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By R. Pressacco

"IntroductionAgrium’s history in fertilizer production and marketing goes back to 1931. Today, Agrium Inc. is a world leader in the production, distribution, and marketing of fertilizers and related products to the agricultural industry. Agrium is the largest North American producer of nitrogen fertilizers, a major producer of phosphate and potash fertilizers, and a world leader in fertilizer wholesale distribution and retail marketing. The mine at Kapuskasing is located some 40 km southwest of Kapuskasing, Ontario (Fig. 1). It has been developed to supply high-quality, low-cost phosphate rock to the company’s Redwater, Alberta facility, where it is an ingredient in ammonium phosphate fertilizer production. The Kapuskasing mine is the only phosphate mine in Canada and will rank as one of the highest-grade phosphate mines in the world (Clark and Duncan, 1999). Apatite is the principal ore mineral mined at the Kapuskasing Phosphate Operations.GeologyThe first record of exploration in the area was from a program executed by Continental Copper Mines in 1955 which evaluated the magnetic anomaly located in the Cargill and Cumming townships for its base metal potential. Intermittent exploration of the base metal potential of this magnetic anomaly continued in the following years, until the phosphate potential of the area was first examined in 1974 by International Minerals Corporation which recognized the presence of a layer of apatite sands overlying the carbonatite host rocks.The local geology consists of a core complex of multi-phased carbonatite rocks which are surrounded by a ring of pyroxenite, and have provided a U-Pb age date of 1907 Ma ± 4 (Sage, 1988). These two rock types are in turn situated within quartz diorite gneisses that form a large portion of the Kapuskasing Structural Zone (Fig. 2). The carbonatite host rock is sub-divided into two sub-types: sovite and rauhaugite. The sovite is a medium- to coarse-grained, white, banded rock in which calcite is the dominant carbonate species and it includes accessory minerals such as phlogopite, magnetite, clinohumite, apatite, olivine, pyrrhotite, and amphibole. Apatite can reach 15% abundance in this rock type (Sage, 1988). In sharp contrast to the sovite, the rauhaugite appears as a massive, fine-grained, dense, beige to tan-coloured rock in which dolomite is the dominant carbonate species. Phosphate values can range to 14% P2O5 in the rauhaugite."

Jan 1, 2001

By Norman B. Davis

THE ceramic group of industries is comprised of those engaged in the manufacture of cement, glass, artificial abrasives, whiteware, including earthenware, stoneware, porcelain tableware, porcelain sanitary ware, electrical porcelain, floor and wall tile, porcelain enamel on metals, refractories of all kinds, sewer-pipe and structural clay products, such as terra cotta, brick, and hollow tile. The various sub-divisions of the industry produce a wide range of articles on which we depend for our creature comforts from day to day, perhaps to a greater extent than we generally realize. The industry, in turn, depends on a great number of minerals, and chemical products derived from minerals, and it is the object of this brief paper to present a list of these with notes indicating the particular applications. In order to bring home the importance of the industry to your daily life, stop and consider the many things around you accepted as a matter of course. Cement provides the smooth surfaces of many of our highways, city streets, and sidewalks. It enters into nearly all types of construction, alone or in combination with other clay products. Glass we hardly appreciate because we can see through it so easily, but it is there to serve us in windows, doors, and other light-transmitting structures. Glass is the universal means of transporting liquids and beverages, our beverages are usually served in it, and, with the recent development in fine spun glass textiles, there is a possibility of glass clothing in the future. Chinaware, a general term for table dishes, may be earthenware (not vitrified), semi-porcelain, or bone china, but it is before us three or more times a day ?and we seldom think of the minerals that have made these products possible. Floor tile, wall tile, and other ceramic specialties for interior and exterior use and decoration please the eye and provide sanitary surroundings.

Jan 1, 1938

"Real time analysis of conveyed bulk materials can be used to improve process performance by reducing variability and upgrading ore quality through selective removal of increments of flow that do not meet appropriate selection criteria. This paper focusses on proven Prompt Gamma Neutron Activation Analysis (PGNAA) and microwave transmission technologies used to representatively measure conveyed ore quality in real time so that meaningful decisions can be made between the mine and mill. This enables the effective removal by bulk diversion of small increments of conveyed flow such as waste, highly deleterious material or sub-economic material from the mill feed. Improved ore quality in plant feed optimises process performance, reduces processing costs and minimises tailings generation. Analysis is unaffected by particle size, dust, layering or segregation, mineralogy and belt speed. Technologies are explained and performance examples given from installations in copper and iron ore. The technology has been used successfully in bulk sorting for over twenty years typically using measured increments of a few minutes. Improvements in technology and calibration performance have resulted in accurate measurements over increments of thirty seconds and below.INTRODUCTION Ore quality variability exists on a number of scales. Block model grades represent a few hundred to many thousands of tonnes. Grade control at the mine occurs on a scale typically down to the size of a haul truck, which may be a few hundred tonnes. Highly variable ore quality is detrimental to process efficiency and effectiveness. Processing waste or low grade ore when higher quality feed is available represents a lost opportunity to generate higher revenues earlier in the operational life. Measuring ore quality accurately over short time increments during conveying enables small increments to be measured and diverted according to their quality. The paper explains the technology and benefits. Neutron irradiation techniques were considered potentially suitable for conveyed bauxite measurement by Beurton et al, 1995. Tran & Evans (2001) concluded there was no equivalent technology to Prompt Gamma Neutron Activation Analysis (PGNAA) in terms of material penetration power. PGNAA was evaluated by Nelson & Riddle (2003) for possible use in the phosphate industry and recommended its use for further characterisation of the mine’s various ore types to improve stockpile allocation and grade control. Cottle (2007) discussed test work for an iron sinter application and Delwig et al (2011) described the successful installation in 2009 and performance of PGNAA for base-to-acid ratio control in sinter feed with the analyser output used to control lime addition. Geoscan (PGNAA) works very well on iron ore and can “improve control over what is happening in the plant” and that comfort can be provided in knowing that the product is on-spec according to Minnett (2010). PGNAA is not yet used in the minerals sector for tariff purposes as has occurred since 2000 with Coalscan (PGNAA) in coal (Minnett, 2010)."

Jan 1, 2017

By Tom Dettweiler

Who We Are A global pioneer in discovery, development and recovery of deep-ocean assets Shipwrecks Deep-sea Minerals Company Overview Founded 1994 HQ ?Tampa, Florida USA Employees 45 Tampa + 150 Abroad Publicly Traded: NASDAQ:OMEX Requires Specific Financial Controls and Reporting

May 1, 2013

By William E. Roscoe

"Non-producing mineral properties include those at various stages of exploration, properties at the pre-feasibility or feasibility stage, properties with currently uneconomic mineral resources, and past-producers. The market approach is applicable to all these types of non-producing mineral properties. Income approach methods such as discounted cash flow and option pricing are generally not applicable to properties at the exploration stage, but may be applicable to non-producing mineral properties with defined mineral reserves or mineral resources.The value of a non-producing mineral property depends on its perceived potential for the existence and discovery of an economic mineral deposit. The potential, in turn, depends on a number of factors which must be considered when choosing market comparables. These comparability factors include such items as geology, mineralization, stage of exploration and results, mineral resources, location and geography, and political jurisdiction. The date of the market comparables must be within a reasonable time period of the valuation date of the subject property. Although it is difficult to find good market comparables because of the unique nature of mineral properties and the small number of transactions, these difficulties are compensated for by analyzing a number of transactions on similar properties to develop a range of values for the subject property.For valuation purposes, market comparables can be expressed in terms of total property value, value per unit area (e.g., $ per hectare), or value per unit of metal contained in mineral resources (e.g., $ per ounce of gold, or $ per pound of copper). The market comparable value can be used to estimate the value of the subject property by using the total property value, unit area value or contained metal value."

Jan 1, 2003

By Jason Palmer

"Water in mining is the commodity that has driven the mining industry for decades. Often used frivolously, modern economic and social pressures are forcing change to use less water and to improve the quality of water and effluents. Used in many processes, water is ultimately consumed in tailings disposal and technologies which can increase the recovery of water are constantly being developed. Filtration and thickening are often seen as competing technologies for water recovery however new cases are developing that show significant advantages can be achieved by combining the two technologies to develop the most effective solution. Supported by case studies this paper investigates the merits of each of the technologies and which strategies of combining the two produce the best outcomes.INTRODUCTIONMineral processing applications generally require water for the processing of ores, whether utilising physical or chemical methods. Water is first added in the milling stage and additional water added as required throughout the circuit. Water losses from the circuit are principally associated with the tailings stream. Optimised water recovery is necessary both because it is a scarce commodity and to minimise the environmental impact.Water recovery is usually accomplished through a sedimentation or filtration processes. Water can be removed from the tailings impoundment by evaporation but this does not improve the mine’s water consumption. The water recovery methodology also determines the water quality; increasing water recovery concentrates solutes in the process water and may create recirculating loads of fine solids."

Jan 1, 2016

By John Blackshaw

NEW sources of supply of tungsten concentrates became necessary when the flow from the Far East was blocked in 1942. In Canada, one source has been noted in the workings of the Hollinger mine at Timmins, Ontario. For many years, a small amount of scheelite had been removed with the gold ore, and an appreciable tonnage of scheelite still remained in the mine. At the request of the Dominion Government, a plant was built to recover this scheelite in the form of a concentrate that could be used by the alloy-steel industry without further preparation. The plant began operating early in March, 1942, and a small tonnage of ore, carrying scheelite and gold values, has been treated daily since then. The possibility of recovering the scheelite had been considered on several previous occasions. Each time the proposal had been given up because the total profits from the enterprise were estimated to be insufficient to repay the capital cost of building the recovery plant. At the time the plant was built, additional information had been gathered about the tonnage and grade of the scheelite ore in the mine, and several thousand tons of ore grading higher than 0. 25 per cent WO3 (tungstic trioxide) were known to be available.

Jan 1, 1943

By M. Lindgren, M. Latva-Kokko

Process performance can be significantly influenced by proper design of hydrometallurgical reactors. Optimal reactor configuration is case specific and depends on process requirements such as reaction rate limiting factor and particle size distribution. Choice of materials and manufacturing methods also play important roles in highly corrosive and abrasive environment often involved in hydrometallurgical industry. In this paper performance of different reactor designs has been compared in some typical hydrometallurgical applications. Results show that significant improvement in energy consumption, gas utilization efficiency and equipment lifetime can be achieved with process specific reactor design.

Jan 1, 2014

By C. Doyle, D. M. Hoffman, C. Díaz, J. Hrepic, W. J. Koshut, R. H. Hanewald

"Recently, lining life of the INMETCO submerged arc furnace has been dramatically extended from an average of eleven months in the 1980s to a current record of 34 months. This paper summarizes test work and operating results describing the development and establishment of slag parameters that reduce corrosion of the magnesite-chrome refractory lining.The desired slag parameters are now maintained by utilizing waste streams as slag additives. This paper also discusses the successful evaluation of a rebonded-fused-grain magnesite- chrome refractory as a lower cost, more thermo-mechanically forgiving alternative to a fused-cast magnesite-chrome refractory that had been the refractory of choice in previous years at INMETCO.IntroductionSince 1978, INMETCO, a wholly owned subsidiary of INCO Limited, has been well known for recycling by-products from the production of stainless steel, namely, EAF bag- house dust, mill scale and grinding swarf. INMETCO operates the only smelter in North America dedicated to the recovery of nickel, chromium, and iron from hazardous and nonhazardous waste. The process was developed in the research laboratories of INCO. In recent years, the process has been successfully modified to accept a wider variety of other specialty steel waste streams including: spent pickling solutions, pickling and waste water treatment filter cakes, acid scale, carbon brick, spent bag-house bags, torch cutter dust, spent dolomitic and chromium-bearing refractories, and rechargeable nickel-cadmium batteries."

Jan 1, 1997

By J. K. Szymanski

"RÉSUMÉPour maintenir de bonnes performances technique et économique dans l’exploitation par chambres vides (open stope) il est primordial d’assurer un contrôle efficace des limites réelles des chantiers d’abattage. C’est pour cette raison que, de plus en plus souvent, les opérateurs miniers utilisent un dispositif de laser (Cavity Monitoring System: CMS) qui permet de mesurer les dimensions réelles de chantiers en vue de calculer principalement la dilution et les pertes du minerai ainsi que d’autres paramètres. Malheureusement, il n’existe présentement aucune méthodologie commune, qui permettrait d’interpréter ces résultats selon les mêmes critères pour faciliter d’évaluations juste et précise de la réalisation par rapport à la planification en vue d’en apporter de corrections, dans les différentes opérations minières, si nécessaire. Dans la première partie du présent article on discute les principales séquences d’exploitation utilisées dans l’extraction par chambres vides. Par la suite, à l’aide des sections transversales et longitudinales on illustre toutes les phases des travaux miniers. Ceci en vue de permettre au lecteur de comprendre mieux c’est qui peut se passer effectivement dans les chantiers d’abattage. Par après on donne les définitions générales de principaux facteurs de performance technique. Finalement, l’exemple numérique, élaboré à partir des résultats de l’arpentage au laser effectué par la mine Bousquet 2 dans un chantier d’abattage, donne les détails concernant les définitions ainsi que les valeurs de nombreux facteurs de performance technique, qui pourraient être utilisés, par après, par les opérateurs miniers dans le suivi de leurs exploitations souterraines."

Jan 1, 1997

By W. D. Breil, C. B. Ison

A collection of general performance data relating to the G.H.H. - Gutehoffnungshiitte multi-rope friction hoist will be discussed together with some aspects of the following: overspeed supervision by a pantam device as opposed to the lilly type of fly ball control, automatic control systems, multi-disc braking, generator and motor winding, constant temperature monitoring, the development of an automatic hoist-rope lubrication system, and the control of rope tensions by the installation of G.H.H. - Gutehoffnungshiitte hoist rope fine tensioning units.

Jan 1, 1972

By V. Estrada, G. Aguilera

"Since the most of mineral processing are wet, and for more specific applications where it is necessary to increase the purity through leaching and / or concentration, the proper dispersion is the first, and perhaps more crucial stage in the whole chain of processing. This specific process is based on the formation of a dispersion or suspension of mineral, trying to make the mixture as homogeneous as possible, and with specific rheological conditions. Sometimes it is not enough agitation to make it happen, so that chemical additives are used as an aid. However, the addition of chemicals strongly alters the viscosity and other rheological properties of the suspension factor to consider for subsequent steps to ore beneficiation. In other hand, in a process where no chemicals used often employ large quantities of water to achieve dispersion. But if an efficient chemical agent, which optimizes said dispersion through a specific physicochemical effect on the particle surface is used, also it can generate rheological advantages, besides achieving rational use of water and increase the recoveries of the product main about also optimal costs. The aim of this work is to find the optimal rheological conditions for a dispersion of kaolin as study case, looking for stability, best disaggregation, viscosity and pseudoplasticity.To find the optimal additive, the evaluation parameters were: 1) Best degree of dispersion of the suspensions according to the analysis of the flow curve; 2) Best level of disaggregation of particle chemical analysis delaminated by Particle Size Distribution; and 3) Best thixotropic rheological parameters and pseudoplasticity. Finally the optimum additive as one that meets the best combination of parameters is proposed.INTRODUCTIONKaolin is a clay material formed by altering of feldspar composed mainly for kaolinite. Depending on the application, the kaolin as raw material must be refined and processed because the ores of clays contain usually a lot of impurities derived of its sedimentary source, such as feldspar, mica and quartz (Torres, et. al., 2011). According to the experience on the plant floor and the publication of several scientific papers, it is known that the dispersion is a crucial stage in mineral processing (Greene, Duke, & Hunter, 1965) (Raghavan, et. al., 2004), not only because of the disaggregation of particles, besides because of the humectation of them. Is clear that disaggregation of particles give to the suspensions rheological stability, and the humectation improves the effect of further processes like grinding or chemical treatment. The dispersion process involves making a suspension of the mineral with a solvent which is usually water, to obtain a homogeneous dispersion, with the aid of energy of stirring. Sometimes is not enough the agitation (even with high energy) for this to occur, so is necessary the use of dispersing substances which introduce ions and molecules as modifiers of chemical potential, forcing the molecules of the material to disperse. Sometimes their use even could affect the pH of the suspension in a non-desirable condition. (Flores, 2013)."

Jan 1, 2016

?Four-wheel, skid-steer, rover developed for CSA ?U-chassis for payload accommodation ?Passive geometric suspension ?Max speed 13km/hr ?Remote workstation ?275kg payload capacity ?On-board processor, IMU, motor encoders ?5.2kW-h battery capacity

May 1, 2013

The Autogenous milling of ores holds an increasing attraction as the focus moves towards reducing energy usage, both direct and embodied in grinding media. However, most of the early AG mills were converted to SAG for improved stability and increased throughput. This imposes a huge penalty in steel grinding media consumption. The LKAB iron ore operations in Sweden process highgrade magnetite through fully-autogenous milling lines to a final product P80 of about 45µm. The outcomes of P9O AMIRA research surveys, covering a wide range of mill fillings and throughputs and with different feed blends, are presented. Insights are provided on operational strategies, opportunities, the influence of feed size control and balancing the blend of competent gangue and softer magnetite. Areas of importance in the successful operation and control of energy-efficient autogenous circuits are highlighted.

Jan 1, 2012

By H. McLeod

Introduction In the period from 1939 to the present, Canada has experienced a remarkable industrial expansion, rising to probably seventh in rank amongst world countries. In the early part of this period, the desperate need for military supplies unloosed tremendous amounts of capital for building new factories and for expanding and converting existing facilities. Mines, factories, and other divisions of the industrial economy bent every energy toward greater and greater output. The result was an 80 per cent increase in the volume of the nation's production within a period of four years, a truly remarkable accomplishment and one in which the mining industry had a very vital part. After the critical year, 1944, the tempo of industry eased off a bit, dropping approximately 20 per cent by 1946. At this time the prospects or post-war industry were clouded by monetary and political chaos in overseas countries, by trade restrictions, and by market uncertainties. There was, of course, a pent-up demand, both at home and abroad, for civilian goods that had been curtailed during the war and for capital equipment that had been destroyed. In the midst of this world-wide uncertainty, if anyone had ventured to predict that by the end of 1950 Canada's industrial output would be back to the 1944 level and humming along at nearly twice the best pre-war pace, he would have been considered rash indeed. Yet this has been the case.

Jan 1, 1951

By Yves Prévost, Guy St-Amant, Guillaume Dion

In 2010, the foreseen increase of copper grade in feed concentrate at the Horne Smelter was a significant challenge to maintain a steady copper flow throughout the process. The Horne Smelter process includes a Noranda Reactor, a Noranda Converter, pyro refining vessels and anode furnaces. Of the many challenges involved, improving the single casting wheel performance was one of the key topics. Its reliability had to be improved to meet the new production objectives, as anode copper production was to increase from 170 000 to 225 000 tonnes/year. A multidisciplinary team was dedicated to improve the casting wheel availability. The improvement project allowed pinpointing failure modes and reviewing operational and maintenance practices. The common understanding developed by the team allowed improving small components with a high gain-to-effort ratio. The project allowed reaching operational targets without any significant investment. INTRODUCTION In operation since 1927, the Horne Smelter, located in Rouyn-Noranda, in Quebec, has undergone several technological changes since its original construction. Built to smelt the Horne mine concentrates, the smelter also accepted some local custom feeds from the first years of operation. When the Horne mines stopped production in 1976, the plant became a 100% custom smelter. With the development of the Noranda Reactor (1973) and Noranda Converter (1997), the Horne smelter increased its productivity and improved its environmental performance. Continuous improvement of the Horne process allowed maintaining a high level of flexibility in the operation of the smelter, while improving its overall capacity.

Jan 1, 2019

By Daniel Hodouin, Robert Lanthier, Yve Dube

"A procedure f or constructing a grinding mill dynamic model is proposed. This model is used in a dynamic simulator of are grinding circuits. The simulator is designed for flexible flow sheets involving different grinding mills and particle classifiers and is able to accept several single variable PID control loops. The dynamic model is validated on a laboratory ball mill, and calibrated to an industrial installation. The simulator is used for characterization of grinding circuit dynamic behaviour and tuning of control strategiesIntroductionThe ore grinding operation is a critical step of the ore preparation process because it is the last comminution stage before the separation of minerals. The properties of the ground minerals to be concentrated, control the quality and efficiency of the separation process. This is why it is important to control properly the operation of the last grinding stage, commonly constituted of a closed circuit ball mill with classifier . To provide an adequate fine product, the grinding operation should compensate for the perturbations of the feed characteristics (size analysis, grindability, etc.). The main objective is to maintain a constant size distribution for providing stable operating conditions to the separation units. Simultaneously another usual objective is to operate the grinding circuit at a maximum capacity.Automatic control applied to grinding circuit s is the appropriate approach to improve its operation. Most frequently average optimal operating conditions are determined from steady -state performances of the circuit , and the automatic control is used for stabilizing the operation at selected values of the process variables . In the traditional approach, one or several single input! single output (SISO) control loops are implemented and empirically tuned. Advanced control practices'!' are based on a quantitative analysis of the circuit dynamics, which could also give a basis for the tuning of conventional SISO 100ps(2)."

Jan 1, 1987

By V. Thangadurai

The critical problems in commercialization of the present solid oxide fuel cells (SOFCs) and useful electrical and physical properties of IT-SOFCs electrolytes are discussed briefly. The conductivity behavior of the perovskite-type and perovskite-related structure metal oxides are summarized. Perovskite-type La0.9Sr0.10ao.8Mgo.203_8 (LSGM) exhibits high ionic conductivity of 0.1 S/cm at 800 °C. In order to improve the electrical conductivity of LSGM and the In analogue of LSGM, substitutions have been made at the A-and B-sites. Substitution of trivalent La3+ by isovalent Pr3+ in LSGM and La09Sro ilno.sMgo.202.85 (LSIM), yield new mixed conductors. Among the investigated compounds in the present study, La0APro.4Sro.21no sMgo.2028 exhibits the highest total electrical conductivity of 3.2 x 10-5 S/cm at 200 °C in air with the lowest activation energy of 0.44 eV (200-700 °C). LSIM and Pr-substituted LSGM and LSIM perovskites show p-type electronic conductivity in the oxygen partial pressure range 10-5 ? 0.21 atm at 750 °C. The perovskite-type solid solution SrSn1-xFex03 exhibits compositionally driven phase transitions. For example, compound of the composition x = 0 to 0.3 crystallizes in an orthorhombic GdFeO3-like perovskite structure, where as that of x = 0.4-0.9 crystallizes in simple cubic SrTiO3-like, and that of x = 1 in orthorhombic structure. The electrical conductivity of SrSn1_xFex03 increases with the increasing Fe content and reaches a value of about 10-1 S/cm at 25 °C in air for x = 1. Compounds with low Fe content exhibit both ionic and electronic conductivity, while the higher Fe content 0.5) perovskites are electronic conductors over a wide range of oxygen partial pressure of 10-22? 0.21 atm at 750 °C.

Jan 1, 2005

By Jing Li, Weiqiang Lai, Joe Zhou, Jiezhen Ma, Shuibo Chen, Ashele Copper Company, Feng Gao, Guofu Feng

"Copper-zinc ores often contain gold and silver, which can be recovered into copper concentrate by flotation as by-product. The challenges for operations that produce copper, zinc, gold and silver are the separation of copper and zinc and the low grade of precious metals. Ashele copper-zinc ore in north China contains 2.38% Cu, 0.69% Zn, 0.21 g/t Au and 18.10 g/t Ag and the plant produces copper and zinc concentrates, with gold and silver being recovered into copper concentrate. Copper occurs mainly as chalcopyrite and Zn occurs as sphalerite. Copper is well recovered with a recovery of over 94%. However, the recovery of Zn is substantially low (around 50%) due to fine grain size of sphalerite. In addition, gold recovery is much lower than expected and only 33% of gold in the flotation feed was recovered. The grade of gold in copper concentrate is also lower than the required payable grade (1.0 g/t). To determine the cause for lower Zn and Au recoveries, a plant survey program was conducted on the operation. The information acquired shows that the loss of Zn was mainly in the copper concentrates (accounting for approximately 38% of the head assay); of which, 24% was liberated, 8.5% was associated with chalcopyrite and 4.6% was associated with pyrite, indicating that the separation of copper and zinc was the main cause for the Zn loss, with liberation being the second cause for Zn loss. Future effort in improving Zn recovery should be focused on the separation of zinc from copper. Gold in the ore occurs as both microscopic gold and submicroscopic gold, accounting for 36% and 64% of the head assay, respectively. Microscopic gold occurs mainly as native gold and electrum; it is relatively coarse with a grain size of 10 to 240 µm and a large portion can be recovered by gravity. Submicroscopic gold was mainly carried by pyrite (accounting for 38%), and to a less extent, by tennantite (15%) and chalcopyrite (10%). Gold in sphalerite is nominal (1%). It is suggested that more coarse gold and tennantite be recovered and a gold recovery increase can then be achieved to obtain a copper concentrate with over 1.0 g/t Au through flowsheet optimization. Gravity concentration should be investigated and may be worth added into the existing flowsheet to maximum the gold recovery and grade.INTRODUCTIONCopper-zinc ores containing gold and silver is a subtype of polymetallic sulphide ores. Unlike porphyry copper sulphide ores and iron-oxide copper-gold ores, this type of ores often contains substantial amounts of zinc and lead. Polymetallic sulphide ores are mainly distributed in Canada, such as at the LaRonde and Horne deposits. Other examples include Mt. Morgan in Australia and Boliden in Sweden. Globally, production and reserves from gold-rich VMS deposits account for 1370 t gold. This is equivalent to 1% of the world production and reserves, whereas the Canadian total for gold-rich VMS deposits is 870 t, representing close to 10 % of Canadian production and reserves (Gosselin & Dube, 2005a, 2005b). Flotation is the principal process for processing the copper-zinc sulphides ores, for subsequent smelting, roasting, or hydrometallurgical treatment. Oxidized copper-zinc ores can also be processed using leaching technology. For example, at LaRonde operation (a Cu-Zn-Pb ore containing 3-4 g/t Au and 60-100 g/t Ag) the flowsheet consists mainly of a copper flotation circuit and a zinc flotation circuit followed by a cyanidation process of flotation tails. The precious metals are recovered with copper concentrate, zinc concentrate and cyanidation of zinc tails via Merrill Crowe precipitation (Zhou et al., 2005)."

Jan 1, 2016

By J. I. Carroll, J. A. Walker

"Abstract - Camelback is a small (=200 000 tonnes), moderate grade (5%-7% Zn+Pb), volcanogenic massive sulfide deposit, which occurs within the Nepisiguit Falls Formation of the Ordovician Tetagouche Group. The host rocks are tuffaceous sedimentary rocks (Little Falls member) that overlie quartz-feldspar porphyritic tufflavas (Grand Falls member). The hanging-wall sequence comprises rhyolite of the Flat Landing Brook Formation, overlain by the Forty Mile Brook tholeiitic basalt. A dike of unaltered andesite was intersected beneath the massive sulfides, but was not found in the hanging-wall sequence in the vicinity of the deposit. The stratiform part of the deposit is made up of two, steeply south dipping, subparallel massive lenses that average approximately 4 m in thickness. Each lens is zoned, with an upper part consisting mainly of a pyrite and a basal part containing pyrite, sphalerite, and galena, with Ag values. The Au content in the massive sulfides is low (average = 52 ppb for 271 samples), but tends to be enriched in the massive pyrite near the top of each lens. Oxide facies iron formation is spatially associated with the massive sulfides, and has been traced up to 1800 m along strike. Footwall hydrothermal alteration is typical of VMS systems, and is characterized by depletion in K2O and Na2O, and enrichment in MgO and Fe2O3T with proximity to massive sulfides. The massive lenses are underlain by intensely chloritic, fine-grained, tuffaceous sedimentary rocks containing locally significant sulfide (chalcopyrite > pyrite > pyrrhotite) veins, which are interpreted to represent feeder zone mineralization. Unlike many VMS deposits, there is no evidence of silicification beneath the massive sulfides at the top of the feeder zone. The oxygen isotopic compositions (d18O = -1.5‰ to -0.3‰) of hydrothermal chlorite coupled with sulfur isotopic compositions (d34S ˜ 12‰) of the massive sulfides suggest that seawater was the dominant fluid in the hydrothermal system. Normalized rare earth element diagrams show flat Ce profiles and positive Eu anomalies, indicating that modified seawater was involved in ore formation; i.e., high-temperature (=350ºC), acidic, and reduced prior to entrainment into the hydrothermal cell. Although, seawater was the dominant fluid in the sulfide-forming system, d34S values of stringer zone sulfides (8.5‰) coupled with elevated Sn (400 ppm) in one massive sulfide sample indicate that there was at least some magmatic component in the hydrothermal cell."

Jan 1, 2006