Search Documents

By Richard C. Repsher

Intermittent mining in the slope section at Dutch Creek No. 1 mine, Carbondale, Colo., of the Mid-Continent Coal and Coke Co. has resulted in erratic and minimal rock noise data, which, in turn, has necessitated a change in the method used to plot daily mine noise in order to be useful to the researchers at the mine. Daily and weekly cumulative plots of rock noise under these conditions have not shown significant stress changes as clearly as bimonthly or longer noise rate plots. Hence, longer term cumulative rock noise plots, as described in this Bureau of Mines report, have been added to the data analysis at Dutch Creek No. 1 mine, and have been shown to delineate unique areas of rock noise activity more clearly than shorter term plots. The longer term plots should aid in the detection and delineation of potential failure areas, when used in conjunction with other proven forms of data analysis.

Jan 1, 1979

By Harold L. Gibbs

The purpose of this paper is to encourage petrographers to prepare thin sections, as the demand for microscopic examination of rocks, ores, and metallurgical products is becoming more general in .the mining metallurgical-fields. This paper has been written with the knowledge that the successful thin-section methods and the several new techniques herein described will be helpful to all engaged in this field of work. Detailed instructions for making thin sections by methods developed at the Salt Lake-City laboratory of the Bureau of' Mines are given in this paper. Several new techniques are described for making thin sections of loose grains and fine sands and for making good thin sections of highly altered and friable rocks. The methods described insure superior bonding of the rock to the glass slide, thus virtually eliminating any failures due to parting of the section from the glass slide, and permit fast mounting, grinding, and finishing, thereby materially lessening the time required to prepare thin sections.

Jan 1, 1950

By R. L. Handy

The goal of this research was to adapt the highly successful rock borehole shear test for use in deep, small-diameter boreholes. Operating somewhat on the principle of a rock bolt, the borehole shear test measures both the expansion pressure and pulling force to give discrete measures of rock shearing strength as a function of the applied normal pressure. A new instrument was designed and built to fit into a 2-3/8 inch diameter hole. Unfortunately the design became so complicated, the operation is nut reliable. This is attributed to constraints of the small hole, and added requirements of an in-hole anchor to push against, and a rotating shear plate cleaner for repeated tests down-hole. A clue to the d: vice complexity is its length, which is over 10 feet. Furthermore it employs concentric cylinders and one hydraulic cylinder bored into the piston of another, or it would be even longer. Meanwhile drilling technology has advanced to greatly reduce costs of drilling 5- or 6-inch diameter holes. The downhole tester therefore should be redesigned and simplified for use in a larger diameter drill hole.

Jan 1, 1982

By L. B. Berger

Studies showing the effect of mixing hot exhaust gases with tie intake air of a four-stroke-cycle Diesel engine are described. The results indicate a marked increase in carbon monoxide in tip exhaust gases, a decrease in oxides of nitrogen, and no significant effect on aldehydes. The increase in carbon monoxide was greater at higher fuel-air ratios and was caused partly by the increase in fuel-air ratio end partly by the decrease in oxygen concentration resulting when exhaust has was added. The application of these results to the use of Diesel engines underground is considered.

Jan 1, 1940

By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

Volumetric measures [ ]

Jan 1, 1962

By H. B. Salisbury

The Bureau of Mines conducted research to determine if low-grade California chromite ores could be beneficiated to produce products suitable for commercial use. This research is part of a Bureau goal to provide technology capable of using low-grade domestic ores to meet emergency demands of the Nation for metals and minerals and in particular those minerals, such as chromite, which are considered critical. Two ores from California were ground and treated using gravity concentration and magnetic separation techniques. An are from Auburn in central California, assaying 2.5 pct Cr203, was treated by tabling and magnetic separation to yield a nonmagnetic product containing 44.7 pct Cr203 at a recovery of 36.4 pct. Core drilling samples from the Seiad Creek area of northern California, assaying about 6 pct Cr203, were upgraded by tabling to yield a concentrate containing nearly 50 pct Cr203 with a recovery of 50 pct. Both products are suitable for metallurgical and/or chemical use.

Jan 1, 1981

By Ralph L. Brown

As a preliminary step in a recent study4 of the phenols present in a low-temperature tar, the writers prepared the hydroxyacetic derivatives of the simpler available members of the phenol series in order to obtain material to assist in fixing the identity of similar derivatives obtained from the phenols of the tar. When comparing the melting points of the pure derivatives we had made with those given in the literature we were unable to find the characteristics of one of the xylenol derivatives which we had prepared--namely the 1, 3 dimethyl-2-phenoxyacetic acid, In the belief that the compound does not appear in the literature we are presenting these notes on its preparation and its melting point. The hydroxyacetic derivatives are easily prepared and in good yield, and are useful in studying mixtures of phenols. The 1, 3 dimethyl-2-phenoxyacetic acid makes the fifth of the six isomeric derivatives to be reported in the literature. Gluud and Breuer report the preparation of the 1, 3, 4, the 1, 4, 2, and the 1, 2, 4 derivatives. A fourth isomer-¬the symmentrical 1, 3, 5--has been reported by Schutz6, although no record of it occurs in the indexes. The remaining derivative--the 1, 2, 8-has not, been found and it is now being synthesized in the Organic Chemistry Laboratory of the. Pittsburgh Experiment Station. It is true, however, that from a phenolic fraction boiling 215.9 to 2180 isolated from natural petroleum, Tanaka and Kobayashi7 obtained a hydroxyacetic derivative melting at 103.3°. They state that this is the 1, 2, dime ethyl-3-phenoxyacetic acid but present no evidence for the assertion. The known derivatives are summarized in Table 1 following;

Jan 1, 1929

By Thomas O. Llewellyn

Laboratory semicontinuous and continuous heavy liquid cyclone separation pilot plant tests were made to determine the feasibility of producing a high-grade kyanite concentrate from a kyanite-quartz rock sample from Graves Mountain, Ga. Use of a three-stage heavy liquid cyclone circuit demonstrated that a 96.4-to 99.0-percent kyanite concentrate could be obtained with recoveries of 95.5 to 96.7 percent. The test work showed that by steam stripping with 6.9 tons of steam per ton of ore and two stages of detergent scrubbing the residual TBE content of kyanite cyclone products was 0.22 pound per ton of ore.

Jan 1, 1971

By N. S. Dalal, X. Shi

"The oxidation of NADPH by vanadate(V) in the presence of glutathione reductase showed typical enzymatic kinetics. The oxidation was inhibited by N-ethylmaleimide, a glutathione reductase inhibitor. Superoxide dismutase had no significant effect on the oxidation, indicating non-involvment of the superoxide radical. The vanadate(V) reduction was found to be a one-electron transfer process. These results suggest a new pathway for vanadate(V) metabolism and a new function of glutathione reductase. Compounds of vanadium(V), such as NaV03 , exert potent toxic effects on a wide variety of biological systems (1-3). Despite intense current activity, however, the biochemical mechanism of vanadate(V) toxicity is still not well understood (1- 14). It is believed that one of the important pathways involves the oxidation (by vanadate(V)) of NAD(P)H (15, 16), but, to our knowledge, there has been no report of the identification of any vanadate(V) reductase. With a view to finding if there exists any vanadate(V) reductase, we have investigated the oxidation of NADPH by vanadate(V) in the presence of glutathione reductase. Glutathione reductase (GSSG-R)2 was selected because our previous studies have shown (17) that GSSG-R can act as a reductase for chromate(VI), which is isoelectronic with vanadate(V). We find that GSSG-R does indeed function as a NADPH-dependent vanadate(V) reductase, thus pointing to a new pathway for the metabolism of vanadate(V), as well as to this property for GSSG-R. MATERIALS AND METHODSSodium metavanadate (NaV03 ), henceforth vanadate, was purchased from Aldrich and its solution was always freshly prepared. The GSSG·R used was from bovine intestinal mucosa and was purchased from Sigma. The oxidation of NADPH was followed photometrically as the decrease in absorbance at 340 nm. The spin trap, 5,5-dimethyl- pyrroline-N-oxide (DMPO), was purchased from Aldrich and used without further purification, since very weak or no spin adduct signal was obtained from the purchased sample when used alone.ESR spectra were obtained at X-band (9.7 GHz) using a Bruker ER200 ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR gaussmeter (Bruker, Model ER035A) and the microwave frequency was measured with a digital frequency counter (Hewlett-Packard, Model 5340A). An ASPECT 2000 computer was used for data storage and analysis. The concentrations given in the figure legends are the final concentrations. All experiments were carried out in the phosphate buffer solution (pH 7.2) and at room temperature."

Jan 1, 1990

By L. B. Berger

Studies showing the effect of mixing hot exhaust gases with the intake air of a four-stroke-cycle Diesel engine are described. The results indicate a marked increase in carbon monoxide in tip exhaust gases, a decrease in oxides of nitrogen, and no significant effect on aldehydes. The increase in carbon monoxide was greater at higher fuel-air ratios and was caused partly by the increase in fuel-air ratio end partly by the decrease in oxygen concentration resulting when exhaust has was added. The application of these results to the use of Diesel engines underground is considered.

Jan 1, 1940

The National Institute for Occupational Safety and Health (NIOSH) National Personal Protec-tive Technology Laboratory (NPPTL) and the Mine Safety and Health Administration (MSHA) conduct a Long Term Field Evaluation (LTFE) program to evaluate deployed self-contained self-rescuers (SCSRs). The objective of the program is to evaluate how well SCSRs endure the under-ground coal mining environment with regard to both physical damage and aging when they are deployed in accordance with Federal regulations (30 CFR 75.1714). This report presents ?ndings of the combined eighth and ninth phases of the LTFE. For these phases, over four hundred SCSRs were evaluated. The units tested include the CSE SR-100, Draeger Oxy K-Plus, MSA Life-saver 60, and the OCENCO EBA 6.5. The OCENCO M-20 was evaluated only in Phase 9. Testing was per-formed between December 2000 and April 2004. Results of the evaluation indicate that all SCSRs experience some performance degradation due to the mining environment. Observed degrada-tion varies from elevated levels of carbon dioxide, high breathing resistance, and reduced capacity. Mechanical degradation to the SCSR components included breathing hoses, chemical beds, outer cases and seals. The LTFE tests discussed in this report are different from tests performed for SCSR certi?cation to the requirements of 42 Code of Federal Regulations, Part 84 (42 CFR, Part 84). LTFE tests reported here are conducted to an end point, oxygen depletion, to enable comparison of the duration of new and deployed SCSRs. The method for obtaining deployed SCSRs for this evalua-tion was not a random selection from the deployed population of SCSRs. Although the results of these tests are useful for observing performance of the tested SCSRs, they are not representative of all deployed SCSRs. A new evaluation protocol, with revised sampling strategies, test methods, and reporting procedures, is currently being designed to enhance the generalizability of the results. This program will be implemented following completion of Phase 10 of the current LTFE protocol.

Jan 10, 2006

By Alfred E. Schwaneke

A versatile torsion creep tester was instrumented with electromechanical and servomechanical components to operate automatically and unattended, producing digital printed outputs. The apparatus uses an electrical system for applying torsional stresses, and a unique angular transducer as a null detector operating a servocontrolled strain measuring system with the digital readout. The tester is designed to measure the creep in single-crystal or polycrystalline zinc, zinc alloys, magnesium, magnesium alloys, or other metals and alloys. Applied stresses may be varied from zero up to 2,000 psi in the outermost fibers of a 1/8-inch-diameter, 4-inch-long specimen. Strain readings to 0.001 degree, equivalent to a strain of 2.73 X 10-7, may be made automatically from one every 5 seconds to one per month. The apparatus has provisions for programed temperature control and special atmospheres or vacuum operation. A discussion of applications of the system to other mechanical testing apparatus is included.

Jan 1, 1970

By T. N. McVay

The Bureau of Mines has developed a field test for detecting the presence of columbium in a variety of minerals containing the clement. The test consists of fusing the mineral or rock powder with potassium pyrosulfate in a porcelain crucible, digesting the melt with hot dilute hydrochloric acid to release the columbium oxide (Cb205), and subsequently reducing the columbium oxide to a lower oxide by adding tin, which gives a blue color to the contents of the crucible. The method will detect 1 percent of contained columbium oxide (Cb205) in a mineral sample provided no tungsten is present. If a mineral containing appreciable titanium is test,-!d in the same manner, the solution in the crucible becomes violet. In the presence of columbium, titanium at first causes a violet coloration of the solution, which after a few minutes is masked by the stronger blue of the reduced columbium oxide. Although tantalum oxide (Ta205) does not interfere with the columbium test, tungsten gives a blue color that is indistinguishable from the color obtained with columbium. A simple method is available to detect the presence of columbium in the absence of tungsten, but when the presence of tungsten is suspected, the sample must be subjected to somewhat more elaborate chemical tests to determine the presence or absence of columbium. Although these latter tests can be made in the field, several steps are involved that arc best performed in the laboratory with simple equipment.

Jan 1, 1962

By Tony Keller, Setsuo Maeda

Hand-Arm Vibration Syndrome (HAVS) was identified as early as 1918 in Bedford, Indiana in the U.S. Since then much research work has been done around the world in the areas of medical, epidemiological, engineering and legal aspects of HAVS. In Japan, much of the pioneering work in this field has been performed by Dr. Setsuo Maeda and his staff at the National Institute of Industrial Health (NIIH) in Kawasaki. Most recently, reports of work done by this group and by Dr. Ren Dong1 of NIOSH in the U.S., as well as many other suppliers and Japanese practitioners were presented at the 13th Japan Group Meeting on Human Response to Vibration held in Osaka2 during August 3-5, 2005. [ ]

Jan 6, 2006

By B. R. Mohal, F. F. Aplan, S. Chander

"Dust abatement by water sprays involves the subprocesses of 1) collision between dust particles and water droplets, 2) adhesion of particles to droplets, and 3) engulfment of particles by the droplets. A review of the fundamental aspects of these subprocesses shows that collisions between particles and droplets are determined by aerodynamics and the size and surface charge of the particles and of the droplets. However, the adhesion and engulfment subprocesses depend upon the wetting characteristics of the particles. Although wetting agents (also known as surfactants) have been used as dust suppressants in several investigations, conflicting results are available regarding their effectiveness. In this paper, we show that these results can be explained if the effects of coal rank on surfactant adsorption and wetting characteristics are taken into account.The influence of several nonionic surfactants containing polyethoxy adducts on the wetting behavior of coal is presented. The wetting was determined by a modified Walker Test method, and contact angle measurements. The results show that the wettability of coal depends upon coal rank, structure of the hydrocarbon chain of the surfactant, and the number of ethoxy groups in the molecule.IntroductionDue to the inherent nature of the mining process, a large number of particles are generated, a portion of which becomes airborne to create dust. Dust can be aesthetically and environmentally unacceptable and it can also be explosive. Fine particles in the respirable size range ( < 5 urn) are con-sidered to cause lung diseases, namely, silicosis, pneumoconiosis, etc.(1) Several approaches to reduce dust in mine environments are practiced throughout the mining industry. These include decrease in generation of dust through improvements in mine machinery, ventilation (in which lower dust levels are achieved by dilution of contaminated air with clean air), and dust removal methods. Water sprays are most commonly used to remove dust par-ticles. Recently, scrubbers are reported to have been installed on mining machines to remove dust,(2,3) which also make use of water sprays to reduce dust."

Mar 1, 1989

By John Gross

"Introduction.Southern Illinois and Kentucky are credited with approximately 90% of the fluorspar production of the United States. A small amount of high-grade acid, spar is obtained from the ore by band sorting; the greater part, however, is recovered by jigs and tables as gravel spar containing approximately 85% calcium fluoride. In the jigging and tabling operations, galena is recovered, and enough silica and calcite are removed to raise the calcium fluoride content of the gravel spar to 85%. However, the removal of silica and calcite results in a large loss of spar. With increasing depth in the mines, zinc sulphide, sphalerite, is encountered in increasing quantity and the removal of this has become a serious problem. While the sphalerite can be fairly well removed from the spar by present milling methods, a marketable zinc concentrate can not be made. The experiments described below were made on fluorspar ore from Southern Illinois, by the mining experiment station of the U. S. Bureau of Mines, at Rolla, Mo., in cooperation with the Missouri School of Mines and Metallurgy.The ore tested contained. 7.3% lead, 27.9% zinc, 35.7% calcium fluoride, 9.5% silica and 4.7%. calcite.Tests and Results. In some preliminary tests it was noticed that a portion of the finely crushed ore adhered strongly to the sample pans, and upon investigation it was found that the adhering material was practically clean spar. By utilizing this property of adhesion 46.8% of the spar was recovered as a product containing 98.3% calcium fluoride. This suggested the possibility of using electrostatic separation."

Jul 1, 1921

By J. Wade Watkins

One potential peaceful application of nuclear explosives is stimulating the production of liquid or gaseous hydrocarbons from essentially nonproductive deposits of petroleum, natural gas, oil shale, and tar sands. Within the United States the appreciable difference between producible proved reserves and ultimate reserves and resources of hydrocarbon deposits is of such magnitude that much petroleum, natural gas, shale oil, and bitumen will not be produced unless significant technological progress is made in production techniques. The shattering effect of contained nuclear explosives and, to a lesser extent, the heat produced, have been considered as stimulative forces when the thickness, depth, and nature of such deposits permit considering the use of nuclear devices. Mechanical production problems would be less in an oil or gas reservoir than in an oil-shale or tar-sands deposit. Also, tar-sands resources in the United States may not be adequate to warrant serious consideration of applying nuclear-explosives stimulation. Gas reservoirs should present the least-radioactive-contamination problem. The technical feasibility of using nuclear explosives cannot be evaluated fully at present. Additional information is needed on the effects of pressure, heat, and radioactivity on the solids and fluids of hydrocarbon deposits, the nature and extent of induced fractures in different rock media, and the possibility of isolating and confining or removing radioactive contaminants. Final technical feasibility can only be determined by a field test. If technical feasibility is established, economic feasibility will depend upon the comparative cost of producing hydrocarbons by nuclear explosives and by conventional means. It is probable that an economic comparison would favor nuclear stimulation only where devices of relatively high yield could be used practicably and safely.

Jan 1, 1964

Develop a method of dewatering ultrafine mineral waste that will increase water recovery from the waste and produce a dewatered material that eliminates the need for large settling ponds. Background In the hydrometallurgical treatment of many ores and concentrates to recover mineral values, slurries of fine particles are generated. Some of these slurries settle slowly and are difficult to dewater. This inherent property causes environmental and handling problems for the minerals industry. Examples of such problem wastes are clay wastes generated during the mining and beneficiation of phosphate ores, the processing of coal to produce a low-ash material, the cleaning of bentonite, beneficiation of potash, and the recovery of mica from clay-containing ores. At the present time these waste slurries are treated by techniques such as impoundment, thickening, and thickening followed by filtration. But factors such as new environmental regulations, the loss of mineral values in the waste slurries, the need to recycle water in the processing facility, and the lack of land suitable for impounding the waste have shown that new technology will be needed in the future to handle waste slurries.

Jan 1, 1986

By A. Gene Collins

During recent years the interest in trace and minor constituents of oil-field water, petroleum, and their associated reservoir rocks has increased. The metals copper, nickel, lead, manganese, iron, zinc, and cadmium are not determined routinely in oilfield brine analyses. Determination of these metals and subsequent correlation of these data should yield information to aid 1n the interpretation of the origin of different waters. The methods of analyzing oilfield waters have several potential applications: (1) Aiding in the search for petroleum; (2) identifying sources of intrusive brines; (3) controlling corrosion; (4) controlling produced water; increasing knowledge of the geology of subsurface formations; (5) identifying incompatible waters in waterflooding operations; (6) increasing the knowledge of the flow of oil, gas, and water in underground formations; and (7) aiding in the identification and location of valuable mineral reserves. Some brines contain enough valuable minerals to be recovered commercially.

Jan 1, 1962