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By John A. Allan

Introduction There are times when meditation on the past is worth while. Too often does it happen that in the busy routine there appears t9 be little time for reflection, and little good or benefit to be derived from what has already taken place, or what has become past achievement. Under conditions such as those that prevail at present, consideration is being given to many subjects that a few years ago were not looked upon as worthy of time or thought. The temporary lull in industrial development is permitting of a stock-taking investigation, a perusal of past activities, and a planning for future development with the return to normality. It is not proposed to include much new data in this address, but the endeavour will be made to survey, in resume, the sequence of events which led up to the birth of the mining industry in Canada, and to show how, as new discoveries were made, the centres of interest changed from time to time until mineral development extended across Canada from the Atlantic to the Pacific. It will appear, also, that external causes have accentuated mineral development at one time and retarded it at another. Early Records A, historical background to the mining industry extends even to an earlier date than the discovery by white men of that part of the continent of North America represented by Canada. It has been stated that the aborigines were still in the neolithic stage when the white man arrived. One metal only was known to the natives, and that was copper, obtained from possibly many parts of Canada, but particularly from the shores of lake Superior in Ontario, from the Coppermine river on the Arctic coast, and from die coastal regions of British Columbia.

Jan 1, 1933

By C. Harold Riches

This article is directed co a commentary on the patent system in its relation to the public interest. As man gained supremacy over his environment, he could devote progressively increasing portions o his time to improving his standards of living. In the history of the human race, we have advanced from the hollowed floating log to the modern steamship of the present age; from the sickle and flail to the reaper and combine; from the trumpet and drum as a means of communication co the telegraph, telephone, and radio; from the horse and ox cart to the automobile, truck, aeroplane, and train; and so on ad infinitum through the list of inventions on which are based the industrial and political economies and standards of living we enjoy today. It has also been a long road from the day of the alchemist and his closely guarded secrets to the era of the patent system and its storehouses of knowledge open to the world. The alchemist and the craft and merchant guilds closely guarded their secrets. In fact, they largely opposed innovations on the grounds that they might injure profits and restrict employment. In these days of unrest, with great clamour out of doors for radical changes in our political and industrial economies, it may not be untimely to examine one of the keystones which support the economic structure we know as the free enterprise system, the system which is predicated upon the right of the individual to own property. Many, through impractical idealism, ignorance, confused thinking, or blind political prejudice, advocate the substitution of ownership by the State ? for the right of ownership by the individual. As civilization has advanced to the high standards of living we enjoy today through the efforts of a comparatively few inventors, the patent system which has provided the incentive that created the inventions on which our industries and our employment are based is fully understood and appreciated by a comparatively small percentage of our people. As a result, the patent system, as a keystone in our free enterprise economy, is an apt target for destructive criticism, with the thought, possibly, that by eliminating or drastically restricting the several rights to individual ownership one by one, ownership by the State will progressively replace ownership by the individual.

Jan 1, 1949

By W. A. Lang

"IntroductionCARBONIZATION, gasification, and chemical utilization of coal are interrelated topics, which makes it difficult to review one without indicating its connection with the others. Hence, in Progress in Coal Technology, Series No. 5: Carbonization, reference was made to gaseous products recovered in the carbonization of coal, and .to a number of chemicals made from the tars, light oils, and ammoniacal liquors which are by-products of coal carbonization.In this, the sixth paper in the review series, prime consideration will be given to the complete gasification of coal to give a fuel for domestic industrial, or power purposes and a synthesis gas suitable for the manufacture of gasoline, Diesel oil, and chemicals. The hydrogenation of coal, an alternative source of liquid fuels and of chemicals, will be reviewed, as will be a number of processes for •the recovery of chemical products from coal by extraction and chemical treatment."

Jan 1, 1952

By W. A. Jones

"The Ross mine, a subsidiary operation of Hollinger Consolidated Gold Mines, Limited, is near the north end of lot 1, con. II, Hislop tp., Ontario. The property comprises the north half of lot 1, con. II, and the south onethird of lot 1, con. III. It is readily reached by a good motor road from the village of Ramore, 7 1/2 miles to the southeast on the Ontario Northland railway. The mine is being developed to a depth of 1,500 feet, and the current daily production rate is approximately 300 tons. From the inception of operations in March 1935 until December 31, 1945, 692,000 tons of ore, with a total value of $5,762,685, was milled . The silver to gold ratio of 1.48 to 1 is unusually high for Ontario gold mines.TYPE OF 0REBODIES AND MINERALIZATIONThe orebodies consist of lens-shaped and pipe-like stringer lodes and tabular vein zones composed of parallel quartz stringers. The host rocks are steeply inclined eruptive breccias and tuffs, striking N.70°W., intruded by very small stocks of red syenite. The orebodies appear to be spatially related to an intricate system of fault planes. Hydrothermal alteration is widespread and is not zonally related to individual quartz stringers. The wall-rocks contain abundant fine-grained pyrite, but gold is confined to the quartz stringers.RELATIONSHIP TO REGIONAL STRUCTURELack of outcrops has prevented the detailed mapping of the Keewatin complex in the vicinity of the Ross mine with the degree of success that has been achieved in the Porcupine area.A northwesterly trending belt of slates and greywackes, bounded by faults, forms the central part of a broad anticlinal arch about 3 1/2 miles north of the Ross shaft. Lava flows forming the south flank of the structure face south toward the mine. If the sediments are to be tentatively correlated with the large areas of Keewatin slates and greywackes of the Porcupine area, it must be assumed that they are younger than the lava flows and that they have been down-faulted."

Jan 1, 1954

By S. A. R. Keneti

Predicting the geomechanical response of the shale gas material during hydraulic fracturing operation in the field needs better understanding of their geomechanical behaviour under laboratory testing. Anisotropy is considered as a critical factor during investigation and analysis of deviated boreholes, borehole stability, stress-strain and strength behaviour, generation and propagation of fracture and fluid flow. In this study, compressive elastic modulus (Ec) of the Montney shale has been investigated in two perpendicular directions: unconfined compressive strengths test was conducted on the Montney sample to measure its Ec in the vertical direction. This value then was compared to the Ec value in the horizontal plane (i.e. foliation plane) which was previously measured throughout a Brazilian test by Keneti and Wong (2011). From the results, the representative values of Ec in the vertical and in the horizontal directions were found as 25 GPa and 40 GPa, respectively. Computer tomography technique was also employed for the experimental data interpretation.

Jun 1, 2012

By R. Le Houillier, M. Nagamori, A. J. Plumpton

"Asbestos tailings are a typical serpentine, hydrated magnesium silicate, consisting primarily of antigorite and a few per cent of unrecovered fibrous chrysotile. Serpentine has unique thermal properties in that dehydroxylating calcination at 600 to 700°C can yield an amorphous structure in which most of the magnesia is liberated from the original bond with silica and thereby rendered chemically active. The amount of activated magnesia can be quantified by selective leaching with a weak acid such as acetic acid. Many wet processes have been proposed to extract magnesium values from calcined or natural serpentine by means of various acids and their ammonium salts. However, the only commercial utilization of serpentine today is found in dry processes such as the production of fused magnesium phosphate fertilizer .The present paper reviews the physical chemistry of the dehydroxylation of serpentine and also various wet and dry processes in order to provide a general view regarding the chemical transformation of asbestos tailings.IntroductionAsbestos fibers occur as chrysotile, a serpentine polymorph. More than nine tenths of mined asbestos ores consist of massive non-fibrous serpentine, primarily the polymorph antigorite, which is discarded as tailings after fiber extraction. For many decades, Quebec has been a world leader in the production of asbestos fibers. As a result, colossal tonnages of serpentine have accumulated in the Eastern Townships'!'. Serpentine minerals are found in large deposit s throughout the world, and significant research efforts have been made, particularly in Japan and the USSR, mostly in attempts to extract magnesia or silica values therefrom.The chemical composition of serpentine (chrysotile and antigorite) may be ideally expressed as Mg3Si2Os(OH). which corresponds to 43.7% MgO and 43.3% SiO2. Natural serpentines often contain a few per cent of Ni-bearing magnetite and other impurities, and therefore the contents of MgO and Si02are both about 40% or lower.Serpentine (hydrated magnesium silicate) is virtually insoluble in weak acids. However, when dehydroxylated under controlled conditions, ' it decomposes to an amorphous state in which magnesia and silica are isolated and chemically active. The magnesia so activated is readily soluble in weak acids. This unique characteristic of calcined serpentine, first discovered in 1942,, has since attracted the attention of innumerable researchers, whence many processes have been proposed."

Jan 1, 1980

By David A. Edgecombre

This paper discusses modern practices in the extrusion of steel. Particular emphasis is given to a description of the Ugine Sejournet method of extrusion, involving the use of glass as a hot work lubricant. Other methods are also mentioned. A brief history of extrusion is presented; present practices in the quality extrusion of tubing and solids are described; and the future potentials of the) process as a tonnage producer are briefly discussed. The advantages of extrusion and the reasons for the use of a glass lubricant, as well as the various methods of using glass, are given. The process, as described, is being used in the manufacture of large commercial quantities of stainless steel tubing and sections. This extrusion process is an essential and unique means of forming such atomic-age materials as titanium, zirconium, molybdenum and other super alloys all of which are materials required in the creation of nuclear installations.

Jan 1, 1963

By James Dickson

Brief History of Discovery and Early Development In the first half of the nineteenth century, the only authority on the Pacific coast between the Columbia river and Alaska was exercised by the Hudson's Bay Company, who had established a series of forts and trading stations on the coast from the Columbia north to Millbank sound. The Hudson's Bay Company were chiefly interested in the fur industry, and the large influx of settlers from the eastern United States into the territory now known as the States of Oregon and Washington, about 1840, not only interfered with the fur business but involved the question whether the territory should be under the British or the American flag. Anticipating the possibility, later realized, of losing control of this area, the Company, in 1845, established their main fort and trading centre on the southern end of Vancouver island under the name of Fort Camosun; shortly afterwards changing the name to Fort Victoria. Realizing that their former policy of discouraging all attempts to develop any other business than the fur industry had lost them several hundred thousand square miles, the Hudson's Bay Company now set about encouraging settlers in the vicinity of Fort Victoria by disposing of lands to suitable parties and also to those in the employ of the Company. The usual pioneering stage was passed through with the starting of small sawmills, grain mills, etc., and the incidental work accompanying such efforts. Any coal required for blacksmithing or other purposes was brought from England around Cape Horn by the few ships that visited the Pacific Coast. About 1849, an Indian who was having his gun repaired by a blacksmith in Fort Victoria asked about the "black stones" used in the fire and, on being told that the "black stones" had to be brought a great distance, he informed the blacksmith that there was plenty of the same stone where his people lived. This information was immediately given to an official of the Hudson's Bay Company who talked with the Indian and told him that if he would bring some of the "black stones" he would get his gun repaired free and a present of a bottle of rum. Nothing more was heard of this coal until April of the following year, when the Indian came into Fort Victoria with his canoe loaded with coal, which was tested and found to be of good quality. It is reported that the Indian got his bottle of rum.

Jan 1, 1935

By A. M. Nordale

Let us first trace a line, mentally, across Alaska and Yukon, starting at a point in the west slightly south of the delta of the Yukon river and from there continuing eastward, loosely following the 63rd parallel of latitude until we have passed beyond the eastern border of Yukon. We will make two pronounced digressions southward to include the greater parts of the Iditarod and Tanana River valleys. That visualized line roughly defines the southern boundary of permafrost. North of it lies a vast region, fully three-fourths of the area of the two territories, which includes Seward peninsula, the great Yukon River basin, and the tractless wastes of the Arctic. During some frigorific cycle in the distant geological past, the ground there was frozen to a depth of many hundreds of feet. How deep the frost actually penetrated is not known, but it has been found to exceed three hundred feet in many places. Nature afterwards provided a perfect insulating cover in the form of heavy moss and dense grass, which has protected the ground from the heat of the sun's rays during the intervening ages. This frozen condition has always been accepted as something indigenous to the North and little thought was given to -it until recently, when the United States Government and, I believe, the Canadian Government, began extensive studies of it, particularly in respect to its effect and bearing on the development of the great oilfields of the Arctic. Within this large region and but a short distance south of the Arctic circle are the three principal producing placer gold fields in the sub-arctic, whose hubs centre at Nome and Fairbanks in Alaska and at Dawson in Yukon Territory. The geological structure and history of the gold-bearing deposits of Dawson and Fairbanks are very similar and probably closely related. They are typical placer deposits produced by stream action during periods of erosion and inundation and subsequently covered with a thick layer of fine, powdery silt mixed with decayed vegetation which, locally, is termed 'muck'. The depth of muck varies from less than 10 to more than 250 feet, with the greater depth near the lateral edges of the valleys. The gravel underlying it is medium in size, well rounded, and composed mostly of quartz and schist. The proportion of sand or fines is approximately 40 per cent. No large boulders and little clay are found, for those districts, as well as that of Nome, have not been subjected to glaciation. The most common bed-rock found is either decomposed or hard schist, but infrequently it is slate, quartz, diorite, or a porphyry. The vertical concentration of the gold is invariably on bed-rock and in the lower few feet of gravel which overlie it. The horizontal concentration or paystreak is roughly parallel to the trend of the valley but does not ordinarily coincide with the course of the present stream. The width of the paystreak usually expands from a few feet at the head of a creek to several hundred feet near its mouth.

Jan 1, 1947

By H. Oterdoom, S. Pilger, T. P. Bui, J. Rotarius

"Most FeNi furnaces used to rely on post-combustion and off-gas cooling inside the furnace to eliminate the produced CO gas, and control the off gas temperature. As furnace load, capacity, and thus gas volumes increased over the years, this led to increased instabilities that can cause problems in controlling the operation. Some of the large capacity furnaces nowadays work with partial or full combustion outside the furnace, more similar to the steel industry. Forced combustion with or without enriched air and other additions can support in controlling post-combustion, stabilizing and even reducing off gas amounts, and affecting composition. This paper presents some of the possibilities and advantages of having a specially designed post-combustion system for the FeNi laterite industry, but that could also be applied to other processes as well.Large Scale Furnaces In the FeNi industry, the Rotary Kiln Electric Furnace (RKEF) process is still going strong in spite of continuous hope that hydrometallurgical processes will one day make the RKEF plant obsolete. Within the pyrometallurgical plants there is a continuous trend for larger scale furnaces. The development for a number of furnaces that were started before 1985 and increased capacity by “natural growth” is given in Figure 1. Natural growth refers to the development of the plants that after having mastered a certain level of operation, were ready for a higher load that could be installed either with a new furnace on the same site, or during a revamp. The advantages of natural growth are numerous, for example: •,Deep knowledge of the ore and its’ behavior, no need for testing, and little risk of surprises. •,Mining, laboratory, equipment, etc. is all proven technology for the conditions on site. •,Starting a furnace with increased capacity is a re-start, not a green-field commissioning. •,Typically, when increasing the production capacity of an existing plant, not the entire plant is commissioned for the first time, but only a part. In the FeNi laterite industry for example, the kilns may already have had the capacity to provide enough material."

Jan 1, 2017

By H. O. Seigel

Induced Polarization includes many types of dipolar charge distributions set up by the passage of current through consolidated or unconsolidated rocks. Among its causes are concentration polarization and electrokinetic effects in all rocks and the phenomenon of Overvoltage in rocks containing electronic conductors such as metallic sulphides and graphite. In normal rocks the polarization effects may be usually con-fined within relatively narrow limits and any large departures may be at-tributable to the presence of electronic conductors. In practice, Induced Polarization is measured in one of two ways. In the first a steady current of some seconds duration is passed and abruptly interrupted and the slowly decaying transient voltages existing in the ~round are measured after interruption. This is known as the "pulse", "transient", or Direct Cur-rent Induced Polarization (D.C.I.P.).The second method entails a comparison of apparent resistivities using sinusoidal alternating current of two or more frequencies, generally within the range of 1/10 to 10 c.p.s. Induced Polarization extends the

Jan 1, 1962

By P. D. Barrette

This paper deals with the flow of granular materials in bins. A hybrid Lagrangian-Eulerian numerical model is introduced. The model is based on Particle-In-Cell (PIC) advection, and continuum equations describing a Mohr-Coulomb criterion. Experiments were conducted to test and verify the performance of the numerical model. Tests were done using three types of particles. Measurements of material properties and flow rates were carried out. Video records were also obtained and used to examine flow patterns. The results indicate that the numerical simulations produce deformation patterns and flow rates which are in good agreement with the experimental observations.

May 1, 2007

"Block caving is the preferred underground mining method to profitably extract massive, low-grade orebodies; however, lack of cave access inhibits understanding the rockmass response to mining, which is needed for safer, more productive operations. Combining large datasets from multiple sources with virtual reality scientific visualization (VRSV) is an alternative method for understanding complex cave behaviour, by providing virtual access to the cave. A customized VRSV module was developed at UNSW Australia to investigate rockmass response to undercut developments at a case-study block caving operation. Time/sequence effects are investigated in rockmass response to blasting, which is an important factor in hard-rock mines.RÉSUMÉ La méthode d’extraction souterraine par blocs foudroyés est la méthode préférentielle pour extraire rentablement des gisements massifs à faible teneur. Toutefois, le manque d’accès à la chambre restreint la compréhension de la réponse de la masse rocheuse à l’exploitation, ce qui est nécessaire pour obtenir des opérations plus sécuritaires et plus productives. La combinaison de grands ensembles de données de multiples sources avec la visualisation scientifique par réalité virtuelle (VRSV) constitue un autre moyen de comprendre le comportement complexe de la chambre en fournissant un accès virtuel à la chambre. Un module de VRSV sur mesure a été développé à l’Université de Nouvelles-Galles du Sud (UNSW) en Australie afin d’étudier, dans une étude de cas d’une exploitation par blocs foudroyés, la réponse de la masse rocheuse aux développements de galeries de sous-cavage. Les effets de temps/séquence sont étudiés dans la réponse de la masse rocheuse au sautage, ce qui est un facteur important dans les mines de roches dures."

Jan 1, 2016

By W. G. Deeks

CANADIANS are world leaders in marketing metal and mineral products. Noranda Sales Corporation Ltd. is an international metal and mineral product marketing company operating from Toronto and London, England, where it operates a wholly owned sales subsidiary and is a 50% partner in Rudolf Wolff and Company Ltd., a charter member and the largest metal broker on the London Metal Exchange. Noranda Sales employs 97 people, of whom 52 are university trained and professionally competent in international resource product marketing. We market for 19 companies or divisions in the Noranda Group and 39 companies for whom we act as agent, consultant and purchaser of resource production. Our business in 1976 was 1.5 billion dollars carried out in 45 countries and covering 24 products and materials. Today, ownership of most of the mining industry in Canada has transferred back to Canadians, and this is said with the knowledge that a significant part of the Canadian industry has been Canadian owned and managed from its very early days. Noranda Mines Limited is such an example. It was born in 1922 as the result of a copper-gold showing at Noranda, Quebec, discovered by Ed Horne, a prospector, financed with a grubstake by a syndicate mainly composed of New York businessmen. Shortly after the discovery, when the shares of the company had risen, the syndicate was sold to Canadian interests and, since that time, Noranda has been dominantly Canadian owned and certainly Canadian managed. Today, over 90% of Noranda's shareholders are Canadian, who hold an equivalent percentage of the stock.

Jan 1, 1977

By S. Shimaya, T. Maejima, M. Shimo

"The authors conducted the in-situ gas-tightness tests in a fractured rock at the Namikata underground LPG storage site in Ehime prefecture, Japan. The test consisted of two independent setups, a gas-tightness test that used boreholes, and a chamber-scale test that used a horizontal drift sealed with a concrete plug. In each test, the gas pressure was increased up to the onset of the measurable gas flow to obtain the maximum containment pressure. This paper discusses the hydraulic conditions for gas leakage initiation and the importance of the pore pressure measurement for monitoring the gas-tightness of the LPG storage cavern based on the test results.INTRODUCTIONJapanese first underground LPG storage plant was constructed by JOGMEC, the Japan Oil, Gas and Metals National Corporation, at Namikata in Ehime prefecture in granitic rocks (Kato et al., 2007). The “hydraulic sealing principle” (Åberg, 1977) that utilizes groundwater flow into an unlined cavern to prevent the leakage of gas through fractures in the surrounding rock mass was employed for storage of LPG. This paper describes the results of the in-situ tests performed at the Namikata Site to obtain information on fundamental gas-tightness characteristics of fractured rock. Two types of in-situ tests, a borehole gas-tightness test and a chamber gas-tightness test, were carried out near the storage caverns. Figure 1 shows the cavern layout of the Namikata underground storage plant and the test locations. The storage facilities consist of three caverns (W26m×H30m×L485m). The cavern crown lies at a depth of 150m below the sea level in Cretaceous granitic rock (Figure 1). Water curtain boreholes excavated from the water gallery tunnel at EL-125m level are located above and side of the caverns to prevent water drainage from fractures during the construction stage as well as during operation. The borehole tests were performed from a drilling adit excavated from the eastern end water gallery tunnel, while the chamber test was conducted at the southern edge of an exploratory drift extending from the central water gallery tunnel."

Jan 1, 2015

The morphology of environmentally assisted cracks in stressed pipeline steel has been investigated, For a dilute and neutral solution (NS4) simulating ground water in contact with the steel, semi-elliptical cracks grow faster on the surface (2c) than in the depth (a), hence, the aspect ratio (a/c) decreases, This is explained using a deterministic concept since corrosion is dominant and the primary constraint is the conservation of charge, By contrast, when mechanistic conditions prevail, significant growth occurs in the depth, When underloads are imposed in the loading history, temporary accelerations in crack growth occur because corrosion rather than mechanical effects become dominant.

Jan 1, 2005

By A. Plumtree

The morphology of environmentally assisted cracks in stressed pipeline steel has been investigated. For a dilute and neutral solution (NS4) simulating ground water in contact with the steel, semi-elliptical cracks grow faster on the surface (2c) than in the depth (a), hence, the aspect ratio (a/c) decreases. This is explained using a deterministic concept since corrosion is dominant and the primary constraint is the conservation of charge. By contrast, when mechanistic conditions prevail, significant growth occurs in the depth. When underloads are imposed in the loading history, temporary accelerations in crack growth occur because corrosion rather than mechanical effects become dominant.

Jan 1, 2005

By H. Z. Liu, J. M. Zhao, F. C. Wang

"Novel silicate-alginate composite beads containing 2-ethylhexyl phosphonic acid mono-2- ethylhexyl ester (P507) were synthesized and applied for the adsorption of Nd3+ from aqueous solutions. The adsorption amount of Nd3+ has been increased owing to the introduction of P507. The effect of equilibrium pH (pHe), the kinetic and isotherm experiments were investigated. The adsorption reaches equilibrium at 9 h and the maximum uptake capacity is up to 195.4 mg/(g dry adsorbent). The Langmuir isotherm equations are used to describe the adsorption process. Complete desorption can be realized with 0.2 M HCl within 20 min. INTRODUCTIONRare earth elements (REEs) have found various applications in different domains, such as metallurgy industry, ceramic industry, nuclear fuel control, photo-electro-magnetic functional materials owing to their unique properties. Neodymium (Nd), as a representative of all of the most valuable REEs, is widely used as catalysts, laser crystals, capacitors, rubber additives, Nd-Fe-B magnets, hydrogen storage and so on. Thus, the separation and purification of neodymium is significant. Unfortunately, Nd always coexists with other REEs and selective separation of the individual Nd from the REEs mixtures is still extremely difficult owing to their strictly similar atomic structures and chemical properties.Liquid-liquid extraction (LLE) and solid-liquid adsorption (SLA) are the most widely adopted techniques for the separation of REEs in the hydrometallurgical fields. The LLE process is well suited for large-scale continuous operation because of its inherent high capacity and fast kinetics. Nowadays, as a commercial extractant, 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (P507) has been extensively studied for extraction and separation of REEs since it has considerably good extractability and high separation efficiency (Xu et al., 1992). SLA is one of the effective and green separation methods with some prominent advantages, such as easy regeneration of adsorbents, small footprint size, less industrial wastes, higher enrichment factors and column efficiency,rapid solid–liquid separation without emulsion and so on. Hence, the introduction of extractants with excellent performance into adsorbents will integrate the advantages of LLE and SLA (Lee et al., 2009)."

Jan 1, 2012

By Zhibao Li, Lanmu Zeng

The behavior of dicalcium silicate in NaOH-NaAl(OH)4-Na2CO3 solution is of significance for controlling the silica level in the production of alumina via the sintering process. Dicalcium silicate samples were obtained through a twostep approach: coprecipitation of calcium and silicate from CaCl2-Na2SiO3-NaOH solutions; and calcination of the hydrated precursor at 1200°C for 4 hours. The optimization of the synthesis parameters including temperature, solution concentrations and aging time was also investigated. Xray diffraction (XRD) and chemical analysis show that the calcined solids include dicalcium silicate with trace amounts of wollastonite. The solubility of the synthesized dicalcium silicate in HCl, NaOH, mixed NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was determined. It was found that the solubility increases with increasing HCl and NaOH concentration. The effect of temperature on the solubility in HCl solutions is limited, but the solubility decreases with increasing temperature in NaOH solutions. The solubility of dicalcium silicate in NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was shown to increase with increased temperature, Al(OH)3 and Na2CO3 concentration. The BromleyZemaitis model for the aqueous electrolyte system was selected to predict the solubility of dicalcium silicate. The model’s predictions yielded certain success compared with experimental solubility data.

Jan 1, 2014

By V. S. Melamud, A. G. Bulaev

"Sulfide ore processing is characterized by significant losses of metals, for example, with flotation tailings. Therefore, flotation tailings can present an important source of metals. The treatment of flotation tailings is a technological issue due to low content of valuable metals (e.g. copper and zinc) and high iron content. The goal of the present work was to investigate extraction of base metals and gold from old flotation tailings containing 17% iron, 0.26% copper, 0.22% zinc, and 0.7 g/t gold. Chemical leaching in columns with 0.5 to 10% sulfuric acid solutions and bioleaching in air-lift percolators were used for the extraction of base metals. 1% H2SO4 provided high extraction of base metals and best selectivity. Recovery of copper and zinc reached 35% and 40%. Increasing H2SO4 concentration did not lead to significant increase in base metals extraction, but led to increased iron concentration in the pregnant solutions. The 1% H2SO4 leaching solid residues were used for further experiments. Acid leaching and bioleaching did not result in significant increase in base metals recovery. Leaching of the residue with 10% H2SO4 provided extraction of 4% copper and 20% zinc, and bioleaching for 100 days provided extraction of 16% copper and 12% zinc. The recovery of gold by cyanidation from the flotation tailings, the 1% H2SO4 leaching solid residue and residue of two-step acid leaching were 50, 49, and 65%, respectively. The results suggest that acid leaching can be effective approach for treatment of old flotation tailings.INTRODUCTIONAbout 80% of base metals (copper, nickel, zinc) are produced through pyrometallurgical treatment of sulfide ores. Mining and metallurgical treatments of sulfide ores are presently characterized by significant losses of non-ferrous and precious metals into the various wastes. For example, flotation of sulfidic ores yields formation sulfide flotation tailings. These wastes pose a problem not just because of their sheer volume, but some of them may affect local ecosystems. Nowadays, mining and metallurgical wastes can be considered as technogenical source of base metals."

Jan 1, 2016