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By G. Onal, E. Gock, H. Dincer

"During the conventional chromite dissolution process; chromite ore concentrates were ground to at least <90 µm using the ball mill and after adding Na2CO3 and leaning material (instead of CaCO3 also residues from the leaching process) at a ratio of e.g. 1:0.75:1.2, depending on the specific formulation, follows the digestion e.g. in a rotary kiln, heated in countercurrent. The reaction time is 3 to 8 h. The calcine is comminuted and leached with water or a thin chromate solution. Depending on the type of ore used, the yield is 75-85 %. The disadvantage of the above-described process is that it is impossible, using current technology, to achieve a complete digestion of the chromite ores and that the chromium-containing residues have to be disposed of as special waste, involving a large financial effort.The subject of this study was the investigation of the effect of vibratory milling on chromite dissolution. The impact stress in the vibratory mill causes the mechanical activation of chromite, which is characterised by lattice defects. The degree of mechanical activation can be quantified by measuring the relative X-ray diffraction intensities at the parent lattice planes of chromite. Each relative X-ray diffraction ratio correlates with a certain degree of digestion. As opposed to vibratory milling, a complete digestion of chromite using a ball mill is impossible, even at extremely long grinding times.In this investigation a chromite concentrate from Pulpinar/Kayseri with content of 44 % Cr2O3 and the Eccentric Vibratory Mill was used. In order to verify the effect of the vibrating grinding on chromite dissolution, reaction kinetic investigations on digestion and leaching were carried out."

Jan 1, 2003

By Stephen Gay, Dewetia Latti

"When improving a plant a mineral processing engineer would like to know the mineral composition distribution. In order to assess this distribution in particles, as compared to the corresponding distribution in particle sections, a procedure needs to be applied to the observed particle sections. Such a procedure is called a stereological correction. There exists many stereological correction procedures, but one group of such procedures is based on using those stereological equations that do not require making assumptions regarding particle shape or texture. These equations are called geometric probability equations.Davy derived a geometric probability equation to estimate the covariance of mineral composition distributions for particles from both particle sections and linear intercepts. This covariance can be used to measure the variance of the particle composition distribution of each mineral. The equation as presented by Davy requires textural information; however the equation was modified by Gay to be more directly applied to particle sections and linear intercepts. The variance obtained from applying this equation is fundamental to the binary stereological correction procedures developed by Gay and his colleagues; the covariance is fundamental to the multiphase stereological correction.Thus far, validation of both the binary and multiphase stereological correction has been achieved using numerical simulation. This paper shall present results comparing the covariance (and variance) estimates from Gay’s equation with actual three-dimensional information obtained from serially sectioning particles. This involved mounting a set of particles and continuously sectioning all particles uniformly so that the three dimensional structure of the particles could be obtained.The mineralogical data to which the equations described above were applied were derived from two individual size fractions from a hard-rock titanium deposit. The deposit contains a range of minerals and of mineral textures and the two size fractions selected were:"

Jan 1, 2003

By Jian Zhang, Yongfu Yu, Fuguang Zhang, Liping Che

There is one large-scaled iron ore deposit in Inner Mongolia of China, but it is very complex which includes about 170 types of minerals and 71 elements. The hematite, magnetite are mainly iron ores. It is difficult that the iron mineral can be separated efficiently by common dressing methods due to the complexity, and the iron concentrates in the mineral processing factory contains many foreign substance such as K, Na and Si so that the process in iron mill is influenced because of the foreign substance, so it is vital reducing the foreign substance.

Jan 1, 2003

By N. Raeis Hosseiny, S. H. Bassir

"Chador-Malu iron ore is one of the most important iron mines of Iran.About 98 percent of Fe in the ore is in shape of Magnetite, Hematite, Martite, aqua oxide of Iron and the other irons are with ferrous silicates, actinolite, cholorite and ferrous dolomites. 1% of Fe has replaced in pyrite. The phosphor distribution in the ore is non-hemogenous and its average in the whole of the deposit is 94%. It is in shape of Apatite.This mine contains considerable phosphor, which makes it useless for metallurgical uses. At this mine the phosphor is reduced in the iron ore at two steps. At the first step, magnetic part of the ore is separated from the gangues and phosphors by magnetic separator. At the second step, the ore is enriched by the flotation methods. Experimental flotation methods to obtain the optimum conditions are as follows:• Effect of Starch as Hematite depressant with ATRAC as Apatite collector• Effect of Sodium silicate as Hematite depressant with ATRAC as Apatite collector• Effect of ASAM as Apatite collector with Sodium silicate as Hematite depressant• Effect of ATRAC (BEROL) as Apatite collector with Sodium silicate as Hematite depressant• Effect of ASAM & ATRAC mixture as Apatite collector with Sodium silicate as Hematite depressant• Effect of Kcarbonate as pH-modifier• Final test to Optimize pH, Collector, DepressantAt this research we have found the optimum circumstance of the flotation of Chador-Malu iron ore in order to decreasing phosphors of iron oxide and floating of Apatite to make pure Hematite.To reach the optimum conditions, some tests were done with different amounts of pH, collector and depressant. The results are as follows:"

Jan 1, 2003

By L. A. Vaisberg

"Crushing and grinding are the two most common industrial processes. These processes consume nearly 20 per cent of the entire electric power produced worldwide. This enormous amount of electric power consumed results from the fact that modern crushing and grinding machines employ the processes first introduced by the prehistoric man, namely those of compression, impact, attrition, and cutting. The material thus handled decomposes indiscriminately, and almost completely ignoring the microscopic cracks and other defects of its structure. Apart from the irrational use of the power, the crushing and grinding processes currently in use result in irretrievable loss of useful components or else in a substantial deterioration of the final products obtained, all as a result of incomplete grinding or, reversely, of overgrinding, palletizing, or fracture of particles.The principal type of equipment that has almost universally been used all over the world for more than 150 years for crushing both natural and synthetic minerals comprises unbalanced jaw and cone crushers. The driving element of crushing bodies in these machines is an unbalanced weight, which transfers the crushing body, allowing it to squeeze the material within the eccentricity value only. The maximum reduction ratio achieved by such a drive is 5, which is due to the rigid kinematic arrangement of the crusher, its dynamic unbalance, and the impossibility of increasing the number of impacts on the material being crushed. Moreover, conventional machines cannot cope with super hard materials, and their mechanism is vulnerable to damage by uncrushable objects.On the basis of fundamental research into the theories of solid body and vibration, OAO Mekhanobr- Tekhnika have developed a range of vibrating jaw and cone inertia crushers that make a reduction ratio of 30 feasible in an open-circuit operation with the reduction ratio monitored within a wide range. In these crushers, the eccentric drive is replaced with a vibrating one. In this way the rigid kinematic drive became dynamic, thus allowing pieces of material to be crushed in a thick layer due to the effect of their bumping into each other, and with the amplitude changing automatically. This results in a number of advantages as compared with conventional crushers:"

Jan 1, 2003

By A. F. Raschenko, Y. A. Golodcov, V. V. Elshin

"The autoclave noble metal desorption in apparatuses with a dense stationary sorbent layer is perspective for the technology of sorption gold and silver extraction from solutions and pulps by carbon sorbents. The study of the mechanism and optimization of the autoclave desorption process involve some difficulties. To overcome them it is necessary to use mathematical and quantum-chemical modelling. The given paper deals with a mathematical model for the dynamics of gold and silver desorption from active carbons by alkali solutions based on the physical-chemical notions of the process. The kinetics and the mechanism of the process were investigated using the mathematical model for gold and silver desorption.The calculation of the efficient mass-transfer coefficient (ße) for various initial and intermediate noble metal concentrations in carbon (Cy) made it possible to find that the dependence of ße on Cy in case of gold desoprtion shows a clear extreme character. The value of the initial metal concentration in carbon therewith does not influence the character of the curve the inflection point of which is changed essentially at elevated process temperatures only. The revealed characteristic property, in the author's opinion can only be indicative of the change in the mechanism of gold desorption under autoclave desorption conditions. The assumed [Au(CN)(OH)]- type intermediate that has a higher diffusion coefficient in comparison with the adsorbed complex [Au(CN)2]- can be considered as an intermediate compound in the process of gold desorption."

Jan 1, 2003

By Leon Lorenzen, Charlene Gokhale

"In excess of 24 x 106 tons (Eskom, 1997) of coal-derived fly ash is produced annually in South Africa for the production of electric power. A large quantity of this ash is disposed of as a solid waste in landfills, thus posing a serious environmental problem. Due to the shortage of landfill sites, new ways of utilising fly ash are needed. Recently several authors have shown that various combustion fly ashes can be converted into zeolites to obtain industrial products with applicability in environmental management. Geopolymerisation has emerged during the last few years as a possible solution to some waste stabilisation and solidification problems. henolic compounds have been shown to be toxic to soil microorganisms at the parts-per-million level. Indeed several of the organic compounds classified by the U.S. Environmental Protection Agency as priority pollutants, are phenols. Immobilisation of phenols by adsorption on zeolites and encapsulation in a geopolymer appears to be a promising solution to this problem.This paper reports a technique for the production of a low-silica sodium zeolitic material from fly ash (zeolite NaP1), and its application for the stabilisation of phenols by adsorption and subsequent encapsulation in a geopolymer matrix. A commercial zeolite, clinoptilolite was also utilised as an adsorbent. Due to their uniform pore sizes and large surface areas, zeolitic materials are suitable for ion exchange and adsorption of certain organic substances. Adsorption data show that the commercial zeolite, clinoptilolite was an effective adsorbent for organics. Adsorption data showed that between 51.2 ppm and 74.3 ppm of chlorophenol or between 15.4 ppm and 32.5 ppm of phenol could be adsorbed. Physical encapsulation of the coated zeolite loaded with organic within a geopolymeric matrix increased the compressive strength of the matrix from 28.80 kN to 40.79 kN. Leaching data for the various geopolymer matrices with encapsulated and loaded zeolites show no organics being leached from the system at a detection level of 2ppm. According to the SABS these would have been acceptable organic concentrations within a waste water stream."

Jan 1, 2003

By Rob Morrison, Andrew Scott

"Long before a modern mine commences operations it has already become a wealth of information. After start up, it can generate enormous quantities of data – especially with semi-automated data acquisition by instrumented mine equipment. Much of this data is of limited use for evaluation of (potential) performance unless it links in some way to the site business model.An underlying reason for this waste of data is that the different cultures, financial, technical, community, environmental, etc, not only have many areas of interest but also have very different conceptual models by which they evaluate performance.It is too ambitious to attempt to bring all of these cultures together – in a single step. However, the success of the Mine to Mill ™ project has demonstrated that substantial operational value can be added by using a more integrated approach to comminution. The next logical step is to integrate measured data and then to track performance from ore body model to saleable product and waste disposal.The path from resource to product also represents a path from very sparse, highly variable data to much more detailed measurement and more representative sampling. However, in both cases the data collected is usually strongly focused on the technical requirements – not on the business model.This paper emphasises the difference between data and information. There is considerable potential for confusion between the two as both data and information are often expressed as numbers. For the purpose of this paper, data and information are distinguished by their uses.A data point (or datum) is a measurement. By way of contrast, information provides a basis for decision making."

Jan 1, 2003

By Atsushi Shibayama, Toyohisa Fujita, Wan-Tai Yen, Ke-jun Liu

"A gold has been leached with ammonium thiosulfate solution and several leaching conditions have been studied. The leached solution has been recovered by solvent extraction and the optimum conditions have been investigated.SUMMARYIn this investigation, a sponge gold sample (99.92% pure) has been leached with ammonium thiosulfate solution. The effects of CuSO4, (NH4)2S2O3, (NH4)2SO4, NH4OH and retention time on the gold leaching % (extraction %) and thiosulfate oxidation % (consumption %) have been studied. The copper ion acts as a catalyst in gold dissolution. On the other hand, it also accelerates oxidation of thiosulfate (consumption). It was found in this study that the best gold extraction condition was obtained at 43.2 ks with 0.8 – 1.0x103 mol/m3 (NH4)2S2O3, 30 mol/m3 CuSO4, 2.0 – 3.0x103 mol/m3 NH4OH, 0.4 – 0.5x103 mol/m3 (NH4)2SO4, pH 10±0.2 and 150 rpm. The thiosulfate oxidation was about 15% of the initial concentration."

Jan 1, 2003

By R. L. Pascual, W. J. Whiten

"The froth flotation process is not well understood. Both flotation models, and the parameters used to describe the stream flows are not well defined. They in fact vary considerably in different applications. This creates difficulties is designing a simulation program suitable for use by plant personnel, consultants, and researchers. In addition to simulation, an effective simulation program can be expected to provide a range of other services.This paper shows how a process circuit simulator can be designed with sufficient flexibility to satisfy these needs, and discusses some of the additional services.OVERVIEWThe development of a simulation program for froth flotation circuits faces several challenges as flotation models and the associated stream descriptions are not well defined. There is little agreement on the best form for a flotation model, or on how the plant streams should be defined.In addition to simulation, a flotation simulator is generally expected to provide other services such as data input, data reconciliation, model fitting, and accuracy estimation. Additional services may also be needed beyond what might initially be envisaged. A summary of some of these possibilities is included.To apply simulation to a flotation circuit it is necessary to develop a flotation cell model, for instance based on the general outline given in the appendices. Experimental data, usually from the plant, is needed to determine cell model parameters. This is generally done by first undertaking data reconciliation to determine if mass flow constraints are sufficiently closely satisfied. At the same time the data is inspected for outliers that might bias subsequent calculations. Next the data is fitted to a model to back calculate ore characteristics. If there is sufficient agreement between the fitted model and the data, the model can then used to make predictions of the effect of changes to the plant. The changes, that the simulation shows are beneficial, can be applied to improve plant performance"

Jan 1, 2003

By P. Harris

"Comparison of the two most commonly used classes of depressant in the South African platinum industry is complicated by the fact that these polymers induce different effects on the surfaces onto which they adsorb. The use of carboxymethyl cellulose (CMC), which is ionically charged in solution, can lead to increased particle dispersion in addition to the effect of reduced surface hydrophobicity (depression). Guar is typically only slightly charged in solution. Comparison of these two depressants is complicated since it is uncertain whether differences in their action is a result of either depression of dispersion effects.This work investigates the role of dispersion independently to that of depression in the batch flotation of a platinum bearing ore. An inorganic dispersant, sodium hexametaphosphate (NaHMP) was added in parallel to the uncharged guar depressant to simulate the action of depressants with varying degrees of dispersion. By distinguishing between the material recovered by entrainment and the floatable gangue and by including the effects of froth stability it was possible to decouple the effects of dispersion and depression.The results show that both dispersion and depression led to increased grade of the sulphide minerals. Depression leads to a decreased recovery of floatable gangue minerals. Dispersion leads to an increased recovery rate of these minerals and an accompanying decrease in froth stability."

Jan 1, 2003

By M. Salas, L. Rolf, H. Z. Kuyumcu

"Industrial use of abrasive stress takes place in the area of fine grinding and in order to clean surface contaminated soil particles. Also, at many mechanical operations abrasion emerge as an unintended side effect. At the Institute for Raw and Waste Material Processing at the Technical University of Berlin systematic investigations are carried out, to further the knowledge regarding the dependence of abrasion process on material properties and stress mechanisms as a basis for design and optimisation of the process or for its avoidance. Aim was the mathematical description of the abrasion process running with a single particle stress. For the purpose of investigations an agitation cell was used. Limestone served as material.In the presented work the influence of particle diameter, particle shape and collision energy on the mass and particle size distribution of abrasion debris was studied. The surface geometry of the particle was characterised by the particle shape factor ?x and the particle diameter dp. The particle shape factor ?x stays in direct relation with the abrasion degree x, and can be substituted by a mathematical function of x.Physically the particle shape factor ?x can be interpreted as a proportion of abrasive stresses splitting up complete crystals and crystal fragments. These two different mechanisms depend on different ratios of curvature of the surface of the stressed particle. The abrasive stress of strongly curved surface areas leads to separation of complete crystals. The abrasive stress of weakly curved surface areas leads to separation of crystals fragments. Accordingly the mass of wear mAb and median diameter of the abrasion debris d50 are different. The derived mathematical relations consider this behaviour by the particle shape factor ?x , which represents the ratio of the mixture of both stress mechanisms. The dependence of the particle shape factor ?x on the abrasion degree x with an exponent approximately to 2/3 points out that the particle shape factor ?x represents a surface area relation."

Jan 1, 2003

By V. Grujic, M. Grujic, D. Salatic

"Two areas are involved in the research work of the comminution process (crushing and grinding). The first one involves the changes of the size class distribution values that are definded by the differential equations in the function of the ore property and working conditions. The second area involves the comminution of the different levels in order to optimize the working parameters and to decrease the operational costs in the grinding process.We have studied, in detail, the possibility of functioning the crusher at the maximal loading, over 4500 kN, ball mills with diameters larger than 5.0 m and semiautogenous mills with diameters larger than 10.0 m.Using the computers, we have achieved the maximal loading range of the crusher, over Fc ? 4500 kN in the crushing process. In the grinding process, using the adequate differential equations in the automation process, we have established the correlation between the pulp mass capacity in the mill, pulp dencity, ore fineness in the pulp and recirculating ore charge.With the appopriate text, equations and graphs, this paper shows the results of our several years research work in the laboratory and in the ore comminution plant of Majdanpek Copper Mine."

Jan 1, 2003

By Malcolm Mudge

"One of the oldest mining areas in the World exist in Africa and the Middle East. This area is being exploited by foreign and local mining entities. Several large plants, both foreign and local as well as small operators, conduct their mining business on a scale which would be could be prohibited in any other part of the world. Relatively recent European disaster with tailing disposal and breakout has highlighted the problem.More important to the author is that the presence of foreign entities in zones which have not remedied the situation but has heightened the concern due to those entities using similar outrageous methods in treatment of waste. The abject misuse of technology cannot be permitted to continue and the lack of any metallurgical knowledge in the treatment of gold ores is considered deplorable for the majority of third world countries.The destruction of cyanide is simple and straightforward and requires no special skills. In South America, we developed a system that is modular, compact and can be operated in batch mode to cater for several clients, as required. Larger installations would require a separate module, as treatmentwould be on a continuous basis."

Jan 1, 2003

By A. V. Nozhkina

"Transformation of diamond into graphite was investigated in the region of diamond metastability under the action of media chemically active relative to carbon in the temperature range from 770 K up to 2200 K and pressure range from 10-3 Pa up to 3 GPa/IV VIII group metals of periodic system and oxygen were used as media chemically active relative to diamond.Methods of electron diffraction, chemical analyses, emission spectroscopy and X-ray phase analyses were used for determination of the reaction products.It was found that in the region of diamond metastability the stage of catalytic phase transformation of diamond into graphite took place during the interaction between diamond and metal. Metal reduce activation energy for transition of diamond into graphite from 109,4 kcal/mole to 77,4 kcal/mole.Kinetic of phase transformation of diamond into graphite was investigated.Pressure does not considerably influence on the rate of phase transformation of diamond into graphite in the presence of transition metals."

Jan 1, 2003

By H. U. R. Kattentidt, W. L. Dalmijn, T. P. R. de Jong

"Research at Delft University aims to develop systems for automatic inspection and sorting of bulk solids which can be applied in the mineral processing and recycling industry. A recent development includes an automatic sorter based on airport X-ray inspection technology. It is designed for continuous inspection and sorting of 5 – 150 mm solids and has as objective a cost effective and high capacity on-line inspection and sorting.Dual energy X-ray transmission imaging provides instantaneous data about particle dimensions and the atomic number distribution. The system provides particle thickness and average atomic number on a pixel level at scanning speeds between 250 and 500 lines / second. With existing X-ray components inspection speeds between 0.5 and 2 m/s at approximately 1-meter inspection width and between 1.5*1.5 and 5*5 mm2 sensor resolution can be achieved.Imaging algorithms that were developed by Delft University for applications in recycling, waste cleaning and other applications acquire shape, size distribution and composition data. Currently on-line processing of a product at a rate of around 200 particles per second is possible using a standard PC. Experiments with a demonstration X-ray unit indicated good potential for various applications in solids processing. They include continuous inspection of organic content, sulphur, chlorine, ash, and metal distribution. It is applicable for coal cleaning, ore sorting, industrial minerals, and various applications within waste cleaning and recycling. Dual energy X-ray transmission fundamentals and recent progress in system development and applications are presented."

Jan 1, 2003

By Elena L. Chanturiya, Vladimir A. Bocharov, Roman A. Amosov

"In many volcanogenic base metal deposits of Russia the gold is closely associated with copper sulphides and pyrite. The recovery of gold associated with pyrite is especially difficult problem.Investigations of gold chemical state and mineral forms in copper-zinc sulphide ores of Gay and Barsuchiy Log deposits in the Urals have been made using EPMA, optic image-analysis, XRA, SEM, thermo-electrical force measurements and selective gold leaching experiments.Two gold varieties are determined: 1) free native gold particles (from 5 µm up to 0,25-1,0 mm), which can be liberated after grinding of ore up to 0,074 µm and named “free gold”; 2)”invisible” gold, including finely disseminated native gold and chemically bound gold. The second variety can’t be disclosed during grinding. Free gold can be recovered by gravitation and flotation while the processing behaviour of “invisible” gold is determined by properties of gold-bearing sulphides: pyrite and chalcopyrite. According to results of diagnostic leaching experiments in ores of deposits mentioned above the part by weight of free gold reaches 70%, the part by weight of the ”invisible” gold is up to 20%. About 10% of gold is enclosed in quartz and acid-soluble minerals.Theoretically (taking into account gold distribution data) it’s may anticipate gold recovery by gravitation up to 60%. However after grinding up to 50-60% of class –0,074 mm only about 40% of gold passes into oversize product including 30% of free gold and 8% of ”invisible” one. It can be recovered by gravitation. Remaining free gold and ”invisible” gold can be extracted by flotation – 25% in total. Inevitable gold losses in tailings may reach 8-10%."

Jan 1, 2003

By Chris A. Bennett, Glenn S. Dobby, David A. Bulled

Establishing reagent dosing strategies for new ore bodies has traditionally involved a combination of experience and empirical experimentation using standard laboratory tests. The grade and recovery data resulting from these lab tests have historically been used as direct indicators of plant performance despite the obvious differences between the flotation environments. A reagent scheme selected in this way would subsequently be employed to generate the grade and recovery information for the geometallurgical model which in turn was used for metal production and cash flow forecasts. If the reagent scheme was sub-optimal then so too would be the forecasts and the resulting cash flow.

Jan 1, 2003

By Jim Petrie, Mary Stewart, Damien Giurco

This paper describes a generic approach to analysing the environmental and economic performance of a generic global mineral/metal value chain, with the express view of improving the quality of prospective decision-making within the industry in order to ensure more sustainable outcomes. As a point of departure we propose that it is not possible to place metals in the context of the sustainable development of society without paying due regard to the entire metals value chain. Thus, the starting point for this analysis is the development of a global stocks flows and transformations model, for the metal of interest. Any aspect of the value chain, e.g. “metals refining, “goods manufacture”, “use and disposal”, can be assessed, either relative to other stages in the value chain, or in more detail by focusing on the technologies used within that stage. The use of this model as a decision support tool is explored here for the case of copper. Both primary and secondary production routes are enumerated, covering a range of processes, for seven distinct geographic regions around the globe. The value of the modelling approach is explored for different energy mixes. In particular, the case study examines the impact of increased recycling on the (re) distribution of global and regional environmental impacts for technologies-in-place in these different regions. The aim of these case studies is to highlight to the minerals processing and metals refining industries their potential role in a more sustainable global society.

Jan 1, 2003

By Briony C. Ruse, David V. Boger, Fiona Sofra1

"The sustainability of the mining industry must be addressed through improving tailings management. The use of thickened tailings and pastes stems from a paradigm shift towards designing tailings disposal sites to suit their surrounding environment, rather than manipulating the environment to accommodate the tailings. Thickened tailings and pastes usually exhibit non-Newtonian behaviour, so a thorough understanding of the rheological characteristics of the material is required in order to determine the disposal plant operating conditions.As environmental factors translate into economic issues, minimising waste production using dry disposal methods is gaining popularity. The use of rheological information is of high importance in evaluating the spreading characteristics, the transportation and the dewatering of thickened mineral tailings. The principles outlined may be applied to many industries encompassing a wide range of waste materials. The main obstacle to the widespread implementation of dry disposal methods has been the high initial capital cost of the methods due to the dewatering step, and the high cost of pumping thick suspensions across any great distance. Proper and thorough costing of tailings disposal activities combined with an accounting approach that shows closure and post-closure care costs on a per tonne basis of tailings disposed throughout the life of the tailings facility will show that dry disposal methods are more favourable than they might seem on initial appraisal."

Jan 1, 2003