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By F P. Hao

Organo-sulphur-based collectors (eg xanthates, dithiocarbamates and dithiophosphates) are widely used in the flotation of sulphide minerals. Xanthates (ROC(=S)Sû), for example, adsorb strongly at sulphide mineral surfaces, in a reaction that is electrochemically coupled with the reduction of dissolved oxygen. One of the oxygen reduction products, hydrogen peroxide, reacts directly with dissolved xanthate, leading to its oxidative decomposition. Experimental work has been conducted, using ethyl xanthate, to understand the molecular mechanism by which hydrogen peroxide reacts with xanthates. A number of degradation products have been identified, some of which have not been reported previously. This oxidative decomposition reaction pathway is discussed in the broader context of xanthate decomposition in flotation systems. One of the identified ethyl xanthate decomposition products, ethyl perxanthate (ROC(=S)SOû), has been observed in the process water of a number of mineral processing operations. The interaction of this molecule with goethite (α-FeOOH) particles, typical of that found in tailings dams, has been studied in more detail using attenuated total reflectance (ATR)-FTIR. The ethyl perxanthate molecule has been found to coordinate to iron (FeIII) at the goethite surface, and undergo a surface-catalysed decomposition process. In the presence of both PbII and goethite, a ternary surface complex is formed, where ethyl perxanthate is coordinated directly to surface adsorbed PbII atoms. The results obtained give some insight into the environmental fate of ethyl xanthate in tailings streams, and a basis on which to consider the environmental importance of such species in tailings dams. Strategies for the destruction of residual xanthate levels in waste water streams are discussed in terms of the likely reaction products.

Jan 1, 2002

By Thomas Barczak

Roof support systems are designed for roof control to prevent unplanned falls. It sounds logical and has been the conventional thinking in support design since supports were first installed. In order to determine which support system should be used or which would be the most effective, the degree of control provided by the support system must be known. This question embodies the concept of a ground response curve, which is a measure of support control by assessment of the convergence in the mine entry as a function of the support capacity. In this National Institute for Occupational Safety and Health (NIOSH) study to optimize standing roof support design, ground response curves were developed for longwall tailgate conditions from numerical models of Pittsburgh Coal Seam geology. The models were calibrated against tailgate convergence measurements that were made in two Pittsburgh Coal Seam mines as the depth of cover varied during the panel extraction. Ground response curves were developed for four loading conditions: (1) development, (2) side abutment, (3) front abutment near the longwall face, and (4) full extraction inby the face. In general, the tailgate convergence and required support capacity increase through each of these loading stages. It was concluded that prior to failure of the rock mass, the support system regardless of its capacity has relatively little impact on tailgate convergence. Recognizing that the support cannot prevent much of the (pre-failure) convergence that is occurring is an important part of support design. Supports that exhibit high loading stiffness but cannot sustain that loading through a displacement compatible with the ground response curve will not provide adequate roof control because they can fail prematurely. The required capacity depends on the loading plus yielding characteristics of the support and the amount of rock failure that has occurred. The loading plus yielding character establishes where the support loading intersects the ground response curve. Design criterion for support capacity based on the identifying the onset of strain-soften rock response leading to ?damaged roof? is proposed as a foundation for assessing support design requirements. The capacity without accounting for the loading and yielding character of one support should not be used to assess the capacity requirement of an alternative support design, particularly when the loading and yielding characteristics are significantly different. A sensitivity study was made to evaluate the impact of mining height and overburden depth. As expected, the results show that convergence increases with increase in mining height and increase in overburden depth. Some specific support examples are also analyzed. Although this is a first step and the two-dimensional numerical models have limitations, these initial studies provide valuable insight into the control provided by the roof support system and will ultimately lead to optimizing support design based on specific mine site conditions.

Jan 1, 2008

By Ettore Contestabile, Cameron Thomas

Implosive connectors such as XECONEXTn have been used extensively for joining electrical conductors. This implosive action of explosives has also been used in other forms of high-energy metal working with excellent results. However, the inherent blast energy of these units can cause environmental side effects (especially airblast) which may restrict their use around inhabited areas.

Jan 1, 1994

By B Crossley

Self-cleaning fluidised bed heat exchangers have demonstrated unparalleled performance internationally for the implementation of indirect heat transfer in severely fouling fluid environments. Recent advances in equipment design have increased the scope of application to include indirect heat transfer in slurry environments, including fouling, scaling and viscous slurries. The ingenious configuration of recirculated cleaning particles through the tubes of vertical shell and tube heat exchangers provides the ability to solve heat transfer problems that arise as a consequence of tube-side fouling during indirect heat transfer to process fluids or slurries. In most cases, the cleaning particles consist of chopped metal wire, however other process-specific materials may be used.

Jan 1, 2004

Study on Basic Theory of the Grain Settlement in Fluidised Bed This paper takes thick goal grains (less than 1.5 cm) as research object. According to different densities and particle sizes, thick goal grains are divided into 20 kinds of narrow density and narrow size level average grains. Free settling and hindered settling tests are respectively carried out in ?100 fluidised bed thick goal separators. Hindered settlement includes hindered settling velocity test and measurements of suspension density. Results show follows. (1) Fluid state in separator belongs to transition region. Alien's law is the appropriate formula of thick coal particles free settlement terminal velocity. (2) The main factors affecting hindered settling velocity are the number of solid particles in medium and the structure feature of the particle group. The bigger volume fractions of solids ? is, the smaller decreasing velocity coefficient of particle hindered settlement ¯ becomes. In the organism from bottom to top, density of suspended particles in fluidised bed gradually decreases, but near the top of the suspended particles, the density increased slightly. With increase of density and size, suspension density reducing extent increases from bottom to top of separators.

Sep 13, 2010

By Richard J. Mainiero, James H. Rowland

When most people think of explosives transport they think of a hazardous operation. We all know that we aren’t allowed to transport explosives through tunnels and are discouraged from traveling through heavily populated areas. Popular opinion suggests that explosives transport is a very risky operation. The authors decided to look into this a little more thoroughly and found just the opposite to be true. While there have been some disastrous world-wide accidents involving the transport of industrial explosives, this is not the case in the U.S. Over the past 10 years, accidents related to the transport of explosives used in mining and construction have resulted in 5 major injuries, 11 minor injuries, and no fatalities. Explosives and ammonium nitrate (AN) transport outside the U.S. has not had such a good record; there have been 4 major explosives or AN transport accidents resulting in a total of more than 300 deaths. Most of these fatalities could have been prevented if the accident site had been evacuated once the explosive or AN cargo began burning. The safe history of explosives and AN transport in the U.S. is due to diligent efforts by government, labor, and industry. However, accidents will become more common and disastrous if we become complacent.

By D. Govender

Theoretical flotation models suggest that there is a positive relationship between bubble-particle collision rates and turbulent kinetic energy dissipation. Fine particle flotation performance is generally enhanced by increased collision frequency and hence higher energy dissipation. Contrarily, increased turbulence in the rotor-stator region is related to higher detachment frequency of the coarser size range. Therefore, the optimal modes of recovery for the 'fine' and 'coarse' size classes appear to be diametrically opposed. Industrial applications have previously confirmed that applying greater power to flotation slurries yields significant improvements in fine particle recovery. However, recovery of the coarser size class favours a different flotation environment. An improvement in the flotation kinetics of the fine and coarse size classes, provided there is no adverse metallurgical influence on the intermediate size ranges, is obviously beneficial to the overall recovery response. Managing the local turbulent kinetic energy dissipation, and hence the power imparted to the slurry, offers the benefit of targeting the particle size ranges exhibiting slower kinetics. FLSmidth recently introduced the practical implementation of this concept. In principle, it decouples flotation regimes where fine and coarse particles exhibit preferentially recovery. In the case of naturally aspirated machines (Wemco®), it is referred to as Hybrid Energy Flotation? and incorporates at least three phases: > Standard flotation machines (standard energy input, rotor speed (r/min), rotor size/type) at the beginning of the row, where flotation is typically froth-phase limited and operational and set-up parameters have a limited influence on the recovery > Higher-powered flotation machines (high rotor speed, high-power rotor size/type) at the end of the row to improve fine particle recovery > Lower-powered flotation machines (low rotor speed, low power rotor size/type) to enhance coarse particle recovery. A CFD-based flotation model is used to highlight the effect of turbulent dissipation energy on attachment and detachment rates. Preferential collection zones for fine, and 'coarse' particles are predicted for both forced-air and naturally aspirated machines. The greater predominance of UG2 ore types, coupled with the skewed feed distribution of platinum group metals (PGMs) to the finer size fractions, suggests that PGM flotation circuits are not designed for optimal recovery across the size distribution. The application of the hybrid energy concept to PGM flotation offers a possible shift towards a more efficient flotation circuit solution through a managed distribution of energy.

Jan 1, 2013

By Turnbull A. G

Thermodynamic calculations based on the ideal system NiO - Fe203 - H2(g) - CO(g) - H2O(g) - CO2(g) show that it is not possible to selectively reduce nickel oxide in the presence of hematite because ferronickel is the zero-valent nickel-containing product. The calculations show that temperature, reducing atmosphere composition and oxide to reductant ratio have a marked effect on the nickel content of the ferronickel alloy and the amount of nickel reporting jn the alloy. The general trends based on the calculations correlltte well with experimental observations.

Jan 1, 1980

By Bruno Gemmi

The objective of the ? 200 million ($280 million) project Parma Railways Station-Urban Transformation was the reconnection of the North and South parts of the town by constructing an 80 m (250 ft) wide sunken artery passing under the four double railway tracks of the station without any impact on train traffic. The site of the project, adjacent to the Parma River, presented water seepage problems at any excavation depth. The use of conventional large diameter bored pile machinery was not allowed by the Railway Authority because equipment dimension and construction phases do not comply with train traffic safety regulations. Foundations for the bypass were thus constructed by minipiles nested into jet-grouted soil using machinery operating within the existing head room and at a safe distance from the tracks. Jet-grouting treatment reached depths of 25 to 28 m (80 to 90 ft) from tracks? grade and embedded minipile-heads were terminated at 2 to 3 m (6.6 to 10 ft) below grade. Load tests on minipiles were pushed to failure. Failure occurred at a 240 t (265 t) load without breakage of the bond between the jet grouted soil and the minipiles. A 0.93 MPa (135 psi) shear resistance ??? between minipile steel casing and the jet grouted soil was measured prior to the failure of the steel casings. Overall measured foundation settlements were well within expected values and were considered insignificant.

Jan 1, 2011

A physical modelling study has been carried out to simulate the slag-metal dispersion induced by a high-strength bottom gas injection. Water and kerosene were utilized to simulate metal and slag respectively. A water model of CLU (Creusot-Loire Uddeholm)vessel was used with three different nozzle orientations, namely, off-centre, triangular off-centre and centre. The gas flow rates changed from 0.00599 m3/s to 0.01081 m3/s. Height of heavy and light phases was kept fixed at 0.23 m and 0.02 m respectively. The dispersed phase hold-up was determined at various axial and radial distances, gas flow rates, and tuyere configurations. The observations revealed that at a fixed gas injection rate, as the vertical distance increased in the centerline, straight off-centre orientation resulted in greater dispersed phase hold-up values than those of the centre configuration and the triangular off-centre orientation. The dispersed phase hold-up was found to increase with gas injection rate and decreased with axial distance. The variation of the dispersed phase hold-up with the dimensionless axial distance and the gas injection rate was correlated by using the modified Froude number. The experimental values of the dispersed phase hold-up were found to be in reasonable agreement with the correlated values obtained from the modelling equations. The findings of the present study may be utilized in the ferroalloy refining vessels in terms of designing tuyere locations for optimum processing conditions.

Jan 1, 2004

By Scott Ellenbecker

Soon New York City will have a new train station. A tunnel project is under construction to extend Line 7 to a new station that is located near the Jacob K. Javits Con-vention Center. This is also part of the Hudson Yards redevelopment project that is intended to aid redevelop-ment of the west side of Midtown Manhattan around the Long Island Railroad?s Caemmerer Railyard. The station, or ?cavern? as it?s called by those excavating it, will be the portal for that growth. In the city, public transportation means high-rise residential proper-ties will have better access to the business district, and those outside the area will have greater access to event facilities ? two factors that are critical for development investment.

Jan 3, 2010

By Colin Lindsay

"The Collahuasi copper mine, located at an altitude of 4300 meters above sea level in northern Chile, commenced operations late in 1998. The mine is currently the 4‘h largest copper producer in the world and comprises an open pit, a 60,000 tpd sulphide concentrator, a 15,000 tpd oxide heap leach and SWEW plant and a 200 km concentrate pipeline to a port facility.Constructing, commissioning and operating a mine at high altitude presents unique challenges in terms of the performance of both equipment and people. It is important that these be recognized and carefully considered during the feasibility study and the detailed design stages and the success of the Collahuasi project is largely due to this. The plant design incorporates a number of features aimed at mitigating the problems of altitude and the construction methodology also took into account the particular site conditions.This paper discusses the Collahuasi project team’s approach to planning for the remote location and also some of the problems experienced during construction, commissioning and operation.INTRODUCTIONThe Collahuasi mine is located in northern Chile, some 250 km to the south-east of the port of Iquique and 15 km from the Bolivian border. The mine facilities lie between 3800-4300 m above sea level on the Altiplano, the central plateau of the Andes mountains, and cover a total of approximately 95,000 hectares. Although the area is arid, it experiences an average of 150 mm of precipitation annually and weather conditions can be extreme. Temperatures during the day range between -3 to +11 º C and are generally below 0ºC at night, sometimes as low as -20°C. High energy winds are common and humidity is low. Much of the precipitation occurs during the winter as snow but there also occurs a period during the Chilean summer known as the “Invierno Boliviano’’ (or Bolivian Winter) which is characterized by severe electrical storms and rain."

Jan 1, 2001

By Kjell Karlsrud

"Abstract New semi-empirical design procedures for the determination of ultimate shaft friction and load-displacement response of axially loaded piles in clay are proposed. Hereunder also prediction of how the capacity will build up with time following the pile installation, primarily as result of reconsolidation. A main basis for developing the new procedures was detailed review and re-assessment of results from a series pile load test programs published over the past 30 years on piles well instrumented to monitor soil- and pore pressures as well as load distribution along the pile shafts. Two new alternative procedures are proposed for predicting the ultimate shaft friction; a-approach using the normalised undrained strength based on direct simple shear tests as a main correlation parameter, and ß-approach using the overconsolidation ratio, OCR. Both approaches include the effects of the plasticity index of the clay, Ip, which is shown to have an especially large impact on the correlations when Ip<25. It is recommended to use both methods in design practice, and select design values for the ultimate shaft friction that represents an average for the two methods. Pile diameter, length or stiffness, or whether the pile is open- or closed-ended seem to have little impact on the shaft friction. However, a moderate effect of pile length or flexibility on the total ultimate pile capacity comes out of the proposed t-z curves, which include some post-peak reduction. The proposed procedure for predicting the time for set-up is based on linear radial consolidation theory. The main input parameters are the insitu permeability and virgin modulus number (or virgin compression index) of the undisturbed clay. The same basic formula and correlations are applicable to both open and closed-ended or partially plugging piles.IntroductionThe design procedures presented herein are primarily based on observations and data collected in connection with “fully instrumented” pile testing programs that the author has been responsible for or has become involved with over the past 40 years, or that have been found in the literature.It was a pre-requisite for the test programs included that there were sufficient high quality soil data available to give a reliable determination of the true in-situ strength and compressibility characteristics of the clay deposits. The soil conditions range from soft NC clays with undrained shear strength down to about 15 kPa, to very stiff clays with undrained shear strength up to about 500 kPa and OCR up to 25. The plasticity index of the clays mostly lies in range 12 to 60 %."

Jan 1, 2014

The sequences in alteration and mineralisation from five copper-gold porphyry systems (Taysan and Didipio, Philippines; Horse-Ivaal and Wafi River, PNG; and Goonumbla, Australia) and one gold-copper skarn system (Browns Creek, Australia) are documented in this paper. Alteration and mineralisation in all these systems reflect a common evolution from crystallisation of melts emplaced at shallow crustal levels (zoned potassic -> propylitic alteration), followed by exsolution of volatile-rich fluids from these melts (porphyry quartz ¦K-feldspar/biotite veins and local high temperature advanced argillic alteration), to a progressive cooling of the intrusion which results in associated retrograde alteration. Copper-gold mineralisation in all cases is almost exclusively restricted to the cooler retrograde events. The recognition of the temporal and spatial zonations in alteration and mineralisation in gold-copper porphyry systems has significant relevance in the interpretation of geophysical signatures, overprinting alteration, vein sequences and structural controls, and can lead to more focused and potentially more cost-effective exploration.

Jan 1, 1999

By S. Sun

Recent studies on the physico-chemical properties of molten slags and oxide solid solutions of interest is reviewed. The review covers redox and phase equilibria in slags, viscosity, diffusivity, electrical conductivity, kinetics of interfacial reactions between slags and CO-CO2, interfacial properties and phenomena. Some highlights from ongoing work on modelling phase diagrams, component activity, viscosity and electrical conductivity of multi-component slags will be presented and results compared with published experimental data on slags with or without suspended solid phases.

Jan 1, 2004

Council for 2001/2002 President A.A.B. Douglas President-elect S.J. Ramokgopa Vice-presidents Senior F.M.G. Egerton Junior Prof. T.R. Stacey Immediate Past-president Dr L.A. Cramer Honorary Treasurer J.A. Cruise

Jan 1, 2002

A mining engineer from South Africa, whose research has taken him to some of the world?s deepest gold mines, is the winner of the St Andrews Prize. Daniel Limpitlaw, 27, picked up a cheque for $25,000 for his dissertation on reversing the damage done by early mining technology, which he claims is partly responsible for blighting the urban environment in many South African cities. Launched in October 1998 by the University of St Andrews and international energy company Conoco, the St Andrews Prize sought practical solutions to environmental problems. It attracted interest from 450 individuals and groups from countries as diverse as China, Pakistan, Canada, New Zealand, Germany, the UK and the United States.

Jan 1, 1999

By Hugo E. Camargo

Noise Induced Hearing Loss is the most common occupational disease in the U.S. and of paramount importance in the mining industry. According to data for 2006 from the Mine Safety and Health Administration (MSHA), Continuous Miner operators accounted for 30.2% of underground mining equipment operators with noise doses exceeding the Permissible Exposure Limit (PEL). This figure becomes more significant considering that 49% of the 2006 national underground coal production was extracted using continuous mining methods. Thus, there is a clear need to reduce the sound radiated by Continuous Mining Machines. The first step towards efficient noise control of a Continuous Mining Machine requires identification of the various noise sources under controlled operating conditions. To this end, a 42-microphone phased array was used in conjunction with 4 reference microphones to sample the acoustic field of a machine in the Hemi-anechoic chamber of the Pittsburgh Research Laboratory. These data were processed using a frequency-domain beamforming algorithm to obtain acoustic maps of 5 sides of the machine. The focus of the test was on the conveyor noise since previous studies showed that operation of the conveyor is the most important contributor to the sound radiated by the machine. From the acoustic maps, the following potential areas for noise control were identified, and included: chain-tail-roller interaction, chain flight tip-side board interaction, and chain-upper deck interaction.

Jan 1, 2008

Tried, Tested and Proven - 300 m3 Flotation Cells in Operation

Sep 13, 2010

By P. J. Foster

A common theme running through recently introduced mining health and safety legislation in many parts of the world is risk assessment. Most recently, risk assessment legislation has been introduced across the mining industry of South Africa and the view that the introduction of risk assessment based legislation provides an ideal opportunity to improve on past health and safety performance is presented. Risk assessment techniques range from highly complex safety system techniques that are used in high technology process industries, to subjective techniques based on simple judgements that are finding use in many other industries. The objective of this paper is to shed some light on risk assessment, not by detailing the risk assessment process but by identifying the crucial elements that need to be considered if risk assessments are to be successful in changing health and safety performance. A case study is presented illustrating the introduction of risk assessment into the Ingwe Coal Corporation, one of South Africa?s largest mining houses, to indicate how the system was developed and how it is being used.

Jan 1, 1998