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This publication summarizes the research (in-house and contract projects) programmed by the Bureau of Mines for fiscal year 1984 (October 1, 1983-September 30, 1984) under its Health and Safety Technology Program. The objective of these projects is to provide an ordered and sequenced advance toward the Bureau's overall goal of providing the systems technology required to create a more healthful and safer working environment for the Nation's mining and minerals processing workers.

Jan 1, 1983

By J. D. Davis

THE CARBONIZING properties of Chilton-bed coal from Lorado No. 5 mine, HE Logan County, W. Va., were determined by Bureau of Mines-American Gas Association tests at 600°, 700°, 800°, 900°, and 1,000° C. and by expansion tests. Chemical analyses, agglutinating and plasticity tests, and low- and high-temperature assays also were included in the investigation. Blends with low-volatile Pocahontas No. 3 coal were carbonized at. 900° C. The Chilton coal bed lies in the Kanawha, or Upper Pottsville formation of the Pennsylvanian system; the estimated original reserves are nearly 3.2 billion tons. The bed was 39/1 to 57 inches thick in the Lorado No. 5 mine, and the coal was 38 to 57 inches thick. The carbonization sample contained 62.6 percent fixed carbon on the dry, mineral-matter-free, basis, and the heating value on the moist, mineral-matter-free basis was 15,190 B. t. u. per pound; it therefore ranks as high-volatile A bituminous. It contained 1.8 percent moisture, 35.2 percent volatile matter, 57.9 percent fixed carbon, 5.1 percent ash, and 0.7 percent sulfur, as carbonized. The sulfur was largely organic, and the ash softened at 2,630° F. The agglutinating value determined on a silicon carbide-coal mixture of 15:1 was 6.8. In the Gieseler test the coal softened at 327° C., fused at 407° C., attained a maximum fluidity of 5,730 dial divisions per minute at 435° C., and solidified at 487° C. Maximum resistance in the Davis plastometer was 45.5 pound-inches.

Jan 1, 1951

By H. W. Kilau

The U.S. Bureau of Mines is evaluating water spray additives for the purpose of improving respirable dust control during coal mining operations, with particular emphasis on the longwall shearer. Recent field tests of surfactant-polymer reagents at two production longwall operations have shown favorable respirable dust reductions compared with water sprays containing no additive. Gravimetric dust samples obtained by a technician downwind of the shearer while following or preceding the machine showed dust reductions in the range of about 40% to 60% for some of the reagent formulations compared with using water alone. Three polymers were tested: two polyethylene oxide compounds of different molecular weight and hydroxypropyl methylcellulose (HPMC). All were effective for dust reduction, and two were cost effective when used in combination with sodium di(2-ethylhexyl) sulfosuccinate surfactant. How-ever, the use of these reagents requires the longwall operator to be more aware of headgate dust control. Experimental evidence indicates that dust captured by reagent-treated sprays at the shearer can be reemitted in the headgate area if stagcloader-crusher sprays and other dust controls are inadequate.

Jan 1, 2010

By Bruce I. Thomas

The Fairbanks mining district forms an arc 40 miles long and 8 miles wide on the north side of the Tanana Valley in central Alaska. This is a region of broad valleys and rounded hills that range in elevation from 600 to 2,600 feet Lode-gold production started in 1910 and has continued sporadically to the present, but the largest single mine produced only 40 tons per 24-hour day. Total recorded lode-gold production of the district is 241,000 fine troy ounces of gold from ore that averaged 1.32 fine ounces per ton. The ore was mined chiefly from narrow veins and veinlets alined along anticlinal folds at Ester Dome and the Pedro Dome-Cleary area. The only proven reserves are reported to be at the Ryan Lode at Ester Dome and at the Keystone Mines, Inc., holdings in the Pedro Dome-Cleary area. An inferred lode-gold resource for the district of approximately 4,000,000 ounces is considered to indicate only the order of magnitude of the lode-gold potential because of the absence of detailed data needed to evaluate the numerous deposits.

Jan 1, 1973

By Robert K. Koch

The Bureau of Mines investigated separating HF from HF-SiF4-H2O mixtures by passing the mixed gases through a sodium fluoride slurry in an airlift scrubber and forming a mixed precipitate of NaHF2 and Na2SiF6. The oven-dried precipitate was thermally dissociated in two stages. The first stage was carried out at 400° C and dissociated NaHF2 to NaF and HF. Condensation and analysis of the evolved HF proved it to be 97 to 99 weight-percent HF containing 0.79 to 0.99 weight-percent H2O and 10 to 93 ppm silicon. The second stage was carried out at 700° C and dissociated Na2SiF6 to NaF (for recycle) and SiF4. The quantity of HF recovered from gaseous HF-H2O-air mixtures decreased with increasing relative H2O concentrations. Air was beneficial when scrubbing extremely dilute wet HF gases. At HF partial pressures of 0.24 and 0.013 mm Hg in the scrubber entrance gases, HF partial pressures of 6.2 x 10-4 and 9 x 10-6 mm Hg were obtained, respectively, in the scrubber exit gases. Scrubber efficiencies were 99.7 and 99.3 percent.

Jan 1, 1966

By J. G. Walters

This report presents the results of an investigation in Which the chloroform solubilities of coals and chars are related to rank, temperature of thermal treatment, time at a given temperature, vacuum thermal treatment, plasticity, oxidation, blending, and mass spectral analyses and molecular weights of the extracts. It was found that the quantity of chloroform extract obtained from chars can be altered by creating a vacuum above the charge during preparation of the char, increasing the time at temperatures within the plastic temperature range, and by utilizing different rates of heating to attain a given temperature. Relationships found between the chloroform solubilities of chars produced at temperatures within the plastic temperature range and the relative fluidities in this temperature range indicate that the chloroform-soluble portion of the char is a significant component of the plastic mass. Chloroform-extract yields from chars made from blends of coals cannot be calculated from chloroform-extract yields obtained from chars made from the component coals.

Jan 1, 1967

By B. W. Gandrud

The upper part of the Alabama deposits of crystalline graphite consists of an oxidized ore derived from the underlying unoxidized ore through prolonged Weathering. The degree of oxidation in different sections and at different depths within the bed is not uniform. The original ore is hard and blue-gray; the weathered product is soft and brown and is the only part that has been mined to any extent. Samples of both oxidized and unoxidized ores were obtained from two of the large graphite deposits of Clay County. Three additional samples of oxidized ore were obtained from different portions of a third property in the same region. In this report, ores 1 to 5 are of oxidized material and ores 6 and 7 of unoxidized.

Jan 1, 1934

By Peter C. Wood

This report describes research directed toward the preparation of chemical oxygen (02) sources which exhibited improved 02 storage and reaction characteristics when compared to potassium superoxide (KO2). The initial focus of the research was the preparation of calcium superoxide (Ca(02)2) by the disproportionation of calcium peroxide diperoxyhydrate. The Ca(02)2) was characterized by chemical, thermal, and x-ray analyses. Several methods for scaling up the Ca(02)2 synthesis process were studied. Next, the reactivity of Ca(02)2 toward humidified carbon dioxide (C02) was evaluated and was compare o that of K02 under flow-test conditions approximating those existing in portable breathing apparatus. The reactivities of mixtures of K02 and Ca(02)2 or lithium peroxide towards humidified CO2 were also studied. Finally, an analysis of two commercial, K02-based, self-contained self-rescuers was conducted to determine the potential weight and volume savings which would be possible if Ca(02)2 or a mixture of K02 and Ca(02)2 were used as a replacement for K02.

Jan 1, 1983

By Homer J. Ballinger

The Alma, Degraff and other mines controlled by the Mon-Ark Mining Co. comprise one of the more important groups of zinc-lead mines in Christian County, Mo. The mines were first operated in .1857 and produced more than 5 million pounds of lead from rich, shallow ore deposits. Recent exploration and development led to the discovery of zinc sulfide ore at a depth of 165 to 214 feet in the northern part of the Alma mine. After examination of these mines in September 1942 by Bureau of Mines engineers, investigation of the extension -of the Alma mine and of the depth of mineralization at the other mines appeared justified in order to encourage the production of additional zinc and lead for war purposes. Twenty-nine churn-drill holes totaling 6.463 feet of bore were completed by the. Bureau from September 1943 to January 1944.

Jan 1, 1948

By Raymond W. Hiteshue, Sam Friedman, Paul Dobransky, Robert Madden

A hvab coal was carbonized in a closed system at 600 ° C and 40 to 1 , 200 psig to produce a high- Btu gas and char . By retaining the volatiles within the system, it was possible to virtually eliminate production of tars and oils . Depending on pressure and residence time , yields of combustible gases (72 to 92 percent methane ) amounted to 4,000 to 6,000 cubic feet per ton of maf coal and gross heating values of these gases varied from 830 to 960 Btu per cubic foot . Yields of char (maf ) were about 1,600 pounds per ton of maf coal . Increased residence time favored production of gases but reduced their heating values , whereas increase in pressure resulted in somewhat higher heating values and lower production . Similar effects were observed from the carbonization of a low- temperature tar . If these results could be translated to an economical carbonization process for producing high- Btu gas from coal , the demand for coal could be expanded by 40 to 50 million tons per year . Because of large yields of char , a process of this type would obviously have to be integrated with coal - fired power plants . Fortunately , operations could be conducted at essentially atmospheric pressure as product gas under this condition can be obtained in satisfactory yields and with good quality .

Jan 1, 1964

By G. B. Atkinson

The Bureau of Mines investigated a method for increasing the leaching rate of bulk superalloy scrap to facilitate recycling and recovery of critical metals such as Ni, Co, and Cr. Three superalloys were investi- gated, the cast-nickel-base superalloy IN-738, the wrought-nickel-base superalloy Rene-41, and the cast-cobalt-base superalloy Mar-M-509. Superalloys melted with 20, 30, 40, and 50 pct Al metal to form inter- metallic compounds were easily crushed to a convenient particle size and reacted rapidly with acid solutions which dissolved the metals. For example, leaching 1/2-in pieces of unalloyed IN-738 with excess 6N HC1 at 95° C for 2 h dissolved about 0.5 pct, while leaching 10 g of minus 20-mesh 30 pct Al-70 pct IN-738 with excess 6N HC1 at 95° C for 2 h dis- solved 96.2 pct.

Jan 1, 1983

By B. W. Moore

The U.S. Bureau of Mines investigated the separation of heavy rare-earth elements (REE) in an ion-exchange process. An ion-exchange column consisting of two sections, a loading section and a separation section, provides high levels of REE loading and good REE separation with an expected processing cycle of less than a month, while current ion-exchange technology requires more than 5 months. A different resin is used in each section: sulfonic resin in the loading section and iminodiacetic resin in the separation section. The separation section is further divided into two segments: the first conditioned with NH4 and the second with acid. Erbium is loaded onto both segments of the separation column as a retaining ion. Bands of mixed REB eluting between separated bands of pure REB were recycled directly to the column. Without mixed-band recycle, over 80% of the REE eluted from the column was separated into fractions with 99% purity of each element; with such recycle, the percentage of separated elements can be increased to around 90%.

Jan 1, 2010

By M. M. Tilman

As part of ongoing research to improve mine safety, the Bureau of Mines conducted research on the corrosion of friction rock stabilizer steels in five Missouri lead and iron mine waters. Electrochemical corrosion tests, including evaluation of pitting tendency, were performed on two types of high-strength, low-alloy (HSLA) steels and galvanized steel in four Missouri lead mine waters and one Missouri iron mine water. The tests were conducted at in-mine water temperatures in both air-saturated and deaerated waters. Static, weight-loss corrosion tests were also conducted on HSLA steel specimens in the five Missouri mine waters for 2,900-h duration at average in-mine water temperatures and air-dissolved oxygen contents of 6 to 7 ppm. Corrosion rates determined by the weight-loss tests were roughly comparable with rates determined electrochemically in deaerated waters containing 0.3 to 0.5 ppm dissolved oxygen content. Passivation of specimen (nongalvanized) surfaces in air-saturated waters resulted in very low electrochemically deter- mined corrosion rates. Pitting-tendency was generally higher for both HSLA steels in air-saturated waters than in deaerated waters. Galvanized steel generally exhibited higher tendency to pitting in the deaerated waters than in the aerated mine waters.

Jan 1, 1985

By Wallace W. Roepke

Research to evaluate the lubricity effects achieved by spraying water on the cutting bit of a mining machine or spraying water on the coal during cutting has shown that neither practice affects cutting forces, as had been believed. However, when water was supplied to the cutting zone axially through the bit at 3,000 to 5,000 psi pressure, tangent'ial cutting forces were reduced an average of 30 pct at a I-in depth of cut while normal bit forces were reduced an average of 65 pct. Lower normal forces mean reduced bit wear, faster advance with greater depth of cut, and fewer coal fines.

Jan 1, 1985

By Leland H. Johnson, D. O. Kennedy, John Hyvarenen

"SUMMARYA chronological list of accidents at metal and nonmetal mines and quarries (excluding coal mines) in the United States in which five or more lives were lost has been compiled. Many accidents were described in more detail because of their unusual features. Tables have been included to indicate the number of major disasters and fatalities by the principal product mined, by State, and by 10-year intervals prior to 1945. The number of men employed to indicate man-hours exposed is unavailable; therefore, a true picture of disaster data by principal product mined, by State, and by 10-year intervals is not possible. However, the data are presented to indicate the causes of major accidents and bring to the attention of those affiliated with metal and nonmetal mines and quarries the hazards involved and lessons that can be practiced to keep such accidents at a minimum.INTRODUCTIONThe Bureau of Mines was requested to compile a chronological list of accidents at metal and nonmetal mines and quarries (excluding coal mines) in the United States in which five or more lives were lost. Data have been assembled on accidents from all causes in these mines and quarries from the earliest available information (describ¬ing an underground mine fire in Nevada in 1869) to the last reported major accident (a fire at a company-owned bunkhouse in Arizona in 1945).The accounts of the accidents were taken from articles in the technical press and from published and unpublished reports of the Bureau of Mines. Many of the accidents have been selected for more detailed descriptions because of the unique circumstances and to show the variety of dangers involved.Tables are included to indicate the number of major accidents, with resultant fatalities, by the principal metal and nonmetal producing groups, by State, and by 10-year intervals previous to 1945. The interval 1869-1875 does not cover a 10-year span because of incomplete records previous to 1869.ACKNOWLEDGMENTSThe information contained in this report was obtained from the Engineering and Mining Journal from 1874 to 1947, the Mining and Scientific Press from 1908 through 1922, from various published and unpublished reports of the Bureau of Mines and from reports by State departments of mines. Daniel Harrington, retired chief of the Health and Safety Division; E. H. Denny, supervising engineer, District H; R. M. Loucks, mining engineer; and other engineers of the Division contributed much valuable information and assisted materially in the study."

Apr 1, 1949

By F. A. Rutledge, H. Marstraander, J. H. Hulbert, G. A. Apell

"INTRODUCTION The inability of Alaska coal mines to supply the quantity of coal required by public and private consumers and by the armed forces in Alaska caused the Coal Procurement Section of the Alaska Department, U. S. Army, to be established. It proposed to investigate the coal deposits and to expedite production of coal. The Bureau of Mines has closely cooperated in this program and was in direct charge of exploration. As to develop and equip an underground coal mine would have taken time and the need for coal was acute, a deposit that could be prepared for mining quickly was desirable. Several such deposits of stripping coal were known to occur in the Nenana field and were examined by the Bureau. One of these, the Diamond strip mine 4 miles west of Healy, was brought into production late in the fall of 1943. This mine was operated for the Army Coal Procurement Section by the C. F. Lytle Co. and the Green Construction Co.The Roth property, or Leasing Block No. 28, in the Healy Creek Valley offered the largest available tonnage of both stripping coal and total reserves. A program of exploration by the Bureau of Mines was inaugurated in 1943 and completed in 1944. Field parties of the Federal Geological Survey mapped the area had correlated the coal beds during the 1944 and 1945 summer seasons."

Nov 1, 1946

By J. M. Mutmansky, C. Lee

"Measurement of the size and elemental characteristics was performed on airborne coal mine dust samples collected by multi-stage cascade impactors as well as channel samples of the geologic materials. Size distributions were obtained using precise weighing techniques on the impactor substrates. Elemental analysis on the samples was performed by the proton-induced x-ray emission (PIXE) method, a rapid and non-destructive method of multi-element analysis.The various analyses were performed on 9 major and 21 trace elements. The results indicate the importance of intake air and shuttle car movements as sources of dust. The association of coal dust characteristics with channel samples was investigated using the coefficient of proportional similarity as a statistical measure. Results show a strong relationship between major elements and the geologic material being cut but a similar relationship between trace elements and geologic materials is not consistent.1. INTRODUCTIONThe most significant occupational disease in the coal industry is known ·as coal workers' pneumoconiosis (CW'P). While CW'P has existed for centuries, its mechanism of occurrence and association with coal dust has been well understood for only a few decades. In the 1930s, the significance of this disease led state and government officials in the USA to perform extensive epidemiological and environmental studies in the major coalfields. Study of these results plus later studies in the coal producing countries of Europe eventually led to the dust regulations that appear in the Federal Coal Mine Health and Safety Act of 1969.The impacts of the 1969 act were a productivity decline and increased production cost. Many analysts attributed this in large part to difficulties in complying with the new dust standards (Brezovic 1981). However, compliance was met in most continuous miner sections rather quickly. The remaining problem area is that of longwall mining where the procedures and layout of the minin~ system make it difficult to meet the standards."

Jan 1, 1989

By G. E. McElroy

"The development of certain mines in the East Tintic mining district, Utah, has been hindered considerably by the presence in the rock strata of heavy irrespirable gases which at times flood the lowest working places, as well as by abnormally high rock temperatures in the lower horizons. A study of these features was completed in the spring of this year, and the information obtained is summarized here.Heavy gases.Only four mines have been affected to date by the presence of heavy gas, and only one of these is producing lead-silver ores in quantity. These four embrace a territory extending about three miles north and south and about two miles east and west, while both within and fringing on this territory are a number of prospects which have not been affected.Thus far no fatalities have resulted from gas inflows, but a number of men have been temporarily overcome, and a few have had narrow escapes from death by suffocation. That the record is not more serious is mainly due to the fact that the gas inflow, as a rule, is relatively slow, mining operations have been quite carefully conducted, and the presence and extent of a gas inflow can be easily determined by its extinguishing action on the flame of miners' lights.When first encountered, about 1910, gas inflows occasioned much lost time. In some months the lost time averaged as much as ten days, while one mine cites for a certain month a maximum of 26 days lost out of a possible 28 working days. With improvements in mechanical ventilation and the passing of time, interference with work from the presence of gas has gradually lessened. During the last few winters, the main trouble has been with the mines being flooded with gas overnight when fans were not operated, although men have been driven out of the lowest development openings several times each winter with fans operating. At present, the main danger is in the lowest development openings having only one exit, wherein men might be trapped and possibly suffocated during an unusual and extremely rapid inflow of gas, or during an ordinary inflow, should the one source of power for the fan be disabled."

Aug 1, 1921

By E. D. Gardner

During the summer of 1935 a plan was proposed by which the Government should establish custom sampling plants for gold and silver ores in the mining districts of the West, where the construction of such plants would be justified as an unemployment relief measure. It was known that in many districts prospectors and small operators had small lots of smelting ore that could not be marketed for lack of sufficient capital to get out enough ore at a time to make carload shipments to distant smelters. Moreover, considerable ore of milling grade was available in many districts in which there were no custom milling facilities. It was felt that. accurate sampling and the classification and consolidation of small lots of ore produced from prospects and small mines, with quick cash returns to the shippers on a nonprofit basis, would stimulate the working of small gold and silver properties: Idle mines would be put to work, and there was a possibility that some of the prospects could be developed into regularly producing mines. Each sampling plant was to be centrally located so as to serve the greatest possible number of mines and prospects. Wherever possible, the plants were to be built on a railroad, is ore of smelting grade accumulated, it was to be shipped to a smelter in carload lots. Where a plant was not on a railroad, smelting ore was to be trucked to the railroad after being sampled.

Jan 1, 1936

By James S. Browning

The Bureau of Mines conducted laboratory batch and small-scale continuous selective flotation tests of barite-fluorspar ores from two deposits near Marion, Ky., to determine the technical feasibility of recovering commercial grade fluorspar and barite concentrates. The lignin sulfonate-sodium fluoride method of floating the fluorspar successfully produced acid-grade fluorspar concentrates. Flotation of the barite from the fluorspar tailing using petroleum sulfonate collector yielded concentrates suitable for use in compounding oil-well drilling mud. The fluorspar and barite recoveries were about 82 and 85 percent, respectively.

Jan 1, 1963