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By I. Osvath, I. Gombköto, G. Mucsi, Z. Molnár

"In the present research, a deposited brown coal fly ash was used as raw material for geopolymer. The reactivity of the fly ash was altered using mechanical activation, which is one of the promising methods to improve bulk and surface reactivity. The mechanical activation experiments were carried out in a high energy density mill using 5 m/s circumferential speed, and various residence times (1, 3, 5, 10, 15 and 60 min). The effect of mechanical activation on particle size distribution was measured by a laser particle size analyzer and structural changes using FT-IR. Geopolymer samples were prepared from mechanically activated fly ash with an alkali solution. The progress of geopolymerisation was monitored using an Isothermal Conduction Calorimeter. The heat flow curve obtained indicated that reactions were more prominent and started much earlier in the mechanically activated samples. This observation is further supported by the compressive strength results which also improved in geopolymers using mechanically activated fly ash. Based on the obtained results, it can be inferred that mechanical activation is a possible way to enhance the reactivity of fly ash and consequently properties of resulting geopolymers.INTRODUCTIONCoal fired power plants generate fly ash and slag in huge amount worldwide, about 780 million tons/year (Heidrich et al. 2013). Due to the relatively low utilization rate, enormous quantities of these wastes are landfilled in ponds. The fly ash is the finest grained particle fraction of the solid ash, which is transported with flue gas, and removed by electrostatic or bag filters. The fly ash has pozzolanic activity, it does not react with water, but in the presence of calcium hydroxide solution hardens and solidifies, producing a reaction product practically insoluble in water (Opoczky, 2001). The most important property of the fly ash regarding geopolymerization is its reactivity, which depends on the chemical and phase composition, the dispersity (specific surface area, particle size distribution), and the morphology of the fly ash particles, and determined by the physical properties and chemical composition of the fly ash. Geopolymers concerning their chemical structure are polysialates, where the sialate (silicon-oxoaluminate) network is built up from the bonds of Si-oxide and Al-oxide by sharing oxygen atoms (Davidovits, 1988)."

Jan 1, 2016

By Philippe Ribagnac, Bruno Courtaud, Jean-Marie Lambert, Valérie Weigel

Mabounié is a polymetallic deposit in Gabon containing niobium (1.2 wt.%), tantalum (0.03 wt.%), rare earth elements (REE) (1.4 wt.%) and uranium (0.03 wt.%) that are mostly carried by pyrochlore minerals. The classical route for niobium recovery is a pyrometallurgical process that consists of pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF. ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore (Donati, Courtaud, & Weigel, 2014). As for most of the oxidized ore processes, the major impurity is iron (~30 wt.%). Thus, in this hydrometallurgical process, the question arises of the elimination and stabilization of the iron as residue. The iron in solution is ferrous; goethite precipitation seems the most adapted crystalline form. Lab and pilot tests have shown kinetics of precipitation of 6 g.L-1.h-1 at pH 4.5. To reduce the salt discharge, sodium-jarosite form is more adapted, but at pH 2, 95°C only 30% of iron is precipitated in 5 hours, compared to 100% in goethite form at the same time and pH 2, 80°C. Different ways of oxidation were tested, air, pure O2, activated carbon, without drastic effect. The more efficient was ozone use, at room temperature; the kinetics of oxidation is five time faster than the other ways with 30% of sodium removed from the solution.

Jan 1, 2016

By G. Dodbiba, A. Otsuki, T. Fujita, J. Ponou, A. Shibayama

"The different types of nano to submicron particles, which are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The information is very useful for mineral processing treatment. The IFA can measure the particle size distribution in low to high concentration of particles in liquids and non-light transparent liquids. Here, mainly the emulsion and bubble size measurements are described.Emulsion (w/o type) is prepared with oil and water mixture. The nano to micro emulsion particle size is usually measured by light scattering method. The particle size distribution of emulsion of light oil measured by IFA agreed well with the one by the dynamic light scattering (DLS) method. The water size distribution in emulsions of gasoline is difficult for the small reflection index and C heavy oil is difficult for the black color by DLS method. The IFA can measure both emulsions.There are many methods to measure fine air bubbles, however, the finer nano size measurement apparatuses are DLS method and IFA. A “ghost” peak appeared in the large particle micron meter size in DLS method. The mean diameter in IFA is similar with DLS for the nano meter size. INTRODUCTIONParticle size distribution measurement of nano to submicron particle, emulsion and bubble size distribution are very useful for ultrafine particle separation and characterization of fine particles by the necessity of recent fine minerals separation (For example, Li et al.2016, Mikhlin et al.2016, Wang et al.2013). As for the size measurement of solid particles in liquids, three different types of nano to submicron particles, that are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The particle size distributions are compared with the one of dried particles measured by TEM or SEM. The well-dispersed nano particle size distribution by IFA is influenced by the nano size surfactant micelles and becomes smaller, when compared with the TEM result. The size distribution of nano size of magnetite particles in water is influenced by the isoelectric point and the mean diameter of coagulation becomes larger. The particle coagulation in diluted suspension is about 2nm smaller when compared with the higher concentration. The submicron nickel particle size distribution is well agreed the result by SEM. The coagulation effect is small in the submicron size of nickel powder in water (Fujita et al., 2013). In this paper, the emulsion and bubble size measurements are mainly described."

Jan 1, 2016

By K. K. Feng

"Spontaneous combustion has always been a problem in coal mines and is identified mainly with the mining of low-rank coals. The liability of coals to spontaneous heating is only one of the factors in determining whether spontaneous combustion will occur. However, knowledge of the relative oxidizability of the coal is a useful factor to take into consideration when selecting new coal seams and mining methods for future mine development.Four methods (static isothermal, ignitability, adiabatic and dynamic) have been used to compare the relative liability of Canadian coal to spontaneous combustion and to investigate the mechanism of spontaneous combustion of these coals. Among these f our methods, the static isothermal method is considered to be the best indicator of the susceptibility of various coals to spontaneous combustion. Western mountain coal adsorbs more oxygen and has a higher tendency to undergo spontaneous combustion than the Harbour seam coal of Nova Scotia. It has also been observed that a higher methane content in coal will indicate a lower liability to spontaneous heating."

Jan 1, 1985

By D. Saramak, T. Gawenda, Z. Naziemiec, A. Saramak

"Crushing and grinding operations are burdensome to the environment due to generating large amounts of dust, noise and waste during course of comminution operations. An indirect negative contribution of industrial crushing processes is an increase of carbon dioxide emissions, which is a byproduct in energy production processes. On the other hand comminution processes in ore enrichment technology are essential due to liberation the useful minerals from the gangue, and producing the demanded particle size fractions of products. The article concerns investigation over negative influence of comminution devices on environment in terms of dust and noise emissions. Several various crushing devices were under investigations, both in laboratory and in industrial scale.The obtained results were analyzed in terms throughput and energy consumption achieved in various crushing devices. The test results allow to conclude that an intensity of dust generation for individual types of crushing devices is varied. An additional aim of this article is to link the aspect of mineral processing with its environmental impact and hence an influence of raw materials beneficiation industry on the quality of life of residents in immediate and close vicinity.INTRODUCTIONMineral raw materials beneficiation processes are an integral part of multi-stage processing of coal, iron ore and non-ferrous metals, production of aggregates, cement, or precious metals and stones. One of the common features of all beneficiation operations is their high energy consumption, which is mainly connected with various operations of feed particle size reduction. Comminution processes in ore enrichment technology are essential to expose and liberate the useful minerals from the gangue, while in aggregate production processes – to obtain the demanded particle size fractions of products. Crushing operations are characterized by a high degree of negative impact to the environment and humans, mainly due to:• High electricity consumption, which indirectly contributes to the increased emissions of carbon dioxide into the atmosphere, since CO2 is often one of the byproducts of energy production;• Relatively rapid wear of device working parts, what forces a production of spare parts and involvement of steel industry;• Intense dust pollution generated during crushing and grinding processes. This is one of the factors affecting the air quality and the consequent deterioration of the living conditions of inhabitants near mines and processing plants; and • Excessive noise emissions."

Jan 1, 2016

By J. Lu, D. B. Dreisinger, G. Houlachi

"Zinc metal is primarily produced by electrowinning from sulfate solution. Zinc electrowinning is very sensitive to impurities such as Co and Ni. These impurities have to be removed to produce high-quality zinc and maintain a high zinc current efficiency. Zinc dusts are used to remove these impurities by cementation. However cobalt cementation is extremely slow and it is typically activated by the addition of Cu and Sb. Even with the use of Cu-Sb activation, cobalt is still difficult to remove. The zinc dust used for cobalt cementation is negligible compared to that consumed for hydrogen evolution. In some plants up to 6-7% of electrolytic zinc is used for cementation. This is a great waste of energy. Cu-Sb activation is not well understood. The objective of this study was to further understand the Cu-Sb activation and then find a way to reduce hydrogen evolution and promote cobalt cementation. The investigation reveals how hydrogen evolution (or zinc dissolution) and cobalt cementation and re-dissolution change with temperature, zinc dust dosage, the concentrations of copper and antimony and time. In the Cu-Sb activation, copper is deposited on a zinc particle to produce a porous shell. The zinc particle as an anode dissolves while the shell as a cathode provides a place where cobalt cementation and hydrogen evolution occur and they are catalyzed by antimony. A certain level of antimony (around 0.1 mg/L) is a key to maintain the catalytic effect of the shell. At a higher antimony concentration, cobalt cementation is accelerated slightly while hydrogen evolution is increased greatly. When a zinc particle dissolves to a certain degree, cobalt loses its cathodic protection and starts to re-dissolve. The change in cobalt concentration is determined by the rates of cobalt cementation and re-dissolution. The operation conditions can be optimized to maximize the cobalt removal and minimize the zinc dust dosage.INTRODUCTIONMost of the world’s zinc metal is produced by electrowinning from sulfate media. Many impurities such as iron, copper, cobalt and nickel are co-extracted into solution with zinc. Iron, mercury, indium, lead and tin are removed by co-precipitation as hydroxides. Copper, nickel, cobalt, aluminum, arsenic and germanium are partially co-precipitated with iron while cadmium, magnesium and chloride remain in solution. Cobalt, copper, cadmium, nickel and etc. are subsequently removed by cementation with zinc dust to achieve an acceptable current efficiency and high purity metal product for the economical production of zinc. Zinc provides a strong thermodynamic driving force for the cobalt cementation:"

Jan 1, 2016

By Tony Lipiec, Ian Orford

"A key part of plant design is the selection of the design tonnage which is the hourly tonnage target that the equipment selection is based on. Its selection is critical for ensuring that the nominal tonnage which is critical to the financial performance of the project will be met. With deposits being developed at lower grades, higher tonnages and a higher degree of hardness variability, it is essential to ensure that the design process selects the comminution equipment which will be able to deal with the impact of this ore quality variation.Ore hardness and its variance are key factors to be taken into consideration for the selection of the design tonnage. It is well accepted that for the nominal or name plate tonnage to be consistently achieved, it is necessary to base the design tonnage on a hardness value greater than the average ore hardness of the deposit to be mined. The question is how much greater should this design value be to ensure that the nominal tonnage is met to the satisfaction of the project financial model. Standard industry practice is to set the design tonnage by:1. Select an ore hardness percentile that is greater than the average ore hardness to be the basis of the nominal tonnage. Typically either the 75th or 80th percentile value from the data set will be selected.2. Selection of a design factor to multiply by for determining the design tonnage, i.e. the design tonnage = tonnage (based on the average ore hardness) multiplied by design factor.This paper discusses the selection of the design ore hardness through the use of modelling or the use of a design factor. It further shows the impact of ore hardness variance on the capacity of the process and its ability to meet the nominal tonnage. Insight is provided as to what ore hardness percentile value should be selected balancing the shortfalls of tonnage for ores harder than the design value versus the above target production achieved for ores softer than the design ore hardness."

Jan 1, 2016

By James Tuer, John R. Goode, Jim Cambon

"Hudson Resources Inc. (Hudson) has defined a major resource of high purity anorthosite (calcium feldspar) assaying about 30% Al2O3 at the White Mountain (Naajat) deposit in Western Greenland. Extensive beneficiation and evaluation testwork has shown that the material can be simply beneficiated to produce a feed material ideal for the production of low-alkali E-glass used for making glass fibre. An offtake agreement is in place with a major US fibreglass manufacturer and, subject to the mine construction schedule, shipments are scheduled for late 2016 or early 2017. In parallel with the E-glass program, Hudson has completed an initial program of metallurgical testwork which shows that the White Mountain anorthosite can be processed by hydro- and pyro-metallurgical processes to yield either smelter-grade alumina (SGA), suitable for conversion to aluminium metal, or a high purity, chemical/specialty-grade alpha-alumina (CGA) commanding a premium price. The process includes dissolution of the anorthosite in hydrochloric acid, HCl sparging to precipitate aluminium chloride hexahydrate (ACH), recycle of the ACH filtrate to leaching with a bleed stream processed for HCl regeneration from CaCl2, and two-stage calcination of the ACH to regenerate HCl and produce SGA and/or CGA. Calcium silicate and amorphous silica are marketable by-products. This paper discusses the White Mountain anorthosite deposit; the process testwork completed to develop production processes for SGA and CGA; production plans, and indicative economics.INTRODUCTIONHudson Resources Inc. (Hudson) holds a 100% interest in the Naajat Exploitation Licence in Western Greenland that cover the White Mountain high-calcic anorthosite deposit. Anorthosite is a calcium aluminosilicate of slightly variable composition but generally containing about 30% Al2O3. The alumina content is similar to that in bauxite and anorthosite has long been studied as a feedstock for the production of alumina. Other potential uses include feedstock for the high-end fiberglass (E-glass) industry and as a filler for use in paint and plastics."

Jan 1, 2016

By K. Adham, T. Buchholz

"Significant capacity increases to meet new production demands can often be fulfilled through debottlenecking of an existing production facility, rather than the more expensive option of building new plants and facing new environmental and infrastructure challenges. To achieve that goal, it is important to model and calculate the existing ultimate capacity of each processing plant area, and that of each key equipment sector within the plant areas. This paper describes a methodology of how process modeling tools can be used to simulate the processing steps, how to estimate their existing and ultimate capacities, and how to determine the sweet-spots (minimum cost points) for a plant expansion – leading to a road map of the subsequent debottlenecking project implementation.The debottlenecking technique is presented through a generic work-flow narrative which can be applied to different mineral processing studies, starting with establishment of heat-and-mass balances, drawing a bottleneck diagram, brainstorming capacity increase options, and preparing a cost-capacity curve. Hatch has successfully applied this technique to a number of plant capacity studies, with great benefits to our industrial clients.INTRODUCTIONWith the softening of the metals and minerals prices, and the escalated costs of building new processing plants, it is now economically more viable to improve and debottleneck the existing facilities, rather than build new ones. However, spending new money on old plants requires careful considerations, in order to identify the most economically advantageous incremental steps of improvement and the best potential returns on investment. Process modeling, hand in hand with plant measurements, can identify the best scenarios to balance the three aspects of plant capacity (nameplate, utilization and yield), both at the global and the individual system and subsystem levels."

Jan 1, 2016

By J. S. Scott

"The Quemont property comprises 640 acres lying directly north of and adjoining the Noranda (Horne) mine. During 1926 to 1928, United Verde Extension Mining Corporation sank a shaft 235 feet and did 3,000 feet of development work on the 215-foot level. Between 1929 and 1930, Quemonr Mining Corporation deepened the shaft to 926 feet, and did further lateral work and drilling on the 500- and 900-foot levels. This work was confined to an area close to the south boundary and met with little encouragement.Following a period of idleness a magnetic survey was made in the winter of 1944, followed in the summer of the same year by some 6,000 feet of drilling. The first successful hole was drilled in February, 1945, from the ice of Osisko lake.To the time of writing, 131,000 feet of drilling, surface and underground,have indicated a large tonnage of gold-silver-copper-zinc ore, and although some knowledge of the geology and structure is emerging, it is too early to draw definite conclusions. The following brief description deals only with those structural features that are reasonably well indicated."

Jan 1, 1954

By C. A. Biley

"A dedicated iron removal stage was installed at Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) during an expansion project which began execution in 2010. The Pressure Iron Removal (PIR) process aims to precipitate iron from a nickel leach solution under medium temperature (145 °C) oxidative conditions using caustic for neutralisation. Since commissioning, the process has been robust in removing iron from the refinery but has shown significant variability in the residues produced. These residues, which are typically comprised of ferrihydrite, hematite or natrojarosite, have varying iron contents and different physical properties which have implications for their filtration and ultimate removal from the refinery. Since over 95% of nickel plated at RBMR passes through the PIR section, volumetric constraints caused by poor filtration performance directly influence nickel production and stabilisation of this process remains central to the continued ramp-up of the refinery to full nameplate capacity. This paper details the development of the PIR process and the journey from concept to implementation. Recent laboratory and plant scale tests have highlighted the importance of the initial phase formed in the autoclave for the ultimate residue requiring filtration and how the feed acid concentration is a critical control parameter. On this basis, a new caustic dosing philosophy was implemented which improved pH control in the autoclave. Further optimisation of the PIR process is on-going.INTRODUCTIONIn 2010, an expansion of Rustenburg Base Metal Refiners (RBMR) to increase nickel production from 21 to 33 ktpa began execution. The management of iron was pivotal in the ultimate configuration in the new circuit and one of the primary differences from the original circuit was the addition of a dedicated iron removal stage: Pressure Iron Removal (PIR). A significant drive for this new unit operation was to facilitate the separation of iron from other leach residues. Not only did this result in a significant decrease in the amount of leach residue but, without the constraints associated with iron precipitation during leaching, has permitted more aggressive leaching conditions and, correspondingly, greater throughput and efficiencies.However, as with many commercial implementations of even mature technologies, the journey from development to implementation has presented challenges for the continued ramp-up of the refinery to full nameplate capacity. Specifically, since all nickel bearing leach solution must pass through the PIR section prior to the nickel purification and recovery circuit, throughput difficulties in the PIR section can directly impact supply of feed to the nickel tank house. Since commissioning, the PIR autoclave has effectively removed iron from the refinery, but has shown significant variation in the solids phases produced in the autoclave. This variation presents difficulties for the filtration of the discharge slurry and represents a key throughput limitation which periodically impacts production. Additionally, the increasing production rates associated with the ramp-up of the refinery have resulted in a significant increase in the required volumetric throughput through the PIR process. This has placed even greater emphasis on improving the stability of the solid phase produced in the autoclave, ultimately targeting an easily filterable residue with high iron content."

Jan 1, 2016

By L. Li

Iron removal is a common procedure in hydrometallurgy of non-ferrous metallic ores. Chemical precipitation and solvent extraction are currently the main methods employed for separation of iron from copper leach solution. However, chemical precipitation methods have the problem of producing large amounts of iron precipitates, and/or requiring high temperature and high pressure conditions for precipitation. The precipitates are difficult to separate from the solution. Emulsification is a general problem for solvent extraction, which causes loss of extractants and contamination of the electrolyte. A common problem for solvent extraction and chelating ion exchange processes is the difficult iron stripping process. Therefore, finding an efficient and environmentally friendly method for iron removal is of great significance. In this paper, new processes of using ion exchange resins to remove iron from copper leach solution have been investigated. Salicylic acid, amino carboxylic acid, amino phosphonic acid and hydroxy-oxime resins were employed to adsorb iron from a simulated copper leach solution containing 40 g/L of Cu2+ and 36 g/L of Fe3+. It was found that a hydroxy-oxime resin, named Z-Fe, has excellent adsorption selectivity on Fe3+. Desorption behavior of the resin was studied by two step elution using dilute H2SO4 and oxalic acid solution, respectively. After optimizing the adsorption-elution processes, the extent of removal of iron from the simulated copper leach solution using resin Z-Fe was 90%, while copper recovery could reach 100% in closed circuit processing.

Jan 1, 2016

By Gaston Giuliani, Jérome Massot, Didier Bourlès, Lionel Siame

"Abstract - We present a new approach for the evaluation of the potential of emerald reserves in gem projects using beryllium (Be) mobility. The distribution of Be in the different phases of hydrothermally altered (albitized) black shale hosting Colombian emerald deposits indicates that Be mobility is associated with the breakdown of Fe-Mn oxyhydroxide phases. The amount of Be that can be mobilized (~0.7 x 10-6 g/g; i.e., 0.7 ppm) may represent up to 18 wt% of the total Be contained in the black shale. A mass balance calculation applied to a well-constrained alteration zone of the Chivor mines, and based on the quantification of Be that can be mobilized under hydrothermal conditions, gives an estimate of the total gem reserves of these mines. Resumé - Une nouvelle approche, basée sur la mobilité du béryllium (Be) pour l’évaluation des réserves d’émeraude dans des projets d’exploitation de gemmes est présentée. La distribution du Be dans les différentes phases minérales de schistes noirs hydrothermalisés (albitisés) qui contiennent les gisements d’émeraude colombiens, indique que le Be mobilisable se trouve dans les oxyhydroxydes de fer et de manganèse. La quantité de Be potentiellement mobilisable (~0,7 x 10-6 g/g; soit 0,7 ppm) constitue jusqu’à 18% poids du Be global contenu dans le schiste noir. Un bilan de masse appliqué à la zone d’altération hydrothermale des mines de Chivor et basé sur la quantification du Be mobilisable, donne une première estimation des réserves à émeraude de ces mines. rieur."

Jan 1, 1999

By J. D. Gillaspie, D. T. White

"Sulphuric acid atmospheric leaching of nickel saprolite / garnierite ores was proposed in the early twentieth century, prior to the development of the pressure acid leaching process for limonite ores. Sulphuric acid leaching with alkali addition for iron precipitation as jarosite has been considered periodically since the early 1970s, shortly after the development of the jarosite process for iron control in zinc refining. In the late 1990’s a series of flowsheets were proposed and tested involving simultaneous atmospheric leaching, iron precipitation and acid regeneration. These were considered particularly suited to sequential leaching of limonite and saprolite ores. A number of laterite sulphuric acid leaching processes utilising this chemistry have been put into commercial operation. Similar sequential leaching flow sheets involving precipitation of iron as goethite were also developed and piloted. This paper will firstly describe some of the important historical developments of both the jarosite and goethite processes. It will then provide descriptions of the commercialised processes involving alkali jarosite/alunite precipitation, with special emphasis on the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution.INTRODUCTION This paper is a summary and extension of previous works with which the authors have been involved, on the subject of sulphuric acid leaching of nickel laterites (Adams, et al., 2004), (Liu H. , Gillaspie, Lewis, Neudorf, & Barnett, 2004), (White, Miller, & Napier, 2006), (White, 2009), (White & Gillaspie, 2013), (White & Gillaspie, 2015). Some of the historical developments of both the jarosite and goethite leaching-precipitation processes will be described, followed by a description of the commercialised sequential nickel laterite leaching processes, involving alkali jarosite/alunite precipitation and acid regeneration, with a comparison to the equivalent goethite based processes. These will include Jarosite Atmospheric Leaching (JAL), Goethite Atmospheric Leaching (GAL) and combined Pressure Acid Leaching – Atmospheric Leaching, termed EPAL®. There will also be an explanation of the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution."

Jan 1, 2016

By Youngjib Ham

Understanding energy performance of existing buildings is vital to increasing their efficiency and reducing the overall energy consumptions. This entails facility managers to systematically monitor building energy performance and reliably identify and analyze potential problems. Currently, infrared thermography is widely used as a primary diagnostic tool for the detection of building performance problems. Nonetheless, applications of thermal images for building inspection are mainly restricted to manual and labor-intensive identification and qualitative assessment of heating or cooling loss. Automated identification of potential problems and reliable cost analysis of the associated energy loss can help homeowners to minimize financial risk of retrofits and maximize energy savings. To that end, this paper presents a new automated method for calculating the cost of energy loss for building diagnostics. In the proposed method, first, using a hand-held thermal camera, the auditors collect digital and thermal imagery from the buildings under inspection. Then, using a recently proposed method for Energy Performance Augmented Reality (EPAR) modeling, an actual 3D spatio-thermal model is generated and superimposed with a computational fluid dynamics (CFD)-based expected energy performance model. The resulting EPAR model is placed into the method proposed in this paper for cost analysis of the energy loss. Through a new 3D thermal mesh modeling using k-d tree structure and nearest neighborhood searching, performance deviations between these models are automatically calculated. Using a temperature threshold, the areas associated with potential performance problems are detected in the EPAR model and are visualized using a metaphor based on traffic light colors. Then, the actual R-values of the detected areas are measured at the level of 3D points. Based on the measured R-values and the estimated air change rate for the detected air leaks, (1) the heat loss or gain caused either by poor insulation or air infiltration/exfiltration and (2) the associated energy costs are automatically calculated. The proposed method is validated on several locations of existing residential buildings. The preliminary results show the potential of the proposed method for minimizing the inspection time as well as the risk associated with the cost analysis of retrofitting potential building performance problems.

Aug 1, 2013

By Mehmet F. Taner

"Abstract - "Les Mines Selbaie" is a large, generally low-grade, polymetallic (Zn, Cu, Ag, Au) "giant" volcanic-associated ore deposit in the Harricana-Turgeon belt, which is part of the northern Abitibi Subprovince of Quebec. Economically recoverable mineralization occurred in three zones: the A1 (open pit), A2, and B Zones (underground). The pre-mining resource was 54.9 Mt, including 8 Mt of sub-economic, locally silver-rich massive pyrite. In the Selbaie region, calc-alkaline andesitic volcanics form the "basement." The Brouillan Volcanic Complex formed within an islandarc setting on this regional basement. Evolution of this complex involved the formation of a felsic magma chamber and the development of a large caldera structure over the Brouillan batholith. Second- order linear and sub-parallel faults and rifts developed as a result of back-arc rifting/extension. The edges of these rifts were feeders for linear felsic volcanism (similar to fissural volcanism). During felsic volcanism, the feeder zones acted as conduits for hydrothermal fluids with associated pervasive potassic alteration. The alteration is characterized both vertically and laterally by well-defined quartz, sericite, K-feldspar and/or, locally, biotite halos, to produce a mushroom-shaped morphology. This K-feldspar alteration is not common in most other volcanic-associated ore deposits. Mafic dikes cut all of the geological units and appear to occupy earlier synvolcanic structures. Regional greenschist- assemblage metamorphism and pervasive deformation affect all units. Thrust faults moved part of the Brouillan batholith and basement units over the Mine Sequence. Although there is no relationship between the earlier mineralizing events and these late thrust faults, the thrust faults probably played an important role in location of ore lenses. Three types of mineralization are present: 1) copper-rich veins and hydraulic breccias; 2) disseminated and stringer, low-grade and high volume zinc-copper mineralization; and 3) finely laminated, massive, locally silver-rich pyrite mineralization within structural basins. At the bottom of these basins and at the contact of welded acid tuff (WAT) units, massive pyrite zones are locally enriched in zinc, and contain the possible vestiges of black smoker-like material. The ore metals were probably derived from leached basement andesitic volcanics in a hydrothermal system powered by one or more heat sources within the Brouillan Volcanic Complex. The Selbaie deposits are mainly characterized by: (1) the presence of small volcano-tectonic subsidence basins, which host chemical sediments and volcaniclastic materials; (2) pervasive potassic alteration; (3) locally high-grade silver mineralization (up to 1-2 kg/t Ag); and (4) the presence of random zones of Pb mineralization. The Selbaie deposits can be closely compared with the copper-rich Murgul deposits, which belong to the eastern Pontides metallogenetic province in Turkey. If conventional classification criteria for the volcanogenic massive sulfide deposits (e.g., Noranda, Mattabi types, and recent subsea floor deposits) are taken into account, the Selbaie deposits still exhibit many differences in terms of alteration assemblages, physical volcanology and some styles of mineralization (low-grade and large volume). Consequently, the "Selbaie" deposits belong to a new sub-type of volcanic-associated sulfide deposit, which may be used in future exploration programs."

Jan 1, 2000

By H. K. Fredrickson

"Midwest Joint Venture (MJV) owns a high-grade uranium deposit in northern Saskatchewan. The deposit is located too deep below surface to be mined economically by open pit methods, and as a consequence, present plans are that it will be mined by underground methods. High-grade uranium ore of the type at MJV, encased in weak, highly altered ground and with radon-rich water inflows, has not before been mined by underground methods.The test mining phase of the project, completed in 1989, had three objectives: 1. to evaluate radiation protection requirements associated with the handling of large quantities of radon-rich water and mining highgrade uranium ore in an underground environment; 2. to investigate the quantity and quality of water inflows into the mine; and 3. to investigate ground conditions in and around the ore zone as an aid in determining the production mining method to be used.With information gained from the test mining project, a mining method for the production mine has been devised. Level plans have been drawn up, ventilation system designed, pumping arrangements made and methods of ore handling considered. All this is to be done in a manner that will be safe for those doing the work underground. Some of the mining methods planned are felt to be unique in that they are designed to cope with mining problems not known to have been encountered before. New problems underground have required new methods to handle them. Remote drilling, blasting, mucking and backfilling form the basis of the planned mining method."

Jan 1, 1992

By S. Hussien, P. Somasundaran, P. Patra

"Rare earth elements (REEs) are essential for many applications in electronics, energy harvesting, and defense. The common resources for economic extraction of REEs are oxides such as bastnaesite and monazite, which are scarcely available in the earth’s crust. On the other hand, REEs are available in many clay and phosphate ores where REEs substitute Ca or Si in the mineral lattices or as physically adsorbed cations at negatively charged sites on the clay surface. While REE oxides readily dissolve in acid, making the chemical leaching of REEs an economically viable option, adopting a similar approach for leaching of silicates and phosphate ores is unfeasible because of significantly low REEs content in these ore deposits. Bio-leaching approaches are environmentally benign and economically viable. We investigated the bio-leaching (Acidothiobacillus ferrooxidans (Af) and the fungal Aspergillus niger (An)) of REEs from a phosphate ore, and examined the factors governing the leaching processes. Based on the shake flask leaching studies, an increase in surface area combined with an increase in pulp density (1-15 wt. %) was found to lead to an increase in the amount of REEs leached. In contrast, an increase in the surface area by reducing the particle size from 75 to 35 led to a decrease in the amount of REEs leached. These differing attributes are proposed to be due to the poor bacterial growth/activity with high F- ions in the leaching media, F- released from the edge-sites of the smaller particles. On the other hand, several advantages that associate with the Af bacterial bio-leaching processes relate to the media composition (Mg2+ and (NH4)+) and phenomena occurring at the electrical double layers of the mineral and bacterial- water interfaces. These studies suggested that leaching of particles occur in a layer-by-layer manner.INTRODUCTIONRare Earth Elements (REEs) are essential for many important applications, such as in electronics, energy generation, and defense. The common resources for economic extraction of REEs are typically carbonates such as bastnaesite and monazite, which are scarcely available in the earth’s crust (Y. Kanazawa and M. Kamitani, 2006). REEs are abundantly available in many clay and phosphate ores where REEs substitute Ca or Si of the mineral lattices. Conventional acid leaching of REEs from oxides is not economically feasible for clay and phosphate ores because of significantly low REE content (parts per billion) in these ores (Tian, J., Chi, R., Yin, J., 2010a; Moldoveanu G. A. and Papangelakis V. G., 2013; WK Goyne, LS Brantley and J Chorover, 2010). In some cases, REEs could be extracted from these ores via chemical leaching routes as they constitute reasonable amounts of REEs (0.1 - 1% REEs). A major challenge faced in general in chemical leaching processes (Chi, R., 1988) is the loss of REEs in the phosphate/gypsum precipitates/crystals, which are overcome in a step-by-step manner by sequentially removing impurities such as fluorine and calcium, including steps carried out at elevated temperatures. On the other hand, bio-leaching approaches provide environmentally benign and economical alternatives. Acidophilic bacteria are currently being used for industrial scale bio-leaching of Au/Cu/Ni from low grade ores. Studies on bioleaching of REEs from red mud (Al2O3) using Penicillium tricolor and Aspergilus niger (An), and, of bio-leaching (lab-scale) of phosphate rocks using Acidithiobacillus ferrooxidans (Af) have been reported (Boon, M., Heijnen, J.J., 1993; Qu, Y. and Lian, B., 2013). We conducted bacterial (Af) bio-leaching of REEs from a phosphate ore in shake flasks and columns, while examining the key factors that govern leaching kinetics."

Jan 1, 2016

By P. I. Laforest, M. S. Moats

"Antimony in smelted copper anodes has been shown to cause problems in electrorefining including brittleness of starter sheets. In order to improve deposit properties, a study was conducted examining the effect of anode chemistry on cathode ductility and electrolyte chemistry. Two industrial anodes with different molar ratios of As/(Sb+Bi) were used in laboratory electrorefining experiments with commercial electrolyte, and the addition of commercial glue and Avitone. The ductility of 21-hr copper deposits was evaluated by a 180° bend test. X-ray diffraction (XRD) and metallography were performed on unbent specimens to characterize the deposit structure. Increasing the anode As/(Sb+Bi) molar ratio from 0.54 to 3.8 resulted in an increase, on average, from four to eight bends to failure in cathode material produced. Significantly lower concentration of antimony (V) in the electrolyte was detected when operating with the higher molar ratio anode. The presence of (111) and (200) planes was noted in cathode material produced from the higher molar ratio anode suggesting that mixed growth character could be responsible for the observed increase in bend test results. The ductility of the starter sheet materials was improved by a higher anode molar ratio.INTRODUCTIONThe presence of antimony in copper electrorefining electrolyte has been reported to cause problems in cathode production (Hiskey, 2012; Peng, Zheng & Chen, 2012; Wang, Chen, Zhou-Lan & Lian-Sheng, 2006; Wang, Chen, Zhou-Lan, Wang, Xiao & Zhang, 2010; Wang, Chen, Zhou-Lan, Wang, Xiao & Tang, 2011; Wesstrom, 2014). To better understand the impact of antimony, laboratory scale electrorefining experiments were conducted using industrial inputs (anodes, cathodes and electrolyte). The influences of anode chemistry on the valences of antimony and arsenic in the electrolyte were monitored and correlated to physical cathode characteristics, such as a bend test to failure and crystallographic orientation.Commercially, starter sheets are produced by electrorefining impure cast copper anodes onto titanium blanks. The starter sheets are then hung in an electrorefining or electrowinning cell using loops of bent starter sheet material. These loops, in the absence of sufficient ductility, fail resulting in cathodes falling into the electrolysis cells. It is thought that the reduction in ductility can be related to anode composition; in particular, the molar ratio of arsenic to antimony plus bismuth As/(Sb+Bi). It has been stated that maintaining this ratio above 2:1 results in numerous improvements to electrorefining operations (Baltazar, Claessens & Thiriar, 1987; Kamath, Mitra, Radhakrishnan & Shetty, 2003; Krusmark, Young & Faro, 1995; Noguchi, Itoh & Nakamura, 1995; Wenzl, 2008)."

Jan 1, 2016

By Bern Klein, A. Tugba Cebeci, Libin Tong

"Sensor based sorting faces two main challenges related to limited capacity/throughput and the ability of sensors to accurately discriminate based on estimated grades. This paper is aimed at improving sensor discrimination. Sensors have the ability to measure more than a single response. X-ray fluorescence (XRF) can detect and provide concentration information about a range of elements. Similarly, electromagnetic sensors (EMs) can generate magnetic susceptibility and conductivity responses over a range of frequency levels. The sensors thereby provide a response signature rather than a simply a single response that is a proxy for a metal grade. Furthermore, integrating sensor responses can improve the discrimination of metal bearing rock from waste. A study was conducted on a gold ore to assess sortability using XRF and EM sensors. A multi-variable regression approach was used to develop models that included a range of responses. Correlations improved significantly when compared to single response correlations. The approach showed that both positive and negative correlations contributed to the improved correlations. Stepwise regression simplified the models and showed that 2nd order interaction effects can be important. The approach also showed that combining different responses can improve discrimination accuracy. An important outcome of the study was that an ore that had been consider not to be sortable was determined to be sortable through the application of an approach that used the sensor responses in a more intelligent manner.INTRODUCTIONMining is aimed at recovering valuable minerals from their host rocks. Many methods are used to recover valuable minerals, and finding efficient and cost-effective ways is the key in research and production. . Ore sorting technology is fitting this definition. It not only discards waste rocks away from the concentrator but also recovers metal bearing ore particles that could be lost to the waste dump. The benefits of ore sorting include increased energy efficiency and reduced water and reagent usage in the downstream operations (Bamber, 2008; Gunson, Klein, Veiga, & Dunbar, 2012; Mazhary & Klein, 2015; Robben, Wotruba, Robben, von Ketelhodt, & Kowalzcyk, 2013)."

Jan 1, 2016