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By M. R. Yalamanchili, J. D. Miller

Discussion by M.R. Yalamanchili and J.D. Miller The authors, M. S. Celik et al., should be recognized for their efforts to describe the flotation behavior of boron minerals. In the case of borax and other soluble salt minerals, analysis of the flotation chemistry has been difficult because of the high ionic strengths associated with these soluble salt systems. However, considerable progress has been made in this area, and recently a surface charge/collector colloid adsorption model was proposed by Miller and his coworkers to explain the collector adsorption phenomena observed in soluble salt flotation systems (Milleret al, 1992; Yalamanchili et al., 1993; Miller and Yalamanchili, 1994; Yalamanchili and Miller, 1994a: Yalamanchili and Miller, 1994b). In this work, the sign of the surface charge of alkali halides in their saturated brines was established on the basis of nonequilibrium electrophoretic mobility measurements by laser-Doppler electrophoresis (Miller et al., 1992). Generally, these results are what would be expected from the simplified lattice-ionhydration theory. This electrokinetic information coupled with the stability and prevalence of collector colloids in such soluble salt flotation systems indicates that the selective flotation of alkali halides is due to the adsorption of oppositely charged collector colloids by heterocoagulation. Experimental flotation/bubble attachment results for 21 different alkali halides (Yalamanchili et al., 1993; Yalamanchili and Miller, I994b) confirmed that the flotation response of soluble salt minerals with weak electrolyte collectors can best be explained by the adsorption of oppositely charged collector colloids rather than by the adsorption collector ions and/or neutral molecular dipoles as originally suggested by many researchers (Fuerstenau and Fuerstenau, 1957; Schubert, 1967; Roman et al., 1968). In addition, the flotation of certain alkali oxyanions (Pizarro et al., 1993) and double salts such as schoenite and kainite can be explained by the same collector colloid adsorption mechanism (Miller and Yalamanchili, 1994). The borax flotation results reported by Celik et al. need to be examined in terms of the above mentioned surface charge/ collector colloid adsorption model. Unfortunately, the authors seem to be unaware of this recent work that nicely describes soluble salt flotation with weak electrolyte type collectors such as amines and carboxylates. In view of our past work, the flotation characteristics of borax were of particular interest, and, in this regard, the results of dodecyl amine flotation of borax reported by Celik et al. have been examined in further detail in the light of experimental results from our laboratory. In our research, a vacuum flotation technique was used to study the flotation response of borax (Na2B407.10H20), which has a solubility of 39 g/L at 25 °C) with dodecyl amine hydrochloride as collector. These chemicals were purchased from Eastman Kodak and used as received. Saturated solutions of borax at desired pH values were prepared by continuously stirring the salt solutions over a period of about 10 hrs. It should be mentioned that the conditioning time to achieve equilibrium is an important variable and can significantly change the flotation response of some soluble salts (Yalamanchili et al., 1993). Collector was added to the saturated borax solutions containing about one gram of 100x 150 mesh borax particles, and conditioning was done for about 20 minutes prior to flotation. The borax flotation recoveries from saturated brine are presented in Fig. 1 as a function of collector addition at the natural pH of 9.3, as reported both by Celik et al. and as measured in our laboratory. In addition, the region of precipitation for the dodecyl amine hydroborate is included in Fig. 1. It can be seen in Fig. 1 that the flotation response curves are separated by about one order of magnitude in R12NH3CI collector addition. The flotation results of Celik et al. show that the maximum borax recoveries can be obtained below the solubility limit of the dodecyl amine hydroborate collector. However, in our experiments borax flotation seems to occur only after the precipitation of the dodecyl amine hydroborate collector as might be expected from the collector colloid adsorption model (Yalamanchili et al., 1993) if borax were negatively charged. Further analysis by nonequilibrium and equilibrium electrophoretic mobility measurements for borax indicates that borax is negatively charged at the natural pH of 9.3, as discussed below. The reliability of the nonequilibrium electrophoretic measurements has been demonstrated previously for alkali halides and alkali oxyanions (Miller et al., 1992; Miller and Yalamanchili, 1994). The equilibrium and nonequlibrium electrophoretic measurements for borax were found to be consistent and are presented in Table 1. These results provide clear evidence that borax carries a negative surface charge in its saturated brine (pH 9.3), and the sign of the surface charge of borax reverses and becomes positive if the pH is reduced to 8.6. The equilibrium between borax and its saturated brine can be described by the following reaction: [2Na2B407.1OH2O-4Na++B407=+HB4O7 +OH+19H20] It appears that the oxyanions of the borax lattice provide

Jan 1, 1995

By R. K. Will

An inactive mining operation in northern California is known to be a source of acid mine drainage and heavy metals which have impacted adjacent creeks. Elevated concentrations of copper and zinc are a concern to aquatic populations, particularly steelhead trout and salmon downstream in the Sacramento River. Previous regional geological surveys of mineralization by the U.S. Geological Survey located and mapped outcrops of massive sulfides and gossan. Recent investigations indicate that a substantial amount of the metals in the local creeks are due to natural causes. The investigations include locating and mapping surface and subsurface minerals, soil and water sampling, and chemical analysis. Groundwater, seeps, and surface water were also sampled and analyzed. A water balance was conducted on a sub-basin level following delineation of surface water drainage and groundwater divides. A chemical mass balance incorporated metal concentrations and water volumes and was then used with other data to determine the contribution of metals from natural versus mining-related causes.

Jan 1, 1998

By O. J. R. Baena, I. C. Sánchez, J. L. G. Guzmán

Frontino, a municipality in western Antioquia, Colombia, has more than 200 years of mining tradition. Currently, mining activities are carried out for lode gold using subway tunnels, where the grinding of the material is done in "cocos", whose energy depends on internal combustion engines and ACPM, environmentally polluting and inefficient methods. In accordance with the Sustainable Development Goals as an initiative developed by the UN, different mining methodologies that are aligned with these are constantly being analyzed. This study proposes to eliminate the use of hydrocarbons in artisanal mining, mainly promoting Sustainable Development Goals 7, 9, 11, 12, and 13. This will be achieved through an energy transition to renewable energy sources that take advantage of the topography and water resources of the area, providing advantages to the communities that live there, such as lighting, electricity for cooking, ventilation for mines, etc

Mar 2, 2022

By Thomas A. Simpson

Heretofore, underground coal mines in Alabama have operated under only 60 to 360 meters of cover: however, new mines (at least 5 in the early opening or development stages) will be operating under cover ranging from 600 to 660 meters. With increased rock confining pressures, roof stability problems will become more critical. Initial studies in two 7 ½ -minute quadrangle areas in the Warrior coal basin of Alabama indicate that the orientation of certain lineament and fracture-trace modes mapped from ERTS-1 (Earth Resources Technology Satellite) imagery correlate closely with the strike of joint and fault modes. High altitude (118,000 m) U-2 aircraft data were used to support these findings. In addition, over 50 percent of the normal faults mapped in the study area could be directly correlated with ERTS and U-2 lineaments and fracture traces. These correlations provide clues to the structural development of the Warrior coal basin and may, in turn, be used as a guide to the prediction of roof-stability conditions in advance of mining.

Jan 1, 1975

By J. R. Maxwell

The development, commercial installation, and operating performance of large capacity Maxwell Flotation Cells. Volumes ranging from 300 cubic feet to 2,000 cubic feet per flotation mechanism.

Jan 1, 1971

By R. J. Bridwell

Acid mine drainage (AMD) occurs in high sulfur coal and heavy metal mining environments. We show remediation methods using 3D numerical ground water flow models and chemical kinetics of pyrite oxidation for acid leaching of pyrite during air and ground water flow. A recently developed numerical model couples air and water flow with kinetics of iron-reactive bacteria, oxygen transport, specific chemical reaction rates, and pyrite oxidation to calculate migration control of pollution. A model is presented which considers diminution of acid mine drainage in pyrite rich ore bodies by raising the potentiometric surface through a vadose zone to reduce acid mine drainage. A ground water model is presented of an initially saturated mountain, containing an adit, with a sloping ground water table. Ground water recharge consists of snowfall and normal precipitation. Simulations indicate that the historically open adit creates a desaturated mountain above the adit. Significant air saturation ranging from 10-90% oxygen can occur to depths of the adit (-270 m). Remediation consists of plugging the adit, which fill s adit and mountain with water from recharge. Plugging the adit required <10 years for resaturation and rise of the water table in the mountain.

Jan 1, 1994

By Luther W. Hyde

Ground water, one of Florida&apos;s most valuable resources, is also one of its most abundant. The State is fortunate to have several prolific ground- water reservoirs that yield tremendous quantities of water to wells and to some of the world&apos;s largest springs. These ground-water reservoirs, or aquifers are of two types artesian and nonarteaian. Ad artesian aquifer is one that contains water under sufficient pressure to rise above the top of the oontaining formation. A nonartesian aquifer is one that contains water which is not confined, and the upper water surface (water table) is free to rise and fall. The principal source of ground water in Florida is the artesian Floridan aquifer which supplies most of the water users in the State. Nonartesian sources include the Biscayne aquifer of southeastern Florida, the sand-and-gravel aquifer of extreme western Florida, and a shallow aquifer which lies at depths of less than 100 feet over much of the State. The accompanying map shows the approximate areas where these aquifers are the main source of supply; however, the boundaries do not represent the areal extents of the aquifers. For example, the Floridan aquifer extends beyond the southern boundary shown on the map, but it is not of great economic significance there because the water is highly mineralized. Aquifers other than the four described occur in the State, but they are, for the most part, of minor significance. One of these is an artesian aquifer which is formed by permeable zones that occur locally within the confining beds above the Floridan aquifer.

Jan 1, 1966

By Peter Cammack

Where raw coal from a mine is treated in dense medium separators ash in the washed product is generally very consistent, provided control of the medium suspension is maintained at a given specific gravity. When, however, the washing process is a Baum jig or other similar apparatus, making a separation at rather arbitrary gravities, the control of the product ash is less accurate, particularly in those cases where the design capacity of the washbox is exceeded by the load of high ash fines. In either of these cases an instantaneous measurement of ash while not essential would be desirable, to check the quality of the washed product and provide operator or management with instantaneous warning of changes in ash. Nearly 60% of all British coal mined goes for electricity generation, to burn at 17% ash, and since the overall average ash content of raw coal as mined is about 30% and varies within a range of 18 ? 40%, incombustible material has to be removed. The ash specification could be met either by total washing, or by washing part and blending the clean coal produced with the remaining untreated coal. Some plants use a straight tonnage split, but generally speaking in Britain it has been found more economical to screen and wash the oversize only. In either case for effective quality control in blending an instantaneous determination of the ash content of the product as it is made has been found essential, since standard ash determination by pyrolysis methods is lengthy and provides information too late to be used in the control of plants blending at the rate of 1000 ton/h.

Jan 1, 1976

By R. M. Cox

Pneumatic coal loading and conveying systems provide alternative methods for the safe and efficient mining of the thin high-grade coal seams found in the Southern Appalachians. Pneumatic systems eliminate most of the health and safety hazards associated with the operation of conventional mining and haulage equipment in small low-coal mines by removing powered mobile equipment from the mine. Ventilation is also improved by the coincidental removal of gas and respirable dust from the mine by the operation of the pneumatic loading and conveying system. Other significant advantages of pneumatic coal recovery systems are relative simplicity, operating flexibility, low capital cost, quiet operations, environmental benefits, and ease of automation. The design considerations and field evaluations of experimental prototype pneumatic coal loading and conveying systems, installed and operated in small thin-seam mines, are presented in this report. In addition, fundamental design criteria and recommendations for the installation and operation of a variety of pneumatic coal loading and conveying systems are proposed, which offer alternative coal recovery systems that alleviate the serious health and safety concerns of current small mine operations.

Jan 1, 1999

By Alessandro Navarra, Aldo Quelopana

For decades, open-pit mine planning algorithms have incorporated geological uncertainty and other elements or characteristics for increasingly realistic representations. Among these complexities is the detailing of downstream processes that occur inside processing plants. Previous studies have demonstrated that the strategic mine plan and mineral concentrator design are coupled, and should therefore be optimized simultaneously within the same quantitative framework. However, existing frameworks offer limited representation of operational modes. This work demonstrates an approach to resolving this gap, in an optimization based on a parallelized Variable Neighborhood Descent (VND). The resulting algorithm embeds mass-balancing linear programming (LP) using a DantzigWolfe decomposition. A case study of a Zn-Pb deposit is presented to show the performance reached.

Jun 25, 2023

By C. Haycocks

The evolution of longwall mining is briefly traced from its inception in England in the 1620&apos;s. In the beginning this method recovered 90% of coal with roof closure controlled by packs and walls. Mechanization began with kerf cutting, crude face conveyors, and improved face support. Full face mining was accompanied by the introduction of self-advancing hydraulic supports. U.S. longwalls evolved a retreating system to recover blocks of coal outlined by room and pillar panels. Computer control combined with the most modern technology has greatly increased productivity. Past trends are used to predict future technological directions.

Jan 1, 1997

By J. Wiebmer

Some thoroughbred racehorses are great routers (distance runners), others are sprinters. Some racehorses perform best on turf, others on dirt, and some in mud. To be a winner, you have to choose the right horse for the course. It&apos;s no different when looking at an electric cable shovel, a hydraulic shovel/excavator, or a wheel loader. Each loading tool has its own zone of application. To be a winner, you have to choose the right horse for your course.

Jan 1, 1993

By J. M. Mutmansky

This paper outlines patterns of methane emission in both longwall and room-and-pillar operations and the effects that these patterns have on the decision as to whether the methane is most economically handled by ventilation alone or by means of a methane drainage system in addition to ventilation. The costs of handling the methane in the ventilation system and the costs of implementing the methane drainage system will be discussed as well as the costs related to the production of coal. The important issue of production slowdowns and gas outs will also be discussed as well as the proper response of mine management to such a situation. Suggestions concerning the keeping of production records related to methane problems will be made as well as justification for more intensive economic analysis of coalbed methane extraction and utilization.

Jan 1, 1998

By John O. Marsden

"This article is an attempt to capture a presentation given at the 2016 SME Mineral & Metallurgical Processing Division (MPD) Luncheon held on Feb. 24, 2016, in Phoenix, AZ. It was presented as a tongue-in-cheek, lighthearted view of several of the issues facing our industry, while identifying some of the challenges and opportunities available to new engineers entering the industry today.Disclaimer• What you are about to read includes personal preferences, biases and occasionally arbitrary opinions.• Some readers may have dissimilar opinions on the contents and/or the rank order of the lists.There are eight top ten lists offered in this article: (1) Industry realities (2) Things a metallurgical or mineral process engineering graduate should do (3) Books every metallurgist should have on their shelf (4) Things I wish I had known (5) Legends of metallurgy (posthumous, with highlights) (6) Things we’ve forgotten (7) Mineral processing innovations of the past 20 years and, finally, (8) The future? For some items, additional context or clarification is provided after the item, while for other items no further explanation is warranted and none is offered. Top 10 industry realities1. Metal price cycles.2. Bigger is better (except when it isn’t).3. Ore grades declining across the board of metals/commodities.4. Ores becoming more complex.5. Three-fold increase in capital costs between 2004 and 2015.6. Three-fold increase in operating costs between 2004 and 2015.7. Less capital availability/challenging financial markets.8. Environmental constraints increasing.9. Socio-political constraints increasing.10. The mine manager is always impossible to work with.As Table 1 shows, there was more than a three-fold increase in gold operating costs between 2004 and 2014. The increases for copper, iron ore and other commodities were similar."

Aug 1, 2016

By Shiou-Chuan Sun

The froth flotation of coal, differing greatly from that of most minerals1-5, is not improved but rather impaired by temperatures higher than room temperature6-10 This phenomenon has long taunted us for an explanation. Gayle and Associates 8,9 reported the lack of relationship between their contact angle measurements and their flotation of American coals under various temperatures. Bailey and Whelan6 stated that the viscosity of flotation reagents, offering some clue for their flotation of British coals at low temperatures, could not be put forward as an explanation either in whole or in part for the effect of temperatures on coal-flotation. In this paper, a froth hypothesis is proposed to explain the flotation behavior of coals under various pulp temperatures. Test work involved the flotation of coals and the frothing of reagents.

Jan 1, 1966

By C. N. Bensley, S. K. Nicol, R. Lamb, G. W. Kidd

Flotation circuits in the metalliferous industry recover high value concentrates from very fine (minus 0.lmm), low grade, slow-floating feeds. Flotation columns acting as final cleaners within these circuits offer the benefits of higher grade concentrates, reduced circuit complexity, improved control and reduced power consumption. By contrast, in the coal industry, these benefits have not been realised, principally because columns are not well suited to the treatment of conventional coal flotation feeds (minus 0.5m). However, this does not imply that columns do not have a place within the coal industry, rather that they must be applied in a role where all the unique advantages of column flotation can be of benefit. The development of a commercial scale column to recover discarded ultrafines from the Riverside preparation plant of BHP-Utah Coal Limited is discussed. Particular emphasis is placed on the column design features pertinent to the recovery of ultrafine coal. Pilot and commercial scale column performances are compared. The results of the commercial scale testwork indicate that a full installation at the 5.5 MTPA Riverside plant would annually recover additional coal worth $US 6.6M.

Jan 1, 1988

By N. Arbiter

The theoretical analysis of tumbling mill energetics and performance has largely neglected mill dimensionality, and, in particular, the importance of the length/diameter ratio. This is in spite of the fact that practice varies substantially in this area: geographically, for semi-autogenous and autogenous mills, as between North America and South Africa/Scandinavia; historically, for overflow ball mills, for which the L/D ratio has increased significantly from the earliest small mills to/the largest mills currently. The present study is concerned primarily with the influence of the L/D ratio on the design and operation of overflow ball mills; on the occurrence of the overload phenomenon; and on the limits, if any, it may impose on mill capacities because of critical pulp axial velocity limits. It will be shown that the shape face or is of major importance in this area; and that its adjustment to the extent that this is practical should remove the diameter limitations previously postulated for this mill type.

Jan 1, 1990

By F. E. Senftle

Preliminary geophysical surveys for nickel deposits are usually carried out by airborne magnetometer and surface electrical methods. Once an anomaly is discovered by these techniques, one must resort to chemistry to identify nickel and determine its concentration. Consequently, a method to determine nickel quickly and quantitatively at the exploration site could help guide detailed sampling and provide analytical data that might otherwise be delayed at distant laboratories. In addition, borehole probes capable of indicating nickel in the rock adjacent to the hole, should prove attractive to the exploration geologist. With these needs in mind, preliminary investigations have been made to demonstrate an in situ analytical technique which appears feasible for nickel exploration. The method depends on the very high energy gamma rays emitted when nickel absorbs a thermal or low energy neutron. These neutron capture gamma rays should be distinguished from the lower energy gamma rays emitted during decay of radioactive nuclides as in conventional activation analysis.

Jan 1, 1971

By Y. C. Lo

This paper presents the development of ultrasonic grinding technology for material and mineral processing. The principles underlying this new technology, as well as their implementation in two laboratory scale devices are described in detail. Ultrasonic grinding experiment results are discussed with respect to operating variables and the achieved product sizes. Special attention has been given to the electrical energy consumption of the grinder, and an attempt to compare its efficiency with tumbling mills has been made. A mechanical system capable of measuring the specific grinding energy is also described.

Jan 1, 1991

By Keith G. Wallace

Coal mine ventilation systems are often subject to high leakage rates. As a result, changes in airflow resistance will strongly affect the efficiency with which air is delivered to the working place. One major source of airflow resistance is the line brattice used to direct air from the last open crosscut to the working face. Because it is a great distance from the fan, the resistance of the line brattice can result in more overall leakage than an equivalent resistance closer to the fan. Substituting auxiliary fans for brattice eliminates this source of resistance, with improvements in system efficiency and cost. Also, in some mines, the leakage that leads to spontaneous combustion can be reduced. The benefits obtained by several different brattice and fan substitutions have been studied by Mine Ventilation Services, Inc., under contract to the Bureau of Mines. Changes in main fan duty were compared with additional costs associated with auxiliary fans. Results indicate that in some circumstances, considerable leakage reductions and cost savings are possible.

Jan 1, 1986