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1. In 2003, a total of 4,357 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA). The major industrial classifications in stone mining are dimension stone (used for construction purposes), crushed and broken stone (aggregates), cement, and lime. • Stone mines comprised 30.3% of all mining operations. • Mines producing crushed and broken stone (n = 3,412) comprised 78.3% of all stone mining operations.

Feb 1, 2005

To improve safety by making speed and direction control of a tracked vehicle simpler and instinctive. Approach A joystick control (which determines vehicle speed and direction of movement as well as the direction of any turning or pivoting) was developed and tested on a loading machine during a long-term underground demonstration. How It Works The control box actuated by the joystick lever contains two multiposition, multideck rotary switches. Fore-aft movement of the joystick rotates one switch through five positions to provide a neutral position and two speeds of travel in both

Jan 1, 1978

By L. B. Pankratz

Enthalpies were determined for synthetic chalcopyrite (CuFeS2) between 298° and 1,050° K and for synthetic bornite (Cu5FeS4) between 298° and 1,100° K by copper-block drop calorimetry. Two transitions were found for each compound. The lower transitions were both crystal transformations from tetragonal (low-temperature form) to cubic (high-temperature form). The chalcopyrite transformation occurred at 830' K with a heat of transformation of 2,405 cal/mole; the bornite transformation was at 485° K with a heat of 1,430 cal/mole. The other transitions were of the second order and were presumed to be magnetic in character. The second-order transitions for chalcopyrite occurred at 930° K, and the one for bornite at 540° K. Enthalpy increments, entropy increments, and heat capacities are tabulated at even temperatures above 298.15° K. Equations of enthalpy are also given.

Jan 1, 1970

By D. A. Doughty

The Bureau of Mines developed two methods for determining iron II and iron III in 2- to 5-mg samples of coal using electron paramagnetic resonance (EPR) spectrometry. One method used solid coal samples; the other method used aqueous solutions. The method using solid samples was more simple, technically, but required the use of X-ray fluorescent analysis, or another independent method, for determining total iron in the samples, and the results were subject to some uncertainty. The method using aqueous solutions appeared capable of greater certainty and did not require additional methods of total iron analysis but was more involved procedurally. The coals analyzed were found to contain much more iron II than iron III.

Jan 1, 1973

By Thomas E. Green

A solvent extraction procedure using 8-hydroxyquinoline and chloroform was investigated by the Bureau of Mines as a preconcentration technique for the determination of aluminum, calcium, cobalt, copper, iron, lead, magnesium, manganese, nickel, and zinc in large samples of high purity tungsten. X-ray spectrographic and atomic absorption methods were used to determine the trace metals after preconcentration. The presence of 10 grams of tungsten had a pronounced effect on the distribution of 8-hydroxyquinoline between the aqueous and chloroform phases. This change in the 8-hydroxyquinoline distribution in turn had an adverse effect on the extraction of the trace metals. Extraction efficiencies can also be adversely affected by an increase in the quantity of extractable metals present, as shown by radiotracer tests using 65Zn. Excess 8-hydroxyquinoline in the extracts did not interfere with the determination -of the serious interference in the combined ion exchange paper--X-ray spectrographic method. Although preconcentration by 8-hydroxyquinoline extraction was found to be partially successful, other preconcentrationn methods based on ion exchange and dithizone extraction were found to be superior.

Jan 1, 1968

By S. J. Page, W. R. Reed, J. A. Organiscak

NIOSH continues to conduct respirable dust control research for surface mine blasthole drilling operations. Research areas have included testing variables (shroud leakage area, drill deck cross-sectional area, shroud height, collector-to-bailing airflow ratio, etc.) that have the most impact on respirable dust control, development of a dust collector inlet hood, development of a dust collector dump point shroud, and testing of a small diameter water separating sub. This paper summarizes the results of the aforementioned research that has been completed. Additionally, past dust control research for drilling operations of both underground and surface mines completed by the U.S. Bureau of Mines, created in 1910 and incorporated into NIOSH in 1997, is reviewed.

By Steve Bessinger, Steve Signer, James Pile

The San Juan Mine and the National Institute for Occupational Safety and Health conducted a study to measure how development mining affected bolt loads. Twelve fully grouted, instrumented roof bolts were installed at two three-way intersections as part of the standard bolting pattern. Newly developed miniature data acquisition systems (MIDAS) were used to measure bolt load changes during initial face advance and cross-cut breakthrough. The effects of cut placement and depth on roof bolt loads were studied. This test showed how bolt loads increased at five positions along the bolt length during initial mining. Both entry advance and cross-cut breakthrough produced a similar percentage of increase in bolt loads. Geologic differences between the test sites were probably responsible for the differences in amounts of bolt loading. The test site with more top coal and a higher rock quality designation (RQD) had lower bolt loads.

By Jeffrey Shawn Peterson

The testing procedures of the U.S. Mine Safety and Health Administration specify that intrinsic safety acceptance tests be conducted using a standard tungsten-cadmium electrode configuration in the break- flash apparatus. However, in realistic mining environments, other materials may be more likely sources of sparking. Information defining the probability of spark ignition between common materials such as aluminum, brass, copper, lead, tin, cold-rolled steel, and stainless steel is of more practical value in determining ignition hazards. The U.S. Bureau of Mines has completed an investigation of the influence of material on the ignition probability using the breakflash apparatus. By comparing ignition currents or ignition voltages corresponding to a probability of one ignition per thousand sparks to those found previously for cadmium, a margin of safety may be estimated for each material. This report presents the results of an investigation into the influence of disk electrode material on the probability of ignition.

Jan 1, 1992

By James R. Boyle

The value of Alabama's nonfuel mineral production in 1985 was $405.9 million, a slight decrease from the record high of 1984. With the exception of clays, output of most nonfuel minerals increased over that of 1984. Alabama was second in the Nation in production of crushed marble and bauxite; third in firre clay; fourth in masonry cement and kaolin; fifth in portland cement and lime; and sixth in ferroalloys and recovered sulfur, Alabama ranked 20th in the Nation in value of nonfuel minerals produced, but ranked 13th in value of industrial minerals. Valuewise, Alabama produced 2.4% of the Nation's industrial minerals.

Jan 1, 1987

By D. E. Shanks

As part of its effort to produce cell-grade alumina from clay, the Bureau of Mines investigated the hydrogen chloride gas-sparging crystallization of aluminum chloride hexahydrate (ACH) from aluminum chloride liquor, to provide information for optimizing the crystallization operation. Four parameters important in controlling the crystallization of the aluminum chloride hexahydrate and the concentration of impurities, particularly phosphorus and magnesium, in ACH crystals are (1) aluminum chloride concentration in the feed solution to crystallization, (2) hydrogen chloride gas flow rate, (3) temperature, and (4) concentration of phosphorus and magnesium also in the feed solution. Parameters 1, 2, and 3 affect crystal formation. The combined effects are very important because the phosphorus and magnesium concentrate in the crystals during the early stages of crystal growth. Aluminum chloride hexahydrate of cell-grade purity was crystallized from saturated aluminum chloride solutions containing less than 0.003 wt-pct P205 and 0.010 wt-pct MgO. Crystallization temperatures less than 600 C decreased crystal purity.

Jan 1, 1981

By Frank G. Schwartz

The Bureau of Mines developed a rapid test method for predicting the stability of motor gasoline during long-term storage. The amounts of gum and inorganic residue formed in 13 gasolines during a l6-hour oven test at 200° F were compared with the amounts formed in the same gasolines stored at 110° F, and analyzed following 8-, 16-, 32-, 44-, and 52-week storage periods. Satisfactory methods were developed for predicting gum and inorganic residue formation during fuel storage periods as long as 32 weeks at 110° F, the approximate equivalent of 5.7 years at 80° F. The only data required to apply the methods are the amount of gum and inorganic residue formed, and the amount of oxygen that reacted, during a l6-hour oven test. A direct relationship existed between inorganic residue formed during the oven test and during 110° F storage. Statistical treatment of the data showed predicted values were as reliable as determined values. By use of a modified Arrhenius equation, the 110° F storage time can be extrapolated to equivalent time at any temperature below 110° F. Thus by combining the stability prediction method with the mathematical extrapolation, the storage performance of motor gasoline for extended periods can be estimated at any temperature up to 110° F.

Jan 1, 1968

By F. N. Kissell

The applicability of the "direct method" for determining the methane content of virgin coalbeds was tested. Preliminary results indicate that the direct method, when applied to exploration cores, can be successfully used to estimate coalbed gas content and also approximately predict the total gas emission from a prospective mine located in the coalbed at the exploration site.

Jan 1, 1973

Provide reasonably priced, reliable fire protection for front-end loaders. Approach Automatic fire sensing and suppression systems were developed and ruggedized for use on front-end loaders operating in harsh mine environments. How It Works Temperature sensors mounted in the loader's engine, transmission, and articulation areas detect the heat from a fire while it is still small and controllable. This triggers the release of the ABC class dry chemical extinguishing agent through a fixed piping system onto the fire. The system can also be manually activated from either the cab or ground level. Locations of the principal components of the system are shown in the drawing. Two control subsystems were designed to respond to varying fire protection needs and mine conditions. One subsystem only initiates discharge of the extinguishing agent. The other subsystem initiates visual and audible operator alarms if there is a fire sensed or if there is a fault in the control circuit.

Jan 1, 1979

Develop a more efficient method of testing the integrity of in-situ leach mining operations. The Problems For economic and environ-mental reasons, in-situ leaching operations must be sure that wells do not leak. Loss of solution in large quantities can be expensive in itself, and if such losses result in pollution the costs can be even higher. Wells are usually tested for leaks by sealing them with packers, pressurizing them and monitoring the pressure drop. However, many commercially-available packers are designed to be used in steel-cased wells rather than the fiberglass-or plastic-cased wells used for in-situ mining. These packers are heavy, cumbersome, expensive, and often leak. In addition, commonly used well-integrity-test systems require lengthy test periods and drill rigs or hoist trucks with rigid pipes must be used to run the packers in and out of the well. The Bureau of Mines has developed a mobile, self-contained leak-testing system that is faster, uses trailer-mounted equipment that can be operated by one person, and features a new inflatable packer.

Jan 1, 1985

By M. Kanefsky, A. Q. K. Rajput

Two channel polarity coincidence and polarity difference statistics are analyzed. The signal, common to both channels, consists of sinusoidal bursts where the exact frequency of the signal is nearly known, but other parameters such as amplitude, phase, and pulse starting time are unknown. The noise inputs are dependent, narrow band, Markov processes. It is shown that the performance depends not only on the signal uncertainties but on the precise shape of the cross-correlation functions between the noise inputs. By using two polarity difference statistics in addition to the polarity coincidence statistic, it is shown that the decrease in performance, as well as the cost of hard limiting due to correlated inputs, can be made small.

Jan 11, 1981

By Paul R. Coyle, Anthony T. Iannacchione

A close look at the Loyalhanna Limestone of southwestern Pennsylvania reveals a complex structural environment. Most exposures of the Loyalhanna occur along Chestnut Ridge and LaurelHill within the Allegheny Mountain Section of the Appalachian Plateaus Province. Because the Loyalhanna is rated as a super-pavement aggregate by the Pennsylvania Department of Transportation and because of its proximity to the population centers of southwestern Pennsylvania, the Loyalhanna has been extensively mined along these prominent anticlinal structures. Geologic and engineering analyses were performed using gas well and core logs, outcrop examinations, underground observations, and mine maps. Strata exposures from both outcrops and quarries were used to construct geologic maps, stereo net, and rose diagram projections so that the Loyalhanna’s structural environment could be understood better. Many of these structural conditions cause ground control problems at local quarries. These problems ranged from small-to-moderate sized rock falls associated with roof jointing to pillar failures associated with dipping discontinuities. Stresses ranged from tensional on structural domes where weathering dominates, to high levels of compression within structural saddles. A greater understanding of these characteristics is a prerequisite to develop engineering controls, such as improved mine layouts, pillar sizes, etc., that lessen miner exposure to these hazards.

By J. K. Richmond

Early research on coal dust explosions by the Federal Bureau of Mines and in other countries is reviewed to examine the effect of a single inhibitor, rock dust, on the explosion limits of coal dust. The parameters studied in this research included coal dust fineness, volatile content, and type of initiation. This research resulted in appropriate safety regulations in the respective countries. Also reported are the results of recent research in the Experimental Mine of the Bureau of Mines to investigate in detail the limits of coal dust explosions; the research used three types of coal with rock dust added as the independent variable. New experimental techniques and new criteria for defining propagation/nonpropagation were applied to the experiments. Also, a limit explosion propagation model is proposed based on the assumption of rapid devolatilization of the coal particles, with the subsequent combustion of the evolved volatile products contributing primarily to the propagation of the explosions. The model assumes also that the resultant char acts mainly as an inert diluent similar to the rock dust. The model also suggests that the function of stronger initiation is mostly to lift more dust from the mine surfaces.

Jan 1, 1975

By Edward L. McHugh, Charles Sabine, Louis J. Denes, Jami M. Girard, Peter Metes

The Spokane Research Laboratory, National Institute for Occupational Safety and Health, is investigating various remote sensing technologies as possible tools to detect, monitor, and mitigate hazardous situations in surface mines that could lead to catastrophic slope failure. Promising technologies include a field-portable spectro-polarimetric imager and a stationary interferometric radar device. Field tests were conducted of a prototype visible and near-infrared spectro-polarimetric imager (SPI) built at the Carnegie Mellon Research Institute. The SPI employs anacousto-optical tunable filter (AOTF) to control wavelength, a phase retarder to measure polarization signatures, and a digital camera and computer to capture data. Images obtained at the Mountain Pass and Castle Mountain mines in southeastern California showed that the instrument is capable of obtaining hyperspectral images of highwalls, outcrops, hand samples and drill core in the field. We have retrieved spectra from Mountain Pass images that closely match those of bastnaesite and have had some success in classifying images. Although radio frequency noise in the data limited spectral classification of imagery, we project that careful alignment of the AOTF should minimize the noise and greatly improve classification.

By David C. Oyler, Paul B. Stubbs

The Bureau of Mines and United States Steel Corp. are conducting a joint project to monitor formation pressures at a large (23-well) coal- bed gas drainage field near Oak Grove, AL. Three monitor holes were drilled in late 1981, and pressure monitoring began in December 1981. The Bureau of Mines direct method was used to obtain gas content data from cores taken in the monitor holes. Comparison of the 1981 gas con- tent data from the monitor holes with initial gas content values obtain- ed from the production wells in 1977 indicates a 50-pct reduction in ad- sorbed gas content inside the pattern and a 29-pct reduction at one point 500 ft outside the pattern. The combination of pressure and gas content data has also allowed an in situ isotherm curve, relating the formation pressure to adsorbed gas content, to be developed for the area of the production wells. From the current rate of pressure decline (1 lbf/inz per month), the observed changes in gas content, and the isotherm curve, it appears that most of the early gas production came from within the pattern, but since 1981 (and possibly earlier) most of the gas produced has been migrating to the wells from outside the pattern area.

Jan 1, 1985

By G. P. Sturm

This work was undertaken by the Bureau of Mines in cooperation with the Environmental Protection Agency to determine photochemical specific reactivities of emissions from automobiles using leaded-premium-and regular-grade fuels and prototype lead-free fuels of comparable octane quality. Emissions were photoirradiated in a 100-ft3 environmental (smog) chamber constructed of aluminum and Pyrex glass at three sets of initial hydrocarbon (HC) and oxides of nitrogen (NOx) concentrations. Reactivity was measured and expressed in terms of rate-of-NO formation (RNo2) and dosages of oxidant, peroxyacetyl nitrate (PAN), peroiypropionyl nitrate (PPN), and formaldehyde (HCHO). The results indicate that the evaporative emission samples and the evaporative plus exhaust emissions samples from the lead-free fuels have, in general, higher reactivities per gram than those from the leaded fuels. For the samples containing only exhaust emissions, the only trend observed was the lower specific reactivity exhibited by the leaded premium fuel exhaust. These differences in specific reactivity are taken to reflect the differences in hydro-carbon composition of the fuels and their evaporative and exhaust emissions rather than any difference in lead content per se.

Jan 1, 1973