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By M. A. Mahboob, T. Celik, B. Genc, I. Atif, S. Ali

"Mapping of hydrothermally altered areas, which are usually associated with mineralization, is essential in mineral exploration. In this research, open source reflectance spectroscopy data from the multispectral moderate-resolution Landsat 8 satellite was used to map altered rocks in the Gauteng and Mpumalanga provinces of South Africa. The unique spectral reflectance and absorption characteristics of remotely sensed Landsat data in the visible, near-infrared (NIR), shortwave-infrared (SWIR) and thermal infrared (TIR) regions of the electromagnetic spectrum were used in different digital image processing techniques. The band ratios (red/blue, SWIR 2/NIR, SWIR 1/NIR), spectral band combinations (Kaufmann ratio, Sabins ratio) and principal component analysis (Crosta technique) were applied to efficiently and successfully map hydrothermal alteration minerals. The results showed that the combination of spectral bands and the principal component analysis method is effective in delineating mineral alteration through remotely sensed satellite data. The validation of results by using the published mineral maps of the Council for Geoscience South Africa showed a good relationship with the identified zones of mineralization. The methodology developed in this study is cost-effective and time-saving, and can be applied to inaccessible and/or new areas with limited ground-based knowledge to obtain reliable and up-to-date mineral information.IntroductionMany developing nations depend on exploration and exploitation of mineral resources to sustain their economic growth. Usually, the traditional mineral exploration techniques require enormous finances, prolonged time, and tremendous manpower, particularly in areas that are not easily reachable (Maduaka, 2014). Furthermore, mineral exploration required state-of-the-art techniques and expertise along with geological, geochemical, and geophysical datasets, which may not be easily available or may be lacking where access is problematic (Kaiser et al., 2002; Bemis et al., 2014). Modern remote sensing technology has proved to be one of the highly efficient and robust techniques used for mineral exploration. The use of remote sensing satellite images for geological mapping and mineral exploration usually involves studying the physicochemical properties of rocks and weathering soils, such as mineralogy, landforms, geochemical signatures, and the spatiall distribution of lineaments (Bhattacharya et al., 2012)."

Mar 1, 2019

"Chairman: Professor C. O. Frush Rapporteur: Mr A. C. SchmidtPapers:Planning of underground copper mining by J. K. Williams, L. Smith and M. P. WellsLinear programming models of copper leach and solvent extraction plants by W. P. C. Duyvesteyn, J. R. Cutland and J. R. L. RusselPlanning and forecasting stope production by D. W. Kappes and P. F. X. Moussett-JonesA proposed method of dynamic ore reserve assessment for a caving system of mining by A. F. Spinks and S. P. NicholsThe initial point made by Mr L. Smith in presenting his paper was that the planning aid outlined in the preprint was neither sophisticated nor complicated. However, it was a system which worked and was a very real way in which the computer was being used to assist miners, in particular, who at the present moment have very little experience in the use of computers.Mr Smith apologised for the fact that the editors of the paper had eliminated all reference to 'time'. This was very unfortunate because the essence of the system was that it saved time, which was one of the main points made in the paper.The operations being planned by this means cover the Rokana orebody which is a stratiform body mined by open stoping.The planner has to decide how much ore to mine from each base in each time period of his plan, that is, from three to four months hence to a year ahead. Normal procedure is for the planner to have discussions with the underground manager on some of the information he requires. The sort of information needed is (i) tramming limits for each face, (ii) extraction and grade factors, (iii) the present status of mining operations so that the planner knows where to start the new plan, and, (iv) details of any other mining consider¬ations that need to be incorporated in the plan.The objective at this point is to produce an initial plan for discussion purposes. All the information required comes from one sheet per stops and shows, inter alia, the stope identifier, the length along strike, the ore tonnage, the copper and cobalt grades and, finally, the extraction and grade factors.The program itself, among many other things, checks the data for validity, compatibility, completeness and credibility and prints error messages accordingly. Output from this system is in the form of a summary of production from each face, as well as giving the figures of ore reserve depletion. This summary indicates which slopes are to be mined in this time period, the original survey grades (copper and cobalt), the estimated production grades, how much is to be mined from each stope and the copper and cobalt production accordingly."

Jan 1, 2014

A Special General Meeting of The South African Institute of Mining and Metallurgy was held at Kelvin House, Johannesburg, on Wednesday, 20th August, 1986. Mr H.E. James (President) was in the chair and declared the meeting open at 15h45. Background The Chairman explained that the meeting had been called to consider a number of amendments to the SAIMM constitution. The proposed changes had been set out in detail in a document that had been mailed to all members on 4th July, 1986. He then briefly reviewed the background to the proposals, which is outlined in the Preface to the Annual Report (page 357 of this issue). The Chairman added that the Executive Committee of SACPE at its meeting on the 8th August, 1986, had resolved that the proposed amendments to the SAIMM constitution did comply with the requirements of Regulation RI525 dated 17th July, 1981, regarding the recognition by SACPE of a society as a Professional Engineering Institute.

Jan 1, 1986

By J. Sepulveda

"Despite the recognized influence of product fineness on line capacity and downstream process performance, few mineral concentrators today use particle size measurement of the final product in automatic control applications for particle size. ‘Near-line’ particle size instrumentation has existed for decades and is utilized in modern concentrators, but low availability and measurement frequency, due to problems with slurry sampling and transport systems, make these technologies unreliable for use in automatic control. An innovative technology for real-time particle size measurement on individual hydrocyclones, named CYCLONEtrac™ PST (particle size tracking), has been developed by CiDRA Minerals Processing, and proven in commercial installations, demonstrating near 100% availability with minimal maintenance requirements, thus overcoming the limitations of previous technologies. Potential stakeholders require convincing, reliable information regarding the economic value delivered by automatic grind control projects. In this paper we present a methodology for estimating such value with the CYCLONEtrac™ PST technology, and demonstrate unique opportunities to improve process stability and performance. Based on actual plant data accumulated over time, the evaluation approach assesses and highlights the significant potential process improvement that can be expected with the particle size tracking technology. As an extension of previous work, in this paper we present the key operating criteria for optimizing the production of valuable metals and increase mill throughput by identifying the optimal grind size. As this requires operating closer to the process boundaries, accurate real-time particle size measurements, such as those provided by the CYCLONEtrac™ PST system, become essential for achieving the maximum potential value from every operation. For further illustration, data from three different copper plants is compared.Introduction Owners and operators of mineral concentrators constantly search for the most economically attractive way to increase the output of valuable metal. A logical approach is to identify a key parameter that has the greatest impact on the performance of multiple stages of the process and then use a holistic analysis methodology to determine how this key parameter can be controlled to optimize the final output.Particle size is widely recognized as such a key parameter; however, very few concentrators today use real-time particle size measurements for automatic control of the final product size due, to a large extent, to the inherent limitations of existing technologies. ‘Near-line’ particle size measurement instrumentation, which has been used for decades, typically suffers from low availability because the fundamental measurement technologies were developed for other, less demanding industries and then adapted to the harsh environment of the typical mineral concentration process. An outline of the key differences among the available technologies used for particle size measurement in comminution circuits has been completed in previous work, and plant data has proven the benefits of measurements on individual cyclones – something that, until now, has not been possible (Cirulis, 2017)."

Nov 1, 2018

By A. R. Javadi

Pyrite (FeS2), chalcopyrite (CuFeS2), sphalerite (ZnS) and galena (PbS) generate hydrogen peroxide (H2O2) when placed in water, with pyrite generating the most amount of H2O2. The order of these minerals for generating H2O2 in water is: pyrite > chalcopyrite > sphalerite > galena. In previous research, the methods of generation of H2O2 in the grinding mill were studied. In this study, data from experiments were included by using MODDE 9 software for six parameters composed of water, grinding media, particle size; adding collector to the grinding, and adding depressant and pH. Finally the optimal condition was achieved. According to the results, most of the recovery is related to the particle 75 μ size and when using processed water, adding 100% collector and without depressant and pH 10. The most recovery of lead in the case of the use of fresh water is in the case of 100% collector, without depressant, pH 10 and 150 μ particle size. Maximum recovery in fraction size 45 μ in the case of water process is 100% collector, without depressant and pH 10. Maximum depressant of pyrite will be the fraction size 75 μ, distilled water, without collector, 100 depressant. Keywords: Sulfide mineral, hydrogen peroxide, flotation, oxidation

Jan 1, 2020

By W. R. Matizamhuka

"The consolidation of nano-sized composite materials presents a challenge using conventional hot pressing methods. Spark plasma sintering (SPS) technology has shown great promise in the successful sintering of nanoreinforced composite materials. This qualitative review seeks to impart knowledge gathered, and progress made over the years on the consolidation of nanocomposite materials using SPS technology. The review is aimed at introducing this technology to the South African science and engineering community. Emphasis is on improving the mechanical properties of structural ceramic nanocomposite materials, which over the years have shown great promise in a wide range of applications, including transport, energy, mining, and the environment. Although success has been achieved within the laboratory for research purposes, there are still great opportunities to commercialize the technology for the production of larger components with more complex shapes.IntroductionSince the pioneering work of Niihara and Nakahira (1991) over a decade ago there have been extensive attempts to harness the potential of nanostructural metals, ceramics, and composites in a number of applications (Niihara and Nakahira, 1991; Selaho et al., 1997; Sekino and Niihara, 1995; Khalil, 2012; Aalund, 2008). It is generally realized that reducing the grain size of materials to nanoscale offers a significant improvement in properties. Attempts to synthesize nanostructured compacts by conventional sintering methods have not succeeded owing to the uncontrollable high rates of grain growth driven by long dwelling times at the sintering temperatures and large powder surface areas (Sergueeva et al., 2009; Gua, Khora, and Chieng, 2004; Tang et al., 2009). Following the development of spark plasma sintering (SPS) technology, it is now possible to process nanocrystalline materials with controlled grain growth. SPS, also referred to as the field-assisted sintering technique (FAST) or pulsed electric current sintering (PECS), was developed with the aim of improving on the well-established hot pressing (HP) technology (Kessel and Hennicke, 2007;"

Jan 1, 2016

By E. Pothas, P. R. Jochens, L. B. McRae, D. D. Howat

Discussion H. J. S. Kriek*: During 1956 Iscor became interested in the acid smelting in a blast furnace of siliceous ores containing 15 per cent silica. This interest was as a result of the successful acid smelting in Germany at a CaO/SiO2-ratio of between 0.4 and 0.8. Acid smelting can become an economic proposition due to a reduction in slag volume accompanied by a lowering of the coke rate. Paschke and Hannel1 found that a free flowing slag (i.e. viscosities of less than two poise) would not be obtained at C/S-ratios lower than 0.82 and that the addition of 3 to 4 per cent alkalies became necessary. In titanium bearing slags it was established that maximum fluidity is obtained with 10 per cent TiO2. Acid smelting resulted in increased sulphur pickup with decreasing O/S-ratio and desulphurization with soda-ash outside the blast furnace was necessary. At Iscor Mr B. B. Segal established that, for slags with (CaO+MgO)/SiO2-ratios of 0.5, 0.6 and 0.7, the addition of alkalies and TiO2 resulted in a substantial decrease in melting point and also of viscosity. At a (CaO+ MgO)/ ratio of 0.53 the addition of 10 per cent TiO2 is as effective as the addition of 3.75 per cent alkalies. This means that a blast furnace can be run without the addition of alkalies and consequently the detrimental effect of alkalies on the lining can be avoided; also that fluid slags with 5 to 15 per cent MgO and 8 to 10 per cent Al203 can be obtained with 10 per cent TiO present. (CaO+ MgO)/SiO2-ratios smaller than 0.5 the addition of titania resulted in a decrease in melting point and also in an increase in viscosity. In ceramic crucibles the slag did not become more viscous with time but thickened appreciably when held in graphite crucibles. No titanium carbonitride could be detected and only Ti20a was found. Prof Howat also did not obtain the TiC-TiN solid solution and therefore it appears that the thickening of the slag is not solely due to the formation of the titanium carbonitrides. This is in agreement with the work of Michailov and Belyakova2 who found that TiO2 decreased the viscosity of acid slags and increased the viscosity of basic slags; that titanium sesquioxide (Ti203) and titanium monoxide (TiO) increased the viscosity of both acid and basic slags and that titanium carbide, which is found in larger amounts in basic slags than in acid slags, considerably increases the viscosity of both acid and basic slags. Patzak et al3 describes the following oxygen deficient titanias, viz Ti2O, TiO, Ti203, Ti3O5, Ti4O7, Ti5O9, Ti6O11- Ti10O9,Ti7O13,Ti8O15 and Ti9O17. Until about 1959 a fair amount of data was available on the viscosity of normal slags to which titania was added2, 4, 5, 6, 7, 8, 9. At Iscor an electromagnetic viscometer based on the viscometer developed by Bockris10 was built. Progress was very slow as our main attention was centred around problems associated with the operation of the Rotor process. During 1962 and 1963 two papers containing fundamental work on the viscosities of slags in the systems CaO-SiO2-TiO211 and CaO-SiO2-TiO2 at 0 per cent A1203, 10 per cent Al203 and 20 per cent Al20312 appeared. The work of Ross and Ohno obviated the necessity of any further work by Iscor on the viscosity of blast furnace slags containing titania. Ross gave the following optimum compositions for blast furnace slags containing titania. Titania % Lime % Silica % Lime/Silica-ratio 20 30-42 38-50 0.6-1.10 30 27-36 34-43 0.63-1.06 40 24-32 28-36 0.66-1.14 The optimum temperature is 1,500°C because at this temperature the largest workable composition range exists. Higher temperatures result in narrower optimum composition ranges and in increased rates of thickening. The factors affecting the rate of thickening were also investigated by Ross and Ohno, as the main problem with slags containing titania is not finding compositions which are fluid at operating temperatures but the thickening due to a lack of oxygen. With these slags when there is insufficient oxygen to co-ordinate each silicon atom with its own individual shell of four oxygen ions, some sharing of oxygen ions must occur, resulting in the formation of large silicate ions and a rise in viscosity. The formation of oxygen deficient titania can be prevented as long as iron oxide or manganese oxide remain in the liquid slag. Iwase13 and also Viens, Camp bell and Rogers14 obtained in the experimental smelting of ilmenite ores fluid slags with more than 3 to 5 per cent manganese oxide and ferrous oxide in the slags. It appears that titaniferous ores can be smelted in blast furnaces under the following conditions: (1) Acid slag operation, i.e. at C/S-ratios from O.6-1.0. (2) Dolomite can be used as a flux as MgO is a network modifier. (3) The Al2O3-content must be less than 15 per cent as alumina promotes thickening of the slag and decreases the optimum composition range. (4) The hearth temperature must not exceed 1,500°C. According to Ross a definite amount of energy is required for each ton of iron produced and in order to increase production an increase in heat

Jan 6, 1969

By Y. Belloa, C. Dorfling

The presence of impurities such as Se and Te in copper sulfate leach solutions can have a detrimental effect on electrowinning efficiency. These elements can be removed from the solution by precipitation; sulfurous acid is commonly used as a precipitation reagent, while studies have also reported improved precipitation with the addition of metallic copper. This paper aimed to determine the effect of conditions used during the solution purification step on the characteristics of the precipitates that formed. Precipitation tests were performed in a batch reactor with copper sulfate leach solutions obtained from the base metal refinery of a platinum group metal producer. The effects of agitation rate (250 and 500 rpm), SO2 flow rate (4.4 and 5.8 mL/min.L), temperature (65 and 95°C) and metallic copper powder addition (0, 1 and 2 g/L) on the characteristics of the precipitates formed during the tests were determined using scanning electron microscopy. The major phases detected in the precipitates formed when using SO2 as the only precipitation reagent were elemental Se and Cu2Se. The introduction of copper powder led to the production of different sulfide phases for the experiments conducted at 65°C irrespective of the values of the other reaction parameters. At 95°C, Cu crystals, Cu2O and tiny inclusions of Cu2(Se,Te) were the prominent phases noticed in the precipitates produced from all the tests conducted with copper powder as precipitation enhancing reagent. Keywords: copper, precipitation, selenium, tellurium

Jan 1, 2020

By J. O. Claassen

"Homogeneous populations are required to perform descriptive, probabilistic, and inference statistics and to support stable, predictable mining operations. The geological and downstream processing environments are, however, highly heterogeneous. The complex nature of mining environments requires means to identify and define multipopulation environments that could affect the performance of mining value chains. A study performed at several operating mines suggests that the impact of heterogeneous or variable geological, mining, and plant processing environments on overall mining value chain performance may not be a key focus area at these operations. This was illustrated through the use of basic and spatial statistics, which included the log-probability plot, a modified range equation, and chronovariography. The findings reflect high relative variability in the geological and processing environments studied and mining operators’ inability to effectively deal with the sources and consequences of variability. The study suggests that a focus on heterogeneity in complex mining operations may significantly enhance overall mining performance. IntroductionHeterogeneity and why it mattersHeterogeneity refers to a state or quality of being variable/diverse and comprising different non-compatible elements or parts. In statistical terms a heterogeneous population can refer to a population comprising different non-compatible sub-populations or a multipopulation environment. The latter is commonly found in natural environments such as geological environments (Bardossy and Fodor, 2001). The inherent heterogeneity of complex geological environments is also referred to as spatial heterogeneity. Heterogeneity or variability, however, also occurs over time at mining operations. A case in point is variable ore composition on a conveyance system feeding a processing plant or product stockpile.Heterogeneity associated with the mining environment can significantly influence key aspects of day-to-day mining operations such as sampling, the use of descriptive, probabilistic, and inference calculations, and an operation’s ability to manage and control the mining value chain as a whole."

Jan 1, 2016

By Y. Yang, L. Li, X. Liu

Coal mining in China is facing the transition from output to quality. Based on the total mining capacity and average production, the current situation of coal mining at mine, city, and province levels is analysed, and data in support for the layout of sustainable mining development and the optimization of output provided. The results show that 87% of China's coal is mined by underground methods, with an average production capacity of 0.93 Mt/a per mine. Open pit mining accounts for 13%, with an average mine production capacity of 5.73 Mt/a. The average mining capacity of coal mines in China is 1.05 Mt/a, with 1181 coal mines with an average capacity less than 0.3 Mt/a, accounting for 35% of the total coal mines but contributing only 4.51% to output. They are distributed in about 48 cities in six provinces, seriously restricting the transition to green coal mining. The coal industry should speed up the closure of small coal mines in key provinces and cities, eliminate outdated production capacity in the central region, increase the speed and proportion of coal resources moving westward, and promote high-quality development of coal mining.

Jan 26, 2023

By Q. Fu, Q. Wang, L. G. Wen, M. X. Jia, J. J. Zhao, J. W. Zhou

The BGRIMM process mineralogy analyser (BPMA) is a new automated mineralogy software platform developed in China. This system consists of the BPMA software platform, controlling a combination of commercially available scanning electron microscopy (SEM) and energy dispersive Xray spectrometry (EDS). The BPMA software controls SEM and EDS through their application programming interfaces, to form an auto-SEM and EDS system that automatically acquires BSE images and X-ray spectra, respectively, and classifies minerals by spectrum-matching. After automated measurement and mineral identification, various quantitative process mineralogical data (e.g., mineral composition, mineral abundance, mineral liberation and intergrowth relationships, mineral associations, particle and grain sizes, particle density distributions, calculated assay, elemental deportments, mineral grade recovery and elemental grade recovery, etc.) would be calculated quickly, accurately and automatically. The BPMA could be used for ore characterisation as a new advanced automated mineralogy technology. Keywords: BSE image; X-ray spectrum; automated mineral identification; quantitative mineralogical investigation; automated mineralogy

Jan 1, 2020

The inherent weakness of the Zincor and similar iron removal processes is the relatively high undissolved zinc loss associated with the iron residue. High soluble zinc losses also occur due to poor filterability of the iron residue even though it may be limited to intermittent events. This work focussed on defining the optimum operating window for the Zincor iron removal process where iron is mainly removed in the form of amorphous, intermediate iron phases such as schwertmannite and ferrihydrite. In terms of the main operating conditions, optimum filterability was achieved under the following conditions: pH of 3.0, temperature as high as practically possible (70C), at least 25 kg/m3 seeding, and a retention time of at least 4 hours. When increasing the temperature from 60C to 70C, the required residence time decreased by almost 50%. Undissolved zinc loss was also reduced from 8% to between 2% and 3% by using a basic zinc sulphate/zinc oxide mixture as neutralising agent to effect iron removal.

Jan 1, 2003

By D. H. Diering

Definition of mineral resources and reserves forms the basis for effective mine planning and reliable public reporting of mineral assets. Historically the mineral resource and reserves declaration process has been the domain of the geology and surveying disciplines, with the declaration of the reserves by the surveyor being based on the application of modifying factors to the declared resources available for mining. As part of an ongoing process to improve efficiency, reliability, and reproducibility of results, this approach has been revised and enhanced through the introduction of a revised process and reconciliation tools. The revised approach to reserve definition is based on the definition of scheduled resources, at an appropriate confidence estimate in the context of an approved business plan, over the anticipated life of the mineral asset being applied to define reserves. This planning and scheduling is developed, during the annual business planning process, by the mine planning department using tools such as CADSMine?. The scheduled area together with the application of revised modifying factors is tabulated in the BME (basic mine equation) and reflects the mine production plan over time. Simplification of the modifying factors to dilution and losses underpins the simple yet robust approach to improved definition of reserves in this process and in the basic resource to reserve equation (BR2RE). Dilution intrinsically affects grade but not metal content, whereas the losses reflect both the efficiency of mining and planning and are reflected in metal losses, area losses, or both. Reconciliation of the derived ?resource converted to reserve? area, (which is based on the business plan from CADSMine?), versus the ?resource available for mining?, (which is derived from Datamine?), underpins the robustness and auditability of the reserves declaration. This R&R accounting and reconciliation approach is transparent and facilitates interrogation of the logic and rationale of long-term business planning and project strategy. These numbers are processed and reported in the logic of the basic resource equation (BRE), which also addresses aspects such as white areas (future and historic), tail management, and partial extraction (non-scheduled pillars, etc.) in compliance with SAMREC definitions. Areas that do not have the necessary confidence and data support to be declared as resources find their space as pre-resource (outside the domain of public reporting), outlining existing potential for future extraction and reporting. Use of the BRE leads ultimately to a complete, refined accounting and reconciliation-oriented approach for all production entities. The revised resource and reserve process includes the discipline of mine planning as intrinsic to the definition and declaration of resources and reserves. Subsequent to the change in process, the resources and reserves have truly become the domain of the mineral resource management discipline. This paper defines the logic of the basic resource equations and outlines their application in the definition and reconciliation of mineral resources and reserves at Anglo American Platinum Limited.

Jan 1, 2012

By T. Ono, B. Altansukh, S. Kawamura, K. Haga, A. Shibayama, Y. Takasaki

In recent years, the grade of silica in zinc concentrate has increased due to the degradation of zinc content and the increase in impurity content in natural ores. It implies that the development of silica removal technology from zinc concentrate is necessary to solve problems in the smelting process caused by the high content of silica in zinc concentrate. In this paper, the authors investigated the silica removal processes from silica-rich zinc concentrate by mineral processing approaches such as re-grinding and flotation. This study focused on the pulverisation process as a pretreatment for the investigation of individual minerals' liberation from the silica-rich zinc concentrates using different kinds of pulverisers. Flotation experiments were performed to separate silica and zinc concentrate from the pulverizsd feed sample using a pH regulator (NaOH), activator (CuSO4), collecting agent (PAX), and foaming agent (DOW froth 250). Results showed that the liberation rate of silica (SiO2) was reached 75% from 13% by pulverisation in an attritor with a 2 mm ball in diameter, while silica accumulated in a fraction over 20 mm in size. Flotation experiments indicated that silica removal efficiency was achieved by 44% from + 20 mm fraction obtained from pulverisation whereas the grade of silica in froth reached 1.85 mass% from 4.5 mass%. Results indicate that silica could selectively separate from silica-rich zinc concentrate, and 99.8 % zinc recovery is achieved under the studied conditions. Keywords: Zinc concentrate, silica, pulverisation, liberation, sieving, flotation

Jan 1, 2020

By G. Akdogan, S. M. Bradshaw, M. I. Isaacs, P. Van Wyk

In the mineral processing industry, Ni-Cu-Fe-S converter matte is leached in order to remove base metals from a concentrate containing platinum group metals (PGMs). This paper investigates the atmospheric leaching process, in order to develop a better understanding of the leaching behaviour of the base metals; in particular Cu, Fe, Ni, and the PGMs in particular Ru and Ir with key process variables, acid concentration, copper concentration under oxidative leaching conditions. Higher initial acid concentration resulted in a higher copper, iron and nickel extractions, as well as higher leaching rates together with faster Cu, Ru, Ir precipitation occurring. On the other hand, a higher initial copper concentration resulted in more nickel but less iron being extracted. Keywords: PGM, converter matte, leaching, precipitation

Jan 1, 2020

By M. B. Shongwe

Pt-based alloys are being developed for high-temperature applications with the aim of replacing some of the currently used Ni-based superalloys (NBSAs) in the highest temperature applications. The Pt-based alloys have a similar structure to the NBSAs, and since Pt is more chemically inert than nickel and has a higher melting point, they can potentially be used at higher temperatures, up to 1300°C, and in more aggressive environments. Several experimental Pt-based alloys were studied at Mintek, and an optimum composition was found to be Pt84:Ahi:Ru2:Cr3 (at.%). On the basis of hardness and microstructure, a later study identified a new optimum: Ptr8:A111:Ru5:Cr6 (at.%). There are at least two Pt3A1 allotropes, and the high-temperature cubic structure has better properties than the lower temperature tetragonal form, and so needs to be stabilized. This work describes the latest results obtained in transmission electron microscopy (TEM) studies of the quaternary Pt-based superalloys. These results are both interesting and important, because the samples have a higher precipitate density compared to those from earlier work. The precipitate morphology is mainly cubic, with minor areas having irregular-shaped precipitates. The high volume fraction of the precipitates is a major breakthrough, since the objective of this work is to improve the alloys. A prior disadvantage was that the proportion of the precipitates was too low in samples before this work, especially compared with the work from Germany on Pt-Al-Cr-Ni¬based alloys as well as the NBSAs. TEM -Pt3A1 diffraction patterns were studied, and for each diffraction pattern, many possible lattice point combinations were tried, with the angle between the lattice spots as well as interplanar spacings being calculated for each phase (cubic or tetragonal) to match the measured results. An overall analysis of the diffraction results indicates that the cubic phase fitted the experimental lattice points with much lower errors compared to the tetragonal phase. Thus, with the close match achieved with the cubic structure, the structure of -Pt3A1 precipitates is likely to be cubic. X-ray diffraction has been carried out on selected samples, and the results confirmed the presence of cubic -Pt3A1 and (Pt). Different X-ray diffractometers were used to further verify the results, and the results were also compared with those from TEM.

Jan 1, 2012

By D. R. Young

Drilling exploration over the Wesizwe Platinum Limited?s Pilanesberg Project has identified the Merensky Reef at depths varying from 594 m to 1 552 m depth. Merensky Reef thickness varies from 0.05 m to 3.63 m and contains PGE(4) mineralization above a cut-off grade of 1.0 g/t over intersection widths of 0.95 m to 2.63 m. Four distinct facies types have been identified over the property, viz.1) Normal Merensky Reef, generally 1.2 m thick, bounded by thin top and basal chromitite layers and composed of upper feldspathic pyroxenite and lower feldspathic olivine pegmatoids containing base metal sulphide mineralization overlying poikilitic anorthosites. 2) Single chromitite Merensky Reef, generally0.15 m thick and usually devoid of internal silicate material, overlying variable stratigraphy containing significant base metal sulphide mineralization. 3) Detached Merensky Reef, generally1.0 m thick, bounded by thin top and basal chromitite layers and composed of feldspathic pyroxenite or pyroxenite containing base metal sulphide mineralization overlying Merensky Pyroxenite. 4) Normal footwall Merensky Reef, generally 1.8 m thick, bounded by thin top and basal chromitite layers and composed of feldspathic pyroxenite containing base metal sulphide mineralization overlying norites also containing significant base metal sulphide mineralization. The PGE(4) content?s (g/m2) distribution for the global intersection data appears to be lognormal, and conversion to lognormal space produces a near normal distribution which could be interpreted as a compound lognormal distribution. The mean PGE(4) contents estimated by these three different distributions are the same, and thus do not impact on the contained metal. Data for the Normal Merensky Reef facies type are sufficient to indicate that a normal distribution is followed for this facies type, and therefore does not need to be transformed to log space for estimation of the mean and the 90% confidence limits. A global evaluation based on all of the data is compared with a facies-weighted evaluation. The latter method is noted to provide a better definition of the associated estimation errors and thus potential classification of Mineral Resources. A valuation of $20.95 for Inferred and $41.90 for Indicated PGE(4) ounces is applied to both of the evaluations and compared. The global evaluation is considered to over-value the project by approximately 40%, thus indicating that valuations based on global summary sampling data that have a compound distribution may be materially flawed, and that cognizance of the underlying geology is crucial for unbiased valuation.

Jan 1, 2006

By S. C. Maji, U. S. Chattopadyay, S. Chaudhuri, T. Gouri Charan

India is devoid of coking coal resources, which is a vital raw material for coke making. As a result it has to import about 80% coking coal for steel making. Indian National Steel Policy, 2017 has envisaged crude steel production around 300 million tonnes Mt) by the year 2030-31 and forecasts coking coal demand of 161 Mtpa (million tonnes per annum). One way of improving the indigenous resources is to study the performance of existing washeries and to improve the clean coal recovery by adopting suitable technology. A study was carried out, mainly to focus on the fine coal circuit of an existing coking coal washery, to generate the desired quality of clean coal. The operating coking coal washery being studied is presently feeding coal from nine different sources with varying feed ash contents. The coal fines varied in ash content ranging from 19.5% - 43.6%. For treating the coal fines, the washery has operated a spiral for the past few years. Performance studies were carried out, and it was found that the spiral is not efficient in recovering the cleans. Detailed investigations were carried out on the coal fines using flotation techniques, and it was found that to achieve a low ash clean coal, the froth flotation is a much better beneficiation option than a spiral, The studies showed that the recovery of clean coal through a spiral is 67.7% at ash content of 27.0%, while flotation tests showed a recovery of 68.1% at 16.5% ash content. Keywords: Coking coal washery, near gravity material, spiral washer, froth flotation

Jan 1, 2020

By C. B. Carelse, M. Manuel, D. Chetty

Automated mineralogical analysis of platinum group minerals (PGM), using the mineral liberation analyser, provides information used to understand flotation efficiency, primarily from a PGM liberation and association standpoint. To date, however, there is no consistent understanding regarding PGM speciation and its impact on floatability. Previous studies of PGM from UG2 ores concluded that a larger dataset is needed from which the various parameters can be modelled. Parameters on telluride, arsenide, sulfurarsenide and alloy species need to be integrated to fully understand the impact of PGM speciation on flotation, and for this, ores other than PGE-sulfide-rich UG2 must be assessed. Flotation rougher rate tests were performed on feed samples from two Platreef ores to determine the flotation response of individual liberated PGM species. This was achieved through automated mineralogical analysis of feed, rougher concentrates and tails. Based on 1529 liberated PGM grains assessed over the circuit for two Platreef ores, preliminary results show that PGM speciation, species grain size and competition from gangue appear to influence floatability in an ‘optimised’ laboratory environment. Keywords: PGM, PGM species, flotation, liberation

Jan 1, 2020

By van der Merwem J. N.

"Coal pillars are prone to scaling over time, and are progressively reduced in size and consequently subjected to increased load and reduced strength. The effective factor of safety therefore reduces. Databases of failed and stable pillars cannot, therefore, be regarded as definitive.More than a decade has passed since the first attempt to predict the lifespan of pillars. This paper presents a review based on the new database and pillar strength equations. The methodology for the analysis is based on the fact that pillars scale. The ultimate safety factor (defined as the ratio between strength and load at the time of failure) is derived, followed by an estimate of the rate of pillar scaling, which results in an estimate of the expected time of failure.It is suggested that the predicted lifespan should not be used as an absolute indicator of expected pillar life, but rather as an index – the pillar life index (PLI) – to complement the safety factor and related probability of failure when evaluating pillar stability. A pillar with a predicted lifespan of less than 500 years would be regarded as being in danger of imminent collapse, while a lifespan of at least 1 000 years should be required for long-term purposes.The differences between this analysis and that published in 2003 constitute a strong case for regular reviews of all the empirically based stability indicators, namely the safety factor, probability of failure, and the PLI. Reviews at 10 year intervals appear to be required.The constants in the proposed method are valid only for the Witbank No. 1, 2 and 4 seams and the Highveld No. 2 and 4 seams.IntroductionIt is well known that over time, coal pillars are prone to scaling, and thus are progressively reduced in size and consequently subjected to increased load and reduced strength. The effective factor of safety therefore reduces and it is quite possible for failure to occur after a long time interval. In fact, scrutiny of the database of failed pillars indicates that failure occurred after periods ranging from 2 to 49 years, and not immediately after mining.The factor of safety for pillars at the time of failure is not the same as that immediately after mining. The concept of the safety factor is based on the pillar strength obtained by statistical analysis of pillar dimensions immediately, or within a month after mining, when the surveys are conducted. Strictly speaking, the safety factor as commonly used is valid only immediately after mining, and it continues to reduce thereafter. The ideal situation would be to base analyses of pillar strength on pillar dimensions at the time of failure, but that is simply not possible because the real dimensions cannot be measured at that time."

Jan 1, 2016