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By W. H. Eddy

The Bureau of Mines made small-scale continuous tests and large-scale commercial plant tests of a calcareous fluorspar ore near Cave-In-Rock, Ill., to determine if the application of the lignin-fluoride process of fluorspar flotation would be industrially feasible for treatment of fluorspar ores, and also to compare the lignin-fluoride process with the quebracho process, which is the method currently used for concentrating calcareous fluorspar ores. The small-scale continuous tests yielded fluorspar concentrates analyzing 93.6 percent CaF2 with a recovery of 87.6 percent of the total fluorspar in the ore. In large-scale commercial plant tests, a fluorspar concentrate analyzing 93.3 percent CaF2 with a recovery of 78.0 percent was produced by the quebracho method. About 86.0 percent of the fluorspar was recovered in a metallurgical-grade fluorspar concentrate from the lignin-fluoride circuit which analyzed 89.9 percent CaF2? with a much simpler flowsheet than that in the current commercial application.

Jan 1, 1967

By Jack L. Henry

The Bureau of Mines conducted seven pioneering experiments in a 12-inch-diameter Kroll reduction reactor to examine the feasibility of coreducing the chlorides of Ti, AI, and V to produce a homogeneous titanium alloy sponge. The coreduction studies proceeded in a normal manner, and the yields of sponge were comparable with those of pure titanium sponge made in the same reactor. Vanadium concentration was very uniform throughout the sponge cake when VC14 in solution in TiCl4 was fed into the molten magnesium. More difficulty was encountered in feeding solid VCl2 and AIC13. Vanadium and aluminum concentration in the sponge was not uniform, and mechanical difficulties were experienced with the small-scale screw feeder. Although the sponge varied in composition from region to region, the ingots prepared from it were uniform in composition.

Jan 1, 1974

By R. D. Govier

The U.S. Bureau of Mines has developed a thin-film X-ray fluorescence technique to rapidly determine Cu, Ni, Co, Fe, and Cr in super alloy leach liquors. Total analysis time per sample was less than 15 min, as opposed to several hours for traditional wet chemical methods. Precision and accuracy were checked by replicate analyses of solutions similar in composition to leach liquors, whose analyte concentrations were well known. Coefficients of variation for all elements were found to be less than 2 pet. With the exception of the results for Fe, all relative errors of estimation were also found to be less than 2 pet. Bulk liquids are not introduced into the spectrometer; thus, the potential for damage to the instrument by leakage of corrosive liquids is eliminated.

Jan 1, 1989

By H. G. Iverson

The effects of adding boron and boron plus carbon to electrorefined vanadium were evaluated with respect to mechanical properties at low temperatures and response to heat treatment. Grain size was significantly decreased with the addition of 0.05 percent boron, the decreases ranging from 30 percent at 800° C to 75 percent at 1,100° C. Increasing the boron content resulted in only a small increase in strength at room temperature, but at 77° K, boron contents of 0.005 to 0.076 percent increased the yield strength of vanadium over 50 percent, from 70,000 psi to 110,000 psi. When boron and carbon were present together, the individual grain-refining effects obtained with either element were retained. Approximately a twofold increase in strength was obtained by age-hardening the alloys containing both boron and carbon. Alloys with only boron additions did not age-harden.

Jan 1, 1968

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) measurements provide evidence for the formation of Cr(V) intermediates in the enzymatic reduction of Cr(VI) by glutathione reductase (GSSG-R) in the presence of NADPH, indicating an initial single-electron transfer step in the reduction mechanism. Depending on the pH, at least two different Cr(V) species are generated which are relatively long-lived. In addition, we have detected the hydroxyl (·OH) radical formation during the GSSG-R catalyzed reduction of Cr(VI) by spin trapping, employing 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) and a-(4-pyridyl-1-oxide)-N-tert-butylnitrone (4-POBN) as spin traps. Superoxide dismutase (SOD) causes only a minor effect on the ·OH radical and Cr(V) formation, indicating that the ~ - is not significantly involved in the reaction mechanism. Catalase enhances the Cr(V) formation and substantially inhibits the ·OH radical formation, indicating the involvement of hydrogen peroxide (H20 2) in the reaction mechanism. Addition of H20i suppresses Cr(V) and enhances the ·OH radical fonnation. Measurements involving N-ethylmaleimide show that the Cr(V) species, produced enzymatically by the reduction of Cr(VI) by GSSG-R, react with H2O2 to generate ·OH radicals, which might participate in the initiation of Cr(VI) carcinogenicity.INTRODUCTIONC(VI) compounds have been found to exert serious toxic and carcinogenic effects on humans and animals [1-4) and to cause mutations in bacteria and transformation of mammalian cells [5-8). In contrast, most Cr(lll) compounds are relatively nontoxic, noncarcinogenic, and nonmutagenic [9, 10]. Cr(VI) and Cr(lll) oxidation states are different in their metabolic pathways: Cr(VI) ions are rapidly transported across cellular membranes [2, 11-13), while Cr(lll) moieties do not easily penetrate cells and are not oxidized by cellular constituents [3]. Since it is known that the reduction of Cr(Vl) is required for its reaction with DNA [2], the molecular mechanisms for the intracellular Cr(VI) reduction have been the focus of studies during the past decade but the details are still not understood."

Jan 1, 1990

By John L. Nieber

This information circular describes a computer program called VARSAT2D, a comprehensive unsaturated fluid flow simulator developed by the U.S. Bureau of Mines. VARSAT2D solves for either a vertical or horizontal, transient or steady-state solution in variably saturated, heterogeneous, anisotropic porous media using the Galerkin finite-element approach. Simplex triangular elements are used. Moisture retention characteristics are described by specifying either the Brooks and Corey, Brutsaert, or Van Genuchten power functions, with hysteresis described using the Maulem independent domain model. Boundary conditions may include any combination of time-varying seepage, pressure along solution domain, boundaries and/or at internal node points, unit hydraulic gradient at the lower boundary, and a uniform source and/or sink. This program should be a welcome addition for mining and environmental hydrologists, researchers, and engineers interested in modeling unsaturated fluid flow.

Jan 1, 1994

By E. C. Lane

The motor gasoline that is being marketed in the United States this summer is slightly more volatile than that sold a year ago. The increase in volatility is shown by a lowering of the distillation temperatures, ranging from 2°F. at the average initial boiling point to 4°F. at the average end point. During the past nine years the Bureau of Mines has made semiannual surveys of the gasoline marketed in the United States, the survey just completed being the eighteenth in the series. The cities in which samples were collected have been chosen as representative of the more important marketing territories, as it is obviously impracticable to obtain a sample of every gasoline sold in the entire country. Samples were collected in Omaha as well as in the 11 cities where samples were taken last winter. It was believed advisable to include samples from Omaha in order to give a better balance to the survey for the country as a whole.

Jan 1, 1928

By Edward D. Thimons

Inflatable stoppings are currently marketed for production use, and numerous mining companies have become interested in using such stoppings in rescue and recovery operations. The Bureau of Mines therefore evaluated the concept of using inflatable stoppings in emergency situations. The stoppings tested by the Bureau were 12-foot-diameter spheres inflated with a blower operated by a small battery pack. Experiments were conducted with the stoppings in a full-scale wooden mine model to evaluate their ability to withstand sliding or slipping at various internal and differential pressures, puncture resistance, various inflation techniques; and internal leakage from the stoppings. The stoppings were then installed and tested in the Bureau's Safety Research Coal Mine at Bruceton, Pa., to determine their effectiveness as mine air barriers. Despite some encouraging results obtained with the model and in-mine studies, the stoppings did not perform well in two operating metal mines where they proved difficult to erect and inadequate as air barriers.

Jan 1, 1976

By B. H. Clemmons

A field method has been devised for rapid determination of heavy minerals occurring in the unconsolidatod beach and dune sands. The method has been proved practical by usage in field evaluations of several hundred beach- and dune-sand samples in the Florida area. The simple equipment required and the techniques involved are described. Other data show that the method is relatively insensitive to variations in the mineralogical content or size distribution of the mixed heavy minerals contained in the samples tested. A modification of this procedure, found to be suitable for plant use in determining the relative purity of heavy-mineral flotation concentrates, is also described. A specific application is determination of the amount of feldspar-quartz in spodumene flotation concentrates. The results of the rapid evaluation techniques closely approximate those obtained by more precise laboratory procedures.

Jan 1, 1957

By Kenneth J. Miller

Laboratory batch flotation tests were conducted to determine the viability of the Bureau of Mines coal-pyrite flotation process in desulfurizing various coals from the midwestern coalfields. Nine coals obtained from western Kentucky and Illinois were used in the study. In addition to the Bureau's coal-pyrite flotation process, some of the coals were subjected to two-stage rougher-cleaner coal flotation for comparison. The results of this work showed that up to a 70-percent pyritic sulfur reduction could be obtained by flotation and that the Bureau's coal-pyrite flotation was superior to rougher-cleaner coal flotation. Because many of the coals retained far too much sulfur even after second-stage flotation treatment, it was concluded that these midwestern coals are more difficult to desulfurize by flotation than are the Appalachian coals tested in earlier Bureau experiments.

Jan 1, 1978

By Gilbert M. Farrior

The electrical resistivity the coefficient of electrical resistivity the Hall coefficient, and the absolute thermoelectric power were determined in this Bureau of Mines investigation for nine compositions of the TiB2-CrB2 sub-system. The numerical values of the electrical resistivity and the thermo-electric power were greater for the intermediate compositions than for the end members. The absolute values of the Hall coefficients and the coefficients of electrical resistivity were less for the intermediate compositions than for the end members. The electrical resistivities and Hall coefficients were about the order of magnitude of most metals--from 34 to 202 microhm-cm and from about 0 to -23.3 X 10-4 cuP/coulomb. The thermoelectric power was somewhat greater than that of most metals--up to 15.6 microvolts per 0 C.

Jan 1, 1965

By Foster Fraas

A comparison has been made between cubes and spheres in the matrix of the high-intensity wet magnetic separator. For two inclined plane surfaces, such as may occur with cubes, the maximum force value, H [dH-dx] is at the point of nearest approach and is much higher than the force resulting from adjacent spheres. Although the maximum force value for cubes is higher, it decreases more rapidly at increasing distances. The maximum force for spheres is at an appreciable distance from the point of nearest approach. At field intensities for magnetic saturation of the iron spheres, the force extends to further distances with greater uniformity approximating that of the constant force or isodynamic field. The force is also independent of the sphere diameter, which permits the scaling of the sphere diameter to provide changes in particle migration distances without changes in force gradient.

Jan 1, 1972

By Van E. Shaw

Bastnaesite is a natural rare-earth fluorcarbonate of the cerium group that affords an abundant and high-grade source of the lighter rare-earth elements. A simple and efficient method has been developed by the Bureau of Mines for extracting rare-earth compounds from this mineral. Digesting of a flotation concentrate with sulfuric acid converts the rare-earth compounds from fluorcarbonates to sulfates. Action of the acid releases gaseous com-pounds of fluorine and silicon, leaving the sulfated material free of these elements; carbon dioxide from carbonate decomposition is eliminated at the same time. Calcining the sulfated material at 1,200° F. renders the gangue constituents insoluble, whereas the rare-earth sulfates are left in water-soluble form. Leaching with water yields a solution of pure rare-earth sulfates. Bastnaesite could become prominent as a source of cerium-group rare-earth elements. It is rich in the light rare-earth elements and comparatively easy to process; reserves of the mineral are extensive enough to supply a greatly expanded market for many years.

Jan 1, 1959

By Herbert R. Babitzke

The purpose of this investigation was to optimize the high-temperature properties of columbium and tantalum. Columbium and tantalum were combined with selected alloying elements to achieve solid solution and dispersion strengthening. Fifty-six alloys were evaluated to determine their formability, hardness, strength at elevated temperatures, and oxidation resistance. The following six alloys showed high-temperature strength: [Cb-15Hf-5W-2Zr-4Al-4Ti-2N Cb-15Hf -5W-5Zr Cb-15.3Ti-4.1Zr-13.7Hf Ta-20Hf-4Al Ta-30Hf-4Al Ta-20Hf-5W-4Al] At 1,200° C, the columbium alloys had strength values of 40,000 psi or greater, and the tantalum alloys had strength values from 50,000 to 58,000 psi. For a 2-hour test period at 1,000° C, weight gains of only 9 and 8 mg/cm2, respectively, were observed on oxidation testing of two alloys, Cb-15Hf-5W-2Zr-4Al-4Ti-2N and Ta-20Hf-5W-4Al.

Jan 1, 1968

Ten years ago we surveyed in "Uspekhi Khimii" the mechanism of the synthesis of hydrocarbons from CO and H2 (1).5 With new data obtained since then, mostly by Soviet researchers, our previous work (2), dealing with new forms and catalysts of the synthesis, is brought up to elate by reviewing research in this field. FORMATION OF CARBIDES The hypothesis that carbides are intermecliates in the synthesis assumes that carbon monoxide reacts with the metals of the eighth group and that this reaction is connected with the reversible reaction 2CO[=]C +CO2 (1) in a certain range of temperatures (3).

Jan 1, 1958

By R. Karl Zipf, Z. T. Bieniawski

"Abstract. Based on the premise that understanding the fundamental mechanics of fine fragment formation in coal will lead to reducing coal dust problems in mines, a thorough study of the mechanics of crack propagation in coal was undertaken. Two approaches were considered in an attempt to understand and quantify the fracture process as it relates to fine fragment formation.In one approach, theoretical models are used which describe the size of the fracture process zone which may relate to the amount of structural damage and fine fragment formation on the new crack surface. The other approach is based on the relationship between crack tip stress intensity and new surface appearance for mixed mode crack propagation. Preliminary observations with a scanning electron microscope support the premise that fine fragment formation is related to fracture surface appearance and fracture initiation conditions.An experimental program designed to supply the input parameters for these approaches is presently underway. The experimentation features mixed mode fracture toughness testing, using a special mixed mode testing rig, and fracture velocity measurements with a crack propagation gage. The interpretation of this data via the approaches discussed will provide further understanding of the mechanics of fine fragment formation in coal."

Mar 1, 1989

By William H. King

The Fannie Ryan deposit is situated about 9 miles northwest of Boulder City, Clark County, Nev. at an altitude of about 2,000 feet on the north side of the River Mountains. The deposit is covered by several unpatented claims owned by Fannie B. Gulick of Las Vegas, Nev. The Boulder City deposit is within the Hoover Dan National Recreational Area. It is situated about 3 miles southeast of Boulder City in sec. 23,T. 23 S., R. 64 E., Clark County, Nev. The Deposit was covered by several unpatented mining claims owned by S. R. Whitehead of Las Vegas. The deposits occur in sedimentary beds of the Muddy Creek formation that overlie older volcanic extrusive. The manganese minerals occur as soft oxides of the wad type. The exploration was conducted by the Bureau of Nines in cooperation with the Federal Geological Survey and comprised a study of the geology, mapping of the areas, and development by shaft sinking; diamond drilling, and sampling. On the Fannie Ryan Gulick property the work consisted of cleaning and sampling seven old trenches on the outcrop and diamond drilling seven holes totaling 1,482 foot. At the Boulder City deposit 188 feet of drilling was done in two holes. A 4- by 6-foot shaft was sunk to a depth of 44.5 feet, and the north and south sides of the shaft were sampled.

Jan 1, 1950

By M. H. Chetrick

An important factor in the design and operation of a lignite-gasification plant is knowledge of the thermal requirements. These not only vary with different-size plants but also with the operating conditions for a plant of given capacity. Thermal data have been collected since 1945 from a commercial-scale lignite-gasification pilot plant operated by the Bureau of Mines at Grand Forks, N. Dak. The description and operation of this plant and a study of the gas-composition data have already been described in previous reports (1, 2, 3, 4, 5).2) / This investigation was made to review the thermal data taken in tests and to correlate them in terms of the fraction of undecomposed steam and the H2:CO ratio.

Jan 1, 1953

By Frank C. Andreuzzi

The Division of Environmental Activities, U.S. Bureau of Mines, conducted a solid waste demonstration project on a burning coal refuse bank. The primary objective of this project was to develop and evaluate an efficient method of extinguishing burning coal refuse and moving it. A series of tests were performed using water monitors and related apparatus to quench the burning material and, at the same time, using earth-moving equipment to transport, spread, and compact the extinguished material. The method found to be most effective consisted of water-quenching the surface material to a workable depth, ripping, and removing the quenched material with a bulldozer and tractor-scraper. The total cost was estimated to be $0.44 per cubic yard.

Jan 1, 1970

By James H. Russell

The Bureau of Mines used a statistical approach to evaluate the effects of temperature, current density, and composition of the electrolyte on the purity of boron prepared by electrolysis of a fused mixture of boric oxide in potassium fluoborate. The quadratic equation which best fits the data was calculated for a temperature of 650° to 850° C, a cathode current density of 40 to 1,150 amp/ft2,and a boric oxide content of 0.3 to 7.1 molal. The best products, better than 95 percent boron, were obtained when the current density was less than 2 amp/ft2 and the boric oxide content was less than 2 molal.

Jan 1, 1967