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By W. N. Marchant

[The citrate process for flue gas desulfurization (FGD) is a product of continuing research by the U.S. Bureau of Mines to meet the goal of minimizing the objectionable effects of minerals industry operations upon the environment. The reduction of SO2, in solution by H2S to produce elemental sulfur by the citrate process is extremely complex and results in solutions that contain at least nine different sulfur species. Process solution analysis is essential to a clear understanding of process chemistry and its safe, efficient operation. The various, chemical species, the approximate ranges of their concentrations in citrate process solutions, and the analytical methods evolved to determine them are hydrogen sulfide (~0M to 0.06M) by specific ion electrode, polysulfides (unknown) by ultraviolet (UV) spectrophotometry, elemental sulfur (~0M to -0.001M dissolved, ~0M to ~0.1M suspended) by W spectrophotometry, thiosulfatc (~0M to ~0.25M) by iodometry or high performance liquid chromatography (HPLC), polythionates (~0M to ~0.01M) by thin layer chrornatogrphy (TLC), dithionite (searched for but~ not detected in process solutions) by polarography or TLC, bisulfite (~0M to 0.2M) by iodometry, sulfate (~0M to 1M) by a Bureau-developed gravimetric procedure, citric acid (-GM to 0.5M) by titration or visible colorimetry, glycolic acid (~0M to 1N) by HPLC, sodium (~1.5M) by flame photo¬metry, and chloride by argentometric titration.]

Jan 1, 1980

By James Westfield

Bureau of Mines activities for safety and health in the mineral industries were reorganized during the fiscal year to provide direct supervision by the Assistant Director -Health and Safety. On December 19, 1954, the field offices conducting these activities were designated as district health and safety offices reporting to the Assistant Director. The functions of determining the causes of accidents and injuries in the mineral industries and recommending measures to eliminate them were continued, with satisfactory results in improved safety records. The inspection of coal mines and enforcement of the Federal Coal Mine Safety Act of 1952 were conducted as directed by the Congress, and safety conditions in the mines were notably improved. One coal-mine explosion classed as a major disaster occurred during the year. The causes of that explosion and means for preventing a recurrence were still under investigation because of the extreme difficulty in recovering several portions of the mine. Basic research on the nature of certain hazards and ways of eliminating them is continued. Training of individual workmen and supervisors in this knowledge is a major part of the work.

Jan 1, 1956

By G. D. Andria

Contract J0275007 was to consist of a thorough two-phase statistical analysis of respirable coal mine dust data from USBM Contracts H0232061, H0232060, H0230029, H0230031, H0210050, and H0242013. Consequently, BCR cataloged and assembled relevant data items from these contracts and formulated procedures suitable for the evaluation. The selected procedure was a Multilinear Regression Analysis which related dust concentrations measured in the mine to other mine parameters. Under the first phase, a thorough analysis of the date from USBM Contract No. H0230029 was completed. Primary results from this analysis are as follows: (1) The five variables that significantly affect dust concentrations in the return behind the brattice are the spray system utilized; the distance from the face to the return brattice; the return airflow; the production rate; and the water consumption rate, in that order. These five variables describe about 85 percent of the total variation in the return dust concentration. (2) Results at the miner and jack-setter locations were somewhat less conclusive due to the fact that only 17 percent of the variation in dust at the miner could be resolved and only 48 percent of the variation at the jack-setter location could be explained. The decision of the sponsor was that these initial results revealed as much information as could be expected; thus, per instructions from the USBM, the second phase (analysis of the other five contracts) was abandoned.

Jan 1, 1978

This report summarizes the results of the Narragansett Win Projec't's activities during the U.S. Bureau of Mines (BOM) Phase 1, which was transitional from and which followed the National Science Foundation (NSF) Phase which initiated the investigation of New England's potential roil resource. The 960 sq. mile basin is structural and topographic lowland containing 12,000 to 20,000 ft. of terrigenous clastic sediments of late Pennsylvanian age, and which rests on an upper Precambrian and Cambrian basement. The Rhode Island Formation, which is the coal-bearing unit, comprising the bulk of the Pennsylvanian rocks consists, in order of decreasing abundance, of sandstone, conglomerate, silts tone, shale, and coal. In the NSF Phase, 24 drill-holes yielded 17,900 ft, of core; in the BOM Phase I study, 4 drillholes yielded 2,100 ft. of core. Anthracite and semi-anthracite was encountered in beds Up to 30 ft. thick in widely spaced parts of the Basin. The coal, typically very low in sulfur, and a high ash anthracite, won mined in substantial volumes from 1808 to 1959 from shaft and open lit in Portsmouth and Cranston, R.I., and in lesser volumes in Mansfield, Mass. Currently coal is now being mined in Plainville, Mass. as a fuel in the manufacturing of light-weight aggregate from the same quarry that serves as the source of the rock being processed. The structurally complex Narragansett Basin is now known to have a greater extent than earlier since recent drilling by others (Chapter 2) has confirmed our interpretation that the Basin extended offshore south A Boston. The, Basin also extends into Rhode Island Sound to the south. The geological structure is more complex in the southern part of the Basin than in the northern part. Three episodes of folding have been documented on Aquidneck Island and four episodes of faulting have been demonstrated for the Basin as a whole. Relatively less well exposed rock in the northern part of the Basin, increases the difficulty of recognizing and correlating structural episodes in the northern part of the Basin. The Basin his hewn subdivided into six structural domains which appear to have distinctive structural, metamorphic, paleontological and sedimentological differences that mw assist in isolating important events in the evolution of the Basin and its component parts. The tentative structural model recently developed in POP Phase I has important implications for exploration and mining. In the first and second folding stages the coal is mobilized and thickened in the crests and troughs of folds whose axes are horizontal to subhorizontal. While conventional coal exploration and mining methods are not applicable, great thickening in the crests and troughs of large scale structures, which can he defined by geology, geophysics and drilling, may provide compensating advantages. Bedrock over most of the Basin is 0-50 ft., but thicknesses of glacial deposits up to 150 ft. are present locally. Pro-Pleistocene topographic trends are controlled by structure and rock hardness; Pleistocene deposits aligned to the S. F. are superimposed on earlier trends. The southern part of the Basin is mainly dominated by high grade Barrovian metamorphism and plutonism of Permian age, related to the Alleghanian Orogeny. About 300 sq. miles of the 960 sq. mile Basin has been affected. The remaining 660 sq. miles, in the chlorite and subchlorite zones of metamorphism are compatible with the presence of high quality anthracite and semi-anthracite. Illite crystallinity studies begun in the NSF Phase, have been carried out in the BOM Phase l with important results. About ME of the northern Basin is now known to be in the diagenetic (unmetamorphosed) or subchlorite zone and the remainder in the chlorite zone of metamorphism. Mite studies, probably best recording temperature effects, show a generally progressive increase from the NW corner of the Basin near Plainville, Mass. toward the south and southeast. Reflectivity and coal petrography studies, probably best recording pressure and effects related to shearing, indicate a generally opposite pattern. Thus these methods provide powerful tools for the ultimate solution of problems important to coal exploration for coals of higher combustible volatile content and exploitation of these. Due to the complex nature of the coal, chemical data may not he easily used to determine rank. The coals have been tectonically deformed and mineralized. This deformation plus thermal metamorphism have altered the coals, in some cases by producing natural coke. Brecciated coal is often coated with a secondary depositional carbon. The coals' hydroscopic nature and high ash contents are due to the deformed nature of the coal and the presence of this secondary carbon. The stratigraphy and sedimentology of the coal-bearing Rhode Island Formation is similar to described alluvial fan deposits. The non-geological studies al-low three conclusions to be made: 1. A substantial number of areas have been identified in the Narragansett Basin in which mining could be carried out without undue difficulty from a land use point of view. 2. Substantially more than two hundred instances of past or current- mining activities have been identified in the Basin. Many of those are in areas defined as geologically interesting, and may be advantageous From the point of view of future exploration. 3. The map synthesis technique developed for this contract is successful and may easily be adapted to future exploration in its current form and also in its expandable form dealing with unit measurements of one-tenth mile. We recommend that BOM Phase 2 exploration should accomplish the intent of the Congressional language in House Report No. 95-1251, to continue a substantial drilling and geophysics program: "The Committee expects the Bureau to continue studies involved in ascertaining the extent and quality of low sulfur coal reserves in the Narragansett Basin in New England including necessary drilling and geophysical studies. The knowledge of the extent of such deposits is of great importance to this 'energy pour' area".

Jan 1, 1979

By L. C. IlsLey

Many accidents rightly classifiable as electrically caused are not so classified for the reason that in numerous accidents the part that electricity played in causing the fatality is only suspected. For instance, a workman might receive a shock that would cause him to lose his balance and fall beneath a trip of cars; if no one saw the first part of the accident, the cause undoubtedly would be charged to "haulage." This paper covers a brief study of fatal and nonfatal electrical accidents. The first usually result from direct contact with the electrical circuit or electrical apparatus; the second more often are the result of arcing or flashing due to handling defective apparatus or making repairs on "live" equipment or circuits. It is hoped that helpful suggestions may be offered for minimizing accidents of these two classes.

Jan 1, 1938

By Henry C. Meeves

The Bureau of Mines, between 1956 and 1963, examined 18 major pegmatite districts in Arizona, Colorado, New Mexico, South Dakota, Utah, and Wyoming to evaluate their content of beryllium, a material in short domestic supply that has become increasingly important to modern industry. This examination report includes the salient statistics on the production of pegmatite minerals other than quartz and feldspar; and brief descriptions of 170 specific pegmatite deposits.

Jan 1, 1966

By John M. Gomes

The preparation of tungsten carbide by molten-salt electrolysis was investigated. Sodium tungstate in the electrolyte and carbon from the graphite anode were the source materials, Optimum results were obtained with an electrolyte consisting of 83 mole-percent sodium chloride and 5.7 mole-percent each of sodium tungstate, sodium metaborate, and sodium hydroxide; a temperature of 1,000° to 1,025° C; an anode current density of 37 amp/dm2 or less; and an initial cathode current density of 150 amp/dm2. The yield was approximately 0.45 g/amp hr. The electrolytic tungsten carbide product contained approximately 5.4 weight-percent combined carbon as compared to 6.1 weight-percent for pure tungsten carbide. Microhardness of the electrolytic tungsten carbide, determined with a 50-gram load, varied from 3,480 to 3,970 dph. The material was friable and could be ground in a laboratory ball mill to less than 400-mesh particle size.

Jan 1, 1969

By Donald R. Corson

The effects of adding varying amounts of type I portland cement to hydraulic backfill are described. Six different fill materials, each with three cement contents, were tested to determine which fill properties have the most significant effect on cemented strength. Two strength prediction equations, based on the physical and mineralogical properties of the fills, were formulated, and these accounted for 96 and 99 percent of the variability of the data. Results of both unconfined compression and triaxial tests of cemented fills are given, and the effects of moist curing and fill densification on the 7-day strength are discussed. Permeability test data are given, and the decreased permeability due to cement content and curing time is shown graphically. A discussion of the limited evaluation of other potential stabilization additives (expansive cement, fly ash, sodium silicate, gypsum, and asphalt) is included in an appendix.

Jan 1, 1970

By Ben Aleck

The objective of this program was to adapt Space Shuttle technology on high-performance spherical pressure vessels to cylindrical pressure vessels. Specifically, a cylindrical aluminum liner overwrapped with fiberglass filaments and prestressed by yielding the liner under a sizing pressure was to be replaced by a higher strength-to-weight ratio steel liner overwrapped with a higher strength-to-weight ratio filament. The steel was cryoworked stainless steel and the new fiber was Kevlar 49. In addition, the heavyweight ends of the aluminum liner were to be replaced by thin-walled domes which required multiple helix angle wraps for their support, in place of the single kite-string wrap from pole to pole of the aluminum overwrapped design. The use of cold swaging of tube-ends to form bosses, demonstrated on subscale development efforts, had not been achieved full-scale when the contract was initiated. Difficulties arose with the full-scale demonstration which were not solvable at the time with the designs and equipment available. hence, an unanticipated development was the finally selected method of making the 4-in.-diameter stainless steel liner with a single boss and no welds in an 0.020-in.-thick wall, from an 0.050-in.-thick, 13-in.-diameter disk. The demonstration vessel failed by leakage during the prestressing step because embedded oxides had formed flaws in the boss region. Such flaws have been avoided by proper temperature control during hot spinning. Hence, a new design was developed which weighs half as much as its recently developed predecessor. Funds ran out before adequate testable hardware was produced.

Jan 1, 1983

By D. E. Traut

A fluidized countercurrent ion-exchange system was developed, operated, and evaluated by the U.S. Department of the Interior, Bureau of Mines. The system consisted of integrated multiple-compartment absorption and elution columns in which the solution flows were continuous except for short periods when resin increments were withdrawn. The exchange of uranyl carbonate between a simulated in situ uranium leach liquor and a strong-base ion-exchange resin together with the subsequent elution with an ammonium chloride solution was studied. The effects of the number of sections, section height, amount of resin withdrawal, solution flow rate, and column diameter were investigated. The kinetic and equilibrium relationships for the absorption and elution steps were also examined. The experimental data indicate a strong interdependence between variables. Solution retention time appears to be a major limiting variable in the absorption process, while resin residence time is the determining factor in the elution process. The column was efficient over a range of conditions, but close control was needed for optimum operation.

Jan 1, 1978

By G. E. Geiger

The purpose of this research was to develop a computer simulator fur predicting the air quality in existing coal mines as well as a design aid for developing new mines. In addition to the air quantity flow, the other variables of tempera Lure, moisture, methane and respirable dust are necessary to determine the air quality. An additional feature of this simulator is that it allows parametric studies of these variables to explore the effect that these variables have on the air quality of an operating mine system. The research has also pointed out arias where more research is needed, and promote better and more systematic data taking techniques. Wang and Hartman (see Reference 9, on page 1-98 of Section 1) had already published a computer program to determine the ventilation of large mines, and Wang and Saperstein (see Reference 10 on page 1-98 of Section 1) later published a refinement of the work in the previous reference. These references were the starting point of the simulator developed by this present research effort, and Section 1 of this report is a slightly modified version of the original vent elation program. The modifications were necessary to permit the additional programs of temperature-moisture, methane and dust to be

Jan 1, 1972

By Ren G. Dong, John Z. Wu, Daniel E. Welcome, Kristine Krajnak

Although the exact mechanisms underlying vibration white finger (VWF) are not clear, it has been speculated that VWF is associated with variations of the blood flow patterns due to the physical damage and/or degeneration in neural and vascular tissue caused by vibration loading [1]. Excessive dynamic deformation of the soft tissues in the fingertip under vibration loading is believed to induce multiple occupation-related hand/finger disorders. However, the in vivo distributions of the dynamic stress/strain of the tissues in the fingertip under vibration conditions have not been studied because they cannot be measured experimentally to date. The goal of this study is to analyze, theoretically, the location and frequency-dependent dynamic deformation of the soft tissue in the fingertip during vibration exposures. [ ] Methods The fingertip considered in the model is the distal phalanx, the portion from the distal end of the fingertip to the distal interphalangeal (DIP) joint articulation (Fig. 1). The external shape of the fingertip was determined using a smooth mathematical surface fitting to the observed fingertip shapes. The fingertip surface was then scaled to the dimensions of a typical male index finger: length 25 mm, width 20 mm, and height 18 mm. The fingertip was approximated to be symmetric, such that only a half of the fingertip was considered in the FE modeling. The fingertip was assumed to be composed of outer and inner skin layers, subcutaneous tissue, bone, and nail. The soft tissues (inner skin layer and subcutaneous tissues) were assumed to be nonlinearly elastic and viscoelastic, while the bone, nail, and outer skin layer were considered as linearly elastic. The simulations were conducted using a displacement-controlled protocol in two stages. First, the fingertip was statically pre-compressed. The contact plate was first displaced towards the finger to achieve a predetermined value of tissue deformation (i.e., 0.5, 1.0, 1.5, and 2.0 mm). Second, the steady-state dynamics responses of the fingertip were analyzed using a linear perturbation procedure. The fingertip was subjected to a continuous harmonic excitation (magnitude 0.5 mm) from the contact interface. The dynamic analysis was performed in a frequency domain ranging from 16 to 2000 Hz. The frequency-dependent distributions of the vibration magnitude and dynamic strain magnitudes in the soft tissues are investigated. Results Typical simulation results for the frequency-dependent distributions of the vibration magnitude in the soft tissues are shown in Fig. 2 (figures show the results with a pre-compression of 2.0 mm). The vibration magnitude at the contact surface is 0.5 mm (specified) for all frequencies, while the vibration magnitudes in the soft tissues are location- and frequency-dependent. It is clear that the fingertip has a major resonance around 125 Hz, at which the vibration magnitudes in the soft tissues are over four times greater than that of the contact plate (0.5 mm). It is interesting to observe that, at this resonant frequency (125 Hz), the soft tissues at the tip has the maximal vibration magnitude while the regions near the contact

Jan 6, 2006

By Arthur M. Hartstein

The Federal Bureau of Mines, under a contract with Ultrasystems, Inc., investigated the thermal oxidative degradation characteristics of conveyor belts used in underground mines. This included the determination of smoke evolution, glow characteristics, char yields, and the identification and quantification of all volatile decomposition products in the form of gram of specific product formed per gram of belt sample tested. In addition to these investigations, degradation studies were conducted on some pure ingredients used in conveyor-belt formulations. Three basic classes of belts were investigated: neoprene, polyvinyl chloride, and styrene-butadiene rubber compositions. The studies indicate that styrene-butadiene-based belts exhibit good flame resistance and are the least hazardous in regard to overall formation of toxic decomposition products. Under this program, thermogravimetric analysis was definitely established as a method of material differentiation.

Jan 1, 1976

By Roy T. Sorensen

As part of its mission to maintain an adequate supply of minerals to meet national needs and maximize mineral production from domestic sources, the Bureau of Mines is investigating the recovery of alumina by hydrochloric acid leaching of kaolinitic clay. Most iron impurities are leached from the clay along with the alumina and must be removed before or during crystallization to aluminum chloride hexahydrate. The thermal decomposition step then provides an alumina product of acceptable iron analysis. Miniplant studies of a Bureau-developed solvent extraction technique, using a tertiary amine in kerosene diluent, have demonstrated that the iron content in aluminum chloride leach liquors can be reduced to levels of less than 0.007 wt-pct (7 ppm), expressed as Fe203. Entrained and dissolved organic matter in the purified pregnant leach liquor from the solvent extraction circuit can be reduced to less than 2 ppm by using a fabric-packed coalescer and subsequent activated carbon treatment. Investigators discovered that a steady buildup of zinc accumulated in the solvent phase within the extraction circuit, proportional to the amount of leach liquor treated. The solvent phase zinc analysis increased by 0.01 wt-pct ZnO for each 1,000 gal of pregnant leach liquor purified.

Jan 1, 1981

By Gene F. ] [Faufaul

This contract was concerned with the design, development, fabrication and testing of an improved tamper-proof filter cassette assembly for use in the, collection and evaluation of dust particulates, primarily in mining areas. This report presents the design effort, fabrication and tenting of five- prototypre unit$ as well as the design and production of 1000 filter cassettes with sampling heads. This new improved filter cassette has been tested and approved by NIOSH as meeting the requirements specified in the contract.

Jan 1, 1978

By Clyde L. Brown

The ignition source of fires and explosions in coal mines is sometimes difficult to explain because resulting widespread destruction often erases valuable evidence that might reveal the cause. However, through years of experience, investigators have been able to piece together enough evidence to establish the reasons and, thereby, have been equipped to recommend corrective or preventative measures. The pattern of hazards is not constant. It changes with the development of new practices and new equipment. Important among the new hazards to coal mining are those introduced by electricity. In addition to the dangers of electric shock, fires and explosions from heat and arcs, and premature blasts, certain others have developed as a result of stray electric currents from direct-current traction systems. The conventional direct-current power-distribution system in coal mines is conducive to electrolysis damage to mine tracks, metallic pipelines, grounded power conductors, and structures in a position to become conductors of stray currents. The voltage drop resulting from power demand on intentionally grounded power conductors and accidental grounds on insulated conductors are common sources of stray currents in coal mines. Uncontrolled electric cur-rents flowing through the earth and metallic structures can be a menace, and these contribute to the estimated $6,000,000,000 annual loss caused by corrosion. The purpose of this publication is to discuss some of the electrolysis hazards in the coal-mining industry and to outline corrective measures to alleviate them.

Jan 1, 1962

By Oliver Bowles

"INTRODUCTION Slate has earned a high reputation as a roofing material, carefully selected and properly placed it is rainproof, attractive, and extraordinarily durable. Despite there qualities in its favor, the slate industry during the past 30 years has suffered marked reduction in volume of sales. An increase in building construction and general improvement in business will doubtless bring renewed activity, but considerable ground has to be recovered before the industry can become prosperous. Influences tending to dwarf this long-established industry producing materials of world-wide reputation are analyzed briefly in the following pages in the hope that they may be rectified.HISTORY OF SLATE PRODUCTIONFigure 1 shows graphically the rise and fall from year to year of sales of roofing slate since 1885. In quantity, the peak was reached in 1902, and the most serious decline was from 1912 to 1918, sales at the end of this 6-year period being only one third those at the beginning. Unlike most building materials, slate experienced only a slight recovery in volume of sales during the post-war period, 1920-29. The value closely parallels the volume up to the World War period. Subsequently, however, as unit values increased the aggregate value rose sharololy above the volume curve, attaining in 1928 the point reached in 1903, although the Lumber of squares sold was scarcely one third as great. The increased unit value was due partly to larger sales of heavy architectural grades."

Nov 1, 1933

The purpose of the contract was to develop an improved coal mine dust sampler whose electrical-to-mechanical energy conversion efficiency would be superior to that of the presently available equipment. The electrical to (pressure) X (volume) conversion efficiency directly affects the size and weight of the air samplers. At least half of the mass of present equipment is composed of the rechargeable batteries. Any increase in efficiency will allow this mass to be reduced or the flow rote to be increased.

Jan 1, 1974

The 1965 Lignite Symposium, the fourth in a series and the third sponsored by the University of North Dakota and the Bureau of Mines, was held at Bismarck, N. Dak., on April 29-30, 1963. Them 7 symposia provide a forum for those interested in the technology and utilization of solid fuels, especially lignitic coals. As part of the meeting, a 200-mile field trip was taken including inspection of (1) the 200-megawatt, pulverized Lignite-fired Leland Olds plant of Basin Electric Power Cooperative, under construction near Stanton, N. Dak.; (2) the site of the Glenharold mine of the. Truax-Traer Goal Co., Division of Consolidation Coal Co., where a wheel excavator was being assembled; (3) the operating Beulah mine of Knife River Coal Mining Co., subsidiary of Montana-Dakota Utilities Co., near Beulah, N. Dak.; and (4) the 400-megawatt, hydro-electric Garrison Dam powerplant, near Garrison, N. Dak.

Jan 1, 1966

By H. H. Fields

The Bureau of Mines is in the process of degasifying a virgin area in northern West Virginia from the base of an 839-foot-deep vertical borehole¬. An in situ gas pressure hole 199 feet long, and seven degasification holes ranging in depth from 500 to 850 feet (average 618 feet) were drilled in an 8-foot-thick virgin Pittsburgh coalbed from the enlarged (14-foot-diameter) bottom of this borehole. The in situ pressure at the back end of the hole and the range of gas and water flows from degasification holes as they were completed and closed off were 203 psi, 79,000 to 257,000 cfd (average 160,000 cfd), and 5 to 8 gpm per hole (average 6.8 gpm), respectively. Twenty-four hours after the seven holes were connected through individual water traps to a common collector for natural venting of the gas through pipes to the atmos¬phere, the total gas and water flows and the in situ pressure dropped, respec¬tively, to 971,000 cfd, 1.3 gpm, and 18 psi. Eighty days later the correspond¬ing values dropped to 529,000 cfd, 0.50 gpm, and 13 psi. After 180 days of degasification, 91 million cubic feet of gas had been removed from the affected virgin area. This represents 60 to 70 percent of the gas calculated to be contained in the area of coal affected by the holes.

Jan 1, 1973