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By Güven Önal, Zeki Dogan, Neset Acarkan

"In general, the processing of glass sand may involve comminution, washing, wet classification and attrition scrubbing. Additional processes may include magnetic separation, flotation and leaching in various combinations.Yaliköy sand dune deposit is located near to Istanbul on the European side by the Black Sea coast. The reserve of deposit is around 70 million tons. Iron content of Yaliköy sand dunes is 0.48 % Fe2O3 and not suitable for glass manufacture. The iron content of glass sand should be less than 0.15 % Fe2O3 for window glass manufacture and 0.05 % Fe2O3 for glassware. In this study, it was aimed to produce glass sand with less than 0.15 % Fe2O3 for window glass and with less than 0.05% Fe2O3 for glassware manufacture from Yaliköy sand dunes. A representative sample with a weight of 200 kg was taken from Yaliköy sand dunes deposit through opening small pits.• Mineralogical studies have shown that iron is present in three forms:• Hematite, limonite, clay and iron silicate minerals such as epidote and garnet occur in free form.• Quartz grains are coated by hematite and limonite.• Iron is also present in the cracks of quartz grains.Free iron minerals such as hematite and limonite and silicate minerals were subjected to magnetic separation and flotation for removal. Iron coatings were tried to be removed by scrubbing and leaching. Iron removal in the cracks of quartz grains was attempted by grinding and leaching.Under optimal conditions, sand concentrate with 0.38 % Fe2O3 was obtained by means of high intensity disc type magnetic separation. Grinding and scrubbing were applied to see the effect of size reduction and attrition at room temperature and 90 ºC, by using non-magnetic fraction. Sand concentrate with 0.13% Fe2O3 was obtained at 90 ºC in this test.Sand sample which was previously ground to minus 0.5 mm and scrubbed, was floated by using sulphonates as collector. After flotation tests, sand Concentrate was obtained with 0.11 % Fe2O3.The optimum iron removal was achieved by H2SO4 leaching at 90 ºC depending on acid concentration and leach duration in static, percolation and agitation leaching. Agitation leaching was done by the use of mixer at 600 rpm, 50% solids and leach duration was 15 minutes."

Jan 1, 2003

By Kilian Neubert, Hermann Wotruba, Henning Knapp

Sensor-based sorting has been integrated into more and more applications in mineral processing over the past decades. Various sensor types, such as line scan cameras, near infrared sensors and X-ray transmission sensors, allow the separation of a vast variety of raw materials. Sensor-based sorting has several economic benefits which can make the difference between an uneconomic operation and a profitable mine. Sensor-based sorters can be applied to fulfill various sorting tasks, such as waste rejection, product quality improvement and ore type diversion, and have a significant impact on the layout of the processing plant. Therefore, it is important to include sensor-based sorting into the planning of a processing plant at an early stage. To evaluate the applicability of sensor-based sorting for any specific ore type, it is currently necessary to provide several hundred kilograms of material for subsequent bulk tests. In exploration, ore samples are usually rare and only available in form of drill cores. The acquisition of drill cores is time-consuming and expensive especially for deposits in great depth. Hence, it is unfavorable to spoil valuable drill cores for bulk tests. This paper describes a methodology to evaluate the applicability of sensor-based sorting based on drill core analysis. That methodology offers the possibility to calculate the achievable performances of different sensor types for various grain sizes without comminution of drill cores. The general methodology is shown on basis of an exemplary test work on drill cores from a currently conducted exploration.

Jan 1, 2014

At times the phosphate industry, in Florida, encounters phosphate rock that gives lower than expected P2O5 recovery in the rougher plant section. The drop in recovery is typically 10% and as much as 30% or more. Variations in feed quality from day to day, shift to shift and even from drag-line to drag line, represent a challenge to the beneficiation plant operators and reagents? suppliers. Therefore, this characterization study has been initiated to identify the reasons for the differences in flotation behavior of such feeds. The study involves many samples to cover such variations. The characterization work includes: ? Mineralogical and chemical analysis; ? Size, shape, surface roughness and porosity analysis; ? Surface charge and surface contamination with other phases (minerals); ? Clay content and its relationship to phosphate and silica particles. The results correlated with flotation data and adsorption density measurements clearly establish the statistically significant variability in characteristic features that influence flotation response. This article discusses results from the above listed studies. On the basis of the obtained data, recommendations of practical approaches to overcome the problem of feed variability in phosphate flotation plants are delineated.

Jan 1, 2014

By K. Hori

In this study, the determination of optimal conditions for jig separation has been investigated with a TACUB jig separator. The TACUB jig, from which a Batac jig originated, is a useful gravity separator that is effective to separate crushed solid wastes as well as coarse ores. A mixture of crushed polyethylene (specific gravity 1.3) and polyvinyl chloride (specific gravity 1.5) was separated by a batch TACUB jig by varying the frequency (wavelength) and the amplitude (pulse stroke length). It was found that the sample particle layer in the separation chamber was fluidized without turbulence by the rising water pulse resulting in the separation. However, a too strong water pulse reduced the efficiency of the separation of the particles. The results indicate that the specific velocity of the rising water is necessary to fluidize the particle layer without turbulence to separate the particles. The expansion ratios of the thickness of the particle layer in rising flows were measured in a cylindrical column. The pressure losses by the particle layer were calculated from the expansion ratios and the velocity of the rising flows by Ergun?s equation. The curve of the pressure loss vs. the velocity of rising flow showed a maximum point corresponded to the point of fluidization. The velocity of a rising flow on the point of fluidization provided the optimal separation condition.

Jan 1, 2014

By R. Hejazi, Saghaeian. M., H. Abedini

Continuous vacuum belt filters mainly carry out an important duty in the solid-liquid separation processes such as iron ore concentrate dewatering. However as the particles become finer, the resistance to filtration and dewatering would increase and as the result cake moisture content tends to increase. So in recent decades, using additives in order to improve the filtration performance has been considered by many researchers. In the present study, the effect of several surfactants on the filtration rate and cake moisture content of Chadormalu iron ore concentrate (80% =40 micron) was investigated using a laboratory scale vacuum filter. The results of several tests indicated that a non-ionic surfactant (Lauryl Alcohol Ethoxylated, LAE) has the best performance on reducing the moisture content of the cake and reducing the cake formation time. The optimum dose of LAE was found to be 300 g/ton which reduced the concentrate cake moisture content from 13.76 to 11.28% (wet weight base). Some industrial filtration tests were performed in Chadormalu iron ore concentrate plant to prove the effectiveness of this surfactant. The surfactant is mixed with water and added to the concentrate slurry before distributing on the vacuum belt filter. The industrial and experimental results were almost similar, so that adding about 300 g/ton of LAE would reduce the final cake moisture content from 12.87 to 10.76%.

Jan 1, 2014

By F. Xie

Low gold and silver leaching kinetics has been commonly observed in traditional gold-silver cyanidation process, especially in those heap-leaching operations. The reactivity and availability of oxidant was believed to be the critical limitation for gold and silver dissolution. The occurrence of silver sulfide such as acanthite (Ag2S) in the ore may also result in low overall silver extraction. Leaching of gold and silver sulfide in the ferricyanide-cyanide solution has been investigated through rotating disc tests and the assistant effect of ferricyanide on increasing the dissolution rate of gold and silver was noticed. The potential use of ferricyanide as an auxiliary oxidant in gold/silver cyanidation process was proposed based on the results of leaching of gold-silver ores.

Jan 1, 2014

By Y. M. Zhu

Lead in environment often causes a serious health hazard. The removal of Pb2+ from aqueous phase is a beneficial project. In this paper, deposited Saccharomyces cerevisiae (S.c.) was chosen as adsorbent, Pb2+ ions as adsorbate, and the process of biosorption was studied. The dynamics of the adsorption was investigated. The adsorption mechanism of Pb2+ by S.c. cells was also investigated by detecting microstructure, zeta potential under different pH value, FT-IR spectra of the S.c. particles before and after biosorption. It was shown that the biosorption of Pb2+ by deposited S. c. is a rapid process, and the adsorbing equilibrium is reached within 10 minutes. The Zero point of zeta potential of S.c. cells is pH=3.3. When 2.0<pH<3.3, there exists biosorption (biosorption rate 76%~88%), which means static bio-sorption been not the only kind of biosorption. FT-IR spectrum analysis showed that groups on bacteria surface were mainly characteristic groups of protein and amylase; oxo-groups and nitric-groups on S.c. cell surface could chelate with heavy metal ions. Chemical adsorption might exist in the process.

Jan 1, 2014

By F. Waanders, Campbell. Q.

This project was specifically aimed at using increased acceleration separation, as a method to optimize the recovery of gold in an ore body mainly consisting of hematite where the specific gravity of gold is much higher in comparison to the carrying material, making it possible to separate gold from other materials like silica, base metals and their oxides, usually associated with gravitation-gold-recovery-processes. The ore body investigated in this project originated from a gold reef containing a large portion of gold locked inside the gold pyrite complexes, which was mined and treated in a conventional way. After gold extraction, the material was pumped to a tailings dump and the gold extraction of this dump was investigated. In order to assemble a concentration plant setup, the head grade and size distribution of the dump and bulk sample were determined accurately. Chemical analysis and mineralogical examination were done on a representative sample of the bulk sample, to determine the chemical composition of the material. The results obtained thereof were evaluated and a pilot plant was configured. A bulk sample was processed in the pilot plant and the results were evaluated. The results at optimum acceleration forces applied, resulted in a recovery of 5% of the mass, with a gold concentrate of 90 g/t Au, which represented 58% recovery of the gold. The hematite with high specific gravity as main phase positively influenced the high acceleration separation process. It proved that if the specific gravity of particles in a suspension were increased, high acceleration separation could be applied effectively to separate much smaller particle sizes.

Jan 1, 2014

By Graeme Jameson

"In current flotation circuits it is customary to grind the whole of the mill feed to an initial size, which is determined by the liberation characteristics of the ore, and the ability of the flotation machines to float the fully liberated particles. Usually, the product of the primary mill will be ground further in a ball mill, to improve the liberation of the values and hence the product grade, before passing to rougher flotation cells. The final grind size is ore-dependent, and is a balance of factors including the relation between surface liberation and grind size, the grain size of the valuable particles within the host rock, and the feed grade. The P80 for the feed to flotation may be as high as 300 µm for free-milling copper ores, and as low as 53 µm for finely disseminated complex ores. The grinding of the feed ore requires considerable input of energy. The rate of replacement of wear components such as mill liners and media, is proportional to the energy input. The costs of these two factors - energy and wear - are usually comparable and together they form the major part of the running costs of a concentrator, and indeed, of the whole mining operation. The energy required increases as the final grind size decreases. This talk will focus on the reduction of milling costs that could be achieved, using a fluidized bed flotation technology that can give high recoveries at coarse particle sizes. A number of different circuit designs will be presented, using the new technology. Calculations show that reductions in the running costs of a mine and associated concentrator of the order of ten to twenty percent could be achieved."

Jan 1, 2014

By C. Gomez, J. Finch, R. Dalhke, J. Torrealba-Vargas

"The dispersion of gas into bubbles is an essential feature of flotation machines. Three measurements have typically been used to describe the dispersion: superficial gas velocity (Jg), gas holdup and bubble size along with the derived quantity, bubble surface area flux. Measurement devices continue to be developed. The McGill Jg sensor based on accumulating bubbles by natural buoyancy comprises a tube with a valve and pressure transducer (Figure 1). The tube is immersed at a desired location and depth (H1) in a flotation cell. On closing the valve pressure increases to a maximum (P1) when the tube is full of air. The Jg is estimated from the slope of pressure-time curve (dP/dt).The relationship between Jg and dP/dt is derived from first principles. Testing the relationship is difficult in a flotation machine as the spatial variation in Jg is generally not known. This problem is overcome using a specially designed experimental setup and the estimated Jg is shown to equal the known Jg.The derivation reveals the importance of bulk density (?b). The sensor was modified to provide an estimate of ?b (Figure 2). A second tube was added immersed to a different depth (H2) and kept full of accumulated air giving a pressure P2. The estimate of ?b is given by (P1-P2)/(H1-H2) (i.e., at the end of collecting the pressure-time data). This two-tube sensor also helps dampen process noise as illustrated by a sudden change in level when collecting the pressure-time curve. Both the original and modified versions have been widely used in plant test work."

Jan 1, 2003

By Vishal Shukla, Ashok Kumar, Manas Ranjan, D. Chakraborty, Narayan Sharma

Jigging has a very important role in mineral processing Industry. Upgrading of Iron Ore by jigging has been an emerging trend. A detailed investigation is carried out to understand the influence of Jig feed granulometry and bed height during jigging operation. Noamundi jig plant data shows that variation in jig feed granulometry, feed quality and bed height are major contributors to fluctuation in jigging performance. At Noamundi the feed size (-10.0+0.5mm) fraction is used for fines jigging operation. To understand the effect of granulometrey on jig plant performance such as yield, separation efficiency and Fe recovery. In this context The performance of jigging was evaluated by daily average data from jig operation was used to study the influence of feed distribution on jigging performance .Coarser fraction (+6mm) has a positive influence , whereas fines fraction (-0.5mm) tends to lower performance . During Jigging rearrangements of Particles takes place due to an alternate expansion and compaction of Jig Bed .These particles are arranged by increasing density from top to bottom. During the particle stratification, Jig bed physically cut at desired horizontal particle density plant to separate the desired product. Investigation shows that optimum bed height is required at different Jig feed quality to achieve desired product quality, maximum separation efficiency and Fe recovery. This Paper will illustrate role of granulometry and Bed height control on Jigging plant performance.

Jan 1, 2014

By H. Hamza, M. R. MacIver, M. Pawlik, L. Malin

"Size and shape are important properties of aggregates formed in engineering processes and natural systems. Measurement of aggregate size or shape is a challenge when the solids concentration is beyond the gel point, ?? > ??g, when the aggregates are in contact and it is difficult to distinguish or segment individual particles in the network. This paper describes the use of a micro-computed tomography (micro-CT) method for the calculation of the aggregate volume fraction, ??, and a characteristic aggregate length, ??a, based on a 3D chord length measurement algorithm. These parameters can be used to quantify changes in aggregate and pore size during a compressive yield stress test to help understand the impact of flocculation and network structure on dewatering. INTRODUCTION In a thickener, flocculation is often used as a pre-treatment step and the final solids content of the underflow depends on the network strength and permeability of the bed formed by settled aggregates (Usher, Spehar, and Scales 2009). This paper describes the measurement and analysis of micro-computed tomography (micro-CT) of flocculated mineral sediments to obtain a characteristic length, ??a, of the aggregate and pore phases during a staged compressive yield stress experiment. This parameter may be used as an indicator of changes in aggregate and pore size to quantify material behaviour in solid-liquid separation processes that depend on self-weight compression or applied pressure. This analysis was carried out to help understand the effect of flocculation on aggregate structure and the thickening process as part of a broader research on the improved solid liquid separation of tailings produced in the oil sands industry.Aggregate properties The solids phase of an aggregated or flocculated suspension will eventually settle – if left undisturbed – under the influence of gravity. As settling of a flocculated suspension continues, the solids volume concentration, ??, may increase to the gel point or gelation threshold (Landman and White 1994), ??g, above which the aggregates form a network of touching particles, or space-filling structure (Kranenburg 1994). In the sediment bed, the aggregates are surrounded by fluid and occupy a partial volume fraction, ??, according to"

Jan 1, 2018

By D. Pienaar, B. McFadzean, T. Jordaan

"Dithiophosphate (DTP) collectors have the lowest affinity for sulfide mineral surfaces compared to other common sulfide mineral collectors, such as xanthates and dithiocarbamates. In some cases it has been found that DTP does not adsorb onto the mineral surface at all and yet increases in recoveries and grades are noticed with the addition of DTP. Many studies have investigated the interactive effects of collector mixtures. However, there have been relatively few studies on the interactive effects between frother molecules and collectors. This study investigates the interactions between different types of frothers and sodium diethyl dithiophosphate.The study found that there were large increases in pyrite and galena microflotation recoveries at both pH4 and pH9 when DTP was mixed with small amounts of frother at a constant bubble size, showing that these increases were neither mineral-specific nor pH-specific. The same effect was not present when xanthate was used as a collector. The increases in recovery when using the DTP-frother mixture were similar irrespective of the type of alcohol or polypropylene glycol frother that was used. In an attempt to distinguish the mechanism of enhanced flotation recovery, various supplementary experiments were performed. It was found through adsorption experiments that no DTP was adsorbing on to the mineral surface. Therefore, interactions at the air-water interface were performed. Surface tension and critical coalescence concentration tests showed that, while DTP is a weak surfactant at the air-water interface, it does not have a synergistic effect in the presence of frother. DTP-frother mixtures do, however, show interactions in the froth phase, indicating an interaction in the thin films. It is proposed that there is a DTP-frother interaction on the bubble surface that enhances the rate of film thinning at the 3-phase bubble-particle contact."

Jan 1, 2018

By H. Koca, D. O. Aksoy, S. Koca

"In this work, modelling of galena flotation from a disseminated Pb-Zn ore containing 0,83 % Pb was investigated. In the flotation experiments, collector type and amount, frother type and amount, particle size, pH and flotation time were kept constant while solid ratio and depressant dosage were varied. The varied parameters are described with a mathematical model by using statistical design method. Central Composite Design method which is one of the principle response surface methodologies was used in statistical design and analysis of experimental results and process modelling. Two quadratic mathematical models were developed for Pb grade and Pb recovery. Analysis of variance showed that models obtained for Pb grade and Pb recovery were found to be statistically significant in 95 % confidence level. Predicted vs actual values of Pb grade and Pb recovery were also given in graphically. It was found that predicted values represent approximately 96 % and 94 % of actual Pb grade and Pb recovery, respectively. The high values of R-square (R2) indicate that the models developed for two response variables are powerful. INTRODUCTION Lead and zinc metals are widely used in electrical, mechanical, military, metallurgical, chemical, light and medical industries. Sulfide ores are the main resources for lead and zinc minerals (Luo et al., 2016). Froth flotation is the main beneficiation method to achieve lead and zinc sulfide minerals separation. There are two basic approaches to obtain lead and zinc separation by flotation. First, flotation of lead sulphide is carried out and zinc sulphide and gangue minerals are depressed by various depressants and second, the bulk flotation of lead and zinc sulphide is carried out to obtain a concentrate of lead and zinc, followed by the lead and zinc separation. (Yuan et al., 2012). Apart from concentration of lead and zinc by flotation, there are a few literature that reports concentrations of lead and zinc by gravity and hydrometallurgical methods with remarkable success (Goktepe, 2005; Yanbo et al., 2016)."

Jan 1, 2018

By Fedotov Pavel

One of the efficient means of ore disintegration during the processing is its volume breakage in such machines as roller-presses. Up to date neither the ore disintegration mechanism in roller-presses nor the reasons of their high efficiency are thoroughly investigated. In this work, the mathematical model of Finite Element Method of bad material disintegration in roller-press is discussed. The mechanism of the interparticle ore disintegration is traced.

Sep 1, 2012

By Vladimir Grujic, Milorad Grujic, Ivan Djurkovic, William Riggs

"In this paper, we have studied efficiency of different chemical structures of frothers on copper ore Majdanpek. The goal was to find out the best suitable chemical structure, which allows good bubble formation, size and interaction, forces on mineral surface. The particle size distribution was between 10 and 100 µm. Our research was oriented on three groups of frothers: alcohols, poly glycol ethers and poly glycols.We also used different collectors based on similar or less similar alcohol group in chemical structure as in frothers, expecting higher stability of air bubble in contact with copper minerals. Minimal potential energy was determinate in the hydrodynamic conditions for different particle sizes. It was founded that it is proportional to air bubble volume on 0.88° and contra proportional to the kinematics viscosity of pulp.Analyzing the results, we find out that poly glycols decreased surface tension the most. Also, it increased amount of coarser particles to the top of pulp. This group is less sensitive to pH value compared to the others too.From the class of frothers with higher efficiency in flotation process, we pointed OrePrep X-75 and X-133 as frothers with expressive frothing characteristic in the alkaline and low alkaline circuits. Special suitability of those frothers for floating copper minerals makes their hetero polar molecules with more than one hydrocarbon radicals connected to one polar group. However, those froters have no nether high or low solubility and are non-ionization. Those froters indicate some small collecting characteristics too. In dispersion systems, those two frothers make two types of bubbles: smaller di < 1.2 mm; V = 0.0008 cm3 and middle di < 16 mm; V = 2.2 cm3 (di – Bubble diameter, V – Bubble volume). Transportation speed of air bubbles it is possible to calculate based on equation: ?s = 27.5 * di 1.4 cm/s. Distribution of free surfaces for chalcopyrite is average 80% in the class –74µm +10µm and 20% in the class -10µm. If we get all class sizes, we find that recovery (R) depends from the time by equation:"

Jan 1, 2003

By A. V. Bauman

"Important for thickening processes is the ability of slurries to form under certain conditions aggregation and sedimentation stable systems. Substantial part of difficult to sediment solid particles in such systems may be in colloidal state. The technique to study the sedimentation and aggregative stability of the slurry developed by the author with co-authors makes possible to define kinetics of changes in the aggregative stability of the system with solid phase varying concentration in it and produce data on sedimentation stability of the system in preliminary investigation of the thickening process. Research of aggregative and sedimentation stability of the slurry complement standard methods of laboratory studies to prevent errors in development of water-slime thickening balance and water circulation to design new and upgrade existing processing plants. Statistical analysis of process audits of more than one hundred upgraded and newly commissioned processing plants carried out in recent fifteen years showed that more than two-thirds of problems arising in commissioning the processing plants are associated with misdesign and errors in thickening and water circulation system. Among the main reasons of process design failures are: non-conformity of actual characteristics of the raw material to design characteristics, low quality of preliminary studies at the stage of sedimentation process simulation, design failures, wrongly selected equipment for the thickening and water circulations systems. As of today a number of problems associated with laboratory studies of sedimentation process, first of all, with interpretation of precipitation curves produced at the stage of laboratory refinement of the thickening process have been pinpointed. (Bauman A.V. Outstanding issues in design of thickening and water circulation diagrams in processing plants // Ore processing. 2016. ?3 P. 58-62) ?????? ?.?. ?????????? ??????? ?????????????? ???? ???????? ? ??????????? ?????????????? ??????. // ?????????? ???. 2016. ?3. ?. 58-62))"

Jan 1, 2018

By Slobodan B. Vujic

"For the requirements of the mining company “Rudnik-Rudnik”, engaged in undergr-ound exploitation of polymetallic ore and lead, zinc and copper concentrates production, the Department of Computer Application of the Faculty of Mining and Geology, University of Belgrade, designed a computer supported and integrated information-management system. This paper presents a concept of this system covering both monitoring and management of production in ""Rudnik-Rudnik"".The ""Rudnik"" Rudnik, Yugoslavia is a mining company, engaged in underground exploitation of polymetallic ore and production of ore, zinc and copper concentrate as well as other metals such as silver, bismuth and cadmium. This mining company runs stable business activities and undergoes a permanent growth of valuable production volume.The basic characteristics of production-technical system of ""Rudnik"" company are: uniform and up-todate technical-technological solutions: linking of production chain from underground exploitation of ore to flotation, namely final product - concentrate of lead, zinc and copper; complete mechanization of production; relatively low level of computer technics implementation; namely, ununiformed implementation of different application of computer-supported information technologies in production and business activities of the Company.These are the assumptions on the basis of which the management of the Company made a decision, in 1999, to upgrade information-management functions through development and application of modern integrated and computer-supported production-business information-management system (hereinafter: IMS, namely IMS Rudnik). For this purpose the Company requested the Department of Computer Application, Faculty of Mining and Geology, University of Belgrade to make the Project on IMS for their needs."

Jan 1, 2003

By Rebecca Hope, Derick Moolman, Frikkie Malan

"Despite the lip service that has been paid to pro-active plant maintenance processes over recent years, a significant portion of maintenance in industry is still reactive. The business driving force to prevent expensive production opportunity costs arising from “break-down maintenance” is obvious. Various benefits can be derived from successfully deploying remote equipment diagnosis technology and associated business processes.From an end-client’s viewpoint these include the ability to predict and take actions to prevent equipment breakdowns, increasing the lifetime of equipment by responding to appropriate operating instructions and therefore improving the return on capital expenditure. Better planning and scheduling of maintenance priorities and resources with performance measures like an Equipment Health Index are also possible. The knowledge that a qualified supplier engineer is constantly in touch with the operating conditions of their equipment, albeit remotely, is more than a comfort, and can be translated into quantifiable cost savings and improved supplier service levels.This paper analyses the reasons for the inadequate level of pro-active plant maintenance practice in industry today, and presents a number of important criteria in selecting appropriate solutions to this problem. A case study of a specific real-time, remote equipment management application is presented."

Jan 1, 2003

By Xin Tan, Changgen Li

"The floatabiliby of chelate CF-collector for zinc and lead oxide minerals was described. It found that CF-collector possesses a strong collection power for zinc and lead oxide minerals as well as excellent selectivity for the gangue minerals. A new technology of zinc and lead oxide flotation with CF reagent as a collector, lead nitrite as a activator and water glass as modifier was presented. The mechanism of interaction between reagents and minerals was discussed by means of adsorption, zeta potential, nephelometric titration, XPS and infrared spectra was investigated.CF-collector, newly developed by Beijing General Research Institute of Mining and Metallurgy (BGRIMM), is a kind of chelate collector for the flotation of oxide minerals. CF-collector mainly consists of N-nitroso-N-phenylhydroxylamine ammonium salt. The CF-collector was used for the selective flotation of scheelite in the Chinese plants.In this paper, the effects of the dosages of activator Pb(NO3)2 and depressants (sodium hexametaphosphate, polyphosphate, water glass and salified water glass) on the floatabilities of several minerals (cerussite, smithsonite, calcite, dolomite, limonite and quartz) as well as their mixtures were investigated in the presence of the CF-collector. The results show that the CF-collector is the excellent collector for selective flotation of cerussite and smithsonite. Pb(NO3)2 can selectively activate the oxides of lead and zinc resulting in a decrease of the CF-collector dosage. The sodium hexametaphosphate plus the salified water glass are the effective depressants for gangue minerals. Based on the above facts, the “CF process”, namely, used CF reagent as a collector, Pb (NO3) 2 as a activator, and sodium hexametaphosphate plus salified water glass as depressant, has been used for the flotation separation of the lead oxide mixtures or zinc oxide mixtures without disliking and heating. For the feed lead assaying 19.07%, the lead concentrate assaying 49.81% Pb at the recovery 80.69% was obtained after one step flotation. For the feed zinc assaying 12.85%, a zinc concentrate of assaying 29.56% Zn at recovery 83.87% was obtained."

Jan 1, 2003