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By F. R. Ploeger, J. H. Crocket

"IntroductionRocks in the Kirkland Lake district form part of the Timiskaming Group, a south-facing homoclinal sequence of wackes, conglomerate, trachytic flows and pyroclastic rocks and syenitic intrusive rocks. Hewitt (1963) indicates that the thickest section, about 5 km, of the Timiskaming Group rocks is attained in Lebel Township. Several writers (Thomson, 1948; Hewitt, 1963; Hyde, 1978; Jensen, 1978; and Downes, 1979) have observed that the Timiskaming Group unconformably overlies the Keewatin volcanics, particularly along the northern contact. Recent work by Downes (1979) in McGarry and McVittie townships to the east of Kirkland Lake has shown that much of what had formerly been classified as Timiskaming actually belongs to an older group of rocks, the Larder Lake Group (Jensen 1978).General GeologyA series of fluviatile, braided-stream sedimentary rocks (Hyde, 1978) form the oldest of the three major rock suites at Kirkland Lake. Conglomerates constitute a large proportion of these sedimentary rocks and typically contain a large percentage of a variety of locally derived alkalic rock clasts as well as the distinctive red jasper iron-formation pebbles (Fig. 1a). The associated wacke units can be massive to finely bedded and are interbedded with the conglomerate. They also contain a large alkalic tuffaceous component.Interbedded with these sedimentary rocks are alkalic extrusive rocks, including tuffs, agglomerates, breccias and flows, which represent episodes of fissure and explosive crater eruption (Cooke and Moorhouse, 1969). The tuffs, although dominantly alkalic in composition, are commonly reworked and contain sedimentary features such as graded bedding, scouring and crossbedding (Fig. 1 b). The trachytic flows are massive to porphyritic and outcrop mainly east of Kirkland Lake in the adjoining townships. Altered leucitic porphyritic flows, locally referred to as red and green spotted trachytes, commonly occur."

Jan 1, 1982

By C. V. Corless

THE origin of various types and groups of ore deposits was some years ago a subject of much controversy. To this statement the copper-nickel deposits near Sudbury afforded no exception. Not since the Report of the Ontario Nickel Commission, in 1917, has there been any serious discussion of the origin of this very important group. This may be because, from the opening-up of Murray mine by the British America Nickel Corporation until the recent work at Frood mine, no new ore-body of importance has been developed in the district. The controversy fifteen or twenty years ago between those who favoured the theory of magmatic segregation, among whom Dr. A. P. Coleman was the leading exponent, and those who considered that most, if not all of the Sudbury deposits could more satisfactorily be accounted for by the theory of replacement, will be remembered by many members of the Institute. Perhaps, as too often happens in controversial discussion, each side tended to overemphasize the importance of those geological phenomena which seemed to be most easily accounted for by the theory it favoured. A more balanced view would perhaps admit that replacement was probably predominant in the formation of most of the offset deposits, and magmatic segregation in that of most of the marginal deposits . But there is danger in generalization. Each body of ore should be studied by itself, and no general conclusion of this kind should be allowed to warp the judgment in making such a study.

Jan 1, 1929

By S. M. Fatemi-Varzaneh

The AZ31 magnesium alloy is considered as a promising alloy in various applications and industries. Furthermore, to design a proper hot working process (rolling, forging and extrusion), the assessment of hot working behaviour of the alloy is necessitated. Accordingly, the hot deformation behaviour of AZ31 alloy was studied through hot compression testing method. The latter was carried out in a wide range of temperature (523 K to 783 K) and strain rates. The obtained true stress-true strain curves and final microstructures were examined and a partial melting was realized at 740 K. It was concluded that the presence of liquid did change the deformation mechanisms thereby affecting the flow behaviour.

Jan 1, 2005

By Gunther F. Leichtle, James A. Finch, Colin A. Hardie, Cesar O. Gomez

"The recycling of wastepaper has become an important and common process worldwide. Techniques similar to those used in the mineral processing industry are used to produce high quality recycled fibers for use in newsprint. The mineral processing group at McGill University in conjunction with the Pulp and Paper industry (Mechanical and Chemi-mechanical Wood Pulp Network) has adapted one of these techniques, column flotation, for the purpose of deinking wastepaper. This article describes the typical process of recycling wastepaper from a mineral processing point of view. It also presents results from McGill University's flotation column test work at a Quebec wastepaper recycling facility.IntroductionThe recycling of wastepaper has become an important and common process worldwide, including Canada which is now the world's largest importer of wastepaper (CPPA, 1996). Much of the current drive to increase the utilization rate of recovered paper is a reaction to the solid-waste disposal problem that faces many Canadian and U.S. municipalities. The real problem in the disposal of solid waste is not the absolute amount of garbage that must be disposed of each year but this amount in relation to available disposal capacity.Environmental restrictions on the creation of new landfill sites and incinerators (the two main options for disposal of municipal solid waste) have tightened the demand/supply balance in the solid waste disposal market. This shrinking availability of waste disposal sites in the face of increasing population with greater disposal requirements defines the Developed World's solid waste crisis. Not only are there fewer disposal sites available, but the costs of using them is skyrocketing. These factors have increased government regulations mandating recycled paper content in newsprint. Conservation and environmental issues make the current drive for wastepaper recycling a real issue and business opportunity.A key to the success of producing quality recycled fibers from wastepaper is the deinking technology. The production of tissue papers, paper towels and newsprint requires regenerated fibers which are substantially free of ink particles. Of the various options available, mineral processing techniques can offer the most economical, environmentally acceptable and versatile strategies (Yoon, 1993). Today, it is recognized that flotation is one of the most effective processes for removing ink particles in the production of a high quality product. In a collaborative program with the Pulp and Paper industry, the mineral processing group at McGill University has adapted column flotation technology for this purpose. This article will describe the typical process of deinking from a mineral processing point of view (Part A). It will also present some results from McGill University's flotation column test work at a nearby paper recycling facility (Part 8)."

Jan 1, 1998

By E. Cauda, K. Phillips

"Diesel particulate matter (DPM) exposures are a serious occupational health hazard in underground mines. While the complex nature of DPM makes direct analysis difficult, its primary component, elemental carbon (EC), can be used as surrogate. The near real-time FLIR Airtec monitor measures EC mass based on laser extinction. It was developed for use in underground metal/non-metal mines, and calibrated to the NIOSH Method 5040. Its effectiveness has not been demonstrated in coal mines, however, where coal-sourced EC could produce analytical interference. To gain preliminary insights regarding the Airtec’s performance in the presence of coal dust, experiments were conducted in a controlled laboratory chamber. The Airtec EC results consistently underestimated Method 5040 EC for both respirable-sized and submicron coal dusts. While underestimation of coal-sourced EC bodes well for limiting coal interference for DPM measurement, one key reason for the observed trend was non-uniform coal particle deposition on the Airtec filter. This may be problematic in coal mines where DPM and coal dust occur together in the instance that DPM deposition is also non-uniform. INTRODUCTION Diesel particulate matter (DPM) is an occupational health hazard, and underground miners have the potential for relatively high exposures due to their work in confined environments with large diesel equipment (NIOSH, 2011). DPM is heterogenous and complex in terms of its chemical composition (Birch & Cary, 1996; Noll et al., 2006), but elemental (EC) and total carbon (TC) are often used as analytical surrogates (Birch & Noll, 2004; Noll et al, 2015). EC is the solid “soot” component of DPM, whereas TC also includes particulate organic carbon (OC) (Noll et al., 2007). EC and OC can be measured in filter samples using the standard NIOSH Method 5040 (NIOSH, 2003), and summed to obtain TC. In US mines, TC has been adopted as the analytical surrogate for DPM in regulatory activities. In metal/non-metal mines, personal exposures are limited under 30 CFR Part 57. In coal mines, limitations are made on emissions from each piece of equipment (30 CFR Part 72) rather than for personal exposures. This is because coal dust has the potential to interfere with TC measurements in personal samples. In some other countries, and for non-regulatory purposes in the US, EC is also commonly used as a surrogate for DPM in mine monitoring applications [e.g., see AIOSH, 2013). EC generally exhibits a linear correlation with TC (Birch & Cary, 1996; Noll et al., 2006 and 2007) but unlike TC measurements, which are analytically intensive, EC can be determined more simply using a laser absorption/extinction principle on filter samples (Noll et al., 2013)."

Jan 1, 2019

By Michel Carreau

Renewable assets have large upfront capital costs but minimal operating expenses over their lifetimes. In some instances, deals can be structured so that direct capital investment is feasible, with paybacks typically within 5-7 years. In others, the burden of renewable CAPEX must be removed in order to create an attractive alternative to fossil-fuel-fired generation. Hatch has designed and oversees the construction of a renewable installation, which is financed, owned and operated by a special-purpose entity. Renewable energy is then delivered to the mining company via a customized power purchase agreement at a price that is lower than the levelized cost of fossil fuels. In this way, the mining company removes the burden of the renewable energy CAPEX from its balance sheet, thus freeing up capital, decreasing risk, and making the predictable, lower cost of renewable power more attractive than the variable cost of fossil fuels. This paper presents the above business model and success stories of hybrid power at remote sites (wind and solar coupled with diesel engine).

Aug 1, 2013

By Peter A. Witt

Highland Valley Copper is a conventional truck-shovel mining and flotation concentrator operation located some 75 kilometres southwest of Kamloops, B.C. (Figure 1). The ore is within a porphyry deposit and is mined at a rate of 135,000 metric tonnes per day from two separate open pits. The nearby mill produces concentrates containing 375 million pounds of copper and 5 million pounds of molybdenum metal yearly. Head grades are roughly 0.40% Cu at a 0.23% Cu equivalent cut-off. The strip ratio currently sits at 0.55:1 with waste quantities made up of separate rock and unconsolidated overburden units. From the mill, concentrates are trucked to nearby Ashcroft and then hauled by rail to ocean port facilities in Vancouver. The mine employs 950 persons and is planned to operate until 2009. The operation is a partnership between three owners: TeckCominco (61.4%), BHP Billiton (33.6%), and Highmont Mining (5%). Management is shared by the two principal owners and directed by an appointed committee.

May 1, 2002

"In mills, metallurgical efficiency is important in every step of the operation through to the tails. Different problems which hinder metallurgical efficiency exist in different mills. One such problem occurred in the Bralorne mill at the tailings end of the circuit, where the washing efficiency of the filters was so low that serious losses in dissolved gold occurred.The new cyanide plant at Bralorne went on stream in August 1961. Test work done showed that: a flowsheet of grinding in water, jigging, thickening, agitating, followed by double filtration, gave satisfactory results and was more economical than a counter current plant. Two filters, 141 x 161, with approximately 700 square feet of filtering surface on each, were purchased and installed in series. Test work showed that this was ample filtering area for 500 tons per day.When the plant started up a density of 45% solids was maintained in the agitators, and a 20 ounce cotton dl1ck was used on the filters. Vacuum was between 23 - 25 inches. Under these conditions the filters would not work and only picked up a very slight skim of pulp. Various speeds were experimented with, 4 minutes per revolution being the most efficient. At this speed the thickness of the pulp on the filters increased to about 1/8”• It was therefore quite apparent that, under these conditions, the filters would not handle very much tonnage and the mill tonnage would have to be reduced drastically until the problem was solved."

Jan 1, 1967

By Frank Ebbutt

Introduction The property of the Britannia Mining and Smelting Company, Limited, is situated on the east side of Howe sound, about six miles from its head. It is roughly thirty miles by water from Vancouver, one of the important ports of the Pacific and the industrial and financial centre of British Columbia. Howe sound is navigable for ocean-going vessels and Britannia Beach is a daily port of call for the commodious boats of the Union Steam-ship Company, sailing from Vancouver. Few mines are so ideally situated or have so many or varied natural advantages. Copper was first found on Britannia mountain in 1888, by Forbes, but it was not until 1898 that five claims were staked here by Oliver Furry, a trapper. It is from these claims that the major production during the past thirty years has come. In 1900 the Britannia Copper Syndicate was formed and development of the property was commenced. In 1903 the late Grant B. Schley obtained control, and through his efforts the Britannia Mining and Smelting Company was organized in 1908 as a subsidiary of the Howe Sound Company. Since that time, a persistent and progressive policy has been followed, which has resulted in a prolonged and profitable operation. The country in the immediate vicinity of the mine is marked by strong relief, with mountains rising abruptly from tide-water to elevations of 5,000 feet and more. Two broad transverse valleys deeply dissect the area. These are the valleys of Britannia creek and Furry creek. The region has under-gone prolonged and relatively recent glaciation. Over much of the surface there is deep overburden and dense vegetation. The geology of the mine and vicinity has been described in reports by S. J. Schofield (1), H. T. James (2), J. G. Barry, and others (3). The present writer is in accord with much of this literature on Britannia, but during recent years, extended observations made underground have shown that the 'quartz porphyry', or 'mine porphyry', of several of the earlier writers is not the host rock to the commercial mineralization; and he contends that the mineralization occurs in highly altered phases of a complex series of ruffs, flows, and pyroclastics and their autoclastic metamorphosed products.

Jan 1, 1935

By Paul Stothart

Context ? Industry is active in urban, rural, and remote regions ? Faces a range of environmental challenges and ?social license? issues ? There are also Aboriginal and northern issues ? Also very active internationally, with associated challenges ? Environmental/social groups often target the industry ? The important contribution of the industry should not be overlooked Useful Minerals and Metals Minerals are intrinsic to the residential, municipal, communications, and transportation infrastructure of modern life. Examples: Hybrid motors - nickel hydride batteries Water purification systems ? nickel, rare earth elements Catalytic converters - cerium Screens and monitors - several rare earth elements Clean electricity - uranium Circuitry - gold, copper, aluminium, lithium, titanium, silver, cobalt, zinc Instruments - copper, silver, nickel, cobalt, copper, brass Protective products ? zinc, calcium carbonate, sulphur

May 1, 2008

By Mauro Chiesa

An Overview on the Presentation A.The Markets ?Mining Industry ?Capital Markets ?A Six-Cell Matrix of Strategic Options B.De-Risking The Mining Assets ?The Value-Added ?The Assets: Current and in Development ?The Feasibility Study C.(Questions, and answers) Post-Crunch: Some Maxims ?Three Metal Market Models No Longer Prevail ?New models are uncharted: ?be prepared?(ref: Lord B-Powell). ?Capital markets are pricey & uncertain: be your own financier first ?focus on value and on cash-flow (not oz, lbs, tonnes, LOMs, etc) ?Know your banker/financier(and it should know mining) ?In the past, it was ?know your borrower? ?It?s a buyer?s market that wants the ?right deal?: so cast a big net: ?Data must be current, concise and consistent ?3rdparty validation of feasibility work is now a ?passport? ?The risk matrix, with de-risking, is as important as the ?math?

May 1, 2011

By Mauricio Olivares

About Largest combined Phosphate and Potash company in the world Corporate headquarters in Plymouth, Minnesota Publicly traded on NYSE under MOS

Aug 1, 2013

By Raj Thamburaj, Li. Ping, Prakash C. Patnaik

"An effective prognosis system for aircraft engines may involve the application of a wide range of technologies and methodologies, which may include: - On-line, real-time and in-situ non-destructive inspection/detection/sensoring - Aircraft/engine instrumentation - Airborne data recording system - Advanced signal filtration - Data compression technologies - On-line engine health monitoring technologies - On-line engine component life usage monitoring technologies - Mission severity analysis algorithm based on life prediction and damage tolerance analysis models - Life assessment methodologies - Optimized repair/overhaul/maintenance planning - Optimization of mission assignment and homogeneous life usage - Web-enabled information delivery and sharing system - Decision making logistics This paper will demonstrate some efforts that Orenda has accomplished over the last decade in collaboration with the Institute for Aerospace Research of National Research Council Canada and the Department of National Defense. The presentation will focus on the following projects:"

Jan 1, 2004

An optimized long-term mine planning determines the best order of material extraction, so that the Net Present Value (NPV) becomes maximum. In the case of oil sands surface mining, one of the key constraints in NPV maximization is the volume of tailings slurry that will be generated downstream. Specifications of tailings slurry are also important from environmental perspective. Moreover, most of the material that will be used for the reclamation of tailings ponds in later periods is generated in extraction and processing of oil sands. In this paper, an integrated optimization framework is proposed to maximize the NPV of the produced oil sands, with respect to tailings capacity constraints and reclamation material requirements. A mixed integer linear programming (MILP) model is developed to find the optimal solution for long-term mine planning problem. The proposed model is coded in Matlab and has been run using CPLEX for verification. The results for real-case oil sands dataset show that the optimal production schedule meets material requirements for reclamation, tailings volume is within tailings capacity range in all periods and the production schedule follows the predetermined horizontal direction.

Aug 1, 2013

By E. W. Johnson

"The current increase in gold price may presage a resurgence of gold milling plants in Canada similar to that of the thirties. Because the industry has been at a low ebb for almost two decades, future operating responsibilities will likely devolve upon personnel with limited cyanidation experience. My comments, which may seem elementary to experienced operators, are directed towards these industry newcomers to highlight operational features in cyanidation which forty years' experience has shown me to 0e of importance. A brief review of what actually takes place in a cyanide circuit may help give a better understanding of the topics to be discussed.These will include: (1) expose the gold (2) dissolve the gold(3) make solid/liquid separation(4) recover the gold from solution.1. Expose the GoldThe chemical key to gold recovery by cyanidation lies in the ready solubility of the metal in a relatively weak solution (0.04%-0.075% NaCN equivalent by weight) of calcium or sodium cyanide. Obviously, dissolution cannot start unless the cya1ide is in contact with the gold. As an analogy, the yolk of a hard-boiled egg can oe taken to represent the gold particle and the egg white and shell, the surrounding gangue or sulphide host. As the sl1ell and white must be fractured to expose the yolk, similarly the surrounding gorngue or sulphide host must be broken or fractured to enable the cyanide solution to contact the gold."

Jan 1, 1979

By Karl J. C. Harries

"9.1. INTRODUCTIONIn Chapter 5 of Volume I royalties are dealt with and several topics would appear to be duplicated in this Volume. However, Volume I may be looked upon as a general guide, whereas this Volume is a reference volume. It deals in considerable detail with specific provisions and concepts relating to royalties between private parties. This does not, however, mean that Chapter 5 can be ignored. It should be looked upon as a source of general information concerning royalties between private parties and as a negotiating aid intended to give an overview of various topics. You may well find that in its general approach it will lead you to ask a question which, hopefully, will be dealt with in this Volume .It should be remembered that royalty agreements are agreements with a particular focus, and so the concepts set forth in Chapter 1 apply to them. This chapter addresses a few considerations specific to royalties that will usually form part of an agreement rather than a stand-alone agreement.9.2. FORMAT FOR ROYALTY PROVISIONSIn many of the cases where royalties arise, they are adjunct to, or part of, other arrangements. For example, a royalty may form part or all of the consideration to be given to an owner upon purchase of his property, or it may arise if a joint venturer ceases to contribute to the venture and has his interest converted to a royalty.1 It is with such situations that this section primarily deals; if the royalty is contained in an agreement that is singularly, or primarily, concerned with creating it, then it is just a normal agreement.Commonly, by the time the right to receive the royalty arises, at least some of the other provisions of the agreement have been performed and/or become redundant. For example, in an option agreement the royalty will be a continuing obligation of the optionee, usually arising only after the option has been exercised.2 In a joint venture agreement, a royalty will often arise where the interest of a non-participating venturer has been diluted and converted to a royalty, in which case the recipient will usually become a passive party, entitled only to his royalty, and most of the rights that he enjoyed as an active venturer will cease to be effective."

Jan 1, 2003

By Yuwang Wang, Yanggeng Tan, Kezhang Qin, Zengqian Hou

Abstract- The large Derni Cu-Co (-Zn) deposit in Qinghai Province exhibits unusual geological features, and its genesis is controversial. Based on previous research and detailed field investigations, petrographic studies of the host volcanic rocks, isotope and trace element geochemistry of the sulfide ore, and comparison with typical ore deposits, this deposit is a VHMS (submarine volcanichosted massive sulfide deposit) type. This argues against previous interpretations of a magmatic or a hydrothermal replacement origin. Systematic rock, mineral and geochemical studies of the host serpentinites of the ore district indicate that the protoliths of several types of serpentinites that are widespread in the ore district are mainly ultramafic volcanic rocks. The mineralization formed within an ultramafic volcanic breccia, or between the breccia and its overlying Mg-rich carbonate rocks and volcanic sedimentary rocks. The ore-forming components were derived mainly from ultramafic rocks and partly from mafic rocks. The ultramafic rocks are MgO-rich, CaO-poor with a high MgO/FeO ratio, and the mafic rocks are rich in Na2O and poor in K2O. The chemical composition of the ultramafic rocks is similar to that of volcanic peridotite, or komatiite. The volcanic rocks that host the Derni deposit are among the most basic host rocks known for VHMS deposits, and the Derni deposit represents the most basic member in the VHMS deposit spectrum.

Jan 1, 2000

By Yves Pépin, Sylvain Lefebvre, Dimitrios Filippou, Guillaume Hudon

"Titanium dioxide pigment plants using the so-called “chloride process” produce considerable amounts of chloride waste, which contains predominantly iron chloride. In most cases, this waste is dissolved in a weak hydrochloric acid solution and then neutralised. The metal content of the waste is dumped as hydroxide sludge, while its chloride content is lost in an effluent.Rio Tinto Iron & Titanium has developed a new proprietary process whereby pure metallic iron and chlorine gas are recovered from chloride waste by electrolysis. This process uses a two compartment cell separated by an anion exchange membrane to prevent iron cycling between its trivalent and divalent valence. The cathode is made of titanium Grade 7, while the anode is a dimensionally stable one of the type “metal–mixed metal oxide” (MMO) for the evolution of chlorine gas. The catholyte is concentrated and pH-adjusted iron-rich chloride solution originating from chloride waste. The anolyte is recirculating solution containing alkali or alkali earth chlorides such as MgCl2, NaCl, etc. Current efficiencies above 90% can be achieved at temperatures about 80°C using catholyte solutions almost saturated in iron chloride and other chlorides.In this paper, we discuss the details of this process, and how this could be integrated within a chloride pigment plant for the treatment of chloride wastes."

Jan 1, 2016

By H. Yoshida, H. Hatta, T. Suzuki

"The effect of the copper and magnesium contents and quenching rate during quenching on the age hardening behavior of 2000 series aluminum alloys was investigated. For the higher copper-containing specimens as conventional alloys, like AA2024, precipitation of the stable phases increased as the quenching rate decreased under the as-quenched conditions. The maximum hardness after the artificial aging of air cooled(AC) specimens was much lower than that of the water quenched(WQ)specimens. On the other hand, for the lower copper-containing specimens, coarse precipitation did not increase even in the case of the AC. The age hardening behaviors of the WQ and AC were very similar such that the maximum hardness and aging rate were almost the same. Many parts of the fine precipitates that increased the hardness were thought to be the GPB zone or fine S’ phase for the WQ and relatively coarse S’ phase for the AC. From the calculated CCT(continuous cooling transformation)diagrams, the lower copper-containing specimens could maintain the copper and magnesium in the solid solution state during the AC, so they could be quenched at a rather slower quenching rate like the AC.INTRODUCTIONThe 2000 series aluminum alloys, containing copper and magnesium as the major chemical components, are some of the well-known heat treatable aluminum alloys. These alloys have a high quenching sensitivity, thus the age hardening ability of these alloys decreases with as low quenching rate. To prevent the decrease of the age hardening ability, quenching is done by a method such as water quenching, which is not very efficient in an industrial situation, because the method requires such large equipment. For these alloys, reducing the quenching sensitivity helps them to be produced in a rather convenient way. For example, 6000 series alloys such as A6063 have low quenching sensitivity, thus they could be quenched by only air cooling just after extrusion and they do not need water quenching. Based on these reasons, investigations of these alloys with high copper and magnesium contents have been conducted in the past to find a way to lower the quenching sensitivity by adding transition elements such as manganese, chromium and zirconium (Kanno, Suzuki, & Itoh, 1986; Suzuki & Itoh, 1986; Kanno, Sakuma, Muromachi, & Watanabe, 1988). However, very few studies have focused on the quenching sensitivity of the lower copper and magnesium containing alloys because of their usage for structural components with high strength, and most of the past studies have used only the fast quenching method like water quenching. On the other hand, from our recent results, there is a possibility to lower the quenching sensitivity of 2000 series alloys with lower alloying elements. In this paper, the effect of the copper and magnesium contents with lower alloying elements and quenching rate, especially in case of slower quenching rate than conventional quenching method, on the age hardening behavior of the 2000 series alloys is investigated by the hardness measurement, structure observation and thermal analysis."

Jan 1, 2018

By J. Ipinza, J. P. Ibáñez, Casas J., S. Cortés

Copper powder generated during the treatment of electro-metallurgical bleeds by reactive electro- dialysis (RED) had totally reduced the content of ferric ions in acidic synthetic electrolytes (Cu (II)- Fe (III) – H2SO4). In batch and columnar experiments 100% of the ferric ions were reduced to ferrous ions with an extremely high kinetics. A preliminary conceptual design for reducing ferric ions based on an integrate RED- Column for treatment of electro-winning bleed system is discussed. This system is able to recover simultaneously sulfuric acid and copper powder, which will reduce ferric ions. INTRODUCTION It is well known the negative effect of ferric ions in the copper electro-winning process. The increase of ferric content in the electrolyte reduces the current efficiency, i.e., there is an increase in the energy consumption, and changes the surface morphology of the copper deposit (Das, Gopala & Krishna, 1996; Vargas & Parra, 2013). The increase of the specific energy consumption due to the loss of current efficiency occurs by the reduction reaction of ferric to ferrous ions in the cathode, at the anode the ferrous ions are slowly oxidized to ferric ions (Shaw, Dreisinger, Lancaster, Richmond & Tomlinson, 2004). To control the level of iron in the electrolyte, bleeds are needed; this bleed electrolyte containing copper, sulfuric acid, cobalt, iron and other impurities normally is waster, which increased the production cost of the plant (Milbourne, 2002; Mckevitt & Dreisinger, 2009). Then, permanent efforts oriented to treat those bleeds to avoid losses of valuables components are made; among them are use ion exchange resins (Shaw et al., 2004; Mackevitt et al., 2009), chemical precipitation (Izadi, Mohebbi, Amiri & Izadi, 2017) and electrodialysis (Cortés, Ipinza & Ibáñez, 2013). The last one allows to the simultaneous recovery of sulfuric acid and copper powder. If one of the valuables obtained by treating the bleed can be used to reduce ferric ion concentration in the electrolyte could be an important asset. This issue at laboratory scale is reported in this work, the use of copper powder, generated by reactive electro-dialysis when treating synthetic acidic electro-metallurgical bleeds, for reducing ferric ions in acidic electrolytes.

Jan 1, 2019