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By Paul F. Ziemkiewicz, Aaron Noble, Christopher R. Vass

Many modern industries rely on rare earth elements (REEs) to produce products that are essential to both civil and defense applications. In a prior study (Vass et al., 2019), we showed that REE grades in acid mine drainage (AMD) and associated byproduct precipitates from AMD treatment (AMDp) warrant evaluation as a feedstock for REE production. The current work extends that effort through a broad survey of 141 AMD treatment sites in Northern and Central Appalachia. In this study, 185 raw AMD and 623 AMDp field samples were obtained and analyzed to assess the REE and major metal concentrations. Results show that an average of 282 μg/L and 724 g/t of REEs occur in AMD and AMDp, respectively. Additionally, both basins contained similar distributions of REEs, and these distributions tended to favor heavy and critical REEs when compared with traditional REE ore deposits. 

By PAITIP THIRAVETYAN, KANJANA KUDPENG

The aim of this study is to compare amino acids and organic acids in the extraction of gold from silicate ore. Amino acids were found to have higher efficiency of gold extraction than organic acids at the same acid concentration, which is likely due to amino acids having both carboxylic and amine groups in their structure, while organic acids only have carboxylic groups. Five amino acids (glycine, aspartic acid, glutamic acid, lysine and tryptophan) and seven organic acids (citric, malic, tataric, fumaric, oxalic, succinic and ascorbic acids) were selected to investigate gold extraction efficiency. Aspartic acid was found to have greater capacity to extract gold than succinic acid. The optimal gold to aspartic acid molar ratio was 1:6, and low concentrations of aspartic acid extracted 35 to 42 percent of gold from silicate ore within 15 days. Further studies are needed to increase gold leaching and reduce incubation time. The results imply that aspartic acid can be used as an alternative reagent to traditional methods for extracting gold from ore. This method is nontoxic to humans, is environmentally friendly and can have real applications.

By Phillip J. Maddex

Transportation is a major part of yours in the industrial minerals industry. Whereas federal income taxes merely take 50 per cent of your firms profits, transportation cost may take 50 per cent of the gross realization - selling price plus transportation - on your product, f. o. b. customers plant.

Jan 1, 1969

By J. A. Lombardi

"EXECUTIVE SUMMARY The use of membranes for the treatment of Acid-Mine-Drainage (AMD) water has been a 35 year mining industry quest that has only recently produced commercial scale Zero-Liquid-Discharge (ZLD) plants. The process of development of the membrane treatment of AMD has been defined by the water treatment industry’s efforts to control gypsum scaling of the membranes, an artifact of the concentration of calcium and sulfate ions on the concentrate or “brine” side of the membranes. Improved anti-scalants, changes to membrane surface geometry and a lowered permeate flux rate were all part of solving the calcium sulfate (gypsum) scale formation problem. Whether used singly or as part of a multi-stage membrane treatment process, the production of “left over” membrane concentrate or brine, in any volume large or small, was a second barrier to adoption of the method by the mining industry. The two identified “final brine” treatments were a) solar evaporation ponds and b) mechanical evaporators. Brine disposal by solar means is typically site limited to flat terrains or high net evaporation locations. Mechanical evaporation-crystallization is applicable at all sites but, typically, at onerously high ownership and operating costs. Miwatek, a South African water treatment start-up, has entered the mining AMD ZLD marketplace with two new, pilot-scale tested, processes, both of which are predicated on the innovative treatment of a reasonably concentrated AMD and neither of which produces a final brine that requires disposal. In the Miwatek Brine Treatment, MBT, method the membrane brine is caustic pH adjusted and de-calcified precedent to passage through a second membrane plant. The caustic is generated on-site by a lime treatment of the second-membrane concentrate. The first- and second-stage permeates are blended for discharge. The process usually yields no “final brine” for disposal. In the Miwatek Ettringite Treatment, MET, method a low pH first-stage membrane brine is lime treated in two or three steps in the presence of aluminum in a way that metal hydroxide and calcium sulfate solids are formed and purged from the system. Sufficient aluminum is often present in the feed water to, with judicious recycling, enable operation of the lime-aluminum treatment without the purchase of outside aluminum reagent. The first-stage membrane permeate is blended with the lime-aluminum treated membrane concentrate for discharge. The indications are that the method can comfortably meet the low 250 -500 ppm SO4 discharge water quality standards that have most recently been proposed in South America. The process yields no “final brine” that requires disposal. Projected own-operate costs for the MBT and MET systems are less than the estimated costs for all identified alternative treatments."

Jan 1, 2015

By Morgan M. Sears

The LaModel program is widely used to calculate stresses and displacements on thin tabular deposits, particularly when multiple seams or complex mining geometry is encountered. The program itself allows the user to create multiple mining steps to show a progressive sequence of mining. However, LaModel considers each individual step as an independent steady-state condition, and any previous loading conditions of the materials are not tracked. It also does not consider any sort of dynamic stress change during the mining process. In certain circumstances, especially in multiple-seam situations, modeling a scenario of the seam of interest without considering the previous mining sequence in the off seams can potentially lead to inaccurate results. The primary objective of this paper is to present a situation where a potentially dynamic, unstable mining condition was encountered. It was not evident until the previous loading conditions in the off seams and the impact of dynamic stress changes in the active seam were considered. It is important to make the mining community aware of these potential modeling scenarios where the path-dependent nature of the mining sequence is of key importance. This paper presents a case history where room-and-pillar retreat mining was being conducted in a relatively deep cover stress regime where multiple seam interactions were present from both undermining and overmining. Mining in the active seam was being conducted with roomand- pillar mining techniques consisting of a series of parallel production panels being successively developed and retreat mined along a set of Mains. In this situation, the traditional global LaModel analysis without any path-dependent adjustments did not fully identify the area of poor conditions that were encountered. This paper explores the impacts of mining in the active seam on the lower seam which, in turn, has a negative impact on the active seam. This provided a solid foundation for the subsequent analysis of the three seams simultaneously. Based on the calibrated model, it is likely that retreat mining in the active seam resulted in increased stresses in the underlying seam that conceivably resulted in additional convergence and, most likely, additionally convergence of the pillars under the panel being developed. This in turn could have caused active subsid- The LaModel program is extremely useful for analyzing multiple-seam mining scenarios. As multiple-seam situations become even more prevalent, the potential for encountering a path-dependent mining scenario also increases. To successfully model path-dependent mining scenarios, the ground control engineer will be required to make sound judgments on the condition of pillars in sub-adjacent seams. These engineering judgments should be based not only on the current state of stress, but also on any prior or future states of stress. This means considering the stresses from over or undermining as well as stresses applied to the sub-adjacent seams from actively mining the seam of interest.

Jun 25, 2024

By C. RAMADINI, F. NURJAMAN, A. SHOFI, B. SUHARNO

Nickel demand is increasing along with the rising need for stainless steel and other alloy steel/iron. The small addition of nickel in such materials can improve impact strength, ductility and corrosion resistance. Nickel is generally obtained from nickel sulfide ores (nickel associated with sulfur) and nickel laterite ores (nickel associated with iron and magnesium silicate). Almost 60 percent of nickel is now produced from sulfide ores, despite its existence in sulfide ores being less than in laterite ores. However, the depletion of sulfide ore reserves makes the mastery of nickel laterite ore processing of important and immediate concern. Selective reduction followed by magnetic separation has been in development in lateritic nickel ore processing to overcome the issues of high energy consumption and pollution associated with conventional pyrometallurgy methods such as blast furnace and rotary kiln electric arc furnace (RKEF).

By Wei Zhang, Jinhong Zhang

An atomic force microscopy (AFM) image analysis has been applied to study in situ the adsorption of hydroxamic acid collector, i.e., octanohydroxamic acid (OHA), on malachite in aqueous solutions. AFM images show that hydroxamic acid collector adsorbs strongly on malachite mainly in the form of insoluble copper hydroxamate complex. Increasing the collectors’ concentration and the adsorption time both increase the adsorption of hydroxamic collectors on malachite. Results from the attenuated total reflectance–Fourier transform infrared spectrometry (ATR-FTIR) also show that the collector adsorbs strongly onto malachite, with strong absorbance spectra being detected, and the ATR-FTIR results confirm those as obtained by AFM. This specific adsorption mechanism explains that a high selectivity with a moderate collectivity will be achieved with a hydroxamic acid collector for the flotation of malachite. The findings of present study also show that AFM image analysis is a powerful tool for the study of the hydroxamic acid collectors’ adsorption on malachite surface and it can help with the development of novel collectors for malachite flotation.

Feb 1, 2025

By Corby G. Anderson, Sheikh Abdul Rezan Sheikh Abdul Hamid, Sanjith Udayakumar, Ahmad Fauzi Mohd Noor, Teuku Andika Rama Putra

Chemical and mineralogical characterization of Malaysian monazite, a phosphate mineral, bearing rare earth elements separated from the tin tailings originated from Ipoh, Perak, Malaysia, was performed in this paper. The study aims to collect detailed information on the chemical composition, crystal phases, and microstructure of the mineral monazite concentrate that would aid to optimize the subsequent hydrometallurgical processes for high-efficient separation of thorium and other associated rare earth elements. A systematic characterization study of the concentrate was conducted using techniques such as optical microscopy (OM), scanning electron microscopy (SEM) equipped with energy-dispersive X-ray spectroscopy (EDS), and Fourier-transform infrared spectroscopy (FTIR). These techniques analyzed the morphological details on the surface, elemental analysis, and mineral association assessment and identified the surface functionalization groups. The bulk composition and the mineral phases in which the elements are present were studied by wavelength-dispersive X-ray fluorescence (WD-XRF) and X-ray diffraction (XRD) studies respectively. The XRF analysis confirmed the presence of Ce, La, Nd, Pr, and Y (rare earth oxides: REO’s ~ 60 wt.%) while thorium dioxide (ThO2) accounted for 7 wt.% of the total composition. Traces of Ca, K, Al, Fe, Ti, and Mn were also confirmed by SEM elemental mapping. The XRD results confirmed that the concentrate was primarily composed of monazite (Ce, La, Nd, Th (PO4)) along with minor impurity phases of quartz. Automated mineralogical analysis was used as a confirmatory tool to corroborate the preliminary evidences. Based on the particle size distribution analysis supported by SEM, the majority of monazite grains were found to be present in the size range of 170–210 μm. Strong bands of PO4 and SiO4 were observed in the IR spectra corresponding to the phospho-silicate matrix of the REE mineral.

By Alexander N. Winchell

"The iron ores of the Lake Superior region are found almost exclusively in rocks of Huronian age, the only exception of importance being in the Vermilion district. It may be estimated that about 95 per cent of the ores thus far mined have been obtained from Huronian rocks. Although these ores come from rocks of varying age and slightly varying type, they have many features in common, and therefore may readily be described together.The iron formations of the Lake Superior region consist essentially of interbanded layers of mixtures in widely varying proportions of silica and iron oxide, and are called taconite, ferruginous chert, or jaspilite. They vary considerably in hard¬ness and color, depending upon the tenor of silica and the history of the rock. Local phases of the iron bearing formation consist of cherty iron carbonates, greenalite or ferrous silicate, rocks, amphibole-magnetite masses, cherts and slates, and pyritic quartz rocks. The average iron content of all the original phases of the iron bearing formations, excluding interbedded slates, is about 25 per cent, while the average iron content for all portions of the formation, whether in the original condition or not, is about 38 per cent. It is believed that this difference is due essen¬tially to the removal of silica in solution from the. primary phases, and, of course, such removal of silica has in many cases produced material now used as iron ore, since it contains con¬siderably more than 38 per cent of iron."

Jan 1, 1920

By Ross W. Whipple

Applying geophysical techniques in potential geothermal areas has received: little attention in the United States, though it is widely used and accepted in New Zealand and Italy. In those countries it has been demonstrated that geophysical surveys can be useful in locating new geothermal areas and in directing test drilling programs. Geophysical studies in a thermal region can provide structural information and, if conditions are right directly; locate subsurface hot waters. They can give indications of sub-alluvial rock types and of the thickness of alluvial cover. In certain cases they can be used to estimate the power potential of a hydrothermal system.

Jan 1, 1963

By E. F. Paski

Geological materials are likely the most complex and challenging substances to quantitate by ICPOES (inductively coupled plasma optical emission spectroscopy). For complex materials having widely varying compositions, spectral overlap interferences govern detection and quantitation limits attained by ICPOES based analytical methods.

Jan 1, 1993

By Richard H. Sillitoe

Gold is an important byproduct and, locally, coproduct of porphyry copper deposits, and possesses potential for discovery as the major metal in porphyry deposits in either island arcs or Cordilleran belts. Tungsten and tin occur as major components of several potentially bulk-minable porphyry deposits, as well as being byproducts from the Climax porphyry molybdenum deposit. Whereas porphyry tin systems are localized in Cordilleran back-arc settings, their tungsten counterparts appear to span a range of geotectonic settings, from Cordilleran principal arcs through back-arcs to rifts. Although silver is a common byproduct of porphyry copper deposits, it tends to be preferentially concentrated with lead and zinc on the fringes of all types of porphyry deposits and/or as late-stage superpositions; the latter situation could be of some interest in the higher parts of porphyry systems. As byproducts, rhenium, uranium, platinoids and magnetite are exploited occasionally, and rutile and the rare metals, such as tantalum and niobium, have merited consideration.

Jan 1, 1982

By Byron R. Berger

Epithermal Ag-Au deposits form at low to moderate temperatures in near-surface environments. Historically, these deposits have been the source of high-grade ores. Increases in the market prices for gold and silver make lower-grade ores economically viable when available in large tonnages. Both the high-grade and bulk-tonnage ores are a consequence of the same processes, and general models of epithermal systems can be useful in the search for new precious-metal resources. A detailed study of deposits at Round Mountain, Nevada; Balei, Russia; Creede, Colorado; Guanajuato, Mexico; and Chanarcillo, Chile, indicates that the hydrodynamics of the fluid systems as determined by fracture geometries, the permeability, and composition of the host rocks are the key factors in the creation of both high-grade and bulk-tonnage epithermal deposits. End-member models that explain the range of observed deposit characteristics are: (1) the hot-springs deposition model; (2) the stacked-cell convection model (where mineral deposition occurs laterally along the interface of two partially separated fluid reservoirs); and, (3) the closed-cell convection model (where deposition occurs in vertical zones due to the relatively unimpeded vertical flow of hydrothermal fluids). Boiling and fluid mixing appear to be agents of precious-metal deposition with the self-sealing of the hydrothermal system being an important adjunct to boiling. Imaginative application of model concepts in exploration has led and can lead to the discovery of new high-grade and/or bulk-tonnage precious-metal deposits.

Jan 1, 1982

By E. A. Metz

Silicon dioxide, silica, is the most common oxide in the earth' s crust. The health effects of silicon dioxide dust have been known since Biblical times. Agricola's book, published in the mid 1500's on occupational medicine, described a lung disease that afflicted miners. He observed a disease in miners that caused shortness of breath, coughing and wasting. Add fever, chest pains and fatigue and we have the current symptom complex of silicosis. As we approached the 21stcentury, the Labor Department began an aggressive campaign to combat silicosis-a preventable disease. Unfortunately, many publications do not clearly differentiate the polymorphs of silica known to mineralogists. Crystalline silica, i.e., alpha quartz, tridymite and cristobalite need to be considered differently from the amorphous forms of silica. Freshly fractured surfaces of the silica and host specific responses will be examined. Recent research focuses on the biologic interactions of free radicals generated by mineral particles. This results in cell injury and DNA damage, in turn leading to fibrogenesis and possibly carcinogenesis. In addition to particle-cell interactions, emphasis is given to lung defense mechanisms.

Jan 1, 1998

By Jerry Wang, Greg Bold, Mahmood Khwaja, Rebecca Caldon, William Simcoe

Phase III and Phase IV of the Beaver Creek Clean River Project, Albany, NY, includes microtunnel construction of 2,320 feet of 48-inch/36-inch internal diameter (ID) conveyance pipe and a 525 foot long 9.5-ft horseshoe shape roadheader excavated tunnel. Notable challenges were encountered during the construction including mixed face tunnel conditions, undocumented existing fill ground conditions that resulted in settlement during shaft construction, and unstable tunnel face conditions. This paper discusses several of the key challenges encountered during construction and selected solutions to construction sequencing and methodology to successfully complete Phase III and Phase IV of the Beaver Creek Clean River Project.

Dec 1, 2022

By D. J. Wood

BHP Copper has grown, in just over six years, from a minor participant to the world's largest privately owned copper producer. BHP Copper's major asset is the world's largest copper mine -Escondida in Northern Chile. Ten years ago investing in Chile was considered high risk. Today, Escondida represents an investment of approximately US$2 billion. Reward is the result of managed risk and Escondida is a clear demonstration of both. The Ok Tedi copper and gold mine in Papua New Guinea represents a Rubicon of risk and a retrospective on reward in a developing country on the doorstep of a developed one. The story of these two mines encapsulates risk in the mining industry.

Jan 1, 1998

By Robert M. Mann

The Ag/S specific ion electrode has been evaluated for analysis of both free and total cyanide. Metal cyanide solutions were prepared from reagent grade compounds and by stoichiometric fixture of the metal with a potassium cyanide solution. Solutions containing Cu+1, Ni+2, Fe+2, Fe+3 and Zn+2 complexes were analyzed prior to and following EDTA pre treatment. This effort provides an understanding of the effect of each metal cyanide complex on the SIE analysis of free and "total" cyanide.

Jan 1, 1981

Roof bolting has been widely used in hard rock underground mines for its many advantages. In this paper, the applicability of roof bolts to mine openings in frozen ground and effects of bolts on the stability of the openings are presented. A comprehensive finite element program ABAQUS, was used to analyze the temperature distribution, the stress field, and the displacement field around a mine opening. Openings supported by roof bolts and unsupported were analyzed. The thermal and mechanical processes were treated as a quasi-coupled problem, with the thermal analyses being conducted first, followed by the mechanical analyses in each case. For the opening under consideration with a roof area of 15 m2, five to seven roof bolts are appropriate. When the number of bolts are less than five, the displacement within the ground can be improved only locally.

Jan 1, 1995

By Thomas Schwind, Elmar Feigl, Gerald Skalla, Angelos Gakis

Cedarvale station was constructed as part of the Eglinton Crosstown Light Rail Line, under the operational Yonge-University Line Subway box of Toronto Transit Commission (TTC). The station was constructed as an open-cut, which necessitated the underpinning of the existing TTC box to minimize the impact on the Subway and allow its unhindered operation. Six mined galleries, 4 m wide by 2.75 m high, were excavated sequentially (SEM) immediately under the existing box, to provide the required space for the installation of the main underpinning beams. This novel solution was executed successfully providing quick access for the main excavation works to commence.

Dec 1, 2022

By James F. Lemons

The potential production of cobalt from nickel sulfide deposits in Canada, from nickel laterite deposits in the Pacific Islands, and from the copper deposits of Zaire and Zambia will be a function of the cost of recovery of the primary nickel and copper products. This cost of production varies significantly for these deposits and is related to the differences in the cost of labor, energy, and supplies, to production technology, and to the grade and recovery of nickel, copper, and cobalt. This Bureau of Mines paper investigates these cost and technology differences as they relate to the cost competitiveness of the deposits in Canada, Zambia, Zaire, and the Pacific Islands.

Jan 1, 1984