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By Norman G. Foster

The mass spectra of 14 previously unreported alkylthiophenes are pre-sented. Low ionization voltage data of selected compounds from these 14 and 23 previously reported alkylthiophenes are presented and discussed for their value in supporting fragmentation mechanisms analytical correlations. A comparison with and corroboration of earlier correlations is made. Additional correlations concerning detection of side chain branching and the detection of ethyl-alkyl and propyl-alkylthiophenes are made. A discussion of the possible fragmentation routes and mechanism of fragmentation is given. Speculative structures are inferred s out some of the ions and hence this work provides a basis for suggesting fation mechanisms for the alkylthiophenes according to modern theories ass spectrometry. Verification of these mechanisms must await the availability of isotopically labeled molecules which are labeled in specific lotions that permit the definition of the paths of frag-mentation. Some suggestions for further work to generalize on the correlations and studies made to this point are presented.

Jan 1, 1965

By Chas. F. Jackson

During the past 5 years the Bureau of Mines has published information circulars dealing with mining methods and costs at 78 ore mines; 7 circulars, each of which is devoted to a discussion of one of the principal mining, methods; and 23 circulars dealing with special phases of mining, such as ventilation, shaft sinking, tunnel driving, the cost of equipping and developing prospects and small mines, underground transportation, diamond drilling, and ground support. These circulars were written by many different authors, and in order that the method of presentation and the basis for compilation of data might be the same in all the papers the Bureau drafted an outline to be followed in their preparation. To clarify the data in these circulars, which are in the libraries of many engineers and mining companies, and the summarized data presented in this paper, that portion of the outline dealing with cost and labor-performance data is reproduced below.

Jan 1, 1934

By D. C. Dahlin

To identify and characterize potential domestic chromium resources, the Bureau of Mines investigated podifom chromite deposits along the Border Ranges Fault in southern Alaska. Part 1 of this two-part report describes an extensive field investigation and preliminary resource evaluation studies by the Bureau's Alaska Field Operations Center. This paper, part 2, describes the mineralogy of 38 samples that were collected from low-grade deposits in the Chugach Mountains, on the Kenai Peninsula, and on Kodiak Island, and presents the results of laboratory batch beneficiation tests designed to concentrate the chromite. The samples are peridotites and chromites that consist primarily of variable amounts of chromite, olivine, and serpentine. They were beneficiated by a sequence of grinding, sizing, and gravity concentration operations. Twenty-four high-chromium or marginal high-chromium chromite concentrates, six high-iron or marginal high-iron chromite concentrates, and five submarginal concentrates were produced with chromium recoveries that ranged from 37 to 95 pct. Three very low-grade samples were not beneficiated. These results indicate that several of the de- posits may be significant chromium resources, Potential precious metals association with the chromite was also investigated. Analysis of these samples indicates that the chromite deposits are not good platinum sources.

Jan 1, 1985

By Kim B. Shedd

The Bureau of Mines measured fiber dimensions on crocidolites (riebeckite-asbestos and magnesioriebeckite-asbestos) from the world's four crocidolite mining regions. The objective of the study was to determine whether there are measurable morphological differences between crocidolite fibers that correlate with the high reported incidence of mesothelioma in miners and mill employees in the Cape Province of South Africa and Western Australia, as compared with little or no reported incidence of this cancer in the Transvaal Province of South Africa or Bolivia. Fiber dimensions measured with the scanning transmission elec-tron microscope showed that crocidolites from Western Australia and the Cape Province have more thin fibers than crocidolites from Bolivia and the Transvaal Province.

Jan 1, 1985

By J. A. Woolf, E. S. Leaver, A. P. Towne

"INTRODUCTION A report giving experiments dealing with factors affecting the floatation of the most commonly occurring silver minerals was published years ago. At that time we could not obtain suitable samples of many of the so-called sulfo-salts of the base metals, which are generally silver--bearing and which comprise an appreciable percentage of the natural silver ores. Since Leaver and Woolf's work was published, samples of impure tennantite and enargite have been obtained, and considerable experimental flotation work has been done with synthetic mixtures prepared from these samples. During the present national emergency, research dealing solely with the recovery of gold and silver must necessarily be curtailed. However, many deposits of strategic minerals and critical base metals contain an appreciable amount of gold and silver, the recovery of which would aid greatly in recovering the strategies by taking care of a considerable part of the cost of treatment. Because of this, the recovery of precious metals should not be overlooked entirely. As the Bureau of Mines is now utilizing all of its facilities for the development of increased domestic productions of strategic and critical minerals, this is the last report not concerned primarily with such minerals that will be published until the war ends."

Sep 1, 1942

Advances were made during 19b5 in many phases of a broad program designed to increase efficiency in the mining, preparation, and utilization of coal. Also recorded were achievements in activities devoted to mine health and safety, coal resources, and mine explosives. Featured in this report is a review of progress in environmental studies relating to coal mining and utilization. Environmental projects comprise a comprehensive program to facilitate mine reclamation and reduce air and water pollution associated with extraction and use of coal. Publications cited throughout this report present results of the coal program in greater detail. Organizations, institutions, and companies contributing to the program are listed in appendix A. Centers and laboratories conducting the coal research and related investigations appear in appendix B.

Jan 1, 1966

Advances were made during 19b5 in many phases of a broad program designed to increase efficiency in the mining, preparation, and utilization of coal. Also recorded were achievements in activities devoted to mine health and safety, coal resources, and mine explosives. Featured in this report is a review of progress in environmental studies relating to coal mining and utilization. Environmental projects comprise a comprehensive program to facilitate mine reclamation and reduce air and water pollution associated with extraction and use of coal. Publications cited throughout this report present results of the coal program in greater detail. Organizations, institutions, and companies contributing to the program are listed in appendix A. Centers and laboratories conducting the coal research and related investigations appear in appendix B.

Jan 1, 1966

By R. K. Koch

The Bureau of Mines developed a zircon sand molding process for static casting of small titanium or zirconium shapes. Castings with unfinished weights up to 3.5 kg (7.7 lb) were produced in an inductoslag furnace and castings up to 7 kg (15.4 lb) were poured in a consumable electrode skull-casting furnace. Molds and cores were made by ram-molding, foundry-grade zircon sand (AFS gfn 93 to 95) bonded by grade D waterglass and tempered with water. Molds and cores were cured either at 250° C (482° F) or 900° C (1,652° F). Castings from the higher temperature molds broke cleanly from the sand while the lower temperature molds produced castings that had to be cleaned by sand-blasting. However, low-temperature cured molds and cores have a number of advantages as follows: (1) A faster, less energy-consuming curing cycle is used; (2) expended cores are water soluble which greatly facilitates core removal; and (3) enough of the binder in crushed expended molds is reactivated by temper water so that the molding mix can be reused five times without any fresh binder additions and up to twenty times without exceeding a total cumulative binder addition of 52 ml/kg dry sand. Crushed used molds that had been cured at 900° C had no detectable binding strength when mixed only with temper water. A large number of oxide and silicate mold washes were studied for improved casting integrity. The most effective wash found for zirconium or titanium casting was monoclinic zirconia (325 mesh).

Jan 1, 1977

By F. E. Griffith

[Unquestionably mine fires new constitute one of the chief causes of sabotaging the effort to produce maximum quantities of mineral products essential to the prosecution of the war. This applies more particularly to coal than to noncoal mines, and presumably the main reason for this is the fact that coal production in maximum quantity is still very much a "must", while the demand for much of the product of noncoal mines has eased materially in recent months.]

Jan 1, 1944

By D. E. Shanks

This U.S. Bureau of Mines (USBM) research simplified an earlier hydrogen chloride (HCI) leach-sparge process developed by the USBM to recover reduction-grade alumina from domestic kaolin clay. Improvements were made by decreasing the initial leaching acid concentration from 25 to 20 pet, decreasing the leaching time from 1 to 2 h to 15 to 30 min, eliminating the solvent extraction step for Fe removal, and eliminating the step to recover the AI content of the bleedstream circuit. A 10-cycle bench-scale experiment of the simplified process showed that the ferric chloride (FeC13) concentration built up to 9.3 g/L in the recycle stream. This did not interfere with any of the unit operations or final alumina product purity because Fe forms stable soluble chloride complexes when sparged with HCI and is easily washed from the large aluminum chloride hexahydrate (ACH) crystals. The reduced leaching time and acid concentration did not decrease Al extraction.

Jan 1, 2010

By James J. Dowd

The investigation to evaluate the reserves of coking coal in the United States suitable for the manufacture of metallurgical coke is being made by the Bureau of Mines in three parts: (1) To estimate known (measured plus indicated) recoverable reserves of all coking coal; (2) to upgrade marginal coals through effective preparation; and (3) to study the carbonizing properties of coals and coal blends not now widely used for metallurgical coke making. This is the sixth of a series of reports giving the results of studies by counties under part (1) of the investigation. (See appendix.) This report covers Fayette County, Pa., which comprises the Uniontown and parts of the Brownsville, Connellsville, Donegal, Waynesburg, Masontown, and Confluence, Pa., Morgantown and Bruceton, W. Va., and Accident, Md., quadrangles. (See fig. 1.) A short resume of the chemical and carbonizing properties of the coals ar.9 included. Data on the coal beds in this county were obtained from mining companies, land companies, individual landowners, and other sources of authentic information.

Jan 1, 1951

By J. P. Dunford

This U.S. Bureau of Mines report describes the development of a yielding steel post for underground mine support. The report covers concept development, laboratory tests, modifications, and field evaluations. The objective of this work was to develop a stiff support member capable both of supporting high loads and yielding when excessive amounts of mine entry closure were present. The 6-to 7-ft steel post was designed to yield nearly 2 ft while maintaining a 45-ton (force) load. The post is a three-piece unit consisting of top and bottom telescoping legs and a separate foot bracket. It develops its load-carrying characteristics when the lower pipe, with an attached interference ring, is forced into the larger top pipe. Laboratory tests were used to determine critical loads and post performance for various post lengths. Field tests showed that the posts could perform in actual mining conditions. The post has the ability to provide support in highly yielding ground and also, because of its slender profile, enhance ventilation and provide more area for travelways and escapeways. The design is simple enough to allow for fabrication at most mine shop facilities.

Jan 1, 1989

By F. W. Wood

ORIGINAL experimentation in specially designed arc-melting furnaces and a comprehensive review of technical literature have helped with an understanding of electric arcs as used in metallurgical applications. Results relevant to the distribution of electric potentials and currents, temperatures, pressures, the consumption of electrodes, the identities of particles participating in electrical conduction, and the modes and mechanisms of discharge are presented and discussed. Present knowledge of high-current arcs is insufficient to test pertinent theoretical suggestions. However, the chief doubts concern the identities and the liberation or formation of current-carrying particles. It seems that either (1) novel formulations of existing concepts are needed, or (2) essentially new concepts must be recognized to explain observations. An analysis of the situation has led the authors to favor the latter possibility and to suggest the existence of supplementary conducting particles. The conduction of current by the streaming of charged agglomerates is postulated. Another outgrowth of analysis is an equation for the arc potential as a function of current densities in the arc. In lieu of conclusions, the potentialities of practical applications and specific needs for fundamental clarification are summarized.

Jan 1, 1965

By J. Dean Warner

In 1984 and 1985, as part of its critical and strategic minerals studies, the Bureau of Mines investigated lode and placer tin occurrences near Rocky Mountain (Lime Peak), in east-central Alaska. The lode occurrences consist of mineralogically complex, generally fault-controlled veins, and contain an average of approximately 0.05 pct Sn, as cassiterite. Beneficiation testing of two bulk samples of the vein material produced concentrates containing 65 and 59 pct of the total tin values at grades of 0.35 and 13.9 pct, respectively. Although as much as 30 million short tons (MMst) of mineralized rock containing up to 20 MMlb Sn may be present, the grade of these occurrences is too low to be considered economic at this time. Trace amounts of cassiterite were also identified in surface samples of glacial out-wash gravels collected along North Fork Preacher Creek, which partially drains the area of tin lode deposits near Lime Peak. Low tin grades in the samples do not account for the former erosion of a large volume of lode tin mineralization from near Lime Peak; higher tin grades may be present in gravels closer to bedrock.

Jan 1, 1988

By A. J. Kraemer

This report is one of a series dealing with oil-shale-operations in foreign countries visited and studied by Bureau of Mines oil-shale technologists within the past 4 years. Many oil-shale deposits have been discovered in Brazil and studied with various degrees of thoroughness. In this report the major emphasis is upon the oil-shale concessions of Companhia Nacional de Oleos Mineraes, in the River Valley of the State of Sao Paulo, because this oil-shale deposit is one of the most promising in Brazil for large-scale utilization for the manufacture of liquid fuels and other products of oil-shale processing, and because the opportunity was afforded to examine the concession area and to study mining, retorting, and. refining operations on these shales. Results of detailed analyses at the Oil Shale Research and Development Laboratories of the United States Bureau of Mines, Laramie, Wyo., are reported, Analyses and other date dealing with other oil-shale deposits in Brazil have been compiled from many sources. As many data have been reported as could be correlated to indicate the range of variation of the several types of shale end similar material. The oil-shale deposits in Brazil differ widely in size, richness of the shale, and of the oil. Some deposits are situate& more favorably for exploitation than others.

Jan 1, 1950

As part of the United States Department of the Interior, Bureau of Mines Health and Safety Research Program, Walter C. McCrone Associates, Incorporated has examined 71 samples of airborne mine dusts using the techniques of x-ray diffraction, electron microprobe analysis and light microscopy. This report details the procedures which were used in this work and documents the results which were obtained.

Jan 1, 2011

By R. L. Levens

The Underground Injection Control program was promulgated in 1981 by the U.S. Environmental Protection Agency under the provisions of the Safe Drinking Water Act. Placement of mine waste backfill underground is considered underground injection under the provisions of this program. A major issue is whether mine waste that is regulated as a contaminant source on the surface should be disposed of underground. The U.S. Bureau of Mines conducted research to investigate the impacts of mine waste sandfill on the quality of ground water. Analyses of water samples collected before and after contact with sandfill in a 10-year-old stope, as well as samples of the sandfill itself, were used to ascertain the influence of the sandfill after mine closure and subsequent flooding. Computer models supported the hypothesis that oxidation of pyrite by oxygen, accompanied by dissolution of carbonates, was the predominant reaction controlling the quality of the water being discharged from the stope. Concentrations of metals released as a result of acid production remained near or below detection limits. Metals release after mine flooding is expected to remain low as a result of the buffering by the sandfill and the reduced rate of oxidation.

Jan 1, 2010

By Raymond O. Dannenberg

The gas-combustion retort developed by the Federal Bureau of Mines at the Rifle Oil Shale Project near Rifle, Colo., is a continuous, gravity-feed retort. The heat required to convert the kerogen in the oil shale to liquid oil is generated by the combustion of product gas and carbonaceous residue remaining on the retorted shale after the kerogen has been converted to oil, gas, and residue. A study of the effects of the process variables on retort operation, product yields, and product properties is important to the successful solution of the problems encountered in the development of a satisfactory process. Statistical methods were used to design the experiments and analyze the effects of the rate of shale throughput, the composition of dilution gas, the height of the shale bed above the air entry, air-gas distributor design, shale size range, and the ratios of the flow rates of the various gas streams entering the retort to the rate of shale throughput.

Jan 1, 1960

By Suresh K. Bhatt

A mathematically simulated modeling technique is used in this U.S. Bureau of Mines report to represent a hypothetical mining operation with existing mining technology and prevalent mining costs. Mining scenarios were prepared and evaluated for potential benefits and costs available through computer-assisted mining. Base criteria, parameters, and methodology are described.

Jan 1, 1991

By H. H. Fields

The Bureau of Mines conducted research to determine the effectiveness of long holes drilled in solid virgin coal in degasifying an area of the Pittsburgh coalbed showing that horizontal holes drilled into a virgin coalbed from the bottom of any shaft will effectively remove methane gas in commercial quantities from the Pittsburgh coalbed. The in situ pressure at a depth of 214 feet into the coalbed and the average gas and water flows from the five degasification holes were 3 lb/in2 gage and 860,000 ft3/d and 1.7 gal/min, respectively. On June 19, 1975, after 593 days of degasification, a compressor was installed and pipeline quality gas was introduced into a commercial pipeline. As of June 1, 1976, after 1,022 days of degasification, over 753 million cubic feet of gas had been drained and 117 million cubic feet of gas had been purchased by the gas company for use in the local community of Wadestown, W. Va. The gas drained to date is six times the gas estimated to be in the area subtended by the holes. Methane emissions at the working face of 1 West mains, Federal No.2 mine has been reduced by 50 pct, proving the value of methane drainage by horizontal degasification holes drilled from shaft bottoms ahead of mining.

Jan 1, 1976