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By Francesco Vegliò, Luigi Toro, Francesca Pagnanelli

"Different hydrometallurgical processes have been studied in order to recover manganese(II) from oxidised minerals such as MnO2 (Vegliò and Toro, 1994). An innovative acid reductive leaching carried out in soft experimental conditions was here considered using agro-industrial wastes containing carbohydrates as reducing agents (Vegliò et al., 1998).The leaching process was investigated from a kinetic and equilibrium point of view in order to optimize the experimental conditions and obtain high purity and concentrated MnSO4 solutions.The overall leaching process (not considering the complex network of intermediate oxidation reactions of the carbohydrates in hot sulphuric acid medium (Vegliò and Toro, 1994)) can be described by the following reaction:24 MnO2 + C12H22O11 + 48 H 24 Mn2+ + 12 CO2 + 35 H2O (1)A Shrinking Core Model (SCM) was modified by a variable activation energy term to take into account both the variable reagent concentrations and the reaction rate change with respect to the manganese dioxide conversion. The influence of the particle size in the kinetic model is discussed with the support of SEM analysis and BET surface measurements before and after leaching.Manganese extraction yield was maximised (170-190 g/L) using appropriate carbohydrates and acid excesses, while impurity concentrations were kept low (Fe<10ppm and Ca<300ppm) pre-treating the ores, using hydroalcoholic leaching medium and different combinations of down-stream processes. In particular precipitation, solvent extraction and adsorption onto active carbon were tested to eliminate Fe and Ca from MnSO4 solutions."

Jan 1, 2003

By Francesco Vegliò, Luigi Toro, Francesca Beolchini, Francesca Pagnanelli, Stefano Ubaldini

"Biosorption is an innovative technology used to remove heavy metals from aqueous solutions from mining waters and other industrial wastes. A wider application of this alternative process is strictly dependent on the understanding of the chemico-physical aspects involved, in order to optimize the operating conditions. Mechanistic models are the most useful tools used for understanding purposes, even if the empirical models are still widely applied for their simplicity.In this paper especially propagated biomasses of Sphaerotilus natans, calcium alginate and some waste materials were tested as adsorbents for single and binary solutions containing heavy metals at different pH. The equilibrium experimental results were fitted according to empirical and physical models with growing complexity outlining the inadequacy of the predictive models; in fact, the non-ideal interactions among metals require the insertion of additional correction parameters."

Jan 1, 2003

By Misra V. N, Cheng C. Y

Two types of Mt Tom Price hematite iron ore from Hamersley Iron P/L were tested using a Humboldt Wedag Jones P40 wet high intensity magnetic separator (WHIMS). The parameters tested were magnetic intensity (7000, 9000 and 11 000 Gauss), groove plate type (8R and 12R) and gap width (2.5 and 1.8 mm). It was found that at 9000 gauss magnetic intensity, reasonably high-grade and recovery in the concentrate were obtained. At 2.5 mm plate gap width, the 12R groove plate performed slightly better than the 8R groove plate. Further testwork is recommended to optimise the magnetic intensity, feed flowrate and pulp density, wash water pressure and flowrate with 12R and 8R groove plates at 2.5 mm gap width.

Jan 1, 1999

By Geoffrey Birch

A skilled and efficient workforce is a pre-requisite for the success of modern construction companies. The drive for improved performance, innovation and best value must be matched by the enhanced skills of the construction personnel. Training has been accepted as one of the essential cost effective elements to achieve these goals. The foundation industry demands particular specialist skills and requires focused training for its dedicated operatives. The introduction and development of specific training qualifications for the foundation sector is providing significant benefits.

Jan 1, 2000

By B. P. Faulkner, M. Weinecke

Svedala started a development program in 1997 to develop a process to convert waste tires into valuable commodities. A review of numerous approaches revealed short-comings in the various approaches either process, mechanical, combination of factors, or trying to emphasis the production of low value products. A market study revealed that a process that could produce a good grade of carbon black would be economically feasible. This paper discusses the laboratory and pilot plant development and commercial plant design.

Jan 1, 2001

The 8 ft by 91/2 ft drive which joined No. 7 Shaft with Browne Shaft on the 1,480 ft level was extended from both ends and met at a point approximately 12,000 ft from No. 7 (2,000 ft from Browne).The surveying required for this 2 1/2 mile haulage drive called for greater accuracy than was obtainable from South Mine standard methods. Procedures and devices from published information were tried and modified as required to suit local conditions. Several new methods were applied and improved as the drive advanced. The control of angular, linear and level measurements was perhaps considerably in excess of the requirements, but this was offset by abnormally large discrepancies resulting from shaft plumbing. The accuracy of the final breakthrough, although not to the standard desired, was sufficient to complete the connection without inconvenience and added cost.INTRODUCTIONThe acquisition of the Browne Shaft leases in January 1962 presented the management of Broken Hill South Limited with the problem of transporting ore from these leases to its mill. It was eventually decided that diesel locomotivehaulage through a 2t mile drive on the 1,480 ft level between the two mines was the best solution. The drive was advanced from both ends after Browne Shaft was deepened by 80 ft to reach the 1,480 ft level horizon. Each end advancedabout 15 ft/day with the miners working three 7 hr shifts. Blasting was restricted to the end of the shift.The survey work involved five shaft plumbings and 78 theodolite stations in a traverse, underground and surface,of more than 5 miles. Because of the exceptional length of the drive, an unusually high degree of reliability was required.The aim was for a maximum error at breakthrough of 1 ft 1 in 30,000, and to secure this, precise methods of linear measurement were necessary. Shaft plumbing in particular posed special difficulties.

Jan 1, 1965

By D. Nag, J. Fernando

Hazelwood Power Mine is one of the largest open pit brown coal mines in Australia. The removal of overburden is the first step in coal winning operation. The primary aim of construction of overburden dump is to provide an effective stable working surface for stacker. The paper discusses site investigation techniques used to determine dump soil properties, stability analysis method using GALENA and GWEDGEM, results of stability analysis. The paper concludes with recommendation for a safe dumping strategy for level 2 stacker dumping.

Jan 1, 2003

By Attie J. Goosen, William L. Spiteri

Although the physical characteristics of ANFO made from porous prilled ammonium nitrate (PPAN) have been altered by the addition of crystal modifiers, the optimisation of prilling processes and the admixture of waterproofing agents, the sensitivity of this explosive has not been modified on a commercial scale in the 40 years since its accidental discovery.

Jan 1, 1995

By Enrique Hermana, Raymond F. Dalton, Raymond Price, Barry Hoffman

Introduction Chloride leaching of sulfidic ores has been known about for 100 years. It is recognized as a highly efficient process to produce concentrated leach solutions. Despite this, chloride leaching found little practical application until recently because of the highly corrosive nature of concentrated chloride solutions. This situation changed with the advent of modern construction materials such as GRP, polypropylene, butyl rubber, etc. And in the past 20 years, research has burgeoned in the area of chloride hydrometallurgy. The research impetus stemmed from the belief that chloride leaching can provide an alternative to smelters for treating conventional copper concentrates. In addition, chloride leaching was thought to be suitable for on-site refining of copper at small tonnage operations located in remote areas. And chloride leaching was seen as a logical choice for treating unusual or complex concentrates that smelters could not handle. Underpinning these beliefs is the attraction of chloride-based hydrometallurgical processes for sulfidic ores. Sulfur is liberated in the environmentally acceptable elemental form rather than as sulfur dioxide. Consequently, sulfidic copper ores have received much attention. A review of Edmiston in 1984 describes 12 chloride-based processes. All managed to progress past the "laboratory beaker" stage of evaluation. In nine of these processes, copper is recovered electrolytically. Key features of these processes are summarized in Table 1. Table 1 shows that the processes must include a copper solvent-extraction step. Only these processes produce a clean copper electrolyte capable, with no further refining, of directly producing high quality cathode copper. The ICI/Elkem process is the exception here. The rest of these processes use o-hydroxyaryloxime reagents for the solvent extraction of copper and are constrained by the performance of these reagents. This is governed by hydrogen ion concentration (Equation 1). The practical result is that only relatively dilute copper solutions can be treated (Canmet, Phelps Dodge), or careful pH control or adjustment is necessary (Minimet Recherche, B.H.A.S.). This negates one of the attractive features of chloride leaching - its ability to produce very concentrated copper solutions, up to 40-45 gl-1. [ ] In all four processes using o¬hydroxyaryloxime extractants, solvent extraction transfers the copper from the chloride to the sulfate medium. To minimize cross-contamination of the two anions, the loaded organic solvent has to be scrubbed to remove the chloride ion. This represents an additional complication in the solvent extraction circuit. And it

Jan 1, 1988

By Evelio N. Horta

The influence of soil improvement replacement area in foundation settlements is discussed for soil improvement methods used in Southeast Florida. A 3D Finite element analysis is used for two typical conditions in the area: foundations bearing on loose sands and foundations bearing on a crust of limestone underlaid by very loose sands. Particular attention is given to Jet Grouting as a soil improvement method. The potential impact of the stiffer jet grout columns on the structural foundation design and quality control issues are also discussed. It is shown that in loose sand conditions 15 to 20% area replacement produces substantial reduction in total settlements. Reduction in total settlements for mixed profile is less significant but the use of the method in those cases is directed to reduce punch through potential.

Jan 1, 2007

By George K. Schenck

This Bureau of Mines publication describes and evaluates a Standard Industrial Classification (SIC) based end-use data system for minerals that is designed to link the demand for minerals to economic activity in commercial uses. The new data system is two-dimensional. The first dimension of technical product classes (TPC&apos;s) measures the consumption of minerals in major primary intermediate products. The second dimension measures the consumption of these TPC&apos;s in SIC end-use sectors in sufficient detail to identify the major determinants of demand for each TPC. Intercomodity comparisons are achieved at the level of SIC two-digit major groups. The methodology was developed so that all available sources of information from Government and industry can be utilized at minimum cost. This information will be supplemented with additional data to be obtained by modifying existing Bureau of Mines canvasses so as to elicit additional quantitative responses from mineral producers. The new data system is expected to improve significantly the ability to forecast demand for minerals, and provide an information base that would, for the first time ever, permit resolution of such questions as trends in substitution among materials and the intensity-of-use of materials in end-use sectors. For the 42 TPC?s identified in the report, data are available for the new system from current sources or, except for three TPC?s that require new canvasses, can be obtained by modification of existing Bureau canvasses.

Jan 1, 1982

By S. Dixon

The Peñasquito deposit in Mexico is one of the largest grassroots precious metal discoveries developed in recent years. Goldcorp Inc. acquired the gold-silver-lead-zinc property with the acquisition of Glamis in 2006. The Peñasquito property is located in the northeast corner of Zacatecas state, Mexico. The elevation of the property averages 1,900 m (6,200 ft) above sea level. It is situated in a wide east-west valley. Minera Peñasquito, S.A. de C.V., wholly owned subsidiary of Goldcorp Inc. has operated twin SABC-flotation lines since June 2010. Each line is capable of processing 50,000 tonne per day using a SABC grinding circuit followed by flotation to produce lead and zinc concentrates. The addition of a Polysius Polycom HPGR 2417 with dual 3,000 kW drives to reduce the crushed pebbles produced by the SAG mills was planned to increase production to 65,000 tonne per day per line. The production has been limited to 100,000 tpd due to operating issues in the grinding circuit. The operating issue has been the amount of pebbles generated by the SAG mills is significantly less than originally planned. This paper describes the planned installation of a crushed augmented feed to maximize utilization of the HPGR capacity. This coupled with full utilization of the SAG and Ball Mill available energies there is the potential to achieve a 50% total capacity increase from the grinding circuit.

Jan 1, 2012

By G. F. Friel, J. C. Edwards

A series of seven underground-coal-mine fire experiments was conducted in the Safety Re-search Coal Mine at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory. Coal and styrene-butadiene-rubber conveyor belting were burned upwind of two sensor stations, 18 m and 148 m from the fire source. Exhaust from a diesel locomotive flowed over the fire sources in six of the tests. Metal-oxide-semiconductor (MOS), CO, and optical-path-smoke sensors were positioned at both stations and found to be an optimum set of sensors for the fire discriminations. A representative set of 7,679 samples of CO data and data from the smoke and diesel-exhaust MOS sensors were used as inputs to train a neural network (NN). By testing 42,538 data samples from the seven experiments, all fires were detected by the NN within 9.67 min from the onset of significant changes in the MOS voltages without any false alarms.

By Stefano Trevisani

Abstract The FIEC Sustainability Vision states that “risks should be identified and allocated in a fair manner across the project team from the early stages of the design phase. A partnering approach, where objectives and timescales are agreed in advance together with all relevant partners in the value chain, offers a useful solution to improve on site efficiency and reduce disputes”. An alliance or collaborative form of contract involving all parties is the best way to ensure fair contract conditions and proper risk allocation in construction projects. Collaborative contracts are particularly useful where there is uncertainty or undefined information or in the event of technical difficulties and other risks difficult to allocate among the parties involved in the project. Owners sometimes require even special output in terms of innovative technical solutions or special performance. In addition, this particular form of cooperation has been construed and developed with the intention of avoiding and mitigating another great risk associated with the construction industry (especially in complex projects): disputes and conflicts, which are often a major cause of delays, increased costs, loss of reputation and opportunities. In contrast, Alliances are a way to increase and strengthen business relationships, technical and economic innovation and effectiveness, in a worldwide global context where the waste of resources must be avoided in order to guarantee future recovery and growth. Of course, the total cost of a project is usually a key factor and the main driver for the Owner and the Contractors in deciding the type of relationship between them as well as the subsequent relationship with subcontractors and lower-tiers. This paper and presentation, will explain the main features and the principle benefits that the use of collaborative contracts can bring to all parties involved in the construction project, including the sustainable financial return that might be achieved if costly and time consuming disputes can be avoided.

Jan 1, 2014

By R. Bruce Patterson

The New Tacoma Narrows Bridge is a classic suspension bridge founded on concrete caissons. Caisson construction was complicated by the proximity of the existing bridge piers, only sixty feet away. High capacity plate anchors were used successfully to moor the new caissons in currents as strong as seven knots during construction.

Jan 1, 2004

By W Farnworth

The Huntly West Mine has undergone significant changes in the last two years, which will affect the remainder of the mine&apos;s life. The paper describes the evolvement of plans and an overview of the technical considerations made in planning for and implementing the first New Zealand longwall operation. The technical investigations involve the longwall equipment, exploration, ventilation and strata control. The focus on these areas was to ensure that unacceptable project risks were addressed. Implementation of longwall mining at West Mine is planned in three phases, Development, Panel One extraction trial, and Full Longwall operation. &nbsp; At present the development phase is complete, longwall installation is in progress and production start-up is planned for the end of August, 1991.

Jan 1, 1991

By C. Ozgen Karacan, William P. Diamond

In This Chapter [Measuring the gas content of coal Predicting gas emissions based on geologic and coal reservoir property data Determining the gas storage capacity of coalbeds and other gas-bearing strata Methane drainage borehole monitoring to forecast the remaining gas-in-place and the influence on mine emissions Forecasting gas emissions during mining as a function of mining parameters and Gas emission prediction based on numerical simulation] This chapter provides guidelines for determining the gas content of coalbeds, estimating the gas-in-place, and predicting gas flow and emissions before and during coal mining operations. The techniques are discussed briefly in the following sections. However, detailed information on the techniques is provided in the cited references. INTRODUCTION Coalbed methane, if not properly controlled in the underground mine environment, is a safety concern due to the potential risk for an explosion. This is a particular problem during longwall mining, where the high rate and volume of coal extraction can result in the release of large amounts of methane from the mined coalbed and other adjacent gas-bearing strata. The variability and potential hazards of these sometimes unexpectedly high gas flows provide the impetus to develop methods to predict methane emissions into the underground workplace. A forecast of the volume of gas that might be released during coal mining is helpful for designing ventilation systems and for implementing optimum methane drainage strategies to help mitigate expected gas emission problems. A complete assessment of the need for methane drainage prior to mine development generally requires both an empirical and a theoretical approach. If there are active mines in the general area with similar geologic conditions and coal characteristics, a review of gas problems in those mines provides an initial insight into the level of gas emissions to be expected at a new location. In addition, relatively simple methods exist to determine the in situ gas content (volume of gas per unit weight of coal) of the coalbeds in a particular mining area, as well as the gas-in-place (volume of gas in the coalbed(s) within a defined geographic area).

Jan 6, 2006

By S Christensen

In August 2001 the Minister for Conservation declined an application by GRD Macraes for an access arrangement to enable work at the Globe Progress Mine near Reefton. In her decision, Ms Lee said:æI have considered whether potential compensation and the proposed safeguards against some of the adverse effects are sufficient to outweigh my concerns as to the loss of conservation values, consistency with the objectives of the Conservation Act, the purposes for which the land is held by the Crown and, to a lesser extent, the North Westland Regional Management Plan. I do not think they are sufficient. To my mind, my concerns as to the consistency with the objectives of the Conservation Act, the purposes for which the land is held and the loss of some conservation values in particular, outweigh any potential compensation and possible mitigation of adverse effects.Æ Commenting on the MinisterÆs decision Guy Salmon of the Ecological Foundation stated that the Minister should have invited the applicant to provide a 10 000 hectare pest-free wildlife sanctuary as part of the æpriceÆ for obtaining that access. However,æfor many people of green persuasion, it has become fashionable to say no every timeàthose who really have the well-being of the environment at heart, will want to look carefully at the bigger picture of environmental restoration needsàThe deciding criterion: the mining company should show that its involvement on conservation land would produce a net conservation gain. That is a criterion that creates the right incentives for win-win-win solutions on conservation land.ÆThis paper considers whether the concept of off site mitigation is one which fits within the current legal regime. Two questions arise:Can such mitigation/compensation be legally considered in access arrangements or required as a condition of resource consents? Is this a realistic option for industry to be pursuing?

Jan 1, 2002

By R. Romano

Some topics, which difficult the effective use of RMR for dam foundations, are reviewed and a new geomechanics classification system, DMR (Dam Mass Rating), is proposed -as an adaptation of RMR- giving guidelines for several practical aspects in dam engineering and appraisal of dam foundation. On revise quelques problems qui ont fait difficile l’application du RMR pour les fondations des barrages. On propose un nouveau classification système, DMR (Dam Mass Rating)-comme un désarroi du RMR-qui donne recommendations pour quelques problèmes pratiques dans le projet et construction des barrages, et de ses fondations. Es werden einige die praxisgerechte Nutzung des RMR (Rock mass Rating) erschwerende Themen betrachtet und ein neues Geomechanisches Einteilungssystem, das DMR (Dam Mass Rating), eine Anpassung des RMR, vorgeschlagen. Daraus resultieren neue Richtlinien für verschiedene praktische Aspekte beim Dammbau und bei der Beurteilung von Dammunterbauten

Jan 1, 2003

By Colin P. Pigott

The paper describes a variety of existing techniques and equipment which when combined together permit faster and cheaper drilling of shafts in soft to medium strength formations. Drilling fluid circulation, methods of hole stabilisation and bit design, including the advantages of flat bottomed and conical bits, shrouds and skirts, tungsten carbide, long tooth and disc cutters are considered. The principles of rock chip transportation and bottom hole cleaning are described together with a new and very efficient fluid circulation system which was invented by the author.

Jan 1, 1985