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By E. Swartzman

"IntroductionGENERALLY, the necessity for mining coals of higher impurity content, the drive for lower costs by intensive mine mechanization, changing market requirements, and the increasing competition of oil and natural gas, have continued to result in an upward rise in coal preparation, and have necessitated a more intensive study of coal preparation problems.Increasing adoption of •continuous mining equipment, for example, is introducing new problems in coal preparation. Limited experimental work in the United States (1) shows that the effect of the continuous miner on size distribution varies with the characteristics of the seam. In some seams, the fines problem is lessened, in others it is greatly aggravated. Generally there is a decrease in the relative amount of the top sizes (plus 2 in.) and a substantial increase in the intermediate sizes (down to about 1/8 in.). Contrary to expected results•, where continuous miners with vertical-moving cutting heads are used, an increase in impurities in the slack sizes does not necessarily occur where draw-slate is taken. This is because the draw-slate tends to be kicked out in lump form. However, if a seam contains bands •and lenses of impurities they are bound to be in the mined product."

Jan 1, 1952

By Dart Wantland

"AbstractThe scope of geophysics in civil engineering and the nature of exploration geophysics are briefly discussed. Engineering problems amenable to geophysical attack are illustrated by specific examples. The various methods available, accuracy of results, and costs are treated. The possibilities of new uses of geophysical techniques are pointed out.IntroductionTHE SCOPE of geophysics in engineering is different than in oil or mining exploration. In civil engineering, geophysics solves specific problems; as for example, what is the depth to bed-rock along the axis of a proposed dam? The area to be surveyed is of limited extent, and the subsurface information .sought is relatively near the surface. The engineering geophysicist is not called upon to investigate geological basins or extensive mineralized areas or to probe for data to thousands of feet in depth. The geophysical tools employed in the three fields are, however, quite similar; the differences are mainly in the objectives.The Natural Geophysical ExplorationThe terms geophysics and geophysical exploration have been used heretofore and will .be employed in what follows. The question is, therefore, What is geophysical exploration?Geophysical exploration is a line of field work where measurements are made at the ground surface with special instruments to get geological subsurface information. Briefly stated, geophysics is a form of exploration that supplements geological work. It is a blend of physics and geology since physical measurements are made •at the surface of the ground that can be interpreted in terms of subsurface conditions."

Jan 1, 1953

By Shantanu Patel, C. Derek Martin

"The objective of this work is to develop a practical numerical approach for applying the confining pressure to discrete element cylindrical triaxial tests. A layer of membrane particles with very low stiffness and extremely high contact bond strength was created around the lateral boundary of the cylindrical numerical specimen. To prevent the membrane particles from penetrating into the rock specimen on application of confining forces and to provide a smooth boundary surface, the space between the membrane and rock particles was filled using small-diameter packing particles. The results of this method were compared with those of rigid boundary method with confining pressure of 20MPa. The results obtained show that new approach gives both peak strength and post peak response that are in closer agreement with laboratory findings. BACKGROUNDThe discrete element method (DEM) has become the cornerstone for simulating both intact material and discrete fractures for low porosity strong rocks (ISRM Classes R3 to R6). Despite the advances in its application, simulating realistic behaviour of intact rock using the DEM remains a challenge. The bonded particle model was introduced as a potential solution for simulating the complex mineral grains in strong rock and other granular materials (Potyondy and Cundall, 2004; Utili and Nova, 2008; Salot et al., 2009). While some issues were resolved, a remaining challenge is the lack of the bonded particle model to simulate the brittle response commonly observed in strong rocks during the triaxial compressive test. Such behaviour is shown in Fig. 1 for Lac du Bonnet Granite at a confining pressure of 20MPa."

Jan 1, 2015

"Block caving is the preferred underground mining method to profitably extract massive, low-grade orebodies; however, lack of cave access inhibits understanding the rockmass response to mining, which is needed for safer, more productive operations. Combining large datasets from multiple sources with virtual reality scientific visualization (VRSV) is an alternative method for understanding complex cave behaviour, by providing virtual access to the cave. A customized VRSV module was developed at UNSW Australia to investigate rockmass response to undercut developments at a case-study block caving operation. Time/sequence effects are investigated in rockmass response to blasting, which is an important factor in hard-rock mines.RÉSUMÉ La méthode d’extraction souterraine par blocs foudroyés est la méthode préférentielle pour extraire rentablement des gisements massifs à faible teneur. Toutefois, le manque d’accès à la chambre restreint la compréhension de la réponse de la masse rocheuse à l’exploitation, ce qui est nécessaire pour obtenir des opérations plus sécuritaires et plus productives. La combinaison de grands ensembles de données de multiples sources avec la visualisation scientifique par réalité virtuelle (VRSV) constitue un autre moyen de comprendre le comportement complexe de la chambre en fournissant un accès virtuel à la chambre. Un module de VRSV sur mesure a été développé à l’Université de Nouvelles-Galles du Sud (UNSW) en Australie afin d’étudier, dans une étude de cas d’une exploitation par blocs foudroyés, la réponse de la masse rocheuse aux développements de galeries de sous-cavage. Les effets de temps/séquence sont étudiés dans la réponse de la masse rocheuse au sautage, ce qui est un facteur important dans les mines de roches dures."

Jan 1, 2016

By Yuhua Wang, Wei Sun, Dongfang Lu, Yuehua Hu, Tao Jiang

"With the continuous depletion of high-grade tungsten ores, the low-grade refractory wolframite has become an important source for the tungsten industry. However, the large-scale utilization of low-grade refractory wolframite is disappointedly scarce, it is due to leanness of valuable minerals, complex mineral characterization and use of toxic collectors.The aim of this study was to develop an environment-friendly processing flowsheet, which was used for beneficiation of low-grade tungsten ore containing 0.45% WO3 from New Brunswick in Canada, and the content of arsenic is 0.68% in this materials. The objective of beneficiation studied was to obtain a concentration containing 60% WO3 with less than 0.5% of arsenic under the condition without any flotation reagents. In this environment-friendly processing flowsheet, magnetic separation technology, classification and gravity separation technology were combined and employed. Firstly, magnetic separation was employed for the first pre-concentration process, over 95% of the feed was rejected as the final tailings, meanwhile, over 85% of arsenic minerals were removed with tailings. Secondly, gravity separation tests were employed on the classified magnetic pre-concentrate in the second pre-concentration process, a second pre-concentrate with WO3 grade of 54.32% and As grade of 5.41% was obtained. Finally, two stage magnetic cleaning were conducted on the second pre-concentrate for upgrading the second pre-concentrate, the mostly arsenic and gangues were removed from the second pre-concentrate. Finally, this novel processing achieved an effective recovery of fine wolframite from low grade tungsten ore with high arsenic. A concentrate with WO3 grade of 64.81% were obtained in new opened processing flowsheet, and As grade was less than of 0.5% in this concentrate. Furthermore, remarkable feature of this processing flowsheet is environment-friendly due to avoid using the toxic flotation reagents during the whole mineral processing.INTRODUCTIONTungsten is an essential metal and is the most widely used in industrial production such as national defense, electro-mechanical products, textile and leather sectors (Srivastava et al., 2000). Wolframite and scheelite are the main mineral sources of tungsten metal. With the continuous depletion of high-grade tungsten ores and the increasing demand for tungsten alloy, the low-grade refractory wolframite has become an important source for the tungsten industry. However, the large-scale utilization of low-grade refractory wolframite is disappointedly scarce, it is due to leanness of valuable minerals, complex mineral characterization and heavy use of toxic collectors."

Jan 1, 2016

By John J. Barakso

A summary of geochemical dispersion processes is presented. Secondary and tertiary dispersion of uranium was examined at several uranium prospects in British Columbia. The vertical migration of uranium from bedrock (primary dispersion) through overburden into the various soil horizons, and into snow and plants, was studied, and relationships were sought to explain the dispersion patterns in the secondary and tertiary environments. Soil developments were examined to obtain information on factors affecting the dispersion of uranium in soil profiles and tertiary substances; samples were analyzed for a number of elements. Biogeochemical data indicate that plant geochemistry is a possible exploration aid in areas of heavy overburden owing to the high selectivity of certain plants for specific elements. Some new data on the geochemistry of snow are discussed as a matter of research interest in the tertiary dispersion of uranium. Analytical techniques and problems are discussed, particularly extraction techniques, which must be carefully chosen to give reliable information on uranium dispersion.

Jan 1, 1979

By J. R. Tickner

"Gold is conventionally analyzed using fire-assay or other destructive chemical methods that impose significant sample preparation, OH&S, and skilled labour requirements. Developed over the past 15 years by the CSIRO, PhotonAssay provides a new approach. A high intensity, high-energy x-ray source is used to activate atoms of gold and other elements in bulk mineral samples. The resulting activity is counted to automatically, accurately and rapidly determine metal grade. Samples weighing 0.5–1.0 kg can be measured in a few minutes with minimal preparation. As the method is matrix-agnostic, traditionally hard-to-assay materials such as highly refractory ores, carbon pulps and copper concentrates require no special treatment. We present the status of commercial PhotonAssay systems being developed by Chrysos Corporation. The first unit with a throughput of up to 80 samples per hour is to be deployed in an Australian assay laboratory in late 2017; smaller systems suitable for providing real-time assay directly at the mine-site will be progressively rolled out from mid-2018. Performance results from extensive testing using both mine-sourced and standard reference materials are presented, demonstrating the sensitivity and accuracy of the method. Implications for replacing conventional gold assay in exploration, mining and processing operations are discussed.INTRODUCTION Accurate methods for assaying ore grade are essential throughout the exploration, mining and mineral processing value chain. The discovery and evaluation of new ore deposits, reserve and resource definition, mine operations planning, ore processing, metal accounting and product quality evaluation all rely on accurate measurement of the valuable metal content of bulk materials. The analysis of gold presents particular challenges, stemming from the very low concentrations at which commercial operations run (often part-per-million (ppm), or equivalently one gram-per-tonne levels or below), and the highly heterogeneous nature of many gold deposits. These challenges mean that any analytical method must have high sensitivity and be capable of measuring large-mass samples. The most widely used quantitative analytical method for gold is fire-assay (Hoffman, Clark and Yeager 1998). An initial ore sample typically weighing several kilograms is dried, crushed and pulverized to allow a small sub-sample (10–50 g is common) to be representatively drawn. The sub-sample is mixed with flux, litharge (lead oxide), a reducing compound and other reagents. The mixture is fired at a temperature of 1000–1200°C until molten. After cooling, the slag is removed and the lead button containing any gold present in the sample is remelted in a porous cupel. The lead is absorbed into the cupel, leaving a gold prill which is either weighed directly, or dissolved in acid and analysed via atomic absorption spectroscopy (AAS) or inductively coupled plasma spectroscopy (ICP or ICP/MS)."

Jan 1, 2017

By D. V. Krefting, D. R. Bennett

"The Cyprus Anvil Mining Corporation established a lead-zinc mine and concentrating plant at Faro in Yukon Territory in 1969. Following some 12 years of continuous operation from a single pit adjacent to the concentrator, the company decided to expand operations into two additional areas on the Vangorda Plateau. The two new deposits, known as Grum and Vangorda, are located some 15 kilometres from the existing concentrator.Confirmation of mining feasibility was followed by determination of the most practical and economical method of transporting the raw ore from the new mine sites to the existing concentrator. This analysis was carried out in two phases. The first phase reviewed the feasibility of alternative transportation systems on an 'order-of-magnitude' cost basis. This work identified systems worthy of more detailed examination. The second phase examined the preferred alternatives in greater detail.Initially, operating principles and parameters were established and catalogued. Then, based on these criteria, complete systems were developed utilizing alternative modes of transportation . In the overview analysis, some transportation modes were judged impractical and discarded, 'order-o f-magnitude' costs were developed for other systems and the most costly were eliminated . In the detailed study, the favourable systems were examined in depth which required development of accurate capital and operating costs, consideration of environ- mental impacts and an assessment of intangibles associated with the operation of a new development."

Jan 1, 1984

By Rufus L. Chaney

A new technology is available to the Ni mining and remediation community to “phytomine” Ni from mineralized or contaminated soils using rare plants which hyperaccumulate Ni to over 1% of shoot dry matter. Research has identified useful plant species, and even bred improved cultivars of Alyssum murale and Alyssum corsicum for commercial phytomining in temperate regions. All agronomic practices (fertilization, soil amendments, planting and harvest methods) needed for economic phytomining were identified to attain high yields and high Ni concentration in the biomass. In tropical regions, other species are available such as Phyllanthus which accumulate over 1% Ni in dry shoots. These species are perennial so they regrow after annual cutting to harvest biomass. Expiration of our patents on the technology opens the opportunity for other organizations which control Ni rich natural soils or contaminated soils requiring remediation to commercialize the technologies. Inexpensive methods to remediate/revitalize Ni contaminated phytotoxic soils using agronomic approaches have also been developed and demonstrated at Port Colborne, Ontario, but adoption is delayed until formal agreements with government are completed. These new simple remediation and profitable phytomining technologies can obtain Ni from soils which contain Ni well below levels considered economic for current mining technologies, and the plants biopurify the Ni so it is easy to recover Ni metal from plant ash by pyrometallurgical or hydrometallurgical technologies. Although increasing pH decreases the solubility of Ni in all soils, raising pH increases Ni accumulation by Alyssum species. Hence usual chemical extraction methods for phytoavailable soil metals such as the DTPA- or NH4-OAc-extraction cannot predict Ni accumulation by Alyssum species.

Jan 1, 2016

By Frank Arthur Forward

FRANK ARTHUR FORWARD was born in Ottawa and attended the University of Toronto, where he received a B.A.Sc. in chemical engineering in 1924. From 1924 to 1929, he was a smelter operator and research metallurgist with the Consolidated Mining and Smelting Company of Canada Ltd. (Cominco) at Trail, B.C. Moving to Australia in 1929, he was assistant smelter superintendent, Mount Isa Mines Ltd., Queensland, until 1934, when he returned to Canada, spend-ing one year as metallurgist with B.C.

Jan 1, 1970

By A. Zaidi

"The mining and metallurgy industry is highly energy intensive and one of the largest energy users in Canada. Energy costs are also a major component of total production costs in this industry as described in the 1990 Report of The Canadian Industry Program for Energy Conservation (CIPEC). For some plants, energy costs are reported to be up to 30% of total production costs. Therefore, a reduction in energy costs provides an opportunity to improve industry profitability. The specific energy intensity and production costs can be reduced by using modem energy efficient natural gas technologies. In addition, these technologies often improve product quality and increase productivity. Natural gas not only offers economic benefits, but is also environmentally benign as compared to other major energy sources. Emissions of NO"", CO2 particulates and SO2 are lower with natural gas than other fossil fuels.This paper provides a brief overview of some state-of-the-art gas technologies for the mining and metallurgy industry including cogeneration, oxy-air-fuel burners, ceramic immersion tube heaters, direct gas contact process, low NOx burners, and energy efficient liquid heating systems.CogenerationCogeneration is defined as the simultaneous production of electricity or mechanical power and useful process heat from a single fuel source. One of the primary considerations in selecting a cogeneration system is the relative quantities of electrical and thermal energy which are to be produced. Two types of systems are discussed below."

Jan 1, 1993

By D. C. R. Espinosa, P. Aliprandini, F. P. C. Silvas, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel ores are divided into two types: sulfide deposits and lateritic deposits. About 60% of nickel resources are found in laterite ore, while the remaining 40% is contained in sulfide ore. Laterite ore is usually processed via pyrometallurgical means or through hydrometallurgical techniques that include acid leaching and metal value recovery from solution. In this study, copper and nickel adsorption by Dowex M4195 ion exchange resin from an acidic sulfate liquor was investigated. The acidic sulfate liquor was collected from an atmospheric leaching process (AL) of laterite ore. Ion exchange experiments were conducted in a batch system by varying parameters such as pH, time, metal concentration and temperature. Initially, mono-elemental synthetic solutions of nickel and copper were used in the experiments and then a synthetic solution simulating AL liquor was tested. Test results showed that the resin exhibited high selectivity towards copper and nickel, however, a high concentration of iron in the synthetic AL solution interfered with the recovery of nickel and cobalt by the resin.INTRODUCTION Nickel is one of the most important industrial metals in the world. It is widely used in industrial applications, such as the production of stainless steel, magnets, electroplating and special alloys (Dizge et al., 2009). The main sources of industrial nickel production are sulphide deposits; only 40% of industrial production uses lateritic ores. However, it is estimated that 60% of global nickel resources are found in nickel laterite deposits (Kuck, 2016). Since industrial nickel demand continues to grow, the development of new technologies for the extraction of nickel from laterite ores has become an interesting research topic (Agatzini-Leonardou, 2009)."

Jan 1, 2017

By B. N. Nandi

This paper is a study of the application of the science of coal petrology to the use of coal in the iron and steel industry. The petrography of coal is given the most attention, with some mention of coal palynology. The history of the petrographical analysis of coal is first out-lined, with a description of the various coal entities, and then the apparatus and experimental techniques employed for coal evaluation are discussed. The coke stability factor and the relation of coke strength to petrographical data are also covered, and some space is given to the new science of coke microscopy, in particular its use in following the oxidation of coals.

Jan 1, 1966

By Fazel G. Jahromi, Ahmad Ghahreman

"Several studies were performed on the atmospheric leaching of copper sulfide minerals in the presence of activated carbon and a new catalyst, AF 5. AF 5 is a carbon based catalyst with similar properties to those of activated carbon however much better mechanical properties. The activated carbon surface chemistry has been investigated in various studies; however the connection of the surface chemistry of activated carbon and AF 5 with the sulfide minerals during the atmospheric leaching process is not well-understood yet. Based on the surface analysis, AF 5 showed higher surface area than activated carbon (AC). Adsorption and oxidation of copper, arsenic and iron ions in the presence of different activated carbon were investigated. Adsorption properties of both catalysts were similar and 18-24% of iron, 12-18% of copper and 10% of arsenic adsorbed on the catalysts surface form 5 g/L Fe(III) and Cu(II) and 2 g/L As(III) at 80°C. In oxidation experiments, both catalysts reduced Fe(III) and Cu(II) ions and re-oxidized the reduced species in the presence of oxygen and oxidized As(III) ions. The addition of oxidizing ions can enhance the oxidation process kinetics and increase the catalytic capability of carbon.INTRODUCTION Hydrometallurgical processes of copper sulfide concentrates are under development and various different methods have been proposed to increase the atmospheric leaching rate of copper sulfide minerals. These methods include using different media, reagents, and catalysts. Among different methods, leaching of the copper sulfide minerals in the chloride media has some advantages over sulfate media. Smaller scale of operation, increased leaching rates, and lower sulfate formation are some of the benefits of the chloride leaching media over other similar media. Moreover, using ferric and cupric ions as oxidants and utilizing activated carbon as a catalyst has been proven to enhance the leaching rate of copper sulfide minerals effectively. Activated carbon (AC) and AF 5 (micro porous carbon based catalyst) are two of the most efficient and practical catalysts in copper sulfide leaching processes. AC can enhance the copper recovery of enargite in chloride media from 69% to 92% after 96 hours of leaching under the similar conditions (Jahromi & Ghahreman, 2016). It has been shown that AC at acidic pH can generate hydrogen peroxide in the presence of oxygen which can leach copper minerals (Ahmumada et al., 2002)."

Jan 1, 2017

By Nickvinder Bhath, Johnson Matthey Plc, Jamie Baker, Daniel Kim, Jeff Lucht, Shijie Wang

"Precious metals (PM) in copper anode slimes are traditionally recovered by pyrometallurgical processes. Due to the compliance with increasingly stringent environmental regulations, it has made hydrometallurgical processing an attractive method for recovery of precious metals, including relatively inert metals such as gold and platinum group metals (PGMs). In this paper, a new method to recover PGM from complex and difficult feed streams is described. Using a proprietary Advanced Ion Exchange (AIX) adsorbent which has a high selectivity for PGMs over other metals and can achieve high PGM mass loadings with a series of incredible pilot test data plus the business case generated from the study results are also presented in the paper.INTRODUCTIONPrecious metals in copper anode slimes are traditional recovered by pyrometallurgical processes. Due to the compliance with increasingly stringent environmental regulations, it has made hydrometallurgical processing an attractive method for recovery of many metals, including relatively inert metals such as gold and platinum group metals (PGMs). Fully hydrometallurgical processes for extraction and recovery of gold and silver from copper anode slimes were employed in major copper refineries since 1995, which was first developed at Rio Tinto Kennecott Utah Copper.In Rio Tinto KUC process, the wet chlorination and gold solvent extraction were utilized to enable recovery of gold and silver as well as other metal compounds. The availability of water and the interaction and amenability of gold processing in water-based solution makes it possible that gold and silver are produced in only five days, compared with a traditional pyrometallurgical process that took 45 days. Most copper refineries are still following the tradition, but the use of hydrometallurgical technologies is increasing as the world demand for metals increases, energy utilization, and environmental viability."

Jan 1, 2016

By L. C. DeCory

"Concrete is a common denominator to the building process and portland cement is an integral and necessary component of concrete. The cost of portland cement is nominal and its cost comprises, in most instances, a small portion of the total cost of ""put-in-place"" concrete.The domestic demand for portland cement in Canada is projected to be slightly less than 11 million short tons in 1980. In order to achieve this projected goal, stabilization or lowering of the cost of put-in-place construction is necessary. This enhancement of the cost of building can be achieved by:(1) improving the building process;(2) refining and improving design techniques; and(3) developing improved and economical concrete products.Some of the techniques and materials that will lead to building cost stabilization include systems building in its broadest sense, slipforming, precasting, prestressing, computer design, lightweight aggregates, fibrous concrete and integration of building components."

Jan 1, 1973

By N. Torres, G. Melcher

"An alternative to building new copper smelters, because of either stringent environmental regulations or in order to expand current plant capacity, could be achieved through the retrofitting of old reverberatory furnaces by making use of tonnage oxygen. The CONTOP® technology offers unique advantages over other techniques for this purpose, especially regarding substantial reduction in bath, capital and operating costs. This is possible to achieve since the reverb throughput could be largely increased with no major structural modifications to the furnace.The following options are offered to the smelter operators: dirty concentrates can be treated in an adjacent Contop system, or the cyclones can be mounted on the reverb roof for either dual operation or full Contop operation. ln the tatter case the furnace will be used as a settling chamber and f or slag c1eaning by top blowing with reducing gases.By incorporating Contop technology, the furnace throughput can be increased, higher malle grade, fixation of sulphur from furnace off-gas and substantial savings in energy consumption are possible to attain.IntroductionCopper smelting has been revolutionized during the last quarter century to such an extent that the standard type of plants consisting o f roasters and reverb furnaces seem a thing of the past, or almost. Though the building of new, more energy efficient smelters is a very likely opportunity for a grassroots plant, it would be hardly justifiable to replace an old existing plant unless there are heavy environmental or economic constraints(1,2,3)."

Jan 1, 1984

By Seong-Ho Ha, Shae K. Kim, Young-Ok Yoon

In the this study, surface segregation of Mg and Ca with Mg addition range from 5 to 10wt% in Al-Mg alloys with Mg+Al2Ca master alloy and its effect on the oxidation resistance were investigated. The addition of Mg+Al2Ca master alloy as the Mg alloying element led to the surface enrichment of Mg and Ca during high temperature oxidation. As a result of the oxidation test by TGA, the oxidation resistance of all the examined alloys was significantly improved with increasing Al2Ca content. The weight change of Al2Ca added Al-5Mg and Al-7.5Mg alloys indicated the complete oxidation resistance during the whole oxidation test time, while a slight weight increase was shown in the case of Al-Mg alloys even with Al2Ca addition. The improvement of the oxidation resistance in Al2Ca added alloys may be attributed to the formation of the protective oxide layer mixed with CaO and MgO on the surface.

Jan 1, 2015

By F. Rashchi, A. Ghahreman, J. Moghaddam, S. Karimi

"In this work, the kinetics of ferric-ferrous redox reaction on a passivated sphalerite electrode is studied by the application of chronoamperometry method in 0.5 mol L-1 H2SO4 solution. The electrochemical behaviour of ferric and ferrous couple was investigated on two sphalerite minerals acquired from two different geological regions (Iran and Canada). The carbon paste electrode (CPE) of sphalerite was initially prepared and passivated in 0.5 mol L-1 H2SO4 solution and after reaching the steady-state condition, ferric and ferrous sulfate solution was added. The registered current density differences between the current density of the passivated electrode and that of the electrode in the iron salts added solution were interpreted for kinetics of ferric-ferrous reduction-oxidation reaction. The equilibrium potential for ferric-ferrous couple on sphalerites surface was about 500 mV vs. Ag/AgCl. The exchange current density (i0) for ferric-ferrous redox reactions on the sphalerite samples had the same magnitude of 10–6 A cm–2. The electrochemical impedance spectroscopy (EIS) measurements at 550 mV vs. Ag/AgCl illustrated that sphalerite oxidation was controlled by two charge transfer process in both of Fe-free and Fe-containing solutions. The charge transfer resistance remarkably decreased when Fe salts added to the 0.5 mol L-1 H2SO4 solution, owing to the ferric-ferrous redox reactions being the predominant reactions on sphalerite surface.INTRODUCTION Direct atmospheric leaching processes for sphalerite concentrates are performed by reduction of an oxidant (e.g. ferric ion and oxygen) and oxidation of sphalerite to zinc ions. Oxygen could be an oxidizing agent as well, but the concentration of oxygen is very low in the solution. The role of ferric ions is predominate in this oxidation (Babu, Sahu, & Pandey, 2002). The oxidation reaction for sphalerite in the presence of ferric in can be presented as follows (Lampinen, Laari, & Turunen, 2015):"

Jan 1, 2017

By Cheryl Devine, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg

The microbial-mediated recovery of valuable metals locked in mining wastes presents an economical alternative to conventional hydrometallurgical processes. The present study investigated the bioleaching response of a low-grade nickeliferous pyrrhotite tailings (0.6 wt% Ni) and an upgraded pyrrhotite tailings (1 wt% Ni) produced by Vale Base Metals in the Sudbury Basin of Ontario, with the ultimate aim of maximizing Ni recovery. The initial part of the study focused on the bacterial adaptive evolution protocol, by repeatedly sub-culturing an indigenous culture from an acid mine drainage site on 2% (w/v) pyrrhotite tailings. The results showed that the extent of Ni dissolution is positively correlated with microbial activity. Microbial profiling revealed A. ferroxidans to be the dominant member of the microbial consortium. The enriched culture was used for optimizing the growth medium by varying the concentration of essential growth nutrients. Finally, an aerated biotic and abiotic leach of a 10% (w/v) upgraded pyrrhotite tailings with and without pH control, showed a higher recovery of Ni in the pH controlled experiments. These results demonstrate that a high concentration of the oxidant Fe3+ in solution promotes the dissolution of Ni. Furthermore, the sulphide conversion into So was found to be higher in the pH controlled experiments (32%), relative to the experiment without pH control (10%).

Jan 1, 2015