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Deep hydrothermal fluids adjacent to the Alpine Fault move through the brittle-ductile transition to mix with convecting fluids from near surface environments. These tectonically driven fluids evolve mainly from prograde metamorphism at mid crustal depth (ten kilometres) within the ductile regime which has been elevated due to advection and drag on the fault plane. Through the onset of brittle failure and cataclasis within Alpine Fault mylonites, fluid overpressuring results in hydrofracturing and localized implosion. Along the length of the Alpine Fault, hydrothermal alteration varies on most levels (Table 1). There is an observable increase in Fe-Mg carbonate between the Waitaha and Taramakau Rivers (between Ross and Aurthur's Pass, respectively). Field studies concentrate to the north east of the Arahura River, noted for historical mineral wealth. Late meteoric fluids move through cataclasite, brecciated mylonite, and other open fractures. Chloritisation is the major retrogressive phase. Dolomitic hydrofracture veins (Figure 1) within coherent mylonites contain iron and copper sulphides. Notably, the enrichment in Fe-Mg carbonate towards the Alpine-Hope Fault intersection seems to represent a region of enhanced permeability possibly related to shallow seismicity, increased regional faulting, footwall variation, strike-slip dip-slip distribution, and/or topographical anomalies (ie saddles). Isotope studies identifying an 'Inboard Fault Gouge Calcite Zone' correlate to values from the Main Divide region at the headwaters of the Arahura River (Browning Pass-Wilberforce Valley) (Becker et aI, 2000). These correlations are supported by rare arsenic anomalies (avg l06 ppm n = 5, Figure 2) found in both regions which suggest that fluids may be interconnected at depth.

Jan 1, 2001

It is a very great pleasure indeed to participate in this interesting and important seminar. My two visits to Australia in the past have been extremely pleasant and this one is equally so. My task is to tell you what has been happening in the United States, in these past few years especially, in regard to the management of our air resources and to present in some detail the difficulties we in the copper, lead and zinc smelting industries have been experiencing. The sudden upsurge in interest in air pollution in the United States is a strange phenomenon indeed - strange because we've had air pollution a long time, just as long as there have been large cities using fossil fuels for heating purposes. And the problem has been studied for quite a long time. As early as 1919 studies by the U. S. Bureau of Mines were done in Salt Lake City, where I .live. In the winter of that year extensive measurements were made of airborne particles - dust and smoke. The average concentration of particles found was 870 micrograms per cubic meter of air. A very large number compared to levels we find today. A microgram of course is a very small unit, one twenty-eight millionth of an ounce. A fine human hair two inches long weighs about 100 Micrograms.

Jan 1, 1971

By Wakamatsu DT, Nakahiro Y

This present paper deals with the fundamental study of the separation of fine cassiterite and quartz by liquid-liquid extraction using iso-octane as an oil phase, dodecylamine acetate (DAA) as a collector, and sodium chloride as a depressant. With regard to the distribution of fine cassiterite and quartz between oil and aqueous phases, the effect of DAA has been investigated in terms of pH, DAA and NaCl concentrations, zeta potential, and adsorption density. From the results of the experimental work, a maximum recovery of cassiterite in the oil phase was obtained with pH around 6.0, DAA concentration of 1.0 x 10-5 mole/litre, and NaCl addition of 0.1 mole/litre. In these conditions of liquid-liquid extraction, most of the fine quartz remained in the aqueous phase. Thus it was found that NaCI was an effective depressant for fine quartz under optimum conditions. A series of separation tests by liquid-liquid extraction was then conducted for the mixed samples (6.0 per cent Sn) of cassiterite and quartz. By a single separating process, the per cent of recovery of cassiterite in the oil phase was about 92 per cent with a grade of 27 per cent Sn. The same results could also be obtained by using kerosene in place of iso-octane as the oil phase.

Jan 1, 1993

The truly scientific method in the study of such questions at the present day is the reverse of that which was followed in the early days of geology, when after the observation of a few isolated facts, some great geological mind was led to a general theory, and humbler followers were only too apt to do mild violence to nature in order to make her facts conform to it tt accumulates year after year a multitude of facts of patient observation, supported by studies with the microscope, and in the laboratory, avoiding general theories, and only making such deductions in regard to locftl conditions as are supported by the overwhelming evidence of facts. S. F. Emmons, on the geological distribution of minerals in the United States, at the "world's congress" of mining engineers, Chicago. Fig. l.-This exhibits the general stratigraphical characters of the southern lodes. The" Indicator" veins, the great barren lode masses, a later fissure than all of these (" B "), and the auriferous lodes of last series cleaving the wrinkled terraces and the older lodes also are" Indicator" veins. B is a later formed vein that leaves no " depositions" behind. ooe are fragments of the" most ancient'' lode wreckage. Db are the auriferous lodes and correspond with those lodes, also whose auriferous characters are not result of secondary impregnations.

By M S. El Salmawy

In order to develop the HF-free flotation reagent system, the main objective of this investigation was to study the possibility of separation of quartz from feldspar using non-ionic surfactants as the collector. The non-ionic surfactants used were polyoxyethyl cethyl ether (PECE) and polyethylene glycol monocethyl ether (PGME). The flotation behaviour of quartz and microcline with PECE and PGME was investigated. Each surfactant was a good selective collector for quartz with its recovery being influenced by pH and surfactant concentration. Quartz is floated favourably by both types of polyoxyethylene non-ionic surfactant whereas microcline was not so much. The floatability of quartz increases as the oxyethylene length of surfactants increases. Zeta potential measurements in the system of PGME/mineral were also carried out. It was determined that in the absence of PGME the points of zero charge for quartz and microcline should be approximately at pH 2.5 and 1.8, respectively. The addition of PGME to the system causes both minerals to become less negatively charged. Differences in the zeta potential value between quartz and microcline, in the presence of PGME, were detected. It can be suggested that the interaction of the oxyethylene group to the microcline surface should not be as strong as that to the quartz surface. In the mixed surfactant system of PGME and dodecylamine acetate (DAA), a small addition of DAA causes drastic enhancement of quartz flotation in the wide pH range of 1 ~ 10. In the mixed surfactant system selective flotation of quartz from microcline would be anticipated at pH

Jan 1, 2005

By Gupta A, Hall ST

The grinding characteristics of quartz which is normally associated with gold bearing ores in Kalgoorlie area was examined in a stainless steel laboratory size ball-mill in the presence of inorganic and organic surface active reagents. The cationic species considered were Fe3+, Cu2+ and Ca2+, and the anions were CO? and S2 as these are normally present during the process of grinding of gold ores in the region. The organic surfactants examined were K-amyl- xanthate, dodecylamine-hydrochloride and the Grinding Aid XFS-4272 manufactured by Dow Chemical The study was primarily based on an examination of the electrokinetic properties of quartz surface in the presence of the grinding reagents. Zeta potential at different reagent additions and pH values in the presence of individual reagents were examined and the corresponding grinding charcteristics determined. A correlation has been indicated between the grinding characteristics, as measured by the -53um size fraction produced, and the surface energy of quartz. It was observed that an

Jan 1, 1978

By Frazer E. J, Lwin T

Measurements of coulombic efficiency (QE) for zinc electrodeposition were carried out under mass-transfer-controlled conditions using a rotating disc electrode in synthetic acidic zinc sulphate solutions. Various methods of solution preparation and purifi- cation were investigated using reagents vary- ing from analytical grade to high purity; the purest solution was obtained-by dissolving 99.9999% zinc (Koch-Light) in sulphuric acid solution (BDH Aristar). Improvements in sol- ution purity did not necessarily increase QE, especially where apparently beneficial impur- ities (e.g., Pb) were initially present. The maximum QE obtainable through variation of temperature (T), current density-(i) and elec- trode rotation rate was established using a statistical optimization technique. The QE was determined principally by T and i, with significant interaction between these factors in the highest purity solution. QE contours, which gave an overall view of solution per- formance, were constructed and predictions about the response under conditions similar to plant practice were made. Wark's Rule (the dependence of QE on zinc/acid ratio) was obeyed in the purest solution over the range of composition commonly encountered in zinc plants. High concentrations of Na2SO4 and K2SO4, which occur in some plant solutions, were found to increase QE marginally ("1.2%). The intrinsic effects of individual impurities such as Cu and Ni were evaluated by additions (up to 5 ppm) to the purest solution. Decreases in QE were found to be minimal at the impurity levels normally encountered in zinc plants.

Jan 1, 1987

Copper entering a lead ,smelter in concentrate or from other sources is recoVered as matte and speiss which contain appreciable quantities of lead. The matte and speiss are usually sold to copper smelters to recover the copper content and also any gold and silver in these products, but the value of the lead is largely lost. Some copper plants pay for portion of the lead content, but regarded as a means of recovering lead it is more costly and less efficient than if the lead were recovered at the lead smelter.Because of the value of this lead loss, the metallurgy of copper recovery has assumed greater importance in recent years owing to the rise on the price of lead.Two processes are in use today to produce matte and speiss, namely the iron matte process and the soda matte process developed by the American Smelting and Refining Co. 1 in D.S.A. The latter process is characterised by a higher copper to lead ratio than the older iron matting process.The following analyses are typical of matte and speiss produced at Broken Hill Associated Smelters, by both processes, although the soda matte process is still in a developmental stage and experience indicates that matte and speiss of lower lead tenor can be produced under favourable conditions.

Jan 1, 1951

Looking back 25 years, the role of the drill and blast engineer in an Australian mine seemed relatively simple, with the primary focal points being scheduling of the drill rigs, oversize control, and budget control with respect to consumption of both explosives and drill consumables. The choice of explosive selection was relatively simple, though many mines were becoming involved in trials of slurry explosives, emulsion blends, and low density ANFO blends. Guidelines to assist the engineer towards specific fragmentation targets were scarce, environmental constraints were light, and computers were rarely found on the desks of any mining engineers. Wall control blasting was in its infancy, with the bulk of attention being given to appropriate slope design and little real attention given to factors such as explosive distribution, and optimum delay timing and sequencing. Quantitative measurement of blasting performance was rare. The science of blasting, for fragmentation control, wall control, and environmental impact control was about to be born, and was heralded in those years by intense efforts by the explosive manufacturers and a proliferation of research centres throughout the world. Since the early 1980s, the role of the Australian drill and blast engineer has gone through a major metamorphosis, and currently requires a greater depth of scientific understanding than any other specialisation within mining engineering.

Jan 1, 2004

A thick sequence of alkaline intrusions and volcanic rocks underlies a Quaternary caldera on Liliir Island. The sequence is host to a still active sub-aerial hydrothermal system and associated epithermal gold mineralisation. Sub-horizontal alteration horizons exhibit progressively increasing chondrite norma-lised (La/Lu) en and (La/Sm) cn ratios from unaltered shoshonites, to the potassic alteration zone, to the argillic altera-tion zone to the advanced argillic alte-ration zone. The increasing fractionation of HEE, and especially of LHEE, up the alteration sequence is the result of de-creasing pH, temperature and alkalinity of the hydrothermal fluids with increa-sing alteration intensity. HRE3 were especially mobile in argillic and advanced argillic alteration units characterised by acid fluid conditions and large fluid volumes. Abundant Cl, S and CO2 within the hydrothermal fluids and thus abundant REE complexing agents and large fluid volumes favoured the mobility of REE during hydro-thermal alteration of the volcanic rocks and intrusions. Steam escape, mixing of the gases with groundwater and a change from a magmatic neutral chloride hydro-thermal system to a meteoric acid sulphate system was accompanied by liquid/vapour ratio changes, pronounced alkalinity, pH and temperature decreases, and fluid/rock ratio increases. This caused the mobili-sation, fractionation and deposition of PF.F.

Jan 1, 1990

Early in 1930 William S. Robinson, Managing Director of Zinc Corporation Ltd., anticipated a rise in the price of gold and a devaluation of the Australian currency. 'WS', as Robinson was known, formed a.syndicate in London, which later became incor- porated as Gold Mines of Australia Limited (GMA) to invest in gold mining properties in Australia. GMA examined many prospects and subsequently undertook the development of several mines in eastern Australia. The syndicate also held a number of options and several large reservations for gold exploration in Western Australia over which it was proposed to carry out an aerial survey and thorough scien- tific assessment. To do this Western Mining Corporation Limited (WMC) was incorporated in Melbourne on the 2nd March 1933. The founding chairman of WMC and GMA was the highly respected `Collins House' figure, Sir Colin Fraser. The aerial survey was carried out, and a group of eminent geol- ogists from Harvard University examined many prospects and identified several which warranted development. To finance these activities `WS' formed Gold Exploration and Finance Co. of Aus- tralia Ltd. (GEFCA), in London in July 1934. GEFCA ultimately held 95% of WMC and 62% of GMA. The finance came mostly from London based South African mining companies which had been subscribers to his earlier syndicate plus some American inves- tors. (The Group Structure in 1936 is shown in Appendix `B").

Jan 1, 1988

By See J. B

The zinc-nickel alloy process, TECHNIGALVA, was developed for the control of the thicknesses of zinc -coatings on reactive silicon-killed steels. These are steels containing between 0.04 and 0.15 per cent silicon which have become more common in recent years as more steel is produced by continuous casting. The introduction to this paper will review the current status of this process in Europe, North America and Australasia. It is well known that the presence of silicon at certain levels in steel can cause sufficient growth of intermetallic phases during galvanising to form a grey coating of excessive thickness. This type of coating is undesirable because it is brittle and has poor adhesion to the steel base. Since the early-1980s a widely accepted practice for suppressing the reactivity of steels containing silicon during general galvanising has been the addition of approximately 0.1 mass per cent nickel to the galvanising bath ie the TECHNIGALVA process. The paper will also discuss metallurgical aspects of the use of nickel in galvanising such as the mechanisms by which nickel suppresses reactivity, the structure and composition of the ternary Zn-Fe-Ni drosses formed when using nickel and the use of nickel in the galvanising bath at a level of about 500 ppm to give thinner, smoother and brighter coatings on steel.

Jan 1, 1993

Around 35 Mt of industrial clays were produced in 1994 under the broad classifications kaolin (25 Mt), bentonite (8 Mt) and attapulgite/sepiolite (2 Mt). A brief review of world sources and markets is given as background to Australia's small production (0.5 Mt) but developing interest in industrial clays. Clay markets have changed significantly over the past 30 years resulting initially in consolidation and expanded production from traditional high-grade clay sources but also creating opportunities for development of new discoveries. Decline in the use of clay-based refractories has come at a time of strong growth in demand for refined kaolin for the paper industry. Traditional markets for bentonite as oil drilling muds, iron ore pelletising and foundry bond sands are mature and in overall decline. Today, bentonite has a significant share of the growth market in pet litter which a few years ago was dominated by attapulgite/sepiolite clays. Both bentonite and attapulgite/sepiolite have good prospects for increased demand in environmental markets both in containment of hazardous wastes and sorption of toxic substances. In common with all industrial minerals, markets for clay minerals will demand continuous improvement in product quality and consistency. Development of new and improved products will be increasingly the responsibility of the raw material supplier. In order to remain competitive, this will require a substantial commitment to quality assurance and research and development. Increase in market share will come for those producers able to translate developments in their products to cost savings or increased competitiveness for the industries that they Supply.

Jan 1, 1997

By Harraway D. H, Draper N

The association of graphite with a fine grained pyrite in the Mount Isa lead-zinc ore was investigated from mineralogical and metallurgical standpoints. The pyrite has been partially or completely replaced by galena and to a less extent by sphalerite, pyrrhotiteand chalcopyrite with the retention of graphite films or inclusions. During lead flotation the graphite imparts a spontaneous flotability to all associated minerals, resulting in a low grade fraction, which we call the carbonaceous fraction, floating with and diluting the lead concentrate. In times of low metal prices this fraction seriously reduces the economic value of the lead concentrate. A flotation procedure was developed to upgrade the carbonaceous fraction separately, producing an economic concentrate and a tailing.INTRODUCTIONThe lead concentrate produced from Mount Isa ores can vary from 20 to 50 per cent lead, depending on the locality in the mine from which the ore is obtained. Variations of this order are independent of ore grade and lead recovery. The large variation is related to the presence in the ore of a variable fast floating low grade fraction known locally as the carbonaceous fraction because of its association with graphite. During conventional lead flotation with sodium ethyl xanthate the carbonaceous fraction floats rapidly and unselectively with normal Mount Isa galena.The paper discusses mainly the examination and treatment of an average carbonaceous fraction, defined here as the fast floating material in the mill feed of late 1956. The ore was drawn from the Mount Isa Black Star orebodies. The fraction represented about 5 per cent of the total ore...

Jan 1, 1961

By C J. Corbett

Many underground mining methods rely on blasted rock moving under gravity to report to extraction points. Mining of orebodies dipping between 20 - 45 degrees poses a unique challenge for mining engineers in that a dip angle in this range will not allow the movement of broken ore down the footwall to the mucking horizon utilising gravity. This is more so in cases where the natural angle of repose of the rock is less than the dip of the orebody. Hence, innovative mining systems are necessary to mine this type of orebodies. In Australia, the method of uphole retreat panel stoping is commonly used to extract orebodies in the dip range of 20 - 45 degrees and thickness range of 5 - 15 m. In the Zambian Copperbelt a method called continuous retreat updip stoping is used for orebodies with similar dips and thicknesses. The mechanised form of this mining method has potential for application in the metalliferous mining industry in Australia. In this study a comparison is made between mechanised updip (MUDS) and transverse retreat stoping (TRS) methods. A hypothetical nickel sulphide orebody located in Western Australia is used as case study. The net present value for mechanised updip stoping is seven per cent higher than that of transverse retreat stoping based on the assumptions applied. Initial results of this study indicate that mechanised updip stoping can be adopted for Australian mining conditions. However, lack of significant local experience with the method is often cited as a reason for not adopting it even in situations where it is clearly the best option.

Jan 1, 2003

By J Safarian, M K. Kar

Bauxite residue is one of the most important by-products from the alumina industry with no commercial use till now. The utilisation of bauxite residue through pelletising with different lime additions, hydrogen reduction, and smelting has been studied in this work. Three different types of green pellets were made with varying calcite-to-bauxite residue ratio and subsequently sintered at elevated temperatures. The sintered pellets were isothermally reduced at 1000°C under hydrogen gas followed by smelting of the reduced pellets in argon at 1500°C. Smelting of the reduced pellets leads to the recovery of metallic iron and the formation of a leachable calcium aluminate slag. X-ray diffraction (XRD) and scanning electron microscope (SEM) were used to characterise the phases and microstructural analysis. The iron produced in the smelting process has a high purity, above 99.5 wt per cent. While the iron content of the slags is quite low, and the slags shows variations of krotite (CaAl2O4), gehlenite (Ca2Al2SiO7), and perovskite (CaTiO3) phases based on the variation of calcite addition. It was found that the more calcite addition in pelletising yields higher percentage of krotite phase as compared to lower calcite-containing pellets. Employing quantitative XRD analysis, the krotite phase fraction was found approximately 85 wt per cent for higher calcite-added pellet, and around 74 wt per cent for lower calcite-added pellet. FactSage™, ver 8.1 (Thermfact and GGTTechnologies) thermodynamic software was used to evaluate the obtained experimental data, they both revealed that the

Jun 19, 2024

In a previous paper in these Proceedings(l) it was shown from a study of the bore'logs and analyses then available, that the brown coal seams of the Latrobe Valley areas show progressive changes in composition with increase of stratigraphic depth, equivalent to a rise in rank: These changes appear as:(i) An increase in ultimate carbon and hydrogen, calculated on a dry, ash-free basis, and(ii) An increase in calorific value, calculated on the, same basis, each of the order of 1% per 100 ft. of depth, and(iii) A decrease in moisture content of the order of 0.5% to 1.0% per 100 ft. of depth. The decrease in moisture content was found to be less regular than the other changes. In some bores the moisture content remained more or less constant throughout a single seam, or fluctuated slightly, decreasing stepwise on passage to the seam below.It was noted that individual analyses within a bore showed irregular fluctuations, tending to mask the general trend in composition change. This was particularly so for the moisture content, which had been determined for 10 ft. lengths of core, whereas the other components were determined for 50 ft. lengths of core. Averaging of the moisture contents over 50 ft. lengths reduced the masking effects of these irregularities. The suggestion was made that these irregularities arose from variations in the relative proportions of pollen, resin, wood (lignite) and woody attritus composing the core. Such variation in the coal seams has since been established in some detail for the...

Jan 1, 1948

This paper describes the oil engihe plant owned and operated by Gold Mines .of Kalgoorlie Limited, and gives some details of installation, operational, and maintenance experiences which have arisen during the years of service, the last 5 years of which have been under the writer's control. Nos. 1, 2, 3 and 4 alternator units have run 50,276, 48,006, 49,677 and 25,930 hours respectively, and much knowledge has been obtained of their performances and faults. During the war years, it has not been easy to obtain spare parts; this, coupled with the loss of No. 4: alternator unit to the Commonwealth Government, made operation and maintenance a very difficult problem.All engines are of the enclosed vertical, single acting, 4-stroke cycle, airless injection type.The electrical power plant originally consisted of four 6-cylinder Belliss & Morcom heavy oil engines, direct coupled to Bruce Peebles alternators, running at 375 r.p.m., and generating 3-phase electric power at 3,300 volts, 50 cycles.No. 1 unit, installed in 1936, is a 6-cylinder 450 b.h.p. standard 12A Belliss & Morcom heavy oil engine, direct coupled to 280 kw. 0.8 p.f. alternator. The remaining three units are 6-cylinder, 660 b.h.p., lSA oil cooled piston type Belliss & Morcom heavy oil engines, direct coupled to 410 kw. 0.8 p.f. alternators, making a total capacity of 1,510 kw.No. 4"alternator. unit, an 18A Bellis.& Morcom set, was taken over by the Commonwealth Government in June 1943.

Jan 1, 1945

By R Hall

The magmatic arcs of SE Asia and SW Pacific contain some of the worldÆs major magmatic-hydrothermal gold deposits. Most gold deposits in SE Asian and SW Pacific arcs formed during periods of plate reorganisation rather than during periods of normal or steady state subduction. These plate reorganisations were caused initially by the collisions of the Australian Craton with the Philippines-Halmahera Arc and the Ontong Java Plateau with the Melanesian Arc at ~25 Ma. A second Mid-Miocene period of mineralisation accompanied plate reorganisation following maximum rotation or extrusion of Indochina and cessation of spreading in the South China Sea at ~17 Ma. However, the vast majority of deposits from New Zealand to Taiwan formed since 7 Ma during an important period of tectonic reorganisation that accompanied and followed changes in the relative motion between the Indian-Australian and Pacific plates between ~8 and 3.5 Ma. Magmatism in unusual tectonic settings produced the most abundant and largest deposits with many deposits associated with high-K calc-alkaline, shoshonite, adakite and alkaline magmatism. In particular peak mineralisation appears related to melting of sub-arc lithosphere that has been previously modified by subduction. During large-scale plate reorganisation this can occur towards or at the end of a period of normal subduction, following arc collision or accompanying subduction reversal at approximately the same time in different parts of a complex system of arcs such as in SE Asia and the SW Pacific.

Jan 1, 2005

By M Hedley

Tracking plant and personnel in mining operations provides multiple potential benefits for a mine including improved safety, better monitoring of production, traffic control and, in the future, monitoring and control of autonomous vehicles. The main techniques currently proposed and used for wireless tracking are radio frequency identification (RFID), signal strength based techniques and time of arrival (TOA) based techniques. RFID provide poor accuracy in the complex radio propagation environment present in mines and does not provide continuous tracking and signal strength techniques. TOA based techniques are potentially the most accurate, however, most current equipment has not realised the potential of the technique. CSIRO has been developing the Wireless Ad hoc System for Positioning (WASP) system for wireless tracking in a range of challenging environments including underground mines and surface operations, where GPS reception is compromised by depth. The system utilises a number of ‘anchor nodes’ that are placed at fixed and known locations within the mine and tags attached to the plant or personnel to be tracked. The system provides an ad hoc data communication network, thus, wired data connections are not required to the anchor nodes. WASP uses transmissions in the 5.8 GHz ISM (instrumentation, scientific and medical) frequency spectrum to perform highly accurate ranging between nodes, hence tracking of tags. The localisation performance of the system depends upon the radio propagation environment, ranging down to 0.1 m in low multipath conditions. In this paper we describe the WASP system and provide results of testing in underground and surface operations showing the system achieving high ranging, hence localisation, accuracy.

Nov 22, 2011