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By H. G. Wolfhard

The propagation of explosions through short cylindrical channels has been investigated by the Bureau of Mines. In the experimental apparatus set up by the Bureau, a single such channel formed a connection between a small explosion vessel in which a gaseous explosion was initiated and a larger, partly enclosing, explosion vessel filled with suitable gaseous mixtures; the larger vessel permitted observation to determine if an explosion was induced therein by mass, energy, and species transfer through the channel, as a result of tie initial explosion, It has been found that transmission of flame through to channel is not an essential to induce the second explosion, for hot gases from an extinguished explosion are able to ignite cold combustible mixtures in the larger vessel. The schlieren patterns of flames or hot burned gases emerging from a channel into the explosion chamber were photographed. These show, in most instances, that vortexes of hot gas ejected from the jet into the cold explosive mixture are responsible for ignition. The study has practical significance in problems of rendering electrical equipment safe for use in potentially flammable atmospheres, INTRODUCTION The propagation of flames through cylindrical or annular channels has practical importance in flameproofing electrical equipment and for flame traps. Much practical work has been done to determine the minimum safe breadth of flanges and the maximum safe gap between the flanges that will permit venting an electric motor without allowing flames to pass.

Jan 1, 1959

By F. W. DeVries, O. B. Mathre

Addition of Kastone® peroxygen compound and formaldehyde to cyanide gold extraction process effluents, containing at least 5 mg soluble copper per liter, will oxidize acid-dissociable cyanide to levels less than 0.2 mg per liter, without appreciable oxidation of thiocyanate. Most of the copper precipitates and is removed by filtration of the treated solutions. The treatment can be completed in less than 2 hours when the excess of hydrogen peroxide over the cyanide is about 75-100 mg per liter. The excess hydrogen peroxide destroys residual formaldehyde and then is catalytically decomposed by the copper-containing solids that separate, so it will not interfere with subsequent operation. A pilot plant using this technology has been operated for more than four months at rates from 1-2 gpm. Clear, filtered effluent containing less than 0.2 mg acid-dissociable cyanide per liter has been produced.

Jan 1, 1981

By A. C. Fieldner

"INTRODUCTION In a previous report3 prepared for the American Gas Association, the influence of washing coal on coke properties and on gas and by-product yields was discussed on the basis of answers to questionnaires sent to coke-oven superintendents and a review of the literature on the subject. This review indicated that the elimination of free impurities by cleaning coal improved coke quality by (a) reducing ash and sulphur, (b) decreasing clinker trouble in burning the coke, (c) diminishing cross fractures in the coke, resulting in greater resistance to breakage on handling, and less small coke and breeze, and (d) greater uniformity in chemical composition and physical properties of coke. Washing also reduced the sulphur in coke and gas and increased the yield of gas and by-products per ton of dry coal charged.This paper is supplementary to the previous report and presents some experimental data obtained with Pittsburgh bed coal from Pennsylvania and Mary Lee bed coal from Alabama.ACKNOWLEDGMENTSGrateful acknowledgment is made to F. J. Pfluke, of the Rochester Gas and Electric Cc., of Rochester, N. Y., for the plant test data on screened lump and washed coal; and to Ray W. Arms, Manager of the Coal Cleaning Department, of Roberts & Schaefer Co., of Chicago, for the data on effect of air cleaning."

May 1, 1931

By W. H. Bassett

In considering the effects of reducing gases on hot solid copper the following conclusions have been reached. (1) Depth of deoxidation of copper heated in reducing gas is greater the smaller the amount of cuprous oxide originally present in the copper, the range studied being from 0.015 to 0.136 per cent. oxygen. It is suggested that the reason for this difference in depth of deoxidation is that, when the copper is low in cuprous oxide, the reducing gas is diluted less by the gas that is formed in the reaction than when the copper is high in cuprous oxide; and the greater the concentration of the reducing gas the deeper the deoxidation. (2) The rate of deoxidation is much mire rapid at the beginning of exposure than at the end, a condition especially noticeable at temperatures around 900° C.; that is, deoxidation is retarded as the depth penetrated by the reducing gas increases. (3) Within the accuracy of the experiments arsenic in copper up to 0.5 per cent. has no tendency to increase or decrease the action of a reducing gas on the cuprous oxide present in the copper. IN 1912 pieces of 0.365-in. hard copper rod 1/2 in. long were heated in a porcelain tube in an electric furnace, while illuminating gas was passed through. An approximate analysis of this gas is: FIG. 1.-EFFECT OF TIME AND TEMPERATURE ON DEOXIDATION RATE OF 0.365-IN. COPPER BY ILLUMINATING GAS; COPPER PLUS SILVER, 99.983 PER CENT. Hydrogen 38 per cent., carbon monoxide 30 per cent., illuminants 13 per cent., methane 10 per cent., ethane 3 per cent., carbon dioxide 3 per cent., nitrogen 2 per cent., oxygen 0.4 per cent. After heating for various lengths of time at various temperatures, samples were quenched

Jan 1, 1926

By Walter Frank

The purpose of the work covered by this contract is to develop a ground and pilot conductor connector which will significantly improve mine trailing cable splice performance. This work compliments the work completed under Contract 00357100 on the development of crimp connectors for the phase conductors of trailing cables. A brief discussion on splice problems is presented as an introductory means and substantiates the need for the development and test programs outlined in this report. As with the phase development work, the ground and pilot connector work is essentially of an empirical nature. As a result time is devoted to explaining the derivations of the test procedures used. In order to familiarize the reader with connector terminology a section is devoted to a glossary of pertinent terms. The connector design effort includes connectors for splicing ground and pilot conductors. A distinction is made between connectors suitable for splicing round and flat ground configurations. The same also applies to the pilot conductors. During the course of this work, much time has been devoted to the question of suitability of round cable configurations for trailing cable applications. This is discussed in detail along with resulting conclusions and recommendations. A field test program was conducted in order to confirm ground and pilot connector laboratory data. This testing also determined the viability of the connector designs and recommended installation techniques in a mine environment.

Jan 1, 1979

By Forrest T. Moyer

The safety record of the coal-mining industry in 1968 worsened appreciably .in fatality experience but was slightly better in nonfatal-injury experience. Work fatalities in 1968 totaled 311 and occurred at a frequency rate of 1.33 per million man-hours or worktime. The fatality total was 89 higher, and the rate of occurrence was 45 percent higher than the corresponding figures of 222 fatal injuries with a frequency rate of 0.92 in 1967. The worsened fatality record in 1968 resulted primarily from two major disasters (a single accident which results in the death of five men or more) which killed 87 men, nine in one and 78 in the second. The total of 9,639 nonfatal injuries was the lowest annual figure in complete records back to 1930. The frequency rate of 41.12 nonfatal injuries per million man-hours of worktime for 1968 was the second lowest annual rate of occurrence. The severity rate of all injuries, 10,513 days lost or charged per million man-hours, and the average severity, 248 days lost per injury, in 1968 were the worst annual data in the series started in 1944. Total worktime of 234.4 million man-hours and coal output of 553.3 million tons in 1968 were, respectively, 3 and 1 per- cent lower than in 1967.

Jan 1, 1972

The mineral industry of Benin contributed less than 1% of the 1977 gross domestic product (GDP), which was estimated at $500 million.' Other than limestone and salt, no exploitable mineral deposits have yet been discovered in Benin, which has been rated by the United Nations as one of the world's least developed nations. In 1977, the economy was further weakened by petroleum price increases and severe drought. The country continued to depend on foreign assistance, which averaged $20 million per year, to finance development projects. The country's first 3-year plan, which was put into operation in October 1977 after many delays, allocated more than $1 billion to projects in infrastructure, agriculture, and light industry. The most important infrastructure project was the expansion and modernization of the port of Cotonou, valued as an entrepôt port for the transit of goods to the neighboring countries of Niger and Nigeria. Plans called for an increase in handling capacity to 1 million tons of cargo annually, the improvement of port and cargo handling operations, and the upgrading of the efficiency of the Port Autonome de Cotonou (PAC) management system. The $46 million project was to be financed by a consortium led by the International Bank for Reconstruction and Development (IBRD) and including Canada, France, Nigeria, and Abu Dhabi. Construction was scheduled to begin in 1978 and be completed in 1980.

Jan 1, 1981

By G. Thodos, D. E. Matschke

Cansiderable time and effort frequently are expended to establish, with a degree of confidence, the PVT behavior of pure substances. In particular, a great deal of experimental information contributed by a number of investigators is available in the literature. The data of each investigator, although significant in themselves, cannot be used with a high degree of confidence until they are compared with the continuum of information presented by others. Current interest in thermodynamic and transport properties, for not only the gaseous state but the con-densed state as well, requires that PVT infarmation be presented for both regions. The density dependence on temperature and pressure, when presented as a continuum, is of considerable value in itself, especially since the available equations of state fail to properly account for the PVT behavior in the condensed state. For this reason and to incorporate PVT data recently presented in the literature, this investigation was carried out. In their studies concerned with the thermodynamic properties of methane, Matthews and Hurd in 1946 utilized the data of Kvalnes and Gaddy and Olds, Reamer, Sage and Lacey to establish the PVT behavim of methane in the superheated region and the saturated liquid densities of Keyes, Taylor and Smithl in conjunction with the Clapeyron equation to develop the densities for the saturated envelope. Current activity sponsored by API Project No. 44 under the direction of F. D. Rossini has led to a tabular presentation of compressibility factors for gaseous methane in the superheated region.la These values were obtained by using smoothed residuals, developed from experimental data and the Ben edict-Webb-Rubin equation,' to establish internally consistent compressibility factors for the real gas. This approach offers probably the most precise presentation of PVT information for gaseous methane to date. The PVT behavior of methane also can be represented accurately by equations of state such as the Benedict-Webb-Rubin equation or the Martin-Hoa equation.' These equations, although valuable for analytically representing the PVT behavior, lack precision in the compressed-liquid region. The PVT data available in the literature for methane were utilized to obtain reduced densities that are presented in Figs. 1 and 2 as functions of reduced temperature with parameters of reduced pressure. The critical constants utilized for methane are those reported by Kobe and Lynn." These critical values, T, = 191.1°K, PC = 45.8 atm and p, = 0.162 gm/cc, produce a critical compressibility factor, z, = 0.289. The PVT information, as obtained from the literature, in many instances was not presented in an immediately

By Rudolf E. Greuer

Two computer programs for the real-time calculation of concentration distributions in the ventilation system of underground mines were designed. They allow one to simulate the movement of fumes or other contaminants with the ventilating air, the calculation of concentrations at any given point and time, and the determination of the total contaminant exposure at different places in the mine. Multiple and time variable contaminant sources can be handled and recirculation is no obstacle. The, first program is based on an airflow distribution which has, in the input data, to be stated. The second program has been linked to in existing program for the calculation of airflow distributions. Two versions of this second program are provided to accommodate the two existing programs. Several executed examples demonstrate the program performance.

Jan 1, 1981

By Terry S. Cory

This report describes the results of a measurement and analysis program to characterize wireless radio transmission In metal/non-metal mines over a wide frequency range from 0.2 -1000 MHz and over a variety of mine environments. Six mines were chosen based on the relative economic significance of their product to the U.S. economy. Mine types Include 01 f shale, uranium, potash, lead/zinc, copper, and silver. Particular mines were chosen so that the group would embody the most Important mining techniques. The results show that transmission at medium frequencies are optimum tor wireless mine communications, In agreement with extensive testing previously performed by the authors in coal mines, and that mine-wide wireless systems are feasible with a minimum requirement for new dedicated wiring. At least one need for such a wireless system was identified in each mine visited.

Jan 1, 1981

By E. L. Garton

Michigan is becoming one of the important oil-producing States of the country. The amount of crude oil produced within its boundaries has increased from only 4,000 barrels in 19253/ to nearly 16 million barrels in 19935.4/ The Bureau of Mines method of crude-oil analysis and classification-indicates that the oils from the several producing fields are predominantly paraffin-intermediate-base, wax-bearing crudes. In general, they will yield 25 to 35 percent of highly paraffinic gasoline and about the t- me amount of kerosene and gas-oil combined, 7.2 to 15 percent of lubricating oil stock, and 20 percent of residuum with a carbon residue or about 6 to 7 percent. In addition, there appears to be some correlation between certain properties of the crude oils and both the geographical location and geological structure of the oil-producing areas within the State. These general conclusions are based on the analytical data presented in this report, which is one of a series of papers that record the general characteristics of crude oil from the many producing fields of the United States. This report discusses briefly the oil fields of Michigan and the characteristics of the crude oils produced from them. The analyses of 15 samples are given. These samples were obtained from 13 fields in 9 counties in the lower peninsula and represent crude oils produced from the Berea sandstone, Upper Traverse and Traverse limestones, and the

Jan 1, 1937

By J. Sottile, J. L. Kohler

Component failures in the electrical control circuits of mining machines account for a large percentage of the total downtime of the machine. Once a failure has occurred it is always a tedious and usually a time-consuming task to locate the failed component. Moreover, the pressure to quickly locate the cause of a delay can lead to compromises in safety. Thus an onboard diagnostic system, essential for an automated machine, would be a very useful addition to existing machines. This report details U.S. Bureau of Mines development of a generic procedure for synthesizing diagnostic systems for electrical-control-circuit failures in mining machinery. A continuous mining machine is used as the testbed to illustrate the application of the developed methodology. Substantive differences among mining machine control circuits made it impossible to achieve a generic diagnostic system, but a generic approach for the synthesis of the diagnostic system was possible. As the research progressed, it became apparent that an algorithmic approach was better than an expert- system-based implementation. A prototype system was constructed and used to evaluate the diagnostic system. Prototype implementation issues are also examined.

Jan 1, 1993

By D. D. Southworth

In 1981, 1982, and 1983, the Bureau of Mines examined the potential for lode deposits of platinum-group metals (PGM) in the Goodnews Bay ultramafic complex, Alaska. The complex consists of the Red Mountain, Suzie Mountain, and Smalls River ultramafic bodies and displays concentric zoning of rock types similar to complexes in southeast Alaska, British Columbia, and the Ural Mountains in the U.S.S.R. Results of the study indicate that platinum is preferentially associated with chromite and magnetite in the dunite core of the complex, and palladium is preferentidlly associated with sulfide minerals in the outer clinopyroxene-rich zones. the most promising targets for PGM lode deposits are the chromite-rich dunite at the heads of Fox Gulch and Squirrel Creek and iron-nickel and iron copper sulfide-bearing magnetite clinopyroxenite and hornblende-rich rocks outward of the dunite core, also in the Fox Gulch-Squirrel Creek area. Significant placer reserves are present in the unmined, deeply buried placer ground in the lower Salmon River Valley, and also in tailings from previous dredging.

Jan 1, 2011

By J K. Wright

In recent years the production of steel from directly reduced iron ore pellets has expanded rapidly. However, continued growth will depend on an adequate supply of suitable raw materials for the various commercial gaseous and solid reductant processes now in operation. Although at present Australia does not produce pellets primarily for direct reduction, there is an increasing awareness of Australia's potential role as a supplier of high grade ores for export and/or domestic use. The properties and quality requirements of iron ore pellets made specifically for direct reduction (DR) are reviewed and the laboratory techniques and test methods used at the CSIRO Division of Process Technology for the evaluation of potential DR feedstocks are described. At the present time most of the evaluation tests for DR pellets are extensions of those designed for existing blast furnace (BF) burdens. In the case of some physical parameters such as cold compression strength, abrasion index and cold strength after reduction this extension is quite satisfactory. In the measurement of parameters such as reducibility, swelling and sticking tendency, however, it is necessary to develop meaningful standardized tests so that ores and pellets can be ranked for DR performance. To do this, data from the laboratory tests and from operating plants must be correlated.

Jan 1, 1980

By Zsuzsanna Zborovszky

Study of different parameters (minimum discharge voltage, minimum discharge current, wire electrode diameter, speed of separation, electrode materials, overlap of the electrodes, etc.), their direct effect on the power going into the discharge, and their indirect effect on the possibility of obtaining ignition with an 8.31% methane-air mixture from a resistive circuit. Critical evaluation of the Cadmium disc breakflash (the presently internationally recommended test apparatus). Description of experimental setup and apparatus.

Jan 1, 1974

By Seong-Taek Yun, Chil-Sup So, Seung-Jun Youm

The greisen-bordered quartz veins are spatially, temporally and genetically associated with a late Cretaceous granite intruding an early Palaeozoic, limestone-rich formation. Paragenetic data indicate three stages of hydrothermal mineralisation, the first typically in or within 500 m of the granite stock and showing vertical zoning between deeper Mo and higher W, the other two more abundant in the upper and outer parts of the mineralised area. Fluid inclusion and stable isotope data indicate that hydrothermal veins formed over a temperature range of 120-395 degrees C from low-salinity fluids. Early wolframite and molybdenite deposition in stage I occurred at temperatures of 300-395 degrees C from magma-derived, low-salinity, CO2-rich fluid, mainly as a result of fluid boiling and associated CO2 effervescence. Progressively larger volumes of local meteoric water entering the system led to the successive deposition of scheelite in stage I vugs, stage II base-metal sulphides and stage III fluorite-carbonates. Remobilisation of W and its later deposition of scheelite in the outer and shallower portions of the system occurred at 215-275 degrees C and stage II and III mineralisation from lower-temperature fluids that became progressively lighter in stable isotopes. It is concluded that the influx of meteoric water increased with distance from the cooling pluton

Jun 18, 1905

By Leslie S. Rubin

A ventilated helical boost pump was developed that can handle varying flow rates and/or solids concentrations while operating at a single rotational speed and without computer assisted feedback controls. The boost pump developed and briefly tested during this program was designed to accomodate flows suitable for a 3-in. diameter pipeline. The boost pump's ventilated design provides the automatic pressure regulation needed to meet the system's requirements for supporting transient pipeline flow.

Jan 1, 1984

By E. P. Ferrero

Crude oils from fields throughout the world are analyzed by the Bureau of Mines to determine the characteristics of the oils and their contribution to the petroleum resources of the world. Analyses are reported for 169 foreign crude oil samples from 122 oilfields in Africa, Asia, Australia, the Caribbean, Europe, North America, and South America. Tables show the geographic and geo- logic origin of the samples, names of companies that supplied the samples, annual production for the fields, general characteristics and analytical and computed data, hydrocarbon-type data, cumulative production of the larger fields, and references to sources of geological and field development information. The analyses were made by the Bureau of Mines routine method and comparisons may be made with more than 8,000 other such analyses.

Jan 1, 1972

By P. H. Davenport, L. W. Nolan

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Geochemical mapping provides a direct approach to delineating areas of epigenetic mineralisation and for relating the regional distribution of this mineralisation to an overall tectonostratigraphic and structural framework, as well as to extensive areas of hydrothermal alteration. Organic lake sediment is a widely available and effective sampling medium for regional geochemical mapping in Newfoundland, that has proved to be valuable in Au, Sb and W exploration

Jul 1, 1991

By L. A. Neumeier

The Bureau of Mines evaluated the properties of zinc alloys containing 25 to 40 wt pet Al and 0 to 0.7 pet Mg. Microstructures, hardness, and tensile properties were evaluated for material as extruded at 285° C, solution treated at 300° to 400° C, and subsequently aged at 100° to 200° C. The alloys without magnesium are characterized by low hardness and strength with high tensile elongation and reduction in area. It was verified that magnesium effectively retards the Zn-Al eutectoid transformation below 275° C and markedly increases hardness and strength with decreases in ductility. Solution treating at 350° C results in large grain sizes and gross embrittlement. Subsequent aging of the Zn-Al-Mg alloys at 200° C restores ductility substantially and stabilizes the structures, but strengths are considerably reduced. Combined strength and ductility properties are better for the as-extruded condition than for any heat-treated condition. There is usually little advantage in overall tensile properties from increasing magnesium above 0.1 pct.

Jan 1, 1971