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By A. S. Ibrado, D. W. Fuerstenau

"Gold, silver and copper form various complexes with cyanide, of which only the singly charged dicyano form adsorbs appreciably on activated carbon. The adsorption of the dicyano complexes appears to be controlled predominantly by chemical reaction at the surface of a shrinking unreacted core. Metal uptake over time is non-linear, which eliminates control by boundary layer diffusion. The rate of adsorption is not enhanced by a reaction interruption, which suggests the absence of concentration gradients in the pores. Finally, the rate of adsorption increases with decreasing activated carbon size in a manner consistent with the shrinking core model. The results of this investigation accentuate the importance of efficient acid washing of carbon and removing carbon fines from the barren carbon stream. INTRODUCTION With the dwindling reserves of high-grade ores, most of the world’s gold is produced from low-grade ores by cyanide leaching. In the past, leaching was followed by the Merrill-Crowe process, in which gold is precipitated from clarified pregnant solutions by zinc cementation. This process is still being used for high-silver ores, where the cost of carbon stripping becomes prohibitive. For deposits with silver-to-gold ratios of about 4 or less, adsorption on activated carbon would be the usual solution purification step taken. The process simplifies solid-liquid separation and offers a viable solution to preg-robbing organic carbon in some ores. The modern industrial application of carbon adsorption started with the carbon-in-pulp (CIP) process, where carbon adsorption was used mainly as a solution purification step. In 1973, Homestake Mining Company commissioned the first large-scale CIP plant in the U.S.A.1 Later, carbon was added earlier in the circuit to control preg-robbing by adsorbing gold cyanide onto activated carbon as soon as it is dissolved. The scheme is successful because activated carbon is a stronger adsorber than the organic carbon found in preg-robbing ores. This process came to be known as the carbon-in-leach (CIL) process. Numerous research investigations have been performed on the chemistry involved in the CIP process, which at the time of its introduction was not clearly understood. Of these, research on the kinetics of adsorption probably bears the most immediate impact on industrial practice,2,3 where adsorption systems rarely reach equilibrium, if at all, and slight slowdowns in the adsorption rate can translate into significant decreases in revenue. To illustrate this, organic compounds, like flotation reagents, have been known to impair CIP circuits. However, laboratory tests showed that the organic compounds do not significantly affect the adsorption capacity of activated carbon. Rather, the harmful effect may be attributed to a lowered adsorption rate.4,5 Also well known is the faster rate at which fine activated carbon powders reach equilibrium compared to coarse activated carbon, even though the final (equilibrium) amount of material adsorbed per unit weight is the same."

Jan 1, 2015

By Martin H. Stanczyk

In recent, years the demand and consumption of finely ground industrial minerals has substantially increased for such uses as fillers and chemically reactive components. The size, specifications for these types of industrial mineral materials vary to a great extent and depend on the particular end purpose' and on the physical properties of the mineral itself. Size reduction of industrial minerals usually is obtained by conventional crushing and grinding methods. However, some specialized milling techniques have been developed for producing these minerals in extremely fine particle size ranges. During recent years the Bureau of Mines has been investigating an attrition grinding method to produce ultrafine subsieve-size mineral particles. The Bureau developed process, which has been patented,2 comprises the intense agitation of a slurry composed of the material to be ground, a relatively fine granular grinding medium, and a suspending fluid. The process has been shown to be effective for the comminution of kaolin in the particle size range of 2 microns and finer on a batch3 and continuous basis.4,5 This report presents the results of batch tests made to determine the effectiveness of the attrition grinding process for comminuting commercial products of (1) mica, a tough lamellar material, (2) fluorite, a brittle intermediately hard material, and (3) barite, a relatively soft, massive material.

Jan 1, 1967

By J. E. Miller

The development of a new means of measuring the relative abrasivity of a slurry came about by necessity in 1967 during a full scale loop test of a 560 H.P. reciprocating pump handling magnetite slurry. In order to evaluate the life of expendable fluid end parts, the question of the amount of attrition in a re-circulated slurry had to be considered. An expected reduction in abrasivity as a result of this attrition would certainly give erroneous data on a parts life test. There- fore, some means of measuring such change in abrasivity became imperative. Several test methods were investigated1 but it was felt that these did not fully represent the wear due to back and forth rubbing action associated with a reciprocating pump. A "rubbing block" device used some years ago to determine the quality of hard facing materials was recalled, along with its shortcomings, in that an attempt was made to suspend a small percentage of abrasive particles in a colloidal viscous "mud". Erratic results were attributed to the fact that it was difficult to maintain a consistent slurry concentration under the metal wear block and the reciprocating speed was not great enough to maintain good agitation.

Jan 1, 1973

By D. P. Patil, B. K. Parekh

Water is the mainstay for beneficiation of fine size coal and minerals; however, it is also the least desirable constituent in the final product. The basic concept of the novel process described in this paper is based on the differential surface heat conduction/ absorption capacity of individual particles, which differs for different species of minerals. When a mixture of fine material is exposed to a radiant energy source, the various solids present in the mixture will absorb heat energy depending on their heat-conducting properties and there will be a difference in the surface temperature of the particles. When this differentially heated solid mixture is placed on a moving belt, which is coated with a low temperature melting resin, the hotter component of the mixture will stick to the belt and relatively cooler particles will stay free on the belt and fall off at the end of the belt run. Experiments were conducted with pyrite, coal, and quartz of 6 × 18 mesh particle size. The goal of the test program was to find the optimum conditions at which there exists a required temperature difference between minerals and coal particles by controlling the operating system variables. Preliminary tests results showed that there is a potential for separating mineral matter from coal using the thermo-adhesive separation technique.

Jan 6, 2022

The dissolution kinetics of cobalt in iodine/iodide solutions was investigated using a rotating disc technique. Variables studied here included temperature, rotating speed, concentration of lixiviants, and pH of the solution. The overall dissolution reaction was found to be limited by mass transfer of tri-iodide through the diffusion boundary layer with Arrhenius activation energy of less than 16.2 kJ/mol (4 kcal/mol) over the temperature range, 2-42°C. The pH of the solution had little effect as long as the pH of the solution was less than 8. However, when the pH of the solution became greater than 8, the dissolution rate decreased dramatically due to passivation. The rate of dissolution was in good agreement with the dissolution model developed by the authors earlier.

Jan 1, 1994

By P. G. Dempsey, J. R. Heberger, J. P. Pollard

During a mine disaster or emergency, underground air can quickly become contaminated. In these circumstances, all underground mine workers are taught to don breathable air supply units at the first sign of an emergency. However, no contemporary oxygen consumption data is available for the purposes of designing breathing air supply equipment specifically for mine escape. Further, it would be useful to quantify the oxygen requirements of breathing air supply users for various escape scenarios. To address this need, 14 participants crawled a distance of 305 m each while their breath-by-breath oxygen consumption measurements were taken. Using these data, linear regression models were developed to determine peak and average oxygen consumption rates as well as total oxygen consumption. These models can be used by manufacturers of breathing air supply equipment to aid in the design of devices that would be capable of producing sufficient on-demand oxygen to allow miners to perform self-escape.

Jan 1, 2015

By G. A. Kordosky

Solution mining followed by solvent extraction-electrowinning (SX-EW) is one possible way to economically extract copper from ore bodies which cannot otherwise be profitably exploited. Published costs for the unit processes of SX and EW are out of date especially in view of the newer reagents now available and the newer circuit configurations, This paper updates the costs for SX-EW in 1985 dollars and also discusses some of the trade-offs which must be made when designing an SX-W plant.

Jan 1, 1986

By Nik Sokol, Eric Sekulski, Leo Weiman-Benitez, Jon Hurt, Shrinidhi Vijayakumar, Phaidra Campbell

The Silicon Valley Clean Water (SVCW) Gravity Pipeline (GP) is the first Progressive Design Build (PDB) tunnel completed in North America. As part of the Regional Environmental Sewer Conveyance Upgrade (RESCU) Program, the tunnel is a key component to replacing and rehabilitating components of the existing conveyance system in San Mateo County, California. The GP consists of a large diameter Fiberglass Reinforced Polymer Mortar (FRPM) pipe installed inside a 4.1 m (13.5 ft) inside diameter, 5.3 km (3.3 mile) long precast concrete segmentally lined tunnel. The tunnel was constructed using a 4.6 m (15.2 ft) diameter Earth Pressure Balance (EPB) Tunnel Boring Machine (TBM) through heterogenous silts, clays and sands. Construction included two separate TBMlaunches from a centrally located access shaft, and a tunnel alignment below but in close proximity to very soft Young Bay Mud. Settlement criteria and mitigation strategies focused on protection of an existing 1.42 m (56 inch) diameter force main and adjoining structures along the alignment. This paper discusses the results of the theoretical settlement analysis versus the actual observed ground movements, while also presenting mitigation measures and adjustments made during tunneling to reduce the risks of adverse settlement.

Jun 13, 2023

By Matthew Wilcock, Kenichi Soga, Peter Wright

"This paper discusses how an existing grey cast iron segmental tunnel lining responds to construction of a new SCL tunnel transversely beneath with zero clearance; how the damage assessment for the existing tunnel was conducted for impact of longitudinal movement; how the tunnel is subsequently instrumented to observe both movement and stress manifestation at its longitudinal connections and how the results from the instruments compare with the prediction. An assessment of neutral axis of the tunnel in longitudinal flexure is also explored using interpolated horizontal displacement data from a conventional monitoring system. INTRODUCTION The Royal Mail Tunnel (RMT) (formely Post Office Tunnel or ‘Mailrail’) was constructed using semi-mechanised deep level construction techniques from 1914 and 1917 (Lee 1938). Commencing full commercial operation in 1926, the system was until 2003; conveying parcels the 6.5 miles between seven sorting offices in the center of London, and linking the system with main line rail stations, Paddington and Liverpool Street (The British Postal Museum & Archive 2013). A single tunnel of 2.74m internal diameter facilitated a bi-directional twin narrow-gauge (~611mm gauge) railway road system for electric driverless operation. The tunnel lining is segmental grey cast iron (grade 10) made up of six flanged segments and a smaller flanged key segment; constructed into a ring of width 508mm The external diameter of the tunnel is 2.971m. For further details of the tunnel lining and material properties are outlined by (Devriendt & Alhaddad 2014).London Underground Bond Street Station is a major station of the London Underground system in the very center of London; in its vicinity, the RMT runs west-east perpendicularly above the north south Jubilee Line tunnels. Historic survey record of the Jubilee Line’s (the then Fleet Line) construction in 1974 and its impact on the RMT case is documented in (Crossrail 1993): it is one of only a hand full of case-studies frequently cited when assessing the impact of new construction scenarios of this type; not least including the assessment of the same tunnel, at the same site some 40 years later, and the subject material for this paper: It noted significant vertical displacement of ~90mm to the RMT without noticeable serviceability or operational impediment."

Jan 1, 2016

By M. W. Smith

Pennsylvania has 2500 miles of streams that do not meet water quality standards due to acid mine discharge (AMD), making AMD the greatest cause of water pollution in the state. The problem is mainly caused by abandoned coal mines. Pennsylvania is using a watershed-based approach to abating AMD which includes remining as a key component of a comprehensive restoration strategy. The Tangascootack Creek Watershed was targeted for AMD restoration through remining. Geologic mapping and overburden data were analyzed using Earth Vision software to identify areas of coal reserves which could be remined to improve water quality. Incentives are offered to encourage mining in these designated areas.

Jan 1, 1999

By H. Sis

The pressure filtration behavior of dispersed and flocculated alumina slurries at high percent loadings is discussed with an objective to determine the effect of surfactant type and concentration on slurry properties. A high purity alumina powder was used as a model solid. Dispersion of the alumina was controlled by surfactants that are considered to act by electric and steric stabilizers. The effect of both the ionic and nonionic surfactants was investigated. Surface charge measurements of the slurries were carried out by electrokinetic sonic amplitude (ESA) method to understand the mechanisms. The effect of surfactant type and concentration on the kinetics of pressure filtration and final cake properties are discussed.

Jan 1, 1998

By George L. Atwood

The Monsanto Company's Henry Mine is located 17 miles northeast of Soda Springs, in the southeast corner of Idaho. Ore being mined is phosphate rock which lies in the Permian Phosphoria formation. The ore is the raw material for Monsanto's three furnace elemental "P" plant near Soda Springs. The finished product from the furnaces is elemental phosphorus which is subsequently used in the manufacture of detergents, food preservatives, fire retardants and other consumer items. Mining is by open pit methods using 0-9 crawler tractors to rip and push-load rubber tired scrapers in stripping and mining operations. The equipment spread consists of six D-9G crawler tractors, four Caterpillar 6578 scrapers, eight Euclid S-24 scrapers, one Reich T750 drill and one Caterpillar No. 16 patrol plus various support equipment. Stripping is performed on a 12-month basis, two shifts per day. Mining is performed mainly in the summer months on a one shift basis. The hauling season begins May 15 and ends November 1 due to freezing weather and snow conditions. Annual production is 1,000,000 tons of phosphate rock and 2,500,000 to 3,000,000 yards of stripping. Stripping, mining and hauling is performed for Monsanto by Dravo-Soda Springs, a mining contractor. Dravo-Soda Springs owns, operates and maintains all equipment used in stripping, mining and hauling. The contractor is paid for stripping by the bank yard and for ore mined and hauled on a tonnage basis. The Monsanto elemental phosphorus plant began production in 1952 with ore being trucked to the plant from the Ballard Mine. Haulage was over public roads in 15, 24-ton semitrucks. A private haul road was constructed from the Ballard Mine to the Monsanto Plant in 1958 and 1959 to accommodate trucks with two twenty-yard trailers. This 11/ mile road was first used in the 1959 hauling season. In 1965, five new Kenworth tractors with two, 'forty yard trailers were introduced into the haulage system. These units carried 120 ton payloads and were used until

Jan 1, 1972

By Tim Langmaid, Steve Skelhorn, Stephanie Robillard, Allen Mitchell

"The Port Mann Main Water Supply Tunnel project provides a critical water main crossing of the Fraser River for the owner, Greater Vancouver Water District (Metro Vancouver). The project consists of two 60-metre-deep slurry panel shafts and a 1-kilometre-long, 3.5-metre excavated diameter tunnel located near Vancouver, British Columbia, Canada. The initial tunnel lining is a precast concrete steel fiber reinforced gasketed segmental lining. The final lining is a 2.1-metre-diameter welded steel pipe. This paper describes the challenges encountered during tunnel construction and the solutions implemented. Key challenges include earth pressure balance tunnelling at up to 6 bar pressure—the highest to date in Canada—a water-crossing without surface access for the majority of the tunnel drive, ground freezing from a river platform for a critical TBM intervention, and boring through cobbles and boulders in dense glacial till. INTRODUCTION Metro Vancouver supplies drinking water to 18 municipalities, one electoral district and one treaty first nation, serving a population of more than 2.4 million residents. Water is collected in three mountainous watersheds to the north of the Greater Vancouver area, in southwestern British Columbia, Canada. To supply the growing demands of Metro Vancouver’s customers, treated water must be conveyed across two significant water bodies: the Burrard Inlet and the Fraser River. The existing Port Mann water main is one of several key links between the watersheds north of Vancouver and the municipalities south of the Fraser River. The Port Mann Main Water Supply Tunnel (PMMWST) is the first of a series of upgrades, to increase capacity, enhance scour protection, and improve seismic resilience. The new tunnel is 3.5 metres (11.5 ft) in diameter and 1 kilometre (0.6 mi) long. When completed, it will contain a new 2.1 metre (7 ft) diameter steel water main that will help ensure the continued, reliable delivery of drinking water to these municipalities, and will more than double the capacity of the existing 1.2 metre diameter main."

Jan 1, 2016

By Joseph Moses Botbol

Two methods are developed whereby; (1) mineralogic data can be arranged in order of typicality, and (2) mineralogic data external to a model can be compared with the model and the degrees of association computed. Thirty arbitrarily selected base metal mining districts in the conterminous United States were classified as copper, lead, or zinc districts on the basis of tonnage of the major base metal produced. For each of the copper, lead, and zinc districts binary-occurrence distributions were compiled for primary (unoxidized) and secondary (oxidized) minerals. Primary and secondary minerals were then arranged in order of decreasing typicality. Model copper districts are most typified by primary chalcopyrite, pyrite, and secondary malachite. Model lead districts are most typified by primary galena, quartz, pyrite, sphalerite, and secondary anglesite and cerargyrite. Model zinc districts are most typified by primary sphalerite, galena, pyrite, quartz, and secondary smithsonite and cerus-site. The Park City district was removed from the model and its primary and secondary mineralogy was compared with the model copper, lead, and zinc districts. The primary mineralogy of the Park City district is about equally associated with the model copper and lead districts, but the secondary mineralogy is much more akin to the model copper districts. Thus, with respect to the model data, the geochemical target presented by the Park City district resembles a copper district more closely than a lead district.

Jan 1, 1969

By Brianna Eiter, Max Barham, Tim Bauerle

Fatigue-related risk is a persistent safety concern for the mining industry. However, fatigue and sleepiness are often treated interchangeably, which can lead to confusion and potentially less effective reduction of safety risk. To provide clarity, we present an overview of similarities and differences between work-related fatigue risk and sleepiness including definitions, theories, measurements, and mitigation strategies. As a supplement, a summative visual model which highlights these similarities and differences is presented. Expanding industry knowledge in this area will assist safety professionals in crafting more targeted risk management practices appropriate for work-related fatigue risk, sleepiness, or both.

Dec 19, 2023

By RIINA SALMIMIES, ANTTI HAKKINEN, PAULA VEHMAANPERA

Better understanding of the mechanisms and kinetics of dissolution can benefit several industrial processes. For example, iron can be leached from clays, which can be further used as a raw material in the ceramic industry. Another important application is the regeneration of ceramic filter media, which are used in the dewatering of iron ores. Dissolution of iron oxides in mixtures of acids is fairly uncommon and a less well-understood phenomenon, but it can result in a more efficient process. This work also shows that the determination of dissolution mechanisms and kinetics is not straightforward in different acid systems.

By III Feeley

Coal is the nation's most abundant fossil energy resource and serves as the primary fuel for the U.S. electric-power industry. However, its continued and expanded use is often challenged by the nature and amount of its associated impurities, such as mineral matter, sulfur, and trace elements. The moderate- to high-sulfur content of many U.S. coals is of particular concern today as potentially more stringent regulations requiring further reductions in sulfur dioxide emissions are being considered. The most prevalent method currently employed to control SO2 emissions from coal-burning facilities is post-combustion flue-gas desulfurization. However, physical coal cleaning (a.k.a. beneficiation, preparation) methods can also be effective in removing sulfur and ash impurities from coal prior to combustion. In a typical physical cleaning operation, raw coal is crushed to about 50-mm (2-inch) topsize, and then screened into coarse, intermediate, and fine size fractions. Crushing liberates some of the ash-forming minerals, including the portion of inorganic sulfur (pyritic) not chemically bound to the coal matrix. The percentage of impurities liberated generally increases as the coal particle size is reduced. Coarse- and intermediate-sized coal particles are typically subjected to specific gravity-based cleaning methods, while fine-sized (less than 0.5-mm) coal particles are beneficiated using froth flotation, a technique based on surface property differences. Greater cleaning potential exists at finer sizes because of increased liberation of impurities, but this potential is not fully realized because of inefficiencies associated with fine particle separation using state-of-the-art coal cleaning technologies.

Jan 1, 1990

By E. C. Watkins

The fiber glass industry is an industry that. hopefully is still in its infancy and far from a mature business. Fiber glass, as will be discussed in this paper, deals with continuous strand glass as used in the textile laminate and reinforced plastics industries. More specifically, we are speaking of glass used for printed circuit boards, tapes, paper, cloth, pipes, tanks, boats, recreational equipment, roofing shingles, and automotive applications. Compared to the flat, container and decorative glass industries, we are very young. The early patents on fiber glass applications were issued in the 1930's. The type of glass most commonly used in the world and that discussed in this paper is designated as "E" glass. This is a boro-silicate type glass having specific chemical and electrical resistance and low thermal expansion properties.

Jan 1, 1986

By John W. Leonard

The typical tunnel boring machine in use on today's tunnel project uses 15'2-inch diameter cutters at a nominal load of 45 kips per cutter. The cutterhead rotates at a speed of 120 over D revolutions per minute where D is the cutterhead diameter in feet. The typical machine operates about 50 percent of the time. Delivery of a new machine takes 12 to 15 months. The TBM is a specialized tool and not applicable to all jobs. There is a range of job conditions that limit the economic use of a TBM. The machine should provide a thrust per cutter at least twice the compressive strength of rock in psi and up to three times the rock strength is required if in "granitic rocks." The rock strength in psi must be at least three times the cover above the tunnel in feet or the machine may stick. For example, 2,500 feet of cover requires at least 7,500 psi rock to avoid problems. When the RQD's over a significant distance of the project are less than 50, the TBM becomes support-bound. When a large percentage of the time is spent waiting while the ground is supported, the TBM cannot perform well (See Figure 1). This problem increased inversely with tunnel diameter. We are finding that increasing the RPM's does not significantly increase progress. The increased RPM results in a substantial decrease in cutter penetration. The explanation for this decrease appears to be vibration, cutterhead drag, or lack of stiffness in the cutterhead (See Figure 2).

Jan 1, 1981

By X. Baolin, R. Guru, M. Peiravi, M. K. Mohanty, Z. Qian, R. Ma, Z. Yude, L. A. Ackah

"Acid mine drainage (AMD) is produced when exposed pyrite (FeS2) reacts with air and water to form an acidic solution that usually contain contaminant levels of heavy metal ions. AMD can potentially contaminate surface water and soil if not treated. The primary objective of this study was to investigate the removal of dissolved aluminum, iron and zinc metal ions from natural AMD using water treatment residue (WTR), a low-cost adsorbent. WTR sorbent generated as waste material in drinking water treatment plants (WTP) was characterized and utilized for the sorption of Al, Fe and Zn in AMD collected from an abandoned coal mine site in southern Illinois that generates approximately 20 gallons per minute of AMD. Sorption experiments were performed using batch technique to obtain rate and equilibrium data. The effects of various parameters on sorption capacities of WTR were observed by varying contact time, pH of the AMD and WTR dosage. The adsorption studies showed rapid uptake in general for the first 80 minutes for Fe and Zn but much earlier for Zn. Further increase in contact time did not show significant change in equilibrium concentration indicating the onset of adsorption equilibrium. After the batch treatment of the AMD water with the WTR, the removal of Al, Fe and Zn were 99.8%, 99.85% and 95.5% respectively. The pH of AMD increased from 2.64 to a near neutral point of 6.74 after treatment. The laboratory results show that the low-cost WTR, which is an abundantly available industrial waste, has proven potential to significantly reduce the high metal ions in acid mine drainage. INTRODUCTION Mining activities provide the basic raw materials needed for infrastructure development and economic growth world-wide. However, it is well recognized that mining activities have been the cause of a variety of environmental pollutions, including AMD. Water seeping out of an old abandoned mine is generally characterized by low-pH with heavy loads of dissolved sulfates (SO4) and metal species such as Fe, Al and Zn among other dissolved elements categorized as toxic metals. The Bureau of Land Management’s Abandoned Mine Lands (AML) program reported the existence of about 46,000 abandoned mines in the United States. Several environmental problems have been reported to be associated with these mined out sites such as heavy metal poisoning, loss of vegetation, air pollution etc. (Boulanger & Gorman, 2004)."

Jan 1, 2017