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By Liguang Wang, Roe-Hoan Yoon

The thin film balance (TFB) technique was used to measure the equilibrium film thicknesses (H3 between two air bubbles in sodium dodecyl sulfate (SDS) and electrolyte (NaCl) solutions. The results were used to determine the magnitudes of the hydrophobic forces (K232) using the extended DLVO theory. The Km values determined from He measurement allowed us to predict disjoining pressure isotherms, which were found to be in excellent agreement with those obtained experimentally using a bike-wheel film holder. The rate of film thinning was measured at low SDS concentrations with varying amounts of electrolyte (NaCl) added. In general film thinning was controlled by the capillary pressure during the initial stages, while it was controlled by the surfaces forces during the later stages. At low NaCl concentrations, it was possible to predict the rate of film thinning using the Reynolds equation, provided that the driving force was corrected for the contributions from the hydrophobic force, which in turn were determined from the KZ32 values obtained from the He values measured experimentally. At high NaCl concentrations, where it was difficult to measure the equilibrium film thicknesses, the contributions from the hydrophobic forces were determined by fitting the film thinning data to the Reynolds equation. The K232 values obtained using both the equilibrium film thickness and the film thinning measurements showed that hydrophobic force deceased with increasing surfactant and salt concentrations. It was found that the hydrophobic force in foam films was very sensitive to the added electrolyte concentration.

Jan 1, 2005

By S. B. Bhagwat

The United States has abundant coal resources that could last at least another century. and probably longer at present consumption rates. Geographically, the coal resources are distributed over the entire nation including Alaska, although there are no coal deposits in the highly populated areas on the two coasts. This allows free access to the coal, but makes transportation more expensive. Not all coals can be utilized equally because they differ vastly in quality. The sulfur content of coals, considered as the most detrimental acid rain-causing element, varies from as low as 0.3 percent in some areas of the western U.S. to 5 percent or more in parts of the Midwest. The chlorine content, which causes corrosion of plant hardware, also varies regionally. The 1990 amendments of the Clean Air Act of 1963 (CAA) require that emissions of sulfur be restricted and rolled back in two stages by the year 2000. There have been a number of reports expressing concern about the future of the industry in the states where high sulfur coal is produced. The remedies devised by the federal government and many coal-producing states in the past to "se-cure" the future of the regional coal industries have focused on the physical task of removing sulfur rather than the economic challenge of doing so at a cost that will enable high-sulfur coals to survive and compete. The past remedies, generally, were not specific enough to account for the characteristics of regional coal deposits and did not look at the coal market as an integrated national and international entity. The State of Illinois has, in recent years, taken a more comprehensive approach to the solution of the problem.

Jan 1, 1992

By R. J. Sheets

In 2009 the Gold Quarry open pit mine, located 11 km northwest of Carlin, Nevada, USA, experienced multiple large-scale slope instabilities of the upper east highwall that reduced gold ore extraction for nearly 18 months. The slope instabilities occurred within a weak, consolidated sedimentary sequence that exhibits strength characteristics that are transitional between soil and rock. Instability initiated as mining exposed the lower clay-rich sub-units of the Carlin Formation (Fm.). This deformation created preferential flow paths that allowed groundwater from the upper sandy sub-units to infiltrate low permeability clay-rich sub-units, thereby enhancing deformation of the slope toe which in turn destabilized the upper portion of the highwall. The outcome was a 160 m high slope instability that had a lateral run-out of 850 m. The effort to return the pit to ore production required both the geotechnical and hydrogeological investigations and the preliminary remediation mining activity to be concurrent. This approach required the development of detailed safety procedures and a requirement to modify the remediation design as new results were obtained. An initial challenge was to mitigate a near vertical, 90 m headscarp with blast induced, localized slope failures. Back-analyses applying numerical modeling indicated that the failure surface did not coincide with initial interpretations based on field observations; drilling results eventually confirmed this alternative failure geometry. The final remediation design incorporated shallower slope geometries and an approximately 3 Mt buttress along the base of the Carlin Formation and bedrock contact to reinforce the lower clay-rich sub-units. The outcome is a stable highwall within the Carlin Fm. following nearly ten years of repeated slope instability, and an example of the necessity to conduct appropriate geotechnical and hydrogeological studies during the early stages of a new layback evaluation or new open pit development.

Feb 23, 2014

By R. J. Weege

Conventional underground mapping methods and diamond drilling are being applied in a study to determine the nature of the copper ore occurrences near the footwall of the Osceola lava flow top, commonly referred to as the Osceola Amygdaloid. Our work to date suggests that structures formed by relatively impermeable barriers, created by flowage and injection of still-molten lava from the interior of the flow into the solidified, brecciated crust, acted as the ore receptacles. Ascending hydrothermal fluids traveling near the footwall contact were trapped and confined in these barriers which retarded the direct upward movement of the ore fluids and caused deposition of copper. Oreshoots located near the footwall appear to have been formed spatially' independently from the hanging-wall oreshoots by fluids traveling simultaneously, but along different channelways. The barrier concept as advanced by earlier writers to explain the concentration of the ore-bearing, fluids into broad shoots con¬stituting entire ore bodies is found to be equally as applicable for the localization of smaller oreshoots within the Osceola ore body.

Jan 1, 1962

By G. D. Hood

The U.S. Bureau of Mines investigated rapid froth flotation through more efficient bubble-particle collisions that improved the overall flotation kinetics. An in-line static mixer efficiently mixed the bubbles, water, and ore, selectively attaching these bubbles to the hydrophobic mineral's surface. As the mixture entered the flotation chamber, the hydrophobic mineral was already attached to the bubbles and was quickly floated away from the remaining ore pulp. The rapid flotation system was evaluated for beneficiation with a western porphyry copper ore containing 0.67 pct copper, and a phosphate-bearing amine flotation tailings sample containing 9.5 pct P2O5 in a quartz matrix. Over 88 pct of the copper was recovered from the ore in a rougher concentrate containing 5.9 pct copper at a rate 7 times faster than conventional flotation. Sixty percent of the quartz in the phosphate-bearing sample was floated at a rate 4 times faster than conventional flotation. The unfloated product retained 80 pct of the phosphate in a l6.9-pct P2O5 concentrate.

Jan 1, 1993

By H. W. Judges

A 16.5-kt/day underground molybdenum mine is being developed at Questa in Northern New Mexico by Molycorp, Inc., a wholly-owned subsidiary of Union Oil Company of California. Construction of the underground mine began in 1979, and first production is scheduled for early 1983. A gravity block caving method has been selected for mining the ore. Access to the mine will be through a service shaft, development shaft, and a conveyor decline. The shafts are being sunk under contract and the conveyor decline is being driven by Molycorp. The driving of the decline began in February, 1979 with a 10-man mining class. By the first of May, enough men had been trained to begin a continuous operation and by March 1, 1980 the face had reached the 1500 m mark. The heading is being driven with trackless rubber-tired equipment using a three-boom drill jumbo, 2.7 m3 LHD units and 7.3 m3 trucks. Ground support has been by rock bolts and wire mesh, followed by Fibercrete. A 16.5-kt/d underground molybdenum mine is being developed at Questa in northern New Mexico by Molycorp, Inc., a wholly-owned subsidiary of Union Oil Company of California. The new $200-million underground project will revitalize mining and milling activity at Questa, where small scale underground mining first began in 1920. Large scale open-pit mining was initiated in 1965 but now, because of the high stripping ratio, surface mining is being phased out. Construction of the underground mine began in 1979, and first production is scheduled for early 1983. The company expects full capacity - 9 Gg of molybdenum per year - to be reached in 1984.

Jan 1, 1980

By Harrison R. Cooper

The expanding use of digital control in the metallurgical industry is a significant recent development. From 1970 to 1975, approximately forty metallurgical plants throughout the world have adopted automation techniques based on digital controls (see Table 1). Several recent technical reports have described development of digital control systems in concentrator grinding control, 1,2 flotation,3 and smelter operations.4,5

Jan 1, 1975

By E. Knell

COM Energy, Inc., a subsidiary of Occidental Petroleum Corporation, has constructed a 1.6 million hectoliter-per-year COM plant in Jacksonville, Florida. COM will be distributed to customers in the region as a substitute for fuel oil presently burned in boilers and kilns. As the market for COM grows, COM Energy, Inc. expects to build additional units both in this country and overseas. This paper addresses the overall status and technical aspects of the project, focusing on the facilities for COM production and utilization.

Jan 1, 1982

By Peter T. Chiang

A brief literature review on metal separations by ion exchange and solvent extraction of their thiocyanate complexes which are practiced in analytical chemistry as well as in industries was performed. Owing to the poor stability of free thiocyanic acid in acidic aqueous and organic media, technical and environmental problems which cause high thiocyanate consumptions often arise during the practice of the separation processes. This prompted the conducting of a second and more thorough literature review on the chemistry of thiocyanic acid. The objectives of this undertaking are to compile and interpret literature data on the physical properties and chemical reactions of thiocyanic acid, thus providing a clearer understanding of the causes of these problems and giving options as to how to minimize them. The best answer found for carrying out the separation processes is to keep the temperature, thiocyanic acid concentration and total acidity as low as practical.

Jan 1, 1984

By Klaus Grebe

Recent investigations by Mannesmann Research have shown that disintegration of sinter with widely varying quality levels is subject to a much more complex set of influences than was previously assumed. It was confirmed that disintegration at temperatures between 300 and 600 °C is triggered by the degradation of hematite. The specific tendency of hematite to disintegrate is, however, not constant: sinters containing the same amount of hematite can show widely differing disintegration tendencies depending upon structural homogeneity, porosity and gangue quantity. Especially sinters with heterogeneous structures transmit stress to the hematite phase and this favours disintegration. Another factor is the brittleness of the glassy silicate phase, which can be influenced even by small modifications of minor gangue constituents.

Jan 1, 1981

By Muriel S. Robinette

Ground-water contamination from uranium operations could be avoided with proper site analysis techniques. Contamination from tailings disposal sites is carried downgradient within permeable hydrostratigraphic units which can be located and delineated with a combination of drill holes, borehole geophysical logs and surface geophysics. Several case studies are presented to illustrate this application.

Jan 1, 1980

By Albert E. Ketler

The AirBoss*200 is a unique ambient airflow sensor with important improvements in accuracy, especially in the critical low end, 0-61 m/min (0-200 fpm) where MSHA regulations apply. All solid state, its design is rugged, and there are no moving parts or delicate filaments. An on-board microprocessor calculates air velocity, linearizes and corrects for temperature, while driving voltage and current loop analog outputs to .3 meters/minute (1 ft/min) resolution. Recent developments also cover both positive and negative flow directions. A hand held computer is available to readout data and to adjust stored range selection, alarm set points, calibration data and the speed of response. Installation in hazardous areas is covered by MSHA Classes G, H and L.

Jan 1, 1993

By I. Iwasaki

The effects of autogenous grinding and conventional grinding on the floatabilities of copper-nickel sulfides were investigated as a part of a pilot-plant development project on the differential flotation of Duluth gabbro. At the same mesh-of-grind copper, nickel, and cobalt recoveries were higher and residual sulfur in the flotation tailings was lower with the autogenously-ground pulps. With the ball-mill-ground pulps the residual sulfur in the tailings could not be lowered to the level attained by the autogenously-ground pulps even at increased levels of the collector addition. From mineralogical examinations of concentrate and tailings samples, an electrochemical interaction between grinding media and sulfide minerals was thought to have a greater effect on sulfide mineral flotation behavior than the breakage characteristics of the ore samples in these two types of mills.

Jan 1, 1981

By P. D. Rao

The combination of high moisture and low heating value has restricted most low-rank coal (LRC) usage worldwide to mine-mouth power generation. Coals from Usibelli Coal Mine and the Beluga coal field have a heating value of approximately 8,000 Btu/lb and 28% moisture. Hydrothermal treatment (at 275 to 352'C) of lump coal from Usibelli Coal Mine and Beluga coal field enhanced the heating value of the coal, on an equilibrium moisture basis, from 8,000 Btu/lb to nearly 12,000 Btu/lb. The product coal with high heating value and 0.2 % S is an environmentally acceptable premium fuel. The Hardgrove grindability index of the coal is greatly improved, further enhancing its value. Increase in hydrothermal drying temperature promotes vesiculation of resinite. Vitrinite reflectance increased to 0.72 and vitrinite was subjected to widespread visiculation resulting in a coke like structure indicative that the material went through the fluid stage.

Jan 1, 1991

By Yi Luo, Jian Yang

Subsurface strata movements and deformations associated with longwall mining operations in underground coal mines could cause various disturbances to subsurface mine structures, ground water bodies, and coalbed methane reservoirs. In order to assess those disturbances correctly and to design effective and efficient mitigation measures, it is necessary to develop an accurate prediction model for subsurface strata movements and deformations. Decades of research have demonstrated that variations of stratification and lithology in the overburden have significant influence on the subsurface strata movements and deformations during ground subsidence process. The key strata theory states that the thick and hard key strata serve as the backbone of the overburden and control the movements of the thin and soft weak strata located above them. From an engineering standpoint, the overburden strata are subdivided into several individual groups by the key strata with each group consisting of a key layer at the bottom and weak layers overlying it. A new subsurface subsidence prediction model considering the key strata effects on subsurface strata movements and deformations has been proposed. In this method, elastic modulus, specific weight, tensile strength, and uniaxial compressive strength (UCS) of each layer are used to identify the key layers and to determine the needed subsurface subsidence parameters. The influence function method, proven to be accurate and versatile for surface subsidence prediction, was employed to predict the subsidence on each of the overburden layers from mining horizon progressively upward to ground surface with the assumption that the predicted subsidence on a given layer serves as the subsidence source for the layer immediately above. The enhanced subsurface subsidence prediction model has been demonstrated with an actual case to show its applicability and improvement.

Jan 25, 2021

By Bobby J. Timmons

Luck; blind, beginner's, fisherman's, or whatever type, plays an important role in romance, racing, football, gambling, and mineral exploration. However, for each of these; education, training, technique, and experience are necessary for a long, continuous, successful relationship. Success, no matter how obtained, is easier to defend than almost success, regardless of the education or the degree of refinement of the seeker. Similarly, investment dollars are more readily available to a successful, uneducated and unscientific practitioner than to his beginning or unlucky professional counterpart.

Jan 1, 1983

By J. F. Brune

"Re-occurring face ignitions in U.S. coal mines are concerning and require a closer look at air quality monitoring systems and practices employed in these mines. The explosion disaster at the Upper Big Branch mine in West Virginia in 2010 caused 29 fatal injuries and was largely caused by inadequate water sprays and inadequate ventilation monitoring. In this comparison, the author compares ventilation system monitoring in Australian, German and U.S. underground coal mines and makes recommendations for improvements and best practices. Mines in Germany and Australia are adhering to more stringent requirements for monitoring air quality and quantity and for monitoring water spray systems on cutters to prevent frictional ignitions. Air quality should to be monitored for sufficient oxygen, toxic gases, explosibility and for fire gases indicating a potential fire. Ventilation monitors must also confirm that sufficient quantities of air are available. Fully automated, continuously recording atmospheric monitoring and alarm systems are established practices in Germany and Australia and should be mandated for U.S. mines as well, in addition to the current, regular spot inspections of the ventilation system by certified mine examiners. BACKGROUND: METHANE EXPLOSIONS, FACE IGNITIONS AND NEED FOR AIR QUALITY MONITORING Accumulations of methane in face areas of underground coal mines frequently lead to ignitions that can cause burns, traumatic injuries and, in the case of the 2010 Upper Big Branch disaster, cause major explosions with multiple fatalities. Table 1 shows the number of reported face ignitions in U.S. coal mines between 2010 and 2014, based on statistical data published by MSHA (MSHA 2010 – 2014). Although there appears to be a downward trend in such ignition incidents over time, ignitions continue to occur with some regularity; and each ignition may cause a potentially catastrophic mine explosion.Per regulation, all U.S. coal mining machinery, continuous miners and longwall equipment, is outfitted with continuously monitoring methane sensors wired to cut power to the equipment as the methane level exceeds 1%. Face ignitions keep occurring because these sensors are usually not positioned in sufficiently close proximity to the coal cutting drums or to the freshly exposed coal face where the methane is most likely released. Therefore, methane may accumulate in explosive concentrations near the coal face and the cutting drums long before the gas concentration reaches the 1% level near the monitor and creates an alarm."

Jan 1, 2016

By V. F. Hollister

Although it is apparent that porphyry copper deposits may have formed in the Andean orogen from Permian time onward, commercial deposits thus far developed appear to have Cenozoic ages only. Following Chilean useage, the porphyry deposits are divided into either: (a) a stockwork, or (b) a tourmaline breccia model. Stockwork type deposits tend to occur on major strike-slip structures which may be either transcurrent or transverse faults related to plate movements, while the tourmaline breccia type may more frequently form independently of regional faults. Stockwork types may be conjugate fractures that intersect and ramify as a network of veins and veinlets, cutting altered rock, and genetically related to a major regional fault, or in other cases they may reflect the intersection of two large fault structures. Circular fracture patterns may more rarely occur in stockwork deposits in response to a specific intrusive. Tourmaline breccia types are characterized by circular and radial fractures genetically connected in some way with tourmaline breccia pipe development or an intrusive piercement that preceded it. Each structural model contains mineralized intrusive8 which have a close time-space relationship to ore and in each model, mineral paragenesis is similar, regardless of age or location in the plate. Also, each model contains the same type of alterntion halos (phyllic, argillic, prophllitic) as are developed in intru- sive centers in porphyry copper deposits found in North America. The potassic zone is exposed best in the older deposits. Examples of each type of deposit are illustrated, demonstrating the feature evolved.

Jan 1, 1973

By A. Fleming

The exploration process, like any other commercial activity, can only succeed if the objective of the exercise is clearly defined and persistently pursued. Successful exploration requires properties, funding, personnel and persistence. Many of us have years of experience in conducting exploration in our countries of residence. Conducting exploration in a foreign country, however, requires a number of significant other criteria.

Jan 1, 1997

By J. R. Allen

Environmental laws and regulations have proliferated over the last two decades. 1/ Within the last year, Congress has dramatically expanded the scope of the Superfund program 2/ and has enacted significant new amendments to the Clean Water Act.3/ In addition, EPA has shown no signs of slackening the pace at which it promulgates new regulations to implement statutory programs. The agency projects that over the next few years it will issue approximately 275 new regulations under the statutes it implements. 4/

Jan 1, 1988