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By Y. Tang

"Rare earth elements (REEs) have many key applications in traditional and advanced technologies. A shortage of several critical REEs is expected due to the discrepancy between the availability of REEs from REE deposits and the REE demand from the market. REE recovery and separation from secondary resources such as uranium wastes and recycled materials might help balance the shortfall in a cost-effective way. This paper presents data concerning the recovery of heavy REEs (HREEs) from uranium raffinate. It also discusses the design, commissioning, and operation of a solvent extraction pilot plant for the separation of REEs.RÉSUMÉ Les éléments des terres rares (ÉTR) trouvent de nombreuses applications importantes dans les technologies classiques et de pointe. On prévoit une pénurie de plusieurs ÉTR critiques en raison des divergences constatées entre la disponibilité des ÉTR provenant de gisement d’éléments des terres rares, et la demande d’ÉTR sur le marché. La récupération et la séparation des ÉTR à partir de ressources secondaires telles que les déchets générés par le traitement du minerai d’uranium et les matériaux recyclés pourraient contribuer à équilibrer cette pénurie de manière rentable. Cet article présente des données relatives à la récupération des ÉTR lourds (HREE, de l’anglais heavy REEs) à partir de raffinat d’uranium. Il aborde également la question de la conception, de la mise en service et de l’exploitation d’une usine pilote d’extraction par solvants pour la séparation des ÉTR INTRODUCTIONSignificant amounts of strategic specialty heavy rare earth elements (HREEs) are present in waste streams in Saskatchewan uranium operations. Selective precipitation including neutralization, oxalate, and double-salt precipitation, as well as sulfide precipitation, ion exchange (IX), and solvent extraction (SX) are commonly used technologies for the recovery and purification of rare earth element (REE) solutions. REE oxalate precipitation can effectively remove Fe, Al, Ca, Si, and other impurities by taking advantage of the solubility difference between REE oxalates and impurities in the acidic solution (Xu, 2005)."

Jan 1, 2018

By Z. I. Zaki

Synthesis of TiC /A1203 Composite from TiO2, Al and graphite using combustion technique has been investigated at different initial temperatures; room, 400 and 600 °C. The effect of initial temperature on the composition of the product, wave velocity and combustion temperature of the reaction was studied. The measured combustion temperature and wave velocity were increased with increasing the initial temperature of the combustion reaction. The maximum wave velocity obtained was 5.9mms-1 when conducting the combustion reaction at initial temperature of 600 °C. Oxidation resistance of the obtained composite was also studied at the temperature range 300-800 °C. No oxidation is detected before 400 °C while it takes place effectively at 700 °C forming different titanium oxides. Wave velocity measurements method was used to calculate the activation energy of the reaction between the starting materials. It was found to be 316.34 kJ mol 1 at the temperature range that was studied.

Jan 1, 2007

By Kenneth G. Thomas

Since approximately 2003 we have witnessed the unprecedented escalation in commodity prices. Coupled with economic chaos following the 2008 economic downturn this has caused difficulties in controlling schedule, capital costs and operating costs for mining projects. Once again escalation has returned to commodity prices fuelled by growth in the BRIC countries especially China and Brazil. This is further exasperated by the missing generation of skilled technical personnel not graduating from universities in the 1980s and 1990s owing to depressed commodity prices. This paper examines the six tenets for successful project implementation.

Jan 1, 2011

By G. W. Poling

Sedimentation behaviour of siliceous mill tailings derived from a magnetite-chalcopyrite ore in fresh water, fresh water - sea water mixtures and full-salinity sea waters are compared. Results of batch settling tests are presented in the form of settling curves and solids flux curves. The addition of a few per cent of sea water markedly enhanced the zone sedimentation rate due to particle agglomeration caused by a reduction in zeta potential of the suspended solids. The presence of a small amount of residual, previously magnetized magnetite in the tailings also enhanced agglomeration and sedimentation. The significance of these results to submarine disposal of mill tailings is discussed.

Jan 1, 1973

By N. Ginouse, S. Reny

"In the mining industry time is critical as production depends on the speed of the mining cycle. During the mining process, the time required to re-open access for the next phase of an underground heading is a key point that strongly depends on the ability of the selected ground support technique to promptly ensure the safety of workers. Fiber reinforced dry-mix shotcrete has been proven to be an efficient and well adapted technique, able to produce a ground support material with the required energy absorption or flexural toughness in a single application phase. In this context, this paper demonstrates the possibility of significantly speeding up the mining process by using a new fiber reinforced dry-mix shotcrete. The new fiber reinforced dry-mix shotcrete is capable of developing flexural toughness in only 24 hours that is equivalent to what is typically achieved after 28 days using current fiber reinforced drymix shotcrete technology.INTRODUCTIONShotcrete is often used for ground support when using the drill and blast method or other tunnelling methods. But before re-opening access for the next phase of the underground heading, the applied shotcrete is required to reach a minimum compressive strength and in case of fiber reinforced shotcrete, a minimum flexural toughness (energy absorption) in order to ensure the safety of the workers going into the heading. Combined with bolts, the use of conventional fiber reinforced shotcrete becomes an interesting method for ground support as it is applied very soon after excavation and works to stabilize ground movements (Bernard E. S., 2009). In this case, the toughness development of fiber reinforced shotcrete becomes an important feature of the material when looking to speedup the mining cycle. However, early re-entry criteria in underground openings are difficult to ascertain as the load carrying capacity of fiber reinforced shotcrete is usually assessed after 7 or 28 days. For this reason, re-entry criteria varies from one mining area to another and are usually based on compressive strength requirements. For example, in northern Ontario, Canada, one of the current practices in the mining industry consists of allowing safe re-entry once fiber reinforced shotcrete has developed a compressive strength of higher than 4 MPa (Dufour, O’Donnell, & Ballou, 2003). Flexural toughness requirements on fiber reinforced shotcrete are also typically based on evaluation after 28 days."

Jan 1, 2015

By A. Ignatieff

This is the first in a series of Coal Technology Reviews being prepared in accordance with a recommendation voted by the Coal Division in session at the Jubilee Meeting, Vancouver, April, 1948, that the Department of Mines and Resources be requested to arrange for publication by the proper Government authority of a Quarterly Review' of Coal Technology, for distribution among those concerned in the production and use of coal in Canada. This recommendation was subsequently endorsed both by the Council of the Institute and by the Dominion Coal Board. Further reviews (or digests) will appear at intervals in the Bulletin, or will be published and distributed by the Board which, meanwhile, has undertaken to distribute reprints of Mr. Ignatieff's review.-En. * * * The fields in coal mining technology which are considered to demand most attention and study at the present time are reviewed under the headings appearing below. Mechanization In the light of the growing shortage of skilled miners and the necessity of mitigating constantly increasing mining costs, interest continues to centre in mining methods and applications of mechanization chat will produce the maximum reduction of man power. The growth of strip or open-cut mining, also, is a consequence of this trend. Mechanization at the face attracts most attention and the trend is toward developing and adopting machines capable of cutting and loading the coal in one operation instead of having the separate operations of cutting, drilling, blasting, and loading. In Great Britain, where longwall mining is? the general practice, the A.B. Meco-Moore machine still receives much attention, and accounts describing its performance over reasonably long periods have appeared in the technical press.

Jan 1, 1948

By W. A. Bain

"AbstractProduction from the Excelsior Reservoir has amounted to approximately one million barrels. This production has caused a 'Pressure •drop of 10 p.s.i. from the original pressure of 1,245 p.s.i.g. Volumetric balance calculations indicate that the pool as being produced by a water drive whose strength is •probably unsurpassed in Western Canada. It has also been shown by 'unsteady state' calculations that the reservoir will still be above the saturation pressure of 915 p.s.i.g. at the time of depletion. The average permeability of the producing formation is approximately 1,000 millidarcys and, consequently, well draw-downs are very low. The field is essentially a bottom-water drive and calculations have shown that gravity drainage will greatly assist the recovery of oil. Water flooding data on several cores •have placed the flushing efficiency at •approximately 50 per cent, which indicates a recoverable oil-in-place of 17.7 million stock tank barrels. Calculations and field data indicate that the MER for the early life of this field is probably as high as 8,000 to 10,000 stock tank barrels per day.IntroductionTHE EXCELSIOR NISKU oil reservoir is located about twenty miles northeast of Edmonton. The field was discovered in November, 1949, by Imperial Excelsior N.o.1 well, in Lsd. 13, Sec. 3, Twp. 56, R. 22, W. 4, at a depth of 3,850 feet.Since discovery, development has continued on a 40~acre spacing pattern. At the end of 1951, drilling over approximately 80 per cent of the estimated productive area of 1,680 acres had established 32 we1ls capable •of production. The field •has been fairly well delineated by dry holes on all but the eastern flank ."

Jan 1, 1952

By J. P. Harrison, N. Bozorgzadeh, M. Dolowy-Busch

"It is common in rock engineering practice to characterize the triaxial strength of intact rock by using only data samples of small size. Practical guidelines such as ASTM support such sample sizes. In this paper, we investigate the reliability of the Hoek-Brown strength criterion estimated from such samples. For this purpose, we use an unusually large published set of triaxial strength data to randomly select a large number of data samples of small size to simulate the situation that frequently encounters in practice. The samples are generated with different arrangements with regards to the confining pressure. We fit the Hoek-Brown criterion to each of these samples, obtain estimates of strength parameters and compare them to those obtained from the complete data set. Our analysis suggests that estimates based on small samples are not reliable and can lead to both over- and under-estimation of strength.Additionally, we use these small samples to investigate the statistical methods for obtaining design values of strength as suggested by limit state design standards such as Eurocode 7. We show that, if used in conjunction with small samples, these methods do not guarantee a safe estimate of strength and in many cases lead to highly over-conservative estimates.We present a potential solution to this problem by augmenting the small data sets with Bayesian informative priors to give much more reliable estimates of strength. We conclude with suggestions for the development of informative prior distributions."

Jan 1, 2015

By C. Hudson, D. Tremblay, A. Frey

"A discussion of the design, challenges and successes associated with the commissioning of the gravity recovery circuit at Canada’s newest open pit gold mine - Atlantic Gold’s Moose River Consolidated Project in Nova Scotia, Canada is presented. An overview of the project, its historical significance and overall flowsheet is provided with special focus given to the design and selection of the gravity circuit equipment including the scalping screen, gravity concentrators and the novel intensive leaching technology selected for the project. The performance of the gravity circuit is benchmarked against the feasibility study process design specifications and the outcomes are discussed. Challenges encountered during commissioning are also presented, including the use of third-party automation and the effects of screen sizing on overall gravity circuit performance. Mechanical modifications made to the Sepro Leach Reactor for the Moose River project are also discussed. A detailed technical review of the mechanical and operational aspects of the Sepro Leach Reactor is provided with key operational data on leach times, recoveries, reagent usage, solid-liquid separation, pregnant solution quality and its influence on bullion purity.INTRODUCTION Atlantic Gold Corporation’s Moose River Touquoy Mill in Nova Scotia, Canada was commissioned in the fourth quarter of 2017 with commercial production declared in March of 2018. The 2 Mtpa process plant uses a conventional, gravity-CIL process. This site was previously mined in the 1870s. Interest waned in the early 1900s but resumed in the 1930s and the mine was brought back into production in 1935 until an underground mine collapse in 1936. This mining district became famous after CRBC radio commenced a ground breaking, around the clock, broadcast of the rescue operations. Over 100 million people listened to the broadcast from Canada, the United States and the United Kingdom. These broadcasts changed radio, transforming it from a medium for music to on the spot, breaking news reporting. The mill was constructed by Ausenco on a fixed price EPC contract in the historic Moose River gold mining district, 95 km north-east of Halifax by road. The mill will process ore from the adjacent Touquoy pit for the first 5+ years of operation; after the Touquoy reserves are exhausted, the mill will process ore trucked 37 km from the Beaver Dam deposit for an additional 5 years."

Jan 1, 2019

By W. A. D. Edwards

"The Edmonton region accounted for 40% of Alberta's sand and gravel production in 1981 (about 12 million m3). Most of this production was by commercial operations (75%) for use in essential public works projects (64% in road and asphalt production).Although the Alberta Geological Survey delineated 1157 million m3 of gravel, a number of areas are considered to be in short supply. An econometric model was used for forecast demand in the region. Predictions, based on this forecast and estimated supply, are that 15% of the region's gravel and 3% of the sand will be consumed by the year 2010.The City of Edmonton is the largest consumer of aggregate in the region. Approximately 40% of the gravel in Edmonton's current supply area (about 55 km radius) will be used by 2010. These estimates are considered optimistic because the supply figures do not account for sterilization of deposits - some has already taken place in the region. If 25% to 50% of Edmonton's current supplies (one major deposit) were sterilized it would result in $1,000 million of additional cost due to increased haulage alone.Information on the value of aggregate resources, the location of sand and gravel deposit s and forecast demand has been made available to all municipalities in the region to aid planners and regulators in effective future use of this important resource.INTRODUCTIONAlberta is the second largest producer of sand and gravel in Canada at ab out 50 million tonnes annually. Value of provincial production exceeded $120 million in 1985. In Albert a, aggregate is used primarily in road and building construction (about 50% and 15%, respectively) and is important in such activities as petroleum exploration, oil sands development and the forestry industry.The Edmonton region (Fig. I) accounts for about 40% of provincial production and has a per capita consumption rate of about 13.4 m3 of sand and gravel per annum. Although Edmonton dominates, with approximately 50% of regional production going into the city, aggregate is produced in every county and municipal district in the region.Sand and gravel is essential to the current way of life in the Edmonton region. The resource is valuable and dwindling. The Alberta Geological Survey (a department of the Alberta Research Council) has collected information on aggregate in this region for the last decade which ca n aid government planners and regulators in pre venting sterilization and misallocation of this critical resource. This paper is a summary of that information."

Jan 1, 1989

By K. C. Marsden, B. Pesic

"Interest in the efficient production and recycling of rare earth elements has increased in recent years along with the prices of these elements. The molten LiCl-KCl eutectic is one ionic solvent which can be utilized for these purposes. The LiCl-KCl eutectic has also been selected as the electrolyte for focused research for advanced pyrochemical recycling processes for used nuclear fuel in several nations. Rare earth elements are fission products with notable neutron absorption characteristics, and thorough understanding of the properties and behavior of these elements is critical to their successful partition from the electrochemically-similar actinide elements. The number of research papers investigating individual rare earth elements has greatly expanded in the approximately 35 years since the last review. These research papers are presented in a variety of languages and technical formats, making data difficult to compare, and are sometimes contradictory. A review and summary of diffusion properties of rare earths in LiCl-KCl eutectic was performed, and the data translated to a common format for evaluation. INTRODUCTIONThe rare earth elements have experienced growing importance in recent decades due to their application in high technology, including optical lenses, lasers, high-temperature superconductors, improved alloys, high energy-density batteries, and powerful magnets for compact electronic devices. Their historic production methods and uses are detailed in several texts (Hampel 1971; Bautista &Jackson 1992; Gupta & Krishnamurthy 2005). A s the p rice o f these e lements has r isen in r ecent years, so has interest in their efficient production and possible recycling options. Rare earth oxides are concentrated through hydrometallurgical techniques, but the high thermochemical stability of their oxides precludes production of rare earth metals in aqueous systems. However, the wide electrochemical window and better control of pO2- in fused salt systems allows the production of these reactive metals from their halides or oxides. The high ionic conductivity and diffusivity of the molten ionic electrolyte allow high currents with limited resistive losses (Fray 1980). Electrolytic methods in fused salts are commonly adopted for the production of bulk rare earths in a variety of molten salt systems. Fluorides are sometimes proposed for oxide electrowinning processes due to ability to dissolve the rare earth oxide, reduced hygroscopic behavior, and the wider electrochemical separation between O2 and halide gas evolution (Mohan Das, Damodaran et al. 1988; Gibilaro, Pivato et al. 2011). However, in most electrolytic production processes, such as that for mischmetal, the rare earth oxides are converted to chloride prior to electrolysis in a chloride bath (Gschneidner Jr. & Eyring 1978; Sharma 1987). Of the chlorides, the LiCl-KCl eutectic is one specific medium in which metal production and production-related investigations have been conducted (Gschneidner J r. & Eyring 1978; Driscoll & Fray 1993). L iCl-KCl eutectic has the advantages o f h igh conductivity, but relatively low viscosity and operating temperature. The low operating temperature allows simpler design, with reduced energy consumption, salt volatility and cell corrosion."

Jan 1, 2012

By W. A. Jankola

Teck Cominco Metals Ltd. operates an integrated zinc-lead smelter at Trail, British Columbia, Canada. The zinc circuit comprises three parallel operations: conventional fluid-bed roasting, direct zinc pressure leaching of concentrates and atmospheric leaching of zinc oxide fume recycled from the lead smelter. The products from these three areas are combined in the main leaching plant where they undergo iron purification. Unlike most leaching circuits, the leach process in Trail begins with an acid leach and is followed by a neutral leach. An evaluation was undertaken to determine if the process at Trail could be improved by converting to the conventional neutral leaching process with a subsequent acid leach of the residues. This paper explores the results of these tests and the implications for Trail Operations.

Jan 1, 2006

By C. Edwards

"The processes for rare earth (RE) extraction include the decomposition of RE ore concentrate minerals, and the concurrent or subsequent leaching of the rare earth elements (REEs) from the decomposed minerals. Ore beneficiation concentrate can be decomposed by, for example, acid roasting, caustic cracking, and chlorination. The REEs can be selectively extracted. The nature of the REE extraction process depends on the concentrate mineralogy and the targeted products. Based on the experience of the Saskatchewan Research Council (SRC) in RE processing, this paper reviews REE extraction from the major RE minerals, including bastnaesite, monazite, xenotime, ion-adsorption clay, allanite, cerite, and eudialyte. An update on the development of RE extraction processes is also provided.INTRODUCTIONRE processing usually involves two operation stages, physical processing and chemical processing. Physical processing, also known as ore beneficiation, separates the RE minerals from gangue minerals to produce an RE mineral concentrate. Chemical processing, which includes extraction and separation processes, converts the RE mineral concentrate to an RE compound which is either an end product or an intermediate product for the subsequent production of individual REEs or other compounds. The RE extraction process uses one or more reagents to decompose the RE minerals and to leach the REEs into solution. The RE separation process uses solvent extraction, ion-exchange, or chemical precipitation to produce either rare earth oxides (REOs) or individual REEs. The authors have previously reviewed RE ore beneficiation processes (Zhang & Edwards, 2012). This paper focuses on extraction processes for a variety of RE minerals. Table 1 gives the chemical compositions of the RE minerals mentioned in this paper. The varieties of RE extraction methods use many different reagents. These reagents are mainly inorganic acids, alkalis, salts, and chlorine gas. The commonly used acids include sulfuric acid (H2SO4), hydrochloric acid (HCl), and nitric acid (HNO3). Sodium hydroxide (NaOH) and sodium carbonate (Na2CO3) are the most common alkalis. Salts include ammonium sulphate ((NH4)2SO4), ammonium chloride (NH4Cl), and sodium chloride (NaCl). HCl is normally used to extract RE from silicate ore minerals such as allanite and gadolinite. The alkalis and H2SO4 are mainly used to leach REs from phosphate ores minerals like monazite and xenotime. The carbonate ore RE minerals such as bastnaesite can be treated using either acids or alkalis. HNO3 is mainly used to leach eudialyte and apatite. The extraction of REs from ionadsorption clay deposits uses salt solutions. Chlorine gas (Cl2) is exclusively used in the RE chlorination process which can be used to treat any RE minerals."

Jan 1, 2012

By Charles B. Newmarch

Abstract In the course of coal studies undertaken by the B.C. Department of Mines in southeastern British Columbia, special attention was directed to problems of coal seam correlation. Methods that had been used successfully in other coalfields were found, in the Crowsnest area, to have a restricted use or furnished only additional evidence that might prove helpful when used in conjunction with other criteria. A correlation technique involving semi-quantitative spectrographic analyses of coal ashes was developed. Elements detected in the ash include Si, B, P, Fe, Mg, Mn, Pb, Ti, Cr, Ga, Ca, Al, Ge, Ba, Mo, V, Ag, ?y;b, Na, Zn, Zr, Ni, Sr, Cu, K. Of these, the elements found to be most useful in correlation were Na, Ba, Si, V, and Mg. The element Na was invariably detected in the ash from one of the seams but was not found in samples taken from any of the others. In all of the four seams sampled statistically, significant differences in the amount of certain trace elements were noted. When the values obtained for these trace elements were portrayed in the form of histograms, the resulting diagrams had a characteristic shape for each seam. The diagrams provided a basis for seam identification within the limited area (8,000 feet by 4,000 feet) that was investigated. Introduction During the field seasons of 1946, 1947, and 1948 the British Columbia Department of Mines undertook a geological investigation of the coal measures of southeastern B.C. As field work progressed in the Crowsnest area it was found that, within the Kootenay formation, which contains all the commercial seams of the region, the coal beds are the most persistent stratigraphic units. Because of relatively rapid changes in ?both the thickness of the seams and the interval between seams, difficulty has invariably been experienced in attempts at correlation. Even short-range correlati0ns by able geologists who have worked in the Crowsnest coal basin have been questioned by the operating companies. It was apparent, therefore, that a more dependable correlation technique was needed so that stratigraphic and structural studies could be of greatest value. This paper presents, firstly, a summary of the results obtained in attempted correlations using methods that have been found effective in other coalfields. Secondly, a method based on semi-quantitative spectrographic analysis of coal ash is described and the apparently promising results are discussed.

Jan 1, 1950

By Leslie Gertsch

Outline First progress report ? ?Introduction ?Non-terrestrial mining ?Near-term targets ?Stages of mining ?Study procedure Capabilities needed for non-terrestrial mining ?Mining methods ?Mining unit operations ?Typical surface mine operations sequence ?Results to date General effects of gravity ?On fragmentation ?On excavation ?On transport ?Conclusions / Recommendations

May 1, 2013

By Stephen D. Butt

Presentation Outline Overview of abandoned mine workings problem. Outline project phases and major outcomes. ? Phase 1 ? Assessment of current imaging technology ? Phase 2 ? Prototype technology development. ? Phase 3 ? Proof of concept ? Montague Gold Mines field trials. Research status - summary of ongoing and future work.

Apr 1, 2005

An essential tool for every step ? Early field survey ? Handheld satellite phones ? Portable satellite phones ? Exploration and Drilling ? Handheld satellite phones ? Portable satellite phones ? Production ? Handheld and portable ? Fixed Satellites systems ? Asset tracking systems Main applications via satellite ? Voice and Fax communication ? Internet access and E-mail ? Video conferencing ? Interconnection to mobile phones, 2 way radios, long range WIFI ? Equipment Tele-maintenance ? Telemedicine ? Crew and morale calling ? Vehicle and asset tracking

May 1, 2006

By Donald Brisebois

The mining of high-grade, narrow vein deposits is an important field of activity in the precious metal mining sector. The principle factor that has undermined the profitability and effectiveness of mining such ore zones is the substantial dilution that occurs when blasting with explosives during extraction. In order to minimise dilution, the Thermal Fragmentation Mining Method enables the operator to extract a narrow mineralised corridor, 50 cm to 1 metre wide (according to the width of the vein), between two sub-level drifts. By inserting a strong burner powered by diesel fuel and compressed air into a pilot hole previously drilled directly into the vein, a thermal reaction is created, spalling the rock and enlarging the hole to 80 cm in diameter. The remaining ore between the thermal holes is broken loose using low powered explosives, leaving the waste walls intact. This patented method produces highly concentrated ore, resulting in 400% - 500% less dilution when compared to conventional mining methods. The mining method reduces the environmental affects of mining operations since much smaller quantities of rock are displaced, stockpiled, and treated using chemical agents. The fully mechanised equipment operated by a 2-person team (1 thermal fragmentation operator, 1 drilling operator) maximises the effectiveness of skilled personnel, and increases productivity and safety. The Thermal Fragmentation is currently employed in 3 mining operations in North America.

May 1, 2010

By H. F. Naldrett

"AbstractAt the end of May, 1950, Imperial Oil, Limited, had completed a total of 192 D-3 wells in the Leduc-Woodbend field, 62 of which lost circulation in the D-3 zone for periods ranging from two hours to fifty days. The majority of the remaining wells •lost some mud without actual loss of returns. In addition, independent operators completed 69 D-3 wells, of which 9 lost circulation. Included among the latter is the now well known Atlantic No. 3 well, which blew wild out of control for seven months. The well was finally brought under control through two directionally drilled wells, but not before the derrick fell and the well caught fire. Practically all known filler materials have been used in attempt3 to prevent or regain loss of circulation, but none has been successful, except in minor cases. Ordinary sawdust has come to be the most commonly used filler material and is added to the mud before the D-3 zone is contacted. In cases of serious loss of circulation, the on1y successful method of getting returns has been the use of a series of small cement plugs.IntroductionThe Leduc field is twenty miles southwest of Edmonton, Alberta. Geologically, it is on the east limb of the Alberta syncline, in the homoclinal belt. The main productive zones are in the Upper Devonian formation and are known locally as the D-2 zone and D-3 zone, respectively (see Figure 1).The D-3 zone is a dolomitized reef with fair average porosity and permeability, and shows considerable evidence of vertical fracturing. Porosity is mainly due to moderately uniform development of vugs which are interconnected by small crevices. However, the formation is known to be, locally, extremely vuggy and in places cavernous. These latter conditions create very serious drilling problems due to the hazard of loss of circulation, particularly in the gas cap, which has a maximum thickness of 200 feet. The D-3 zone is contacted at an average depth of 5,300 feet."

Jan 1, 1950

By H. W. Kasaini, E. Bourricaudy, T. Larochelle

Rare Element Resources Inc., a U.S. based company, has developed a three-stage process for producing a +98% mixed REO powder from hard rock feedstock (-48 mesh, 2.9-4.8% REO) consisting of bastnaesite and ancylite minerals. Firstly, the whole ore is digested in chloride media at low temperature in counter-current flow mode. Secondly, the rare earths (REEs) are selectively precipitated as oxalates directly from an impure pregnant leach solution (PLS). Finally, significant amounts of free acid and water are recovered from the REE-depleted filtrate and subsequently recycled within the process. Excess heat from the oxalate calcination process is captured and reused in the plant. Due to the low leach temperature (45 ºC) and moderate acid dosage (240-297 kg/t, HCl), rare earth oxides (REOs) are preferentially leached out of fine solids leaving most of the base metals (Ba, Fe, and Al ) in the residue. Selective recovery of REEs from the PLS is achieved by mixing dilute oxalic acid (33% H2C2O4) and PLS at elevated temperature (85-95 ºC). The REEs plus thorium are precipitated as oxalates (REE2 (C2O4).xH2O) while the base metals are left behind in the barren filtrate. Multiple batch and pilot test results have confirmed that 50-80% of the oxalic acid can be recovered from the REE-depleted PLS through low-temperature crystallization (10-15 ºC). Typical leach efficiencies of critical rare earths at 45 ºC range from 85-99% (average 93%) while oxalate precipitation at high temperature increases the crystal size of RE oxalates (>450 microns, d80) thereby improving filtration. The economic benefits of this process include elimination of flotation and magnetic separation Capex and driving hydrometallurgical Opex down to $6- 7/kg, REO produced. As part of a comprehensive risk mitigation strategy, Rare Element Resources Inc has operated multiple pilot plants at SGS in Lakefield, Ontario, Canada to optimize counter-current leaching (CCL), REE oxalate precipitation (OXP), and thorium removal circuits. This paper presents pilot testing data from CCL and REE OXP circuits.

Jan 1, 2016