Search Documents

By S J. Schafrik, E S. Gilliland, E C. Jong, J Waynert, C W. Weiss

Two commercially available through-the-Earth (TTE) communications systems were evaluated at an active underground longwall mine in West Virginia. One system utilises magnetic field (H-field) antennae while the other system utilises electric field (E-field) antennae to achieve communication. A large portion of this mine is overlain by an inactive gas-oil field composed of densely spaced wells. This feature provided a unique opportunity to determine the impact of cased wells on both TTE technologies. The following communication modes were investigated: surface to underground, underground to surface, underground to underground and real-time two-way communications. Standard deployments of the TTE systems using the manufacturer’s recommended procedures were able to achieve clear communications between underground and surface locations under certain circumstances. As a result, the design and deployment that will optimise TTE transmissions are unique to each system and to the specific area of the mine. This field study was conducted as a part of a larger multisite evaluation of available TTE systems in an effort to determine their operational sensitivity. The performance of these two TTE systems suggested that one may be preferable over the other depending on the conditions present during deployment.CITATION:Jong, E C, Schafrik, S J, Gilliland, E S, Weiss, C W and Waynert, J, 2015. Pairing magnetic and e-field through-the-Earth communication systems based on mine site conditions, in Proceedings Third International Future Mining Conference, pp 245–252 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By M de Freitas Silva

One of the main steps during the decision-making process of long-term mine planning is the definition of the optimal sequence of extraction, which usually is synonymous with maximising the discounted cash flow of the project subjected to several constraints arising from aspects of technical, physical, and economic limits.Open pit mine production scheduling (OPMPS) comprises several intricacies related to its size and uncertainty of input parameters. Due to its complexity and prohibitive size, traditional mine planning usually relies on heuristic or metaheuristic methodologies which are able to provide good solutions in a reasonable amount of time. However, most of the uncertainty that surrounds the mining complex is ignored leading to non-realistic results.In this paper, a new heuristic approach is explored in order to solve a stochastic version of the OPMPS problem accounting for geological uncertainty in terms of metal content, multiple processing streams, and stockpiling option. The methodology involves generating an initial solution by solving a series of subproblems and this initial solution is improved using a network flow based algorithm.The algorithm was applied to a relatively large gold deposit with more than 119 thousands blocks. Results have shown that the methodology is promising to deal with large-size mine instances in reasonable time.CITATION:de Freitas Silva, M, 2014. Solving a large stochastic integer programming model for production scheduling at a gold mine with multiple processing streams and uncertain geology, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 389–396 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By A N. Parry

In May 2018 Kasbah Resources Limited (“Kasbah”) completed an ore sorting test work program which was a precursor to releasing in July 2018 an updated Definitive Feasibility Study (“DFS”) for the Achmmach Tin Project in Morocco, which it is proposing to develop along with its joint venture partners. The testwork program evaluated ore sorting as a pre-concentration option to achieve early elimination of gangue and the low-grade component of ROM feed, thereby potentially:  Significantly upgrading the head grade of tin to the downstream processing plant.  Significantly reducing the required throughput capacity (and projected capital expenditure) of the downstream processing plant.  Reducing total consumables, power and water requirements in downstream processing.  Increasing the recovery of tin in the gravity and flotation circuit due to the higher feed grade achievable with ore sorting.  Reducing tailings tonnage, tailings cost and environmental footprint.  Using sorter rejects for mine backfill or road base applications. Key aspects of the design of the metallurgical testwork program centred around the need to ensure that samples representative of ROM ore feed (including projected mining dilution) were selected for the ore sorting testwork. The design and implementation of the ore sorting bulk testwork program is described, as well as a summary of the test work results and a discussion of the enhancement of the project economics reported by Kasbah, which led the company to adopt ore sorting as part of the proposed processing circuit in the updated 2018 DFS.

Nov 10, 2020

By A Bossilkov

Although environmental and sustainable development reporting has now become widespread in the Australian mining and minerals processing sector, there remains a great deal of diversity in reporting contents and practice. Moreover concerns remain about the effectiveness of reporting for delivering the companyÆs business case for sustainable development as well as for communicating sustainable development performance to a range of external stakeholders. This paper therefore reviews the status of sustainable development reporting in the Australian minerals processing industry. Pertinent international and national developments are briefly captured, leading to a discussion of the framework for integrating sustainable development reporting with sustainable development management (as proposed by the World Business Council for Sustainable Development). This leads to a discussion of the results of a comparative review of sustainable development reports of a cross-section of eight Australian resource companies. Best practice elements are highlighted in regard to reporting on company context, governance, performance and assurance.

Jan 1, 2004

By P B. Hills

Almost a quarter of a century since Bridges (1993) documented techniques for the assessment of ground conditions in a seminal paper in the Proceedings Second International Mining Geology Conference, the necessary role of the geologist in recording geotechnical data on exploration properties and in mines remains. Typically, the geologist is the first professional on the exploration property. Of course, most exploration properties don’t become mines. However, when a property does start to come together and form a coherent mineral deposit and professionals from across the minerals industry spectrum, including specialist geotechnical engineers, become increasingly involved, it remains the geologist who has the most intimate knowledge of the deposit. By association, that knowledge extends to the character of the rock mass.Throughout the various phases of prefeasibility, feasibility, construction and production, culminating in the mature mine, the knowledge of the rock mass held by the geologists continues to grow. In the current era of minimising cost and optimising profit, meeting the requirements and expectations of stakeholders ranging from fellow employees to investors, industry and financial regulators and the broader public, in a social environment where occupational health and safety concerns are of uppermost concern in every endeavour, the value of the geologists’ observations cannot be understated. Mines nowadays employ more geotechnical engineers than they did in the early 1990s when Bridges (1993) wrote his paper. More funds are available for specific geotechnical investigations of exploration properties and mines; none-the-less, those programs remain limited in their extent and there is a wealth of additional data available for collection with the appropriate training, at little additional effort. Fundamentally it is all about the numbers. Any hole not geotechnically logged is a hole that will need to be drilled again if the data is required. Any face, surface or underground, not geotechnically mapped is one that may need to be mapped a second time. That doesn’t mean every hole or every face. However, it is the proposition of this paper that the opportunity for additional geotechnical data to be gathered during traditional geological investigations is an opportunity that cannot be ignored. Occupational health and safety requirements demand that the geotechnical risks associated with mining are appropriately managed. Mining regulations in most Australian and overseas jurisdictions requires the consideration of geotechnical risk through formalised management plans. The Joint Ore Reserves Committee (JORC) Code requires the consideration of modifying factors more than ever before. The benefit to be realised through improved geotechnical understanding by geologists on the ground leads to improved occupational health and safety, optimised reporting compliance, and improved financial and social outcomes for the exploration property and ultimately for the mine that follows.CITATION:Hills, P B, 2017. The necessary role of the geologist in geotechnical data gathering, in Proceedings Tenth International Mining Geology Conference 2017, pp 347–354 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

Problems caused by water discharge from surface mine ventilation shafts can be significant and are usually unforseen. The discharged water is often hyper-saline or acidic and can cause environmental degradation over a wide radius. It can also lead to recurring power pole fires and primary fan breakdowns. A range of solutions to the water discharge problem has been implemented in many Australian mines. In most cases the solutions have been ad hoc, with the overall cost and effectiveness varying tremendously. This paper reviews and contrasts the practicality and effectiveness of the various available remedial options.

Jan 1, 2002

By A Gustafson, G Shekhar, P Boeg-Jensen

The amount of material extracted from each blasted ring in sublevel caving mines is vital when deciding the overall mine production target. The orientation of the production drifts is normally perpendicular to the strike of the orebody, and rings are blasted from the hanging wall side to the footwall side in a retreating manner. For an inclined orebody, a given ring will contain different amounts of material based on its relative position along the production drift. This layout creates a distinctive problem with respect to the extraction ratio optimisation along the axis of the production drift. This paper describes the current drawpoint control strategy practiced at LKAB and presents the variation of drawpoint performance parameters along the production drifts. It uses automatically generated data from a bucket weighing system that measures tonnage drawn per bucket, and it classifies the blasted rings into four zones based on their relative position along the production drift. It considers the loading procedure for blasted rings at Kiirunavaara mine and analyses the variations in drawpoint performance along the production drift. The paper finds that although the current draw control strategy is sensitive to ring position along the drift, it could be modified to optimise the final extraction ratio.CITATION:Shekhar, G, Gustafson, A, Boeg-Jensen, P and Schunnesson, H, 2016. Draw control optimisation along the production drift in sublevel caving mines, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 241–250 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By R J. Hardy

The aim of this study is to examine the volumetric and mass movement characteristics of load and haul operations using statistical modelling of relatively large samples of bucket loads that are transported as small samples in the form of truck payloads. Generally, the factors influencing bucket load variability are random, difficult to predict and to control. In the process of loading trucks the underlying variability of individual bucket loads will determine the variability of truck payloads. Bucket loads of material prepared by drilling and blasting for loading into trucks are fundamental quantities in open pit mine production. A study of payload data from a large surface mining operation indicates that bucket loads and truck payloads that are a small sample of bucket loads are normally distributed. Truck payloads have a reduced dispersion compared with bucket loads that is an inverse 0.5 power function of the number of passes per truck payload. Comparison of statistical modelling results with the æ10/10/20Æ policy promoted by Caterpillar Global Mining Inc, indicate that compliance with the æ10/10Æ part of the policy, applying to truck overloading is facilitated, as the coefficient of variation of truck payloads decreases, as a result of the increasing number of loading passes. Compliance with the more stringent æ20Æ part of the policy, relating to safe steering and braking is also facilitated, albeit at lower coefficient of variation for similar reasons.

Sep 26, 2011

By D Cliff

"It has been 17 years since the mine disaster at Moura No 2 Mine in Queensland. Recent disasters in the USA and New Zealand prompt the question what has changed since 1994. This paper att emptsto answer this question and identify areas that need improvement."

Jun 1, 2012

By M S. Manono, K C. Corin

The optimisation and process developments surrounding the beneficiation of Cu-Ni-PGM ores is of fundamental importance when considering the continued rise in global demand for these precious metals. The selective sequential flotation of these ores is accompanied with various processing challenges such as the successful separation of the Cu-Ni-PGMs from non-sulfide naturally floatable gangue and pyrrhotite. Reagents such as sodium iso-butyl xanthate (SIBX) and sodium carboxymethyl cellulose (CMC) have proven to significantly improve the selectivity of the flotation process in their respective roles. The use of recycled water with abnormal inorganic electrolyte concentrations can modify the selectivity of these reagents, as ions may adsorb onto minerals such as pyrrhotite, thereby hindering or promoting the hydrophocity and floatability of pyrrhotite. Process water quality effects on the behaviour of pyrrhotite may have negative or positive influence on the recovery and grades of the wanted Cu-Ni-PGMs as valuable minerals associated with pyrrhotite such as pentlandite may be affected in like manner. Thus, the impact of concentrator process water quality on the behaviour of pyrrhotite needs to be determined. In this study synthetic process water at various ionic strengths was investigated against various CMC dosages to understand the behaviour of pyrrhotite during the flotation of a Cu-Ni-PGM Merensky ore in a batch flotation cell. This study showed that pyrrhotite grades increased with an increase in CMC dosage for fixed ionic strengths whereas the recoveries of pyrrhotite increased with an increase in ionic strength until 3SPW, then a trend of a decrease in recoveries was seen with 5SPW resulting in the lowest pyrrhotite recoveries. Furthermore, this study showed that moderate CMC dosages of 100 g/t resulted in the highest pyrrhotite recovery for all four ionic strengths of synthetic process water tested. It can be said that to maximise value recovery from Cu-Ni-PGM ores, understanding the behaviour of pyrrhotite against degrading water quality and reagent suites could be of paramount importance given the sensitivity of pyrrhotite to oxidising chemical conditions.

Aug 24, 2022

By Z Li, Z Yan, M Yang

Recycled cement paste (RCP) is a kind of CaO-rich recourse, which is separated and recycled from waste concrete. Due to its chemical composition, RCP could partially replace lime as a flux and be loaded into electric arc furnace (EAF) steelmaking process. Rapid RCP assimilation and liquid slag formation have significant effects on EAF steelmaking process. In this study, the dissolution behaviours of RCP and lime at temperatures of 1400°C to 1500°C were investigated using static dissolution experiment. The dissolution rate, interfacial microstructure, as well as dissolution mechanisms were discussed. It was found that the dissolution rate of RCP was much higher than that of lime. RCP could be completely dissolved into slag in 60 secs at 1500°C. The dissolution rate of lime was in range of 3.910-4 g/(cm2ꞏs) to 2.610-3 g/(cm2ꞏs), while that for RCP was in range of 1.510-3 g/(cm2ꞏs) to 4.910-3 g/(cm2ꞏs). As for lime dissolution, a dense layer of dicalcium silicate (C2S) generated at the dissolution interface, and the diffusion of Ca2+ in C2S layer was the limited step for lime dissolution. Some of calcium ferrite could be observed at the interface between lime and C2S layer. As for the RCP dissolution, there is no obvious product layer of C2S formed at the dissolution interface, Fe2+ continuously diffused into RCP layer during the dissolution, and small amount of FeOꞏMgO solid solution generated and gathered at the dissolution interface. The dissolution rate of RCP in EAF slag was quite higher than that of lime, partially add RCP as flux in EAF could accelerate the slag formation process.

Aug 21, 2024

By P Oikkonen

Sprayed concrete has played an integral role in underground rock support for nearly a century. However, concrete is also considered to be one of the biggest environmental problems in construction and mining, largely because of the high carbon footprint of cement and aggregates production. This is driving the industry to find ways to cut concrete usage where possible. Improving sustainability by cutting concrete material consumption also reduces application time and costs. Improving concrete properties can make it possible to design thinner linings, but as awareness of safety and longer design lifetimes are driving developments in the opposite direction, it is not realistic to see this as a major factor in cutting concrete consumption. More accessible solutions are focusing on layer thickness control and minimising rebound and wastage. Digital technology and innovation offer excellent tools for improving sustainability while optimising other aspects of the spraying process at the same time. A digital layer thickness control system gives near-real-time information to the sprayer operator with full coverage of the sprayed surface. This enables the operator to achieve consistent layer thickness on the first pass, in comparison to the traditional methods of overspraying with the aim of achieving sufficient layer thickness, probe drilling after the concrete has set, and respraying at a later stage if needed. Operator competence is the single biggest variable in a successful sprayed concrete process, affecting rebound and wastage levels. Unfortunately, the learning curve to become a master sprayer is quite steep and training on a real sprayer and real concrete requires a significant amount of time and money. Training in a virtual reality (VR) environment enables operator training to be carried out in a low-risk environment and provides a way of measuring performance and assessing and certifying the operators. After the VR training period, a novice nozzle operator has the basic understanding to start working on a real sprayer, and an experienced nozzle operator can benefit from the possibility of assessing their performance.

Mar 29, 2023

By J Schrank

Double-stack trains in the United States date back to the early 1980s, starting about the time deregulation of the rail industry occurred. Freight rail became increasingly more competitive to trucking and barge or ship, and led to major investments in railroad infrastructure. Since most railroad tunnels in the United States were constructed between 1880 and 1930, they were not built tall enough to accommodate modern double-stack intermodal railcars. Therefore, as double-stack trains became the norm, existing tunnels became bottlenecks, and railroads wanted the tunnels made larger without impacting traffic. This need to increase the clearance while not impacting rail traffic launched a very specialised industry: the design and construction of replacement lining systems in existing tunnels.Several large multitunnel railroad clearance improvement projects have been completed in the country in the last decade, and they have all been done under ‘live track’ conditions. Live track conditions consist of work windows, often anywhere from four to 12 hours, that are provided to the contractor to complete the construction work. By the end of each work window, the tunnel must be secured so that the railroad can run trains.In addition to improving the clearance, these projects provided the railroads with an opportunity to improve the general condition of the tunnels, including structural, seepage, drainage and icing conditions. This paper discusses the design considerations, tunnel assessments and construction methods used for these live track railroad tunnel projects. Seepage and drainage improvements that were incorporated into the clearance improvement projects are also discussed.CITATION:Schrank, J, 2014. Live track railroad tunnel repair and clearance improvement in the United States, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 619–628 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

Forty years ago Dr Pierre M Gy, a metallurgist, introduced variography as applied to monitoring a process. Consequently, his followers used the variogram to elaborate meaningful process control charts, especially since 1993. The name æChronostatisticsÆ was suggested several times by Gy as a logical name for this new science. The intent was to draw a parallel between the variogram identifying the variability components affecting a process parameter as a function of time, and the variogram used in geostatistics identifying the variability components of a given mineral content as a function of space. Heterogeneity problems encountered have indeed strong similarities. However, there is a fundamental difference. The variogram used in geostatistics is often stationary within a given type of mineralisation. While investigating a dynamic process through Chronostatistics, there is no such thing as a stationary variogram. Still, the evolving variogram provides essential information about subtle, often overlooked process difficulties. Chronostatistics is especially useful for management to take advantage of existing data that are often a forgotten source of valuable information to pinpoint recurring structural problems. The superiority of Chronostatistics over conventional statistical process control approaches is that it links observations to the inherent heterogeneity of materials under investigation, therefore to the sampling theory. Chronostatistics is like opening a new world to the metallurgist, making the process variability speak in a more comprehensive and in-depth way. Several case studies are presented to demonstrate the potency of this new science. For each of them, observations lead to solutions for continuous process improvement, therefore attractive economic opportunities. The philosophy is this: if a control chart shows a process is out of control, it must also suggest logical and pragmatic directions for solutions. The intent of this presentation is to vastly expand on these valuable, almost forgotten ideas.

Jan 1, 2006

By A T. Spathis, K E. Leslie, K R. Blay

Many open pit mining operations seek to control blasting-related movement of ore and waste to minimise loss and dilution. Tracking the movement of ore boundaries can result in the maximisation of ore recovery and minimisation of waste sent to the mill, thereby optimising the economic performance of the operation.A novel solution for tracking the ore–waste boundary location before and after a blast uses subsurface markers placed along the boundary with all measurements and scans conducted remotely from the blast block. Upon system activation, user-operated equipment on the surface determines the three-dimensional (3D) location of the subsurface markers.The patented system concept combines two electromagnetic mechanisms, magnetic positioning and radio frequency through-rock communications to enable remote battery-powered markers, buried within the rock to be accurately located in 3D space.Field trials at a quarry have demonstrated the system can comfortably handle over 100 subsurface markers with a complete scan, including set-up, taking less than an hour. Location accuracy for each marker in 3D space is better than 0.5 m at a range up to 50 m from the magnetic source, and the system has an overall operational range in excess of 75 m.CITATION:Blay, K R, Spathis, A T and Leslie, K E, 2015. A remote, rapid and accurate three-dimensional ore waste boundary tracking system, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 297–306 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Chitombo GPF

The dilution of blasted ore with cemented backfill materials has been recognised as a significant factor influencing the economics of some underground metalliferous mining operations. Several mechanisms have heen identified as possible causes of fill failures. The purpose of this study was to determine the possibility of damage as the result of one mechanism, that of production blasting adjacent to bodies of cemented hydraulic fill (CHF). A vibration amplitude transfer function has been developed to model the transmission of blast vibrations from the source, through ore, across the ore to CHF interface and into the CHF mass. The model may be applied in the near field. The model has permitted estimation of vibration amplitude at a point in a CHF mass, to which damage criteria may be applied. A number of assumptions and simplifications have been made to render the problem relatively tractable. Ore and CHF material characteristics recorded by a number of authors were utilised to formulate preliminary damage estimations. A simple application of the amplitude transfer model indicated that a zone of plastically deformed CHF would be produced, and would extend to a distance of approximately 0.5 metres from the interface into the CHF. A sensitivity analysis was also conducted, that indicated that the zone of plastic deformation would be more extensive given appropriate conditions. Recommendations for further model development and future laboratory and field investigations have been made.

Jan 1, 1998

By V Malysiak, N J. Shackleton

In the flotation of platinum group minerals pyroxene is a major gangue mineral. This study shows using zeta potential and ToF-SIMS analyses that when pyroxene is exposed to copper, nickel and/or calcium ions in solution at alkaline pHs a surface reaction occurs between the hydroxy species, in the case of copper and nickel, or divalent calcium ions and the pyroxene surface which influences the floatability of the pyroxene. Following exposure to copper and nickel ions at pH 9 addition of SIBX resulted in the pyroxene floating readily. It is also shown, in the case of copper, that the activating effect of the adsorbed copper hydroxy species can be reduced by the addition of complexing amines prior to SIBX. Proposals are made to explain these observations.

Jan 1, 2005

By J R. Manuel, M J. Peterson

Selected drill core samples from a Ferrobamba-limestone-hosted, magnetite-haematite skarn deposit, located in the Apurimac department of the Andahuaylas-Yauri skarn/porphyry belt of south-eastern Peru, were mineralogically and texturally characterised to gain a preliminary indication of the deposit's potential as an iron ore resource. Optical microscopy, X-ray diffraction (XRD) and scanning electron microscopy/electron probe microanalysis (SEM/EPMA) techniques were utilised to determine the characteristics of magnetite, haematite and/or goethite dominated ore types, including variations in the relative proportions and textural relationships of the ore and gangue minerals. The deportment of elements deleterious to processing performance (eg copper, sulfur and potassium) was determined and the beneficiation potential of the samples was briefly assessed. In drill core sections, the ores are grey to reddish in colour, massive and 'metallic' to dark brown and earthy in character, moderately hard and porous (macro and microporous), with variable gangue infill. Ores often appear weathered, typified by ochreous goethite staining and common minor goethite (except in dense core fragments), occasionally exhibiting a more friable texture with coarse magnetite/martite grains. Silicates and lesser carbonate gangue are visible as blue-green to beige to white scaly and/or shaly surface coatings, and finely particulate infill, often goethite stained. Sulfide-rich ore types also occur in part of the deposit, but are restricted to specific drill holes. Magnetite grain size is relatively coarse, compared with magnetite from typical banded iron formations, whereas discrete silicate gangue is mainly bladed/fibrous and/or layered and micaceous in form. XRD analysis indicates the presence of vermiculite, serpentine, stilpnomelane, chlorite, actinolite and clays. There is a spectrum of ore types representing the gradation from 'fresh' (magnetite-dominated) to oxidised and weathered (martite/goethite-dominated). Martite-dominated samples are generally higher in grade, due to leaching and removal of silicate gangue, resulting in higher macroporosity. Where gangue has been leached out, partial replacement by vitreous goethite and/or hydrohaematite is typical, often preserving the fibrous/layered characteristics of the original silicates.

Jan 1, 2009

By B D. Sowerby, N G. Cutmore

Improved process control can be achieved through the accurate and reliable on-line measurement of critical process parameters in real time. Over the past few decades on-line analysis techniques have been developed and applied in the mineral and energy industries for the measurement of process stream composition, mineralogy, particle size and flow rates. This has led to increased throughput and product quality while reducing processing costs and minimising emissions. The support of a sustainable mineral processing industry will require the further development of on-line analysis and control technologies. The application of developments in instrumentation combined with improved control strategies will lead to improvements in process efficiency resulting in large economic benefits to the industry, reduced energy usage and lower process emissions. There is a clear convergence of interests in being able to better measure and control minerals processing in terms of the triple bottom line of economic, social and environmental impacts. Technology is increasingly becoming available enabling measurement across the entire spectrum of minerals processing from mining to hydrometallurgy and pyrometallurgy. CSIRO is developing a range of these new technologies. A number of these developments are discussed in the present paper, namely: on-line particle size analysis and acoustic emission methods to enhance the control and optimisation of grinding circuits; on-line mineralogy of dry powders and slurries; on-line bulk elemental analysers for application on conveyor belts and in smelters; and the development of new sensing technologies for sorting base metal ores.

Jan 1, 2002

By I H. Jung, W O. Choe

Gallium (Ga)-containing compounds such as Gallium Arsenide (GaAs) and Gallium Nitride (GaN) are widely used in electronic devices due to their superior electro-optical properties and their usages increase rapidly. For the sustainable supply of Ga to electronic industry, therefore, the recycling of Gallium becomes essential. Pyrometallurgical Ga recycling process involves the complex chemical reactions between slag, matte, liquid metal, gas, refractories, etc. Therefore, the accurate thermodynamic information and phase diagram data for the oxide system containing Ga2O3 is important. In the present study, new phase diagram experiments for binary SiO2-Ga2O3 and ternary CaO-SiO2-Ga2O3 system are carried out using Differential Thermal Analysis (DTA) and quenching experiments followed by Electron Probe Micro-Analyser (EPMA) and X-Ray Diffraction (XRD) phase analysis. Based on new phase diagram data and available literature data, the thermodynamic modelling of the entire CaO-SiO2-Ga2O3 system is performed for the first time.

Jun 19, 2024