

THIS PAPER will review Canada's fossil fuel situation as we understand it today and indicate some of the options available to meet our energy requirements during the next 15 years. It would therefore be helpful to examine Canada's total energy requirements and discuss the un certainties of the data base on which we must base future energy investment decisions. On the world scene, Canada is at the top of the energy-consuming nations, using about 49 bbls of oil equivalent per caput/ year. This appears to be slightly ahead of the U.S. and of course much higher than that of many countries. It is generally accepted that there is a more or less direct relationship between energy consumption and material standard of living. However , as we know, Canada, when compared with other industrialized countries on a GNP, an individual-income or some other standard basis, is lower in the list. This situation may be explained by our more severe climate and a relatively small population distributed over a land mass second only to that of the Soviet Union.

Jan 1, 1977

During the past decade, the miner-al industries have been faced with an increasing shortage of engineers. The point has now been reached where the shortage may be termed critical. This shortage may be attributed directly to declining enrollment in the mineral science programs offered by the universities on this continent. Although the reasons for declining enrollment are undoubtedly many, two major hypotheses may be postulated. The first is that high-school graduates are either unaware of the mineral industries and the opportunities in them or that they are aware of them but have somehow obtained a false image of their true nature. The second is that they are aware of the true nature of these industries and the opportunities they offer but find them exceedingly unattractive. The problem of dwindling enrollments has, in recent years, been subjected to a concerted attack by the industries and professions concerned. However, their efforts to date have been based essentially on the first hypothesis. Sufficient results are now available to suggest that either the methods of attack are inappropriate

Jan 1, 1965

By W. E. Segsworth

Introduction By far the largest part of the money raised for mining is raised by honest and legitimate means; but a not inconsiderable amount is raised by fraudulent sales methods. It will be conceded without argument that the greatest menace to the mining business is the fraudulent promoter. The sale of worthless mining stocks to the public by high-pressure. salesmen, house to house canvassers, telephone campaigns, fraudulent use of the mails, fraudulent statements, and reloading, has seriously prejudiced the public against even legitimate mining. A very small percentage of the funds raised by such fraudulent means is ever spent on the property, but instead is absorbed by the promoter in illegitimate' profits, enormous commissions, high office rents, and other expenditures, and is just so much subtracted from the fund which the legitimate developer needs to bring new mines to the point of production. The mining fraternity has been at fault in that, while they recognized this situation, they made no adequate attempt to rectify it. They knew that these fraudulent practises were conducted by parasites who attached themselves to the mining business in boom times and claimed to be part and parcel of it, but who were merely professional salesmen and promoters who, when there was not a mining boom, were selling sky-line real-estate, worthless oil stocks, or fraudulent securities which happened to be popular with the public. While mining people had this distinction well in mind, the public did not differentiate between the crooked promoter temporarily selling fraudulent mining stock and the honest promoter who made mining finance his life work; and we did little to make this distinction clear to the public or to sweep these money grabbers out of our house. The historic boom of 1927-8 and '29 brought with it the usual crop of crooked mining promoters, and the scandals resulting from their operations forced the Governments into the enactment of laws to attempt to protect the gullible public against the operations of these meanest of thieves and to appease public clamour.

Jan 1, 1934

By Vicki Tschirhart, Bill Morris, McMaster University

A new method for mapping faults within basement rocks underlying the Thelon Formation and glacial overburden was developed and tested in the Aberdeen Sub-basin. This method utilizes newly acquired aeromagnetic data, the Blakely algorithm for defining magnetic source edges, a calculated dip-direction map, a digital elevation model (DEM) derived from the Canadian Digital Elevation Database, and the positions of identified, inferred and newly mapped faults that are within and adjacent to this sub-basin. Combining these data revealed three age groups of faults. One group is seen only on the DEM; these faults are young brittle structures that have no effect on the sub-Thelon basement unconformity, and are not visible on the dip direction map. A second group is evident on the dip direction map but not the DEM; these faults are old basement structures that did not propagate upward through the Thelon Formation. The third group is expressed on both the DEM and dip direction map; these faults are also old structures that propagated upward during and/or after deposition of the Thelon Formation. The latter group of faults may be of greatest interest for uranium exploration, with reactivation increasing their potential to serve as conduits to transport uranium-rich fluids and focus deposition at or near the unconformity surface. This methodology has promise for comprehensive mapping of basin faults and tracking the tectonic development of the whole Thelon Basin through time.

Jan 1, 2013

By T. Vovan, A. Galibois, M. Fiset

"In order to establish some links between the 22 specimens found on the site of Les Forges du St. Maurice, their slag inclusions have been analyzed by electron microprobe. Comparison between their contents of various specific oxides allowed us to segregate them into two major groups and even to isolate two sub-groups possibly characterized by some equilibrium between their oxides and/or the type of ores used.In all probability, limes/one coupled systematically with a soil rich in hydrated aluminum silicates was used as a flux.Based upon the existence of a pseudo equilibrium between the slag and the metal, the elaboration of the bulk of the specimens can be ascribed to the indirect rather than the direct method whereas the process temperature can be estimated at at least /400°C.RESUMEDans le but d'etablir des liens entre les 22 objects provenant des Forges du St-Maurice, leurs inclusions de scories ont été analysées par microsonde. La comparison des teneurs en divers oxydes a permis de les séparer en deux groupes majeurs et même d'y distinguer deux sous-groupes pouvant être reliés à la forme d'équilibre entre certains oxydes et/ou au type de minerai utilisé. Selon toute vraisemblance, le fondant utilisé était de la pierre à chaux à laquelle on ajoutait systématiquement une terre riche en silicates hydratés d 'aluminium.Des considérations sur l'existence d'un certain équilibre entre les scories ei le métallaisset croire que la plupart des objets ont été élaborés plutôt par la méthode indirecte que directe et que la température d'élaboration se situait à au maint 1400°C."

Jan 1, 1984

By G. Rong, W. Du

Stability of some potential unstable blocks in the left bank slope of Baihetan hydropower station is evaluated in this paper using the three-dimensional (3D) limit equilibrium method. The Baihetan hydropower station is in the downstream of Jinshajiang River, China. The geological condition in the river valley is complex, and many large discontinuities are detected in the slope of the two banks. As a result, much attention should be paid to the stability of the slope in the feasibility study stage. Because the left bank slope is an oblique consequent one, we mainly focus on the slope stability analysis in the left bank. Comprehensive geological exploration is conducted in the studied area and the detected discontinuities are well researched. By building a 3D geological model of the left bank slope, three potential unstable blocks which are close to the dam site are detected. An irregular wedge analysis method is then used to calculate safety factors of the three blocks under three conditions, which are natural condition, rainfall condition, and seismic condition, respectively. It is found that the safety factors of the block 1# and the block 2# are quite low when compared to the suggested values. Extra care must be exercised when excavating the slope near the block 1# and the block 2#. A preliminary reinforcement is also suggested.

Jan 1, 2015

By J. O. Pitts

"Background The preponderance of Canada's coal resources is located in areas remote from high demand domestic users and at some significant distances from deepsea ports. This places great demands on the transportation system and has forced the coal and the transportation industries to adopt highly efficient methods of handling the product and hauling it to market position. Most of the coal not consumed in minemouth thermal power stations is carried by rail over lines operated by the two transcontinental railway systems, Canadian National and Canadian Pacific. These rail networks are extensive and have the advantage (as compared to most other North American railways) of being able to handle coal movements from origin through to destination without interchange to other rail carriers. Coal SourcesWith exception of the coal produced in Cape Breton, Nova iScotia, all the significant shipping volumes in Canada emanate ifrom mines located in the three most westerly provinces. Figure I ishows the geographic distribution of the major mining operaitions shipping coal to domestic and export markets. The prinicipal routes and the tonnages carried (1980 calendar year) are ialso indicated. iThe 1980 shipping data are summarized in Table I. Saskatchewan lignite began moving from Bienfait to Thunder Bay by CP Rail unit trains in mid-1981 at the rate of one million tonnes per year. The product is handled through Thunder Bay Terminals and delivered directly to a nearby Ontario Hydro electrical generating station."

Jan 1, 1985