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"Decreasing gold-in-ore grades is one of the main drivers of poorer productivity and rapidly escalating unit costs. Grinding costs, water use and reagent consumption are all intimately related to the ore grade processed. Various pre-concentration technologies have been developed that can be applied at various stages of crushing prior to ore grinding. This paper will review the amenability of ores to coarse particle barren gangue rejection for fine crush sizes in the pumpable particle size range (i.e., particles between 5 mm and 0.3 mm in size). The liberation of oxide gangue achieved during crushing is evaluated by proxy using sink-float analysis and the deportments of gold, sulfur, and arsenic into sinks and floats are monitored. Amenability of gangue rejection by continuous gravity separation is evaluated after various crushing modes (vertical shaft impact crushing, cone crushing, and HPGR crushing). The potential to identify coarse particle mineral association and liberation using three-dimensional x-ray computed tomography will be discussed.INTRODUCTIONThe aim of research in this area is to explore some of the attributes which make some ores amenable to preconcentration, or rejection of a significant component of the feed mass to tailings at a coarse liberation size. Characteristics such as ore type, mineralogy, breakage pattern, particle shape, and liberation characteristics may need to be examined to identify amenability to pre-concentration amenability.It is intended to focus on continuous gangue rejection in the pumpable size range (0.3–5.0 mm) as this remains one of the key opportunities to reduce processing costs through a combination of techniques including screening (for mineral differentiation rather than size classification only) and gravity separation (using jigs). This is to be contrasted to conventional preconcentration as performed with automatic ore sorters."

Jan 1, 2016

By R. Erpelding

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By D. Seo, P. Au, X. Husang, D. Nagy

The production of single crystal (SX) turbine blades represents the current stateof- the-art in Ni-based superalloy design. With complex casting processes and alloy composition modifications, SX superalloys exhibit superior high temperature mechanical properties to their polycrystalline counterparts. Stresses and plastic deformation can occur in SX nickel-base superalloy engine components at various stages during their manufacture and use. For examples, stresses are created during initial solidification and also during solid state processing such as shot peening, grit blasting, blending, electrodischarge machining and welding. Stresses may also be created during service due to random events such as foreign object impacts. Subsequent exposure of SX to high temperatures during solution heat treatment and brazing repair can result in recrystallization which has been shown to be detrimental to both creep rupture strength and fatigue performance of the components. It is therefore the objective of this paper to understand the recrystallization behavior of two SX superalloys, PWA 1484 and 1483, subjected to pre-stressing and subsequent heat treatments.

Jan 1, 2006

By Donald O. Downing

"IntroductionThis paper provides an overview of the coal mining industry in Canada with a description of current circumstances. The Canadian industry is placed in a global context and the future prospects of the industry are described. The export market is very important to the future of Canadian coal production and the essential aspects of the market are explained. Future prospects are very much tied to metallurgical coal exports and some key characteristics of that market are discussed, including major technological changes in the industry. Stability in 1996The Canadian coal industry enjoyed another strong year in 1996 continuing a trend established over the last four years. The strength of the industry is based on a stable domestic industry and a relatively healthy inter- national market. The figures bear out these statements. In 1996 total production reached 75 million tonnes and consumption was 52 million tonnes. The major markets for coal in Canada are electricity generating stations (Alberta, Saskatchewan, Manitoba, Ontario, New Brunswick, Nova Scotia) and the steel industry in southern Ontario. Approximately 11 million tonnes of coal were imported and exports reached a new record of 34.5 million tonnes, mainly from western Canada. Canadian Coal FlowsCanada represents a unique case in the coal world because we both import and export coal (Fig. 1). The reason for this apparent dichotomy is Canada’s geography. Eastern Canadian coal markets are located closer to the eastern United States coal fields and are basically served by them. This is true for both thermal and metallurgical coal. Major imported coal users are the steel industry, electricity generators and other industry including the cement industry in southern Ontario, Quebec, New Brunswick, with a little coal imported into Manitoba. Only about 2.2 million tonnes of western Canadian coal move into the east, including both lignite and bituminous coal."

Jan 1, 1997

By Barbara A. Filas

The IFC goal is to promote private sector investment in developing countries which will reduce poverty and improve people?s lives. The developing country goal is to promote health, education and employment opportunities that improve their economies and their standard of living. The mining company goal is to Promote successful ?triple bottom line? mining projects that will grow shareholder equity

May 1, 2002

By J. Keith Haddock

"Introduction The Coal Valley Mine is operated by Luscar Stereo (1977) Ltd. with the Alberta Energy Company having a minority interest. The mine produces 2.0 million tonnes of bituminous thermal coal per year. Deliveries include 1.5 million tonnes to Ontario Hydro and 0.5 million tonnes to the export market via bulk handling facilities on the west coast near Vancouver, B.C. There are a number of mining methods utilized at the mine including open-pit by truck and shovel, strip mining with large draglines and stripping with scrapers. The mine is located 100 km south of Edson, Alberta. Geology The coal measures are concentrated within a 210-metre int~rval of the Paleocene section. The coal seams were originally named by the mining companies in the earliest days of development of the area and these names continue to be used today. Of the five main seams, only three are presently economic to mine based on quality, thickness and depth of cover. These are the Val d'Or, Upper Silkstone and Mynheer. The Coal Valley Mine is located in the structurally deformed foothills area of Alberta and the structure of each mining area is therefore very complex. The general bedding strike is 305 degrees azimuth but major thrust faulting and folding has extensively deformed the natural seams as a closer examination will show. The Mynheer Seam, located at the base of the coal measures, ranges in thickness from 5 m to 10 m and has numerous bentonite and shale partings. Because of inherent geological features, the Mynheer Seam has been subdivided into two zones, the Mynheer 'A' and the Mynheer 'B', and the mining of coal in these zones has necessitated the utilization of distinctly different mining methods. The structural regime of the Mynheer 'A' zone consists of an overturned asymmetrical anticline crest containing a steeply dipping major thrust fault which has raised the seam above the present topographic level. Further extensive shearing and rotation of the coal has resulted in the coal taking a 'pod' shape. The Mynheer 'B' Zone is a continuation to the southeast along strike from the Mynheer 'A' Zone. The bedding dips to the southwest at an average of 12 degrees and is interrupted at the south end by a transverse fault and to the north by its outcrop at the surface."

Jan 1, 1985

By Kazutoshi Haga, Batnasan Altansukh, Yasushi Takasaki, Mohd Yazid Bin Abdul Razak, Atsushi Shibayama

"In this study, the volatilization behaviour of arsenic (As) and antimony (Sb) from arsenicantimony bearing minerals such as tennantite (Cu12As4S13)/tetrahedrite (Cu12Sb4S13) in copper ore was investigated using a roasting process. Specifically, the thermal decomposition of tennantite and the arsenic volatilization were investigated under nitrogen and air atmosphere. The roasting experiments were performed at temperatures ranging from 500 to 1,200oC and different retention times using a laboratory electric furnace. The results indicated that over 95% volatilization was achieved at 700oC. On the other hand, when the temperature increased to 1,200oC, volatilization rate of Sb reached to 90%. Therefore, volatilization of Sb requires high temperature compared to As. It suggests that As and Sb can be separated using temperature difference. Selective removal of As is possible at 700oC, subsequently Sb can be recovered as a volatilized product by increasing the temperature to 1,200oC. Meanwhile, volatilization of Cu and Fe was not observed on these conditions. The content of As and Sb in the residues obtained from roasting at 700 and 1,200oC was less than 0.3 and 0.75 mass%, respectively. The Cu content in solid residue at 1,200oC increased to 34 mass%. The clean copper concentrate with lower amounts of arsenic and antimony was obtained from the process. INTRODUCTIONRecently, arsenic (As) and antimony (Sb) contents in copper (Cu) concentrates are increasing year by year. Arsenic and antimony are present with Cu minerals such as enargite (Cu3AsS4), tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that associate with copper sulfides [chalcopyrite (CuFeS2) and bornite (Cu5FeS4)]. They are normally concentrated by flotation and treated in copper smelters. However, treatment of copper concentrates containing high amounts of arsenic and antimony by a smelting process is difficult due to environmental implications of toxic arsenic and antimony. As demand for copper continues to grow, the need to source copper from several types of resources including those that contain high levels of As/Sb becomes necessary. Therefore, a novel processes for the treatment of As/Sb bearing Cu concentrates are required. Reviews on copper resources such as enargite, tennantite and tetrahedrite containing high amounts of arsenic and antimony are covered widely in literatures by many researchers (Padilla et al., 1998; Welham, 2001; Vinals et al., 2003; Guo & Yen, 2005; Balaž & Achimovicova, 2006a; Filippou et al., 2007; Mihajlovic et al., 2007; Lattanzi et al., 2008)."

Jan 1, 2016

By James H. C. Martens

Among the many interesting problems of the pre-Cambrian of the Canadian Shield is that of the origin of certain types of gneisses which are intimately associated with the granites on the one hand and with the metamorphic rocks of known sedimentary origin on the other. The observations recorded in this paper on the structure and composition of these ancient rocks found in a small part of northern Quebec may help to lead to a clearer understanding of the way in which they were formed and also constitute a contribution to the regional geology and petrography of a district for which little detailed information is available. The area considered is located near the Ashuapmuchuan, or Chamuchuan, river about 180 miles north-northwest of the city of Quebec, and therefore well within the Canadian Shield. Although most attention was devoted to the rocks along this river from the 57th to the 70th mile above its entrance into Lake St. John, a few observations on other localities to the north and northwest of that lake will be included. The field work was done in the summer of 1924 in cooperation with L. W. MacNaughton, E. S. Roberts, and B. M. Shaub, all of Cornell University. The party ascended the Ashuapmuchuan river by canoe and spent about a month near the mouth of Stacker, or Brochet, river, the outlet of the lake of the same name, returning by way of Mikoasas river. The writer wishes to express his obligation to his associates for their co-operation in the field and for their permission to publish the results. He is especially indebted to B. M. Shaub for the photographs of rock outcrops. Professor A. C. Gill g:ive many suggestions which were helpful in the laboratory study of specimens and in the preparation of this paper.

Jan 1, 1927

By J. Bensabat, B. Figueiredo, A. Niemi, J. Rutqvist, C. F. Tsang

"A hydro-mechanical model was developed to study the interaction between mechanical deformation and fluid flow in the fault zones during CO2 injection and storage at the Heletz site which was chosen as a test site for CO2 injection experiments in the framework of the EU-MUSTANG project. The potential reservoir for CO2 storage at the Heletz site consists of three sand layers separated by lowpermeability shale layers. The potential consequences caused by fault reactivation, focusing on the shortterm integrity of CO2 storage, are evaluated. The difference in the results obtained by considering the three-layer as an equivalent layer storage formation is analyzed.INTRODUCTIONLarge-scale storage of CO2 in deep underground reservoirs may cause considerable pore-pressure perturbation as well as flux migration and concern has been raised over whether shear slip displacements may be induced in nearby faults, as a consequence of their reactivation. A state-of-the-art review can be found in Rutqvist (2012), which describes the various possible effects resulting from CO2 injection into a deep sedimentary basin, including those involved in reservoir stress–strain changes, micro-seismicity, caprock sealing performance, and potential fault reactivation. Moreover, several studies have recently shown how CO2 injection may produce seismic events both on major faults (i.e., large faults with large initial shear offset) (Cappa & Rutqvist, 2011a, b, 2012), and on minor faults that might have gone undetected during the site characterization, e.g., faults less than 1 km long and without detected initial offset (Mazzoldi et al., 2012).The present paper is concerned with the Heletz formation which was chosen as a test site for CO2 injection experiments in the framework of the EU-MUSTANG project. The Heletz site located at the southern Mediterranean coastal plain of Israel and the structure is an anticline fold with a crest of about 4 km by 2 km. The structure is gently dipping to the east, truncated by a pinch-out line to the west and subdivided into a number of blocks by transversal normal faults with small displacements. The water table is located at 300 m below the land surface. An areal sketch of the site with the elevation of the caprock and the location of the borehole that has been chosen for the CO2 injection experiment is presented in Figure 1."

Jan 1, 2015

"Le présent article porte sur la diminution des rejets de concentrateurs produits durant l’exploitation et le traitement des minerais métalliques.Le minerai dilué envoyé au traitement a, très souvent, un certain pourcentage du stérile qui affecte directement la rentabilité des opérations souterraines et amplifie l’impact négatif sur l’environnement. Les essais de la séparation du stérile et du minerai effectués en milieu dense sur quelques types de la minéralisation d’or, ont démontré les deux possibilités qu’offre cette technique:• Dans le cas d’un minerai riche, il a été possible de séparer la part importante du toutvenant (minerai dilué contenant le minerai et le stérile) provenant de la dilution, tout en ayant un taux de récupération élevé (supérieur à 96%).• Dans le cas d’un minerai ayant une teneur sub-économique à cause d’une dilution importante, il est possible de produire un concentré ayant une teneur économique à l’entrée de l’usine de traitement, en éliminant une partie du tout-venant.En plus la séparation du stérile peut accroître, en outre, la rentabilité de l’exploitation minière, car le fait d’éliminer la partie de stérile le plus tôt possible diminue certains coûts (transport, traitement et autres). On conclue que la pré-concentration du minerai (séparation du stérile et du minerai) est probablement une seule solution actuellement étudiée qui diminue l’impact environnemental de la mine, sans avoir des conséquences négatives sur la rentabilité de l’exploitation souterraine."

Jan 1, 1997

By Steve Scott

Green Economy Toyota Prius Hybrid contains about 50 kg of copper. All-electric cars have about 100 kg of copper. From where will all the copper come? Wind turbines have 1 metric ton of copper China is building 221 cities of 1 million people by 2025 (13 cities per year from 2008) = 10 New Yorks. The Greater Toronto Area has 5.6 million people, so a new GTA every 22 weeks!

May 1, 2013

By W. B. Dingle

"IntroductionMANY PAPERS presented on developments in the Canadian Petroleum Industry •during the past few years have commenced with this general sentence: ""The past year has been a record •one for the oil industry in Canada, with new records being set in nearly all phases •of exploration and development ,activity"". This sentence applies equally well to 1951. It is not possible to outline all the details of the broken records in exploration, development, and production but general comparisons can be made. There are several significant developments that have stolen the spotlight during 1951, some of which were foreseen in 1950 and some which were not. Among the high-lights were the following:(1) The greatly •expanded activity in the search for gas, which was touched off by the new Alberta regulations covering gas leases and reservations.(2) The discovery of commercial oil production in the Williston basin of North Dakota and Manitoba, which will have far reaching effects on Canadian oil.(3) The greatly increased activity in northern Alberta, northwestern British Columbia, the southern Northwest Territories, Saskatchewan, and Manitoba.(4) The new discoveries in the general central Alberta area.(5) The granting •of a permit for an oil pipeline to the Pacific coast.(6) The arrival of Western Canadian crude in central Ontario.(7) The number of new refineries completed, commenced, or proposed.(8) The present •and proposed expansion in the petrochemical industry.Most of the remarks made on various exploration and development •activities will refer to Western Canada operations, primarily because the greatest •activity and the most significant developments have been there. Eastern Canada exploration and development operations were at a slightly higher level than in 1950."

Jan 1, 1952

A series of field and laboratory evaluations were conducted in order to characterize the effects of a Mann+Hummel SMF-AR® diesel particulate filter (DPF) system on the aerosols and criteria gases emitted by diesel engines. This system, with a durable sintered metal filter media and available active regeneration via an on-board electrical heater, has been considered for retrofitting diesel engines used in light- and medium-duty underground mining applications. Two DPF systems were installed on a forklift and locomotive from the underground mining fleet of the Vale?s Creighton Mine and evaluated over a 1,500-hour trial. This evaluation was complemented with field and laboratory emissions tests. The field tests were performed on the vehicles while at the Creighton Mine surface shop. During those tests, the emissions were assessed for the engines operated at hydraulic stall, high idle, and low idle conditions. The laboratory tests were executed at the diesel engine emissions laboratory at the National Institute for Occupational Safety and Health (NIOSH), here the DPF removed from the forklift was further evaluated at four steady-state engine operating conditions as well as at transient conditions using a custom-designed duty cycle. Very similar methodologies were used during field and laboratory tests to measure concentrations of aerosols and criteria gases in the diesel exhaust, both upstream and downstream of the DPF system. The concentrations and size distributions of aerosols were measured using a fast mobility particle sizer spectrometer, in exhaust diluted by a partial flow dilution system. The concentrations of CO2, CO, NO, and NO2 were measured in the raw exhaust using a Fourier transform infra-red spectrometer. Both field and laboratory emissions tests showed that the evaluated DPF systems were very effective in reducing aerosol emissions from all tested engines, and for all test conditions. The systems were found to have minor effects on gaseous emissions from those engines. The findings from this study should help the mining industry to better understand the benefits and challenges of using DPF systems to control the exposure of underground miners to diesel aerosols.

Aug 1, 2013

By J. E. Nelson

This paper will examine the problems inherent in matching grinding mills with electric motors through connecting elements such as clutches. Emphasis will be on the uncertainties of mill torque and power demands and the need to recognize these if dependable, safe designs are to be obtained.

Jan 1, 1972

By B. Chareyre, H. Pourpak, L. Scholtès, E. Papachristos

"Numerical methods used to study hydraulic fracturing in low permeability rock masses need to take into account the interaction between the progressive failure mechanism of the intact rock matrix and the pre-existing natural fractures. A fully coupled hydro-mechanical 3D discrete elements model dealing with such interaction is presented here. The ultimate objective is to grasp the role of the rock-matrix failure on the propagation of the main fluid driven fracture under different stress fields and pre-existing fracture orientations. The proposed method provides the spatiotemporal distribution of the induced crack events which can be tracked during the simulations, making possible the identification of the local mechanisms leading to macro-failure in the rock matrix or reactivation of the discontinuity planes. Fluid flow inside a fracture, pressurized crack and hydro-fracking experimental tests were simulated as part of the validation process of the model and, are presented in this paper.INTRODUCTIONWith the expansion of shale gas and geothermal reservoirs exploitation, the technique of Hydraulic Fracturing (HF) has been widely used over the past years (McClure, 2012; Britt, 2012). Despite recent advances in micro-seismicity analysis or numerical modeling (Nagel et al., 2013), the way progressive failure of rocks affects the fluid flow depending on the in situ stress conditions or the rock heterogeneities is not fully controlled yet (Zoback, 2010).In this work we focused on setting up a three-dimensional discrete elements model to study fluid driven fractures propagation. The intact rock is modeled by a discrete element method (DEM) able to reproduce fracture initiation and propagation (Scholtès and Donzé, 2013, Garcia et al., 2013). The pre-existing fractures are explicitly modeled and can be individually defined or be part of a discrete fracture network (DFN) (Harthong et al., 2012). Their mechanical response is fully coupled with the fluid within a HM-DEM framework. The fluid flow and it’s interaction with the intact matrix and the pre-existing discontinuities is modeled through a Pore-scale Finite Volume (PFV) scheme specially enhanced for fractured rock modeling (Chareyre et al., 2012, Catalano et al., 2014) ."

Jan 1, 2015

By Lluís Fontboté, François Lieben, Robert Moritz, Massimo Chiaradia

"Abstract - The Las Cañas stratabound Pb-Zn deposit, in northern Chile, is hosted by the Lower Cretaceous back-arc marine carbonate and subordinate andesitic volcanic and volcaniclastic rocks of the Chañarcillo Group, one hundred meters above a thick pile of magmatic arc-related basaltic to andesitic lavas of the Bandurrias Formation. The deposit is not obviously related to local intrusive rocks, which include an Upper Cretaceous granodiorite batholith and dacite dikes emplaced along normal faults. Stratabound Pb-Zn-Ba mineralization is constrained within several porous stratigraphic units, including a 50 cm thick lapilli-tuff and less well mineralized algal-laminated limestone. Veins that locally carry some Pb-Zn occur along normal faults that displace the stratabound orebodies, and this study shows that they represent a different type of mineralization.Fluid inclusion microthermometric data for ore-stage quartz and barite indicate saline fluids (6 to 30 wt% NaCleq) and a formation temperature in the range of 80°C to 160°C for the stratabound mineralization. Two types of fluid inclusions occur in the veins. The type I vein fluid inclusions indicate less saline (average 7 wt% NaCleq) and slightly higher temperature fluids, in the range of 110°C to 220°C. The type II vein fluid inclusions indicate highly saline fluids (25 to 40 wt% NaCleq) which might be related to minor copper mineralization.206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios for galenas from the stratabound mineralization, with mean values of 18.42, 15.59, and 38.25, respectively, fall within the range of stratabound polymetallic deposits of northern and central Chile, and indicate a Lower Cretaceous magmatic rock source. Galenas from veins have slightly more radiogenic 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios, with mean values of 18.47, 15.61, and 38.34, suggesting two distinct episodes of mineralization.?34S values for galena and barite range from negative values (-31.2‰ to -12.5‰ and -7.7‰ to +12‰, respectively) in the mineralized tuff to higher values in the algal-laminated limestone (-2.5‰ to +1.2‰ and +13.2‰ to +17.4‰, respectively), close to Lower Cretaceous marine sulfate values for barite, and homogeneous values for the galena from veins (-12.0‰ ±1‰). Changing redox conditions can partly account for ?34S variations in the tuff. Sulfur sources include magmatic rock sulfur (-1.5‰ to +9.7‰) as well as sedimentary sulfides and marine sulfate."

Jan 1, 1999

By Ellie Condolios

Hydraulic hoisting offers a number ~f attractive features over conventional hoisting methods: small shaft space requirements; great flexibility of layout, including pick-up or delivery of the material at points distant from the mine shaft; low investment and operating costs. However, limited practical experience with this type of hoisting dictates that careful design and, frequently, extensive testing be done by competent engineers before large-scale installations are built. This paper covers the following: basic laws and design criteria for hydraulic hoisting installations; a description of a coal hoisting installation which has been in industrial operation since 1960, with a vertical lift of 600 feet and an annual capacity of 500,000 tons of -3 ~-in. coal; and a tentative appraisal of the process, including cost estimates. THE transportation of solids in water flowing through a pipe-line has, for a number of years, been common practice in dredging, public

Jan 1, 1963

By L. Shang

In conventional continuous hot rolling processes, metals are usually reheated to a temperature such that the workpiece will maintain appropriate hot working characteristics as it proceeds through the rolling mill, assuming that the temperature is continually decreasing. Metallurgically, reheating will reduce micro-segregation in the as-cast material, may increase the as-cast grain size and will affect any second phase particles present in the as-cast structure. All these changes can affect the hot working characteristics, and the final as-hot rolled microstructure. In order to study the effect of reheating on AZ31 magnesium alloy, a plate sample was cast in a water cooled copper mould and a series of compression tests was performed at a temperature of 350 °C, strain rate 0.01 5-1, and strains from 0.2 to 1.0, after different reheating schedules. It was found that there is no significant difference in flow behavior between the as-cast sample and all but one of the reheated ones. The reheat treatment of the 'anomalous' sample was a two stage heat treatment; it was first reheated to 450 °C, cooled to room temperature, then reheated to 350 °C. The effect on the flow curve was to increase the flow stress. This result may be related to changes in second phase particle characteristics.

Jan 1, 2006

By V. Barranco, K. Yliniemi, A. Hubin, B. P. Wilson, D. Janas, M. Lundström, P. Hannula

Typical copper electrorefining electrolyte contains tens of grams of copper, some nickel and a wide variety of impurities. Some of these impurities comprise trace amounts of dissolved precious metals like Ag, Pd and Pt that currently are not fully exploited. This study presents an electrochemical method to recover precious metals via a combined electrodeposition-redox replacement (EDRR) process, where energy is used only to deposit copper during the ED-step, while the RR-step relies on the spontaneous replacement of copper by the precious metals (i.e. cementation). In order to conduct the recovery successfully, process parameters such as deposition potential (EDE), deposition time (tDE), redox replacement time (tRR) and the number of cycles (n) was adjusted. Investigations performed in synthetic electrolyte (40 g/L Cu, Ag = 10 ppm) proved the possibility to recover a high purity silver. Short deposition times (tDE) were found to result in small Cu particles that provided a suitably high surface area for silver cementation. In addition, experiments performed in real industrial electrolytes containing 44 g/L Cu and 54 ppb Ag (Boliden Harjavalta, Pori), demonstrated that EDRR could attain Ag recoveries of between 46–67% in an energy efficient, additive-free manner. INTRODUCTION The raw materials used in the state-of-art primary and secondary copper smelters contain mainly base metals, but also notable amounts of Ag, Pt and other precious metals. These valuable metals distribute mostly into the copper matte during the pyrometallurgical treatment (Tirronen et al., 2017) and end up into the cast anodes. During the electrorefining stage, metals more noble than copper such as gold and platinum, are not dissolved but enrich into the anode slimes. In contrast, silver may dissolve slightly and thus, minor chloride addition is used to retain silver in the slime as sparingly soluble AgCl. Moreover, other metals less noble than copper may also dissolve, such as nickel. Therefore the electrolytes used in electrorefining typically contain substantial amounts of copper, nickel and even arsenic as well as minor metals such as antimony and bismuth. In the Boliden electrorefinery these were reported to be in the magnitude of 51.2– 60.4 g/L of Cu, 10.9–15.8 g/L Ni, 7.2–15.9 As, 0.2–0.4 Sb and 0.1–0.4 Bi with an associated sulfuric acid concentration of 139–155 g/L (Lehtiniemi et al., 2018). Copper is the most noble of the dominating base metals in the electrolyte and is thus deposited on the cathode as 99.99% purity LME-A grade. Anode slimes are collected and subjected to precious metals treatment e.g. via pressure leaching—selenium recovery— Doré smelting—Ag refining—Au/Pt/Pd leaching and reduction process (Ludvigsson & Larsson, 2003). The Pori refinery, operating in Finland since 1941, not only produces 133 000 t Cu cathode and 2300 t nickel sulphate annually but also 66 t silver, 4.6 t gold and palladium and platinum (in year 2017).

Jan 1, 2019

By C. A. Young, H-H. Huang, L. G. Twidwell

Solid particles, especially oxides/hydroxides, develop an electrical charge on their surface when submerged in aqueous solution. Parks was able to relate PZC (point of zero charge) of an oxide to its minimum solubility and isoelectric point. Dzombak has compiled an extensive database for adsorption reactions on ferrihydrite surfaces using the double layer theory. The equilibrium calculational program, STABCAL has been used to extend the considerations of Parks and Stumm. The PZC for many hydroxides, complex oxides, and non-oxides have been investigated and the results are reported in the literature. Removal of arsenic and metals by adsorption on ferrihydrite as the substrate has been computed using ST ABCAL and the computational results are compared to experimental data. Absorbents other than ferrihydrite such as aluminum hydroxide are also discussed.

Jan 1, 2005