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By Oliver Bowles

"A Product from Mica Mines.Mica commonly occurs in pegmatites which consist of large crystals of feldspar and quartz, mica constituting but a small proportion of the total rockMuch of the feldspar thus thro n out during the process of mining is pure and of high quality, end the Bureau of Mines has suggested that much of it could be utilized for ceramic purposes. Encouragement is given to such utilization by the fact that several mines now worked for mica were formerly operated for the production of feldspar. ""'here mines are not readily accessible to railroads feldspar utilization might not be feasible, for it is a much lower priced product than mica and cannot therefore bear as heavy transportation expense. '""here mines ire located close to railroads, however, such utilization would tend to reduce the cost of mica mining, and at the same time assist in the solution of the waste disposal problem.The Bureau has recently been informed that some of the feldspar from mica mines near Spruce Pine, N.C., is now being sold and shipped away. An extension of this by-product industry is to be recommended.A Mica Deposit in New York City.The Bureau recently received a mica specimen obtained from a. building excavation at 157th St. and Riverside Drive, New York City. The specimen was about 2 by 4 inches in size, and fairly clear though containing numerous hair cracks. It was obtained only 7 or 8 feet below street level. At greater depth and with more careful methods of excavation material of much better quality might be obtained. The material submitted could be used for mica washers but not for sheet mica. It is stated by an official of a prominent mica company that many such fragments are obtainable in this locality and the possibility of the occurrence of a good mica vein is thereby suggested."

Jun 1, 1920

Investigate and demonstrate the possible use of low-density (45-lb/ft3) foam concrete for sealing abandoned mine openings. Although foam concrete has been used in the construction and geotechnical industries for some decades, it has not previously been used in abandoned mint shaft reclamation. Approach A structurally engineered permanent mine seal for an abandoned coal mine shaft, using low-density foam concrete and other appropriate structural materials, was designed by the Bureau and installed at a field site, the No. 22 Shall in Logan County, West Virginia. The field work was conducted by a private contractor under the supervision of the West Virginia AML Section (WV AML). The No. 22 Shaft is situated immediately adjacent to a frequently traveled county road. A few feet away from the shaft is a branch of Pine Creek. On the other side of the road is a railroad line that serves an active mining operation located several miles away. The shaft measures 9.5 by 9 feet in cross section and is about 300 feet deep. It was used at one time as a dewatering shaft and still contains two large-diameter dewatering pipes with steel drive shafts inside them. Before the beginning of the reclamation, the shaft included a concrete cap a few inches thick, with a 4 - by 5-foot access opening covered by a steel grate. The interior of the shaft was quite humid, and considerable flow of water at the bottom of the shaft could clearly be heard from the surface. Methane tests were conducted that showed the shaft to be clear of this gas.

Jan 1, 1992

By C. M. Frost

Crude shale oil produced during in situ retorting by the Bureau of Mines at Rock Springs, Wyo., was refined by three schemes. In the first, the crude oil was fractionated to raw naphtha and 400° F+ residuum. The residuum was hydrogenated over cobalt molybdate catalyst at 815° F and 1,100 psig. The blended raw and 160°-400° F hydrogenated naphthas were hydrodenitrified and then catalytically reformed. The 400° F+ hydrogenated oil was catalytically cracked. In the second scheme, the crude was hydrogenated over nickel-tungsten catalyst at 800° F and 1,500 psig. The hydrogenated fractions were processed by methods used in the first scheme. The third scheme resembled the second but, prior to hydrogenation, the crude was "hydrostabilized" over cobalt molybdate at 500° F and 500 psig. Yields of reformate and cat-cracked gasoline as volume-percents of the crude, and research-method octane numbers (with 3 ml TEL) for the three methods were as follows: First method, 32 pet reformate, 90 octane; 19.5 pct cracked gasoline, 99.2 octane. Second method, 29 pet reformate, 81.1 octane; 21.3 pct cracked gasoline, 99.6 octane. Third method, 28.2 pet reformate, 86 octane; 28.7 pct cracked gasoline, 95.9 octane.

Jan 1, 1974

By Edmund S. Leaver

This information circular is written is response to the marry requests for information on the recovery, or reason for poor recovery, of fine gold by the amalgamation process. Checking Gold Content Experience has shown that in many cases error has been made because the true told content of a particular sample or deposit was not known. Fire assays of representative samples give accurate results and should be considered final in determining the gold content.

Jan 1, 1928

By John R. Reeves

The development of an new industry, which must prepare its marketable products at or near the source of the raw material, and ship them to a market which may cover half a nation, is more or less influenced by a number of natural and cultural conditions such as (1) location of plants with respect to a large market, (2) climatic conditions, (3) transportation facilities, (4) labor supply, and (5) water supply. An effort is made in this pager to give in detail a number of the more important of these conditions as they affect, either favorably or unfavorably, the development of the oil-shale resources of southeastern Indiana. The utilization of the New Albany formation for the production of oil will be similar to a large scale low-grade ore proposition in which the raw material can be obtained in very large quantities at a relatively low cost. It appears, therefore, in considering the value of this shale or its economic position in relation to other oil shales, tie cost of mining and preparation for the retort are of prime importance.

Jan 1, 1923

By H. E. Powell

Because of increasing consumption of high-and super-duty refractories, the Bureau is studying the feasibility of beneficiating submarginal and marginal clays. Diverse mineral dressing tests were used to beneficiate samples from the east-central Missouri fire clay district. Standard ASTM tests were used to determine refractory properties of both crude and beneficiated clay samples. Marginal and submarginal clays containing impurities were effectively beneficiated by both wet-cyclone and wet-table treatment, but the wet-cyclone treatment was cheaper. Ion-exchange resins in the hydrogen form will probably prove more effective in removing potassium, the only alkali in Missouri fire clays to be a problem. Resins with greater cross linkage are more effective than resins with less. Roasting the crude clays before removing alkalis by chemical leaching was ineffective. By applying ultrasonic energy at a frequency of 10 to 25 kilocycles to aqueous suspensions of the clays, subsequent ion-exchange extraction of potassium was slightly improved. Higher frequency ranges did not help.

Jan 1, 1963

By W. K. Sawyer

In this Bureau of Mines investigation, one-and two-dimensional gas reservoir simulators were combined in such a manner that pressure distributions both in an induced vertical fracture and in the surrounding formation, could be determined as a function of time for any specified well production rate. The technique used consisted basically of the alternate ust of one-and two-dimensional algorithms for obtaining new pressure distributions in the fracture and in the reservoir, respectively. The pressures at adjacent reservoir and fracture nodes were used to calculate flow rates from the formation into the fracture, which provided source terms for both algorithms. The combination model developed provides the only known means of simultaneously simulating transient gas flow in a vertical fracture and the surrounding formation. Thus, the technique developed would be useful in locating wells in a gas storage field in that the effects of both fracture length and conductivity could be considered prior to drilling and fracturing operations. In addition, it will be helpful in analyzing pressure drawdown tests in a vertically fractured gas well since the entire test can be readily simulated for a wide range of reservoir and fracture properties.

Jan 1, 1974

By E. G. King

The work described in this Bureau of Mines report was undertaken to fill a need of industry for high-temperature heat-content data for uranium tetrafluoride. Without such data, heat balance evaluations of processes involving this substance are seriously hampered. Measurements of the heat content of uranium tetrafluoride were conducted at temperatures from 298° to 1,350° K. The melting point and heat of fusion were determined. The results are presented in suitable tabular form, and representative heat-content equations are included.

Jan 1, 1961

By G. R. Hopkins

"Summary An apparent decline in fuel efficiency at refineries, which first became came evident in 1930 and continued through 1933, was checked in 1933 when the average amount of heat needed to refine a barrel of crude oil amounted to 660,000 B.t.u. This compares with an average requirement of 692,000 B.t.u. In 1932 and with a low of 639,000 B.t.u. in 1929. (See fig. 1.) The improvement in fuel economy in 1933 probably was closely related to the increase of 5 per cent in crude runs to stills. As much of the fuel burned at refineries is utilized for purposes other than under crude-oil stills and in relatively stable amounts, it is evident that a material increase in crude runs will usually reflected in a decrease in average fuel requirements. Another factor which has influences fuel economy at refineries in the past is the trend in cracking, a refining process requiring more than the average expenditure of heat. In 1933 production of gasoline by cracking increased slightly, but no appreciable rise in heat requirements resulted as an equivalent amount of fuel was saved in improved technique, particularly in the field of heat exchange.Since the beginning of the refining industry, the transition in fuels has been from solid to liquid to gaseous; in other words, the leadership was first held by coal, then passed to oil, and is now held by gas. In 1933, 54.7 percent of the total heat units generated came from gas, 39.0 percent from oil (including acid sludge), and 6.3 percent from coal and coke. The principal change in the relative importance of the various refinery fuels in recent years has been the rapid growth in consumption of refinery or still gas at the expense of all the other common fuels. Still gas owes its ascendency to its cheapness and availability, and probably it would have become the primary refinery fuel years ago if recovery methods had been perfected. The relative importance of coal showed a small increase in 1933, the first gain recorded since these surveys were inaugurated in 1925. The increase in use of coal was undoubtedly due to increased operations at plants using it,"

Feb 1, 1935

By William P. Diamonds, David C. Oyler

Stimulated vertical boreholes are an effective means of removing gas from coalbeds in advance of mining. This Bureau of Mines report examines the coal mine roof damage potential of stimulation treatments. Twenty-two Government-sponsored stimulation treatments have been mined through to determine the effects on the coalbed and roof strata. Vertical fractures in the coalbed were discernible for most treatments and horizontal fractures were present for about half of the stimulations. Sand-propped vertical fractures were usually short in lateral extent. Evidence of stimulation fluid movement could generally be traced beyond the maximum extent of sand-filled fractures when fluorescent paint was added to the treatment fluids. The maximum lateral extent for a sand-filled vertical fracture was 416 ft and a paint-coated vertical fracture extended 630 ft. Horizontal fractures were generally found within bedding planes, most commonly on top of the coalbed. The maximum lateral extent for a horizontal fracture was 265 ft at a coalbed depth of 630 ft. Horizontal fractures have been found to occur as deep as 1,145 ft. Penetration of strata overlying coalbeds was observed in nearly half of the treatments intercepted. Most of these occurrences have been interpreted to be penetrations into preexisting joints. No roof falls or adverse mining conditions were encountered that could be attributed to the stimulations.

Jan 1, 1987

By S. B. Levin

"INTRODUCTION An exposure of large beryl crystals in pegmatite on Beryl Mountain, in Sullivan County, N. H., was the basis for investigation by the Bureau of Mines to determine the extent of the beryl mineralization and to expose other parts of the same zone that were favorable for additional beryl-rich shoots. Testing by surface cuts, trenching, and tunneling was conducted by the Bureau of Mines from August to December 1943.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to the national security and economy. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual investigative work, and prepares the final report. The Metallurgical Division, O. C. Ralston, chief, analyzes samples and makes beneficiation tests. The field work was supervised by Paul M. Tyler, regional engineer, and John D. Bardill, district engineer. S. B, Levin was in direct charge of the project.LOCATION AND ACCESSIBILITYThe deposit is on the northeast slope of Beryl Mountain, 1 mile south of the village of South Acworth. The village, on State Highways 101 and 123a, is 12 miles northeast of Bellows Falls, Vt. The deposit is reached from South Acworth over a gravel-surfaced road and about 1,000 feet of good truck trail (fig. 1).The nearest railroad siding is at Cold River, on the Boston & Maine Railroad, where there is also a fairly modern, but now idle, feldspar mill."

Mar 1, 1948

By Charles L. Kusik

As part of an effort to establish processes that could be exploited in case of adverse changes in international chromium production and trading patterns, this study was sponsored by the Federal Emergency Management Agency (formerly the Federal Preparedness Agency) through the Bureau of Mines, to experimentally determine the feasibility of recovering chromium from critical scrap metals containing significant quantities of this element. Based on a conceptual pyrometallurgical chromium recovery flowsheet developed at Arthur D. Little, Inc., the experimental program described in this report demonstrated key process steps for the recovery of chromium as ferrochromium in a batch process. The process involves oxidation of chromium into a slag phase, subsequent separation of the slag phase from the remaining metal, followed by reduction of chromium from the slag phase to produce ferrochromium.

Jan 1, 1981

By John R. Benham

The Blue Joint Mtn. RARE II area may contain barite resources. One claim, the Woods Creek Barite No. 1, contains two veins of barite of drilling mud quality. The quantity of barite present could not be determined due to limited surface exposures. Sections 1, 2, 11 and 12 of T. 2 S., R. 23 W. in the study area are classified by the U.S. Geological Survey as prospectively valuable for geothermal energy resources. These sections border Blue Joint Creek Hot Springs, which are outside the study area.

Jan 1, 1981

By E. R. Cole

Bench-scale research at the Bureau of Mines has resulted in the successful development of a combination electrorefining-electrowinning method for recycling all the lead in scrap batteries. The method reduces energy consumption and eliminates toxic emissions, in contrast to present pyrometallurgical smelting, and the lead produced is pure enough for use in maintenance-free batteries. Anodes cast from molten lead scrap were electrorefined in 1-and 2-liter plastic cells using an electrolyte composition of 70 g/l Pb and 90 g/l free H2SiF6 (fluosilicic acid). Both reagent-grade and waste H2SiF6 were used. Cathode starting sheets were made from refined lead. Aloes, and later bone gelatin, and calcium lignin sulfonate addition agents were employed. The sludge remaining after separation of the lead metal was treated in a two-step leaching operation to solubilize the lead for recovery by electrowinning. Conditions for electrowinning were essentially the same as for electro-refining, except that insoluble Pb02-Ti (lead dioxide-coated titanium) anodes were used. The best results for both electrorefining and electrowinning were obtained with a current density of 170 amp/m2 and a cell temperature of 25° to 35° C. Cathode purity ranged from about 99.9 to 99.99+ pct Pb. Maximum energy consumption after 3 days, for electrorefining and electrowinning, was 90 and 700 kwhr per metric ton of refined lead, respectively.

Jan 1, 1981

By T. A. Johnson

Recovering from low demand in 1975, raw mineral production in the United States maintained a steady climb in value and quantity throughout 1976, keeping pace with the gross national product (GNP), which increased 11.5% compared with that of 1975. The minerals industry, in the past, has met ever-increasing demand while keeping production costs to a minimum. To maintain this capability, technological research and development of more efficient processing methods must continue. The role of Government and its increasing involvement in minerals industry actions received unfavorable comment from various segments of the industry in 1976. Government pricing controls were of concern to most industrial firms marketing like products. Public land withdrawals in large blocks were of concern to the mineral industry.

Jan 1, 1978

By B. J. Dalton

This report gives general expressions for evaluating various thermo-dynamic properties applicable to a two-component system, including liquid-vapor equilibria. In addition, expressions are developed for some of the quantities useful in making thermodynamic consistency checks on phase equilibria data. These formulas were developed from the general principles of thermodynamics and are expressed in terms of the compressibility factor, which is assumed to be an explicit function of the molal density, the absolute thermodynamic temperature, and the composition.

Jan 1, 1968

By R. E. Brown

The objective of this Bureau of Mines study was a laboratory-scale evaluation of the sodium sulfate refining process for removing copper from molten ferrous scrap. Maximum copper removal is achieved in carbon-saturated melts at 1,300° C. Low carbon concentrations and higher temperatures result in a less efficient copper removal and an increased sulfur concentration in the iron. Sodium sulfate refining significantly lowers the concentration of aluminum, manganese, and silicon; however, the copper removal efficiency is adversely affected by the presence of manganese and silicon. Compared with other reagents tested, sodium sulfide-forming slags were found to be the most suitable for both copper removal and sulfur control. The sulfur content of the refined iron was higher in tests conducted in acid-type refractory crucibles. Earlier studies showed that tin, a significant metallurgical impurity, is not removed by the sulfate process. During the present investigation, results showed that chlorination, using organic solid sources of chlorine, reduced the tin concentration to acceptable levels in molten iron.

Jan 1, 1975

By G. W. Eiger

Bureau of Mines laboratory tests show that ilmenite concentrates with titanium dioxide contents as low as 33 wt--pct can be beneficiated to produce a crystalline substitute for natural rutile suitable for direct chlorination. The synthesized product prepared by a three-step procedure was comparable with natural rutile in titanium content. Reduction smelting of ilmenite removes iron as a pig iron byproduct, and the remaining slag phase is greatly enriched in titanium. Oxidation of the slag in the presence of phosphorus¬bearing slag additive converts the titanium-bearing phases to discrete rutile crystals and a glass phase containing most of the associated impurities. Rutile is separated from the glassy impurities by attrition scrubbing ground slag in dilute phosphoric or sulfuric acid solutions. Tests made in a laboratory fluid-bed reactor show that synthetic rutile responds to chlorination at the same rate as natural rutile and that more than 95 pct of the titanium contained in the feedstock was extracted as titanium tetrachloride.

Jan 1, 1974

By F. J. Bailey

"In the fall of 1919, the U.S. Bureau of Mines began an inquiry as to the possibility of utilizing airplanes in conjunction with its rescue work, for quickly transporting engineers and oxygen rescue-apparatus to mine disasters.It was realised that this proposed use of airplanes has serious limitations, and if it were feasible, that the Bureau would have to rely on the cooperation of the established aviation fields of the U. S. Air Service for furnishing airplane service. Therefore Van. H. Manning, Director of the Bureau of Mines, under date of October 28, 1919, wrote the Director of Air Service outlining the rescue and first aid organization of the Bureau, the location of headquarters of district engineers, the distribution of safety cars and stations, and other essential details, and asking whether the Air Service could cooperate with the Bureau in the event of serious mine disasters. Major-General Charles T. Menoher, Director of Air Service, responded that the Air Service would be glad to cooperate insofar as possible, and designated those Air Service stations nearest the district engineers' headquarters, which might be best able to assist.The Bureau of Mines has ten mine rescue cars and eight mine safety stations distributed throughout the mining regions of the United States. The cars are each equipped with sets of oxygen mine-rescue breathing-apparatus and first-aid supplies. The car personnel consists of a mining engineer, surgeon, foreman, first-aid miner, clerk and cook. A foreman miner is in charge of each station and at five of the eight stations are mine safety trucks. The work of the cars and stations is two-fold; (1) Assisting in rescue and recovery work at mine disasters, and (2) training miners in mine rescue and first-aid methods, and in investigations looking to prevention of mine accidents. The country is divided into nine safety districts, with nine district engineers in charge."

Apr 1, 1920

By John Gross

"Introduction.Southern Illinois and Kentucky are credited with approximately 90% of the fluorspar production of the United States. A small amount of high-grade acid, spar is obtained from the ore by band sorting; the greater part, however, is recovered by jigs and tables as gravel spar containing approximately 85% calcium fluoride. In the jigging and tabling operations, galena is recovered, and enough silica and calcite are removed to raise the calcium fluoride content of the gravel spar to 85%. However, the removal of silica and calcite results in a large loss of spar. With increasing depth in the mines, zinc sulphide, sphalerite, is encountered in increasing quantity and the removal of this has become a serious problem. While the sphalerite can be fairly well removed from the spar by present milling methods, a marketable zinc concentrate can not be made. The experiments described below were made on fluorspar ore from Southern Illinois, by the mining experiment station of the U. S. Bureau of Mines, at Rolla, Mo., in cooperation with the Missouri School of Mines and Metallurgy.The ore tested contained. 7.3% lead, 27.9% zinc, 35.7% calcium fluoride, 9.5% silica and 4.7%. calcite.Tests and Results. In some preliminary tests it was noticed that a portion of the finely crushed ore adhered strongly to the sample pans, and upon investigation it was found that the adhering material was practically clean spar. By utilizing this property of adhesion 46.8% of the spar was recovered as a product containing 98.3% calcium fluoride. This suggested the possibility of using electrostatic separation."

Jul 1, 1921