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By M. Rafati

In this investigation, the effects of T4 and T6 heat treatments of AZ91 magnesium cast alloy have been studied. The effects of different microstructural details such as morphology, size and distribution of precipitates and their influence on fracture mechanisms were investigated by optical and scanning electron microscopy. The mechanical strength of the alloy after T6 treatment was found to increase in comparison to the T4 treatment, due to the formation of discontinuous precipitates in the grain boundaries. Precipitation in this alloy occurs in two ways: continuous precipitation, which nucleates and grows inside the grains, and discontinuous precipitation, which forms at the grain boundaries. During ageing, the length of the continuous precipitates increases, and, hence, interprecipitate distance decreases. The formation of discontinuous precipitates causes initiation and propagation of cracks at and the weakening of the grain boundaries. This is the principal reason for the reduction of the ultimate tensile strength in T6 heat treatment in comparison to the T4 condition.

Jan 1, 2006

By P. Fellner, A. Sýkorová, J. Thonstad, J. Jurišová, V. Khandl

Adsorption of S02 on alumina used in the aluminium industry, so-called smelter grade alumina, was studied in the temperature range 15 C-120 C. The specific surface area of the smelter grade alumina was 88 m2/g. It was found that at temperatures lower than 40 C, sulphur dioxide is bonded to alumina reversibly by physical forces, and the adsorption can be described satisfactorily by the Langmuir adsorption isotherm. The heat of adsorption was estimated to be -33 kJ.mor1. At temperatures in the range 80 C- 120 C, which prevail in dry scrubbers in the aluminium industry, the heat of adsorption was determined to be -56 kJ.mor1. When S02 was adsorbed at temperatures higher than 80 C, about 30 % of the S02 could not be desorbed when heating the samples up to 250 C. In the presence of S02 and oxygen, the formation of sulphate was determined at temperatures above 90 C.

Jan 1, 2006

By D. J. Archambeault, A. Saigal

Substantial cost savings have been demonstrated by material design changes after initial product development. As more information about a product's operating environment becomes available to a designer, it is possible to consider a more costeffective material that still meets or exceeds the design intent, such as minimum low cycle fatigue life. This is especially true in the aircraft engine industry, where precise operating cycle data is not available until after the first engine is built and tested. A methodology for predicting estimated low cycle fatigue life has been developed to investigate potential material change candidates for an aft cooling plate. A twodimensional macromechanical finite element model (FEM) has been developed using ANSYS and used to determine the effects of varying material properties. It is shown that slight changes in density, coefficient of thermal expansion and modulus of elasticity have profound effects on component and effective stresses, and therefore, estimated low cycle fatigue (ELCF) life. Aerospace

Jan 1, 2006

By H. A. Kishawy, S. Kannan, M. Balazinski

Metal Matrix Composites (MMCs) are new generation engineering materials that possess superior physical and mechanical properties compared to nonreinforced alloys. However, the presence of abrasive ceramic reinforcements in the ductile matrix causes severe tool wear and premature tool failure. Flank wear was found to be the dominant wear mode while the main wear mechanism was abrasion. Analysis of the cutting tools using scanning electron microscopy has shown that both two body and three body abrasion are operational during machining MMCs. A methodology for predicting the tool flank wear progression during bar turning ofMMCs was presented in an earlier paper [1]. In the proposed model, the wear volume due to two body and three body abrasion mechanisms was formulated. Then, the flank wear rate was quantified by considering the tool geometry in 3D turning. The main objective of this paper is to investigate the contribution of two body and three body abrasion towards the tool wear volume during cutting MMCs.

Jan 1, 2006

The uranium ore processed by the McClean Lake Operation is co-mineralized with niccolite, rammelsbergite and gersdorffite (nickel arsenides). During the strong acid leach process, the majority of the reduced arsenic is oxidized and liberated into the lixiviant solution as As+5. Following uranium extraction, the residual raffinate solution, enriched in As+5, reports to the tailings preparation process. In this process, Fe+3 is first added and mixed with raffinate (pH~1) to achieve a Fe+3/Astotal molar ratio of at least 3. This is followed by two stages of neutralization, using slaked lime to achieve a solution pH of 4, and approximately 7.5, respectively. Synchrotron based x-ray absorption techniques (XANES, EXAFS) applied to neutralized raffinate solids and tailings samples collected from the tailings management facility provide evidence that arsenic has been precipitated as a poorly crystalline form of the mineral scorodite (FeAsO4?2H2O).

Aug 1, 2010

By Julie Q. Shang

The electrokinetic (EK) technology for dewatering of two tailings from the uranium mines in Northern Saskatchewan is studied in bench scale experiments. The study includes four phases: 1. Characterization of two uranium mine tailings; 2. Assessment of voltage loss on the coated Ti anode and water interface. 3. EK cell test series to measure electrokinetic permeability (ke) of two tailings; 4. EK dewatering test series to study electrokinetic enhanced gravity dewatering on two tailings samples. The results have demonstrated that both tailings responded positively to the EK process. For the tailings containing gypsum, the EK dewatering should be a short term process (within one hour) with anode conditioning (pH adjustment). The tailings containing clay minerals responded well to EK dewatering, in which pH adjustment is optional and will further enhance the EK flow. Both tailings as tested have low hydraulic conductivity and are particularly suitable for EK dewatering and consolidation.

Aug 1, 2010

By J. M. Shneerson

Gipronickel Institute, Saint-Petersburg will The copper concentrate was extracted from copper and nickel matte after its hydrometallurgical treatment and nickel removal. The concentrate containing 60-74% of copper was represented by two principal copper minerals, digenite and covellite. The oxidising leaching of this kind of concentrate was studied at the Gipronickel Institute. The effect of key parameters, such as temperature, oxygen partial pressure and initial solution compound, on the rate of copper dissolution and transfer of sulphur from sulphide to elemental form was investigated. It was shown that at temperatures about 90DC, the sulphur content of covellite converts to elemental form. Under autoclave conditions at 11ODC, the elemental sulphur dissolves as a sulphate-ion. At the temperature range from 50 to 90DC, the copper dissolution rate is in direct relation with temperature. By increasing the temperature to 130DC, this effect is reversed. Based on the research work, a technological flow sheet for the leaching of the copper concentrate was developed.

Jan 1, 2007

By M. Mohammadi Zahrani

The morphological modification of primary and eutectic Mg2Si phases by bismuth (Bi) addition in Mg-5wt.% Si in-situ composite was investigated. It was found that with addition of 0.5wt.% Bi, the morphology of primary Mg2Si precipitates was altered from coarse dendritic to polygonal shape, and their mean size was significantly decreased from more than 20 µm to about 8 µm. Moreover, the rod-like eutectic Mg2Si in Bi modified Mg-Si alloy solidified much finer than that of the base alloy. Such improved microstructure of the modified alloy resulted in 10% tensile strength and 20% elongation improvement. The isotropic growth manner of primary Mg2Si particles in modified alloy was attributed to the poisoning of growth in preferred directions by dissolving Bi atoms in Mg2Si lattice. The reduction in size of eutectic Mg2Si was found to be the result of Mg3Bi2 compound formation around eutectic Mg2Si rods.

Oct 1, 2011

By Louise Grondin

Laronde Mine has been working for a number of years to identify substances that could contribute to process water toxicity and to find an effective way of removing these contaminants from the water. Initial studies have identified ammonia, nitrite, cyanide, thiocyanate, cyanate, dissolved organic carbon, copper and zinc as potential toxicants. Bench-scale tests were carried out with Lakefield Research to find a water treatment process that could effectively remove the suspected toxicants. Nine treatment processes were evaluated: 1) granular activated carbon (GAC) filtration followed by zeolite, 2) zeolite filtration followed by GAC filtration, 3) aeration followed by GAC filtration, 4) multi-stage GAC filtration, 5) chlorination followed by dechlorination, 6) addition of clay based polymer, 7) treatment with peroxide and ultra-violet light, 8) bulk addition of GAC and zeolite powder, 9) treatment with bacteria. This article presents a summary of the test results and of the problems associated with the evaluation of technologies for the treatment of toxicity.

Nov 1, 2002

By T. Watanabe, M. Nakagawa, K. Kimapong

Ultrasonic wave was irradiated on metal surface in water to introduce compressive residual stress. The ultrasonic wave that was oscillated with 19.5 kHz ultrasonic transducer and amplified with a step type horn was irradiated. Slight plastic deformation occurred at the surface region of pure metal such as Cu and compressive residual stress was introduced. It seemed that the plastically deformed depth from the metal surface corresponded approximately to the depth of introduced residual stress. The higher compressive residual stress could be introduced into the surface of Cu-Zn brass and SUS304 stainless steel because work-hardening was simultaneously induced to those alloys. Furthermore, since martensitic transformation was induced by the plastic deformation in the case of SUS304, the compressive residual stress could be introduced more deeply into the surface region. The residual stress of SUS304 reached to the maximum value of 574 MPa by irradiating for 5min.

Jan 1, 2004

By G. T. Fisher

A continuous process is used at Phelps Dodge Sierrita Inc. to produce copper sulfate pentahydrate via a solution extraction ? crystallization approach to supply the animal feed market. A review of the fundamental concepts of the process and unit operations is presented. Improvements in the process are aimed at achieving a controlled size distribution of product crystals (-40+80 mesh) with minimization of fines by primary nucleation and crystal breakage. An independent temperature control design was implemented for the heat transfer medium (water) in each crystallizer, albeit using common headers in and out of the chiller. This design was developed to maintain a controlled degree of supersaturation in each vessel while preventing localized spontaneous nucleation of fines and reducing encrustation of the heat transfer surfaces in each crystallizer. A model was developed to calculate the heat load and heat transfer coefficient of each crystallizer along with the saturation copper tenor as a function of temperature and free acid.

Jan 1, 2007

By B. T. Lu, J. L. Luo, J. F. Lu

The present paper investigates the chemo-mechanical effect in slurry-erosion corrosion process of carbon steel to understand the synergistic mechanism due to interaction of chemical and mechanical factors. The erosion-corrosion tests were conducted with A1045 steel in slurries comprising tap water and silica sand. Various heat treatments were adopted to achieve different hardness in the test material. The chemo-mechanical effect is evaluated in line with the correlation between the degradation of hardness in the surface layer and anodic current density. During the erosion-corrosion tests, various anodic currents were applied to find the relation between the anodic dissolution rate and erosion rate. The experimental results indicate that the hardness decreased with increasing anodic dissolution. Based on the fact that pure mechanical erosion rate increased with decreasing hardness, this result suggests that the corrosion-induced degradation of mechanical property is a mechanism of corrosion-enhanced erosion. This theoretical prediction is verified by erosion-corrosion experimental results.

Jan 1, 2004

By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

In addition to the harsh environment, materials for high-temperature applications are often subjected to a significant mechanical loading. Several researchers have noted that the rate of oxidation can be affected by stress in a range of materials. We have recently studied this effect in y-TiAl, based on the preliminary work of Magnan and Weatherly which showed that nitridation rates on the tensile side of a flexural creep specimen could be 10 times higher than on the compressive side. We have since developed a four-point bending creep setup capable of controlled atmosphere testing. We present quantitative data on the effect of creep on scale growth under a range of atmospheric conditions. Finite element analysis will also be used to show how modest applied stresses can have a large effect on scale growth rates through the generation of large stresses due to the mismatch of creep rate between the metallic substrate and the scale.

Jan 1, 2004

CFD (Computational Fluid Dynamic) models have been developed and validated for a pulsed column with disk-doughnut internals, as used for solvent extraction. First a single phase model was developed to simulate the turbulent oscillating flow around the internals of the column. This model was successfully validated using detailed PIV measurements of velocity taken at eight different phases through the pulse cycle. Second, the CFD model was extended to allow for a continuous aqueous phase and a dispersed organic phase (kerosene) flowing counter-currently. The model was a two-fluid model that accounts for droplet breakup and coalescence, and solves for droplet size distribution using a population balance model incorporated into the CFX4 package. PDIA (Particle Droplet Image Analysis) measurements were taken on a pilot scale solvent extraction pulsed column to determine droplet size distribution for calibration and validation of the CFD model. The measurements were made under pulsing intensities ranging from 10 mm/s to 32.5 mm/s.

Jan 1, 2007

By Ch. Wenzl

Anodes must have a certain physical and chemical quality in order to provide uniform anodic corrosion and meet the requirements of electrorefining, i.e. to achieve a high current efficiency, low energy consumption, low amount of anode scrap and low effort together with high cathode quality. Various properties of the anodes can be influenced directly by the casting process, which is the interface of pyro- and hydrometallurgy of copper. The aims of anode casting ? high output and long mould lifetimes ? are not consistent with good physical anode quality. The physical requirements of an anode are smooth surfaces, uniform weight and thickness, minimal edge effects, minimal distortion of the body and the lugs, as well as a homogeneous microstructure, in order to achieve uniform dissolution behaviour. The chemical quality of the anode copper is a task of electrorefining operations, but the elemental distribution within the anodes, which should be as homogeneous as possible in order to provide uniform anodic corrosion, can be influenced by the casting process.

Jan 1, 2007

By K. Koyama

As a study to establish a new energy-saving copper recycling process, the copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) were investigated in order to examine the feasibility of electrolysis in this solution.. The current efficiencies were greater than 95% in the current density range of 200 to 1000 A m-2. The current efficiency decreased with the increasing Cu(II) concentration and temperature. In the batch-type electrolysis at the anode, during the initial stage, the current efficiencies were 100%, and the anode potentials ranged from 0 to 0.15V vs. SHE at a current density of 100 A m-2. During the subsequent stage, the current efficiency decreased with time, and the anode potential was around 1.35V vs. SHE where oxygen evolution at the anode surface was observed. As a result, the present electrolytic method can be the core technology in the said copper recycling process.

Jan 1, 2007

By D. Harris, S. Murugesan, G. Ye, G. Oprea, J. Rigby, T. Troczynski

The spinel-added and in-situ spinel bonded castables have been developed and widely used in steel industry. It is challenging to develop magnesia-based castables for the non-ferrous industry because the temperatures in industrial furnaces are significantly lower than those in the steel industry and therefore the binding systems of these castables must have the capability to develop a ceramic matrix below 1300°C. It is also challenging to develop a good binding system without addition of fume silica, because the hydration of magnesia may take place during installation, curing and firing of the castables. This work presents the experimental results on developing magnesia-based cement-free, silica fume-free refractory castables using hydratable alumina as the hydraulic binder and a spinel phase as the final ceramic binder. In order to activate the sintering and have a ceramic matrix well developed at the relatively low required temperatures, ultrafine aluminas, chromia, magnesium-aluminate spinel and aluminum titanate powders were used as components of the binding system.

Jan 1, 2004

By N. Ntakaburimvo, C. Allaire

This paper presents an innovative experimental set-up which simulates refractory degradation by separate and simultaneous action of abrasion, erosion and partially or totally immersion corrosion whether dynamic or static. It also presents abrasion testing results obtained from five commercial aluminosilicate refractories used in aluminium melting and holding furnaces. Abrasion wear was quantified by measuring the weight loss and the depth of wear, as well as by determining materials properties degradation, such as the residual rupture force and the residual modulus of rupture. Results were correlated to as- fired materials properties, such as rupture force, flexural strength, elastic modulus, toughness, and apparent porosity; in order to establish which property could be used for refractory abrasion wear prediction. They were also related to the critical length of pre-existing defects and to those generated by the abrasion process. Positive correlation was established between abrasion resistance and mechanical properties, particularly for refractory castables. For similar mechanical strength, the castables tested offered less abrasion resistance than the brick sample.

Jan 1, 2004

By Jörgen Appelgren

Atlas Copco, a leading supplier of equipment and services to the mining and construction industries, is consistently pursuing its strategy to offer the most productive and economical solutions by continuously offering new innovative products. These are in most cases developed and tested in close cooperation with demanding end users before being officially launched on the international market. The demands for higher productivity and improved overall economy have resulted in systems for automation of the drilling cycle and also tools for integrating the Drilling equipment to the production control system used by the customer. In terms of improving the blasted material quality, Atlas Copco has placed emphasis on hole straightness and the need for hole logging and positioning. By applying state of the art technology to today?s computerized drilling rigs, major steps in improving overall drilling and blasting performance have been achieved. This paper will give some examples derived from the latest development of solutions for the Rotary drilling product line.

Oct 1, 2009

By Marcel Vallée

Abstract -Traditionally, samples collected for mineral deposit evaluation have been viewed without explicit reference to reliability, with the illusion that a true value is attainable from a few samples and verifications. For exploration, mineral deposit estimation and production quality control the following definition is proposed: "a sample is a small quantity of material relative to the geological mass it represents, collected according to a systematic procedure, of measurable reliability, from which the grade/quality of the mass which it represents may be estimated, based upon appropriate protocols. This paper will concentrate on the actual rock sampling process. Too often, sample size has been, and is still viewed as a matter of convenience, leaving out representivity considerations, despite the importance of samples on project estimation. Linear samples (chips, channels, drill), panel samples, broken rock or mining samples and very large samples are considered. Collection procedures and quality control protocols to improve the representivity of non-mechanical samples are proposed.

Jan 1, 1998