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The kinetics of adsorption of gold di-cyanide onto activated carbon has been investigated extensively over the past two decades. These studies have demonstrated that both film and intra-particle mass transfer affect the kinetics. The dominant mechanism of intra-particle mass transfer has not yet been identified. In the work described, surface diffusion and pore diffusion are considered as possible rate-determining mechanisms of intra-particle mass transfer. Mathematical models are described that incorporate film mass transfer and the respective intra-particle mass transfer mechanism with equilibrium described by a Freundlich isotherm. Rate constants of film mass transfer and pore or surface diffusivities were estimated by the fitting of the respective models to experimental carbon adsorption data. The estimated pore diffusivities, after they had been corrected for the porosity and tortuosity of the carbon, were found in most instances to be higher than the molecular diffusivity of dilute gold di-cyanide in aqueous solution. This situation is not physically viable. The surface diffusion mechanism acting in parallel with the pore-diffusion mechanism is thus responsible for the intra-particle transportation of most of the gold.

Jan 1, 1996

By G. C. Howell, H. A. D. Kirsten

The mining-induced effects around narrow tabular stopes have traditionally been evaluated in terms of elastic continuum analyses. An understanding of the phenomenological behaviour of the rock surrounding deep-level gold mines has accordingly been developed on the basis of such analyses. However, elastic analyses do not afford reliable representations of the behaviour of rock in which failure may occur on discontinuities. This paper describes investigations that show how the stress and stiffness characteristics of a rockmass are affected under such circumstances for representative ranges of values for the relevant parameters (depth, span, support stiffness, field stress ratio, and discontinuity strength). These investigations afford a substantially different understanding of the mechanical behaviour of rock that is subject to failure. Instead of forming an arch across the abutments, the rock in the hangingwall bears directly across the stope onto the footwall and, instead of being subjected to tension, the nether hangingwall is clamped in compression in the horizontal direction.

Jan 1, 1993

By J. W. Wilson, P. C. Graham

Raise-boring experiences in the gold mines of the Anglo American Corporation Group by J. W. Wilson M.Sc., M.I.M.M., F.S.A.I.M.M., M.A.I.M.E. and P. C. Graham M.Sc. (Eng.) Gold mining is being carried out at ever-increasing depths in South Africa. For reasons of safety and human comfort, it is becoming imperative for raises to be developed by means other than conventional drilling and blasting. Raise-boring is an attractive alternative method. Initial raise-boring experiences in South African gold mines showed disappointingly high costs due to the abrasivity and difficulty of drilling Witwatersrand quartzites. Consequently, a research and development project was instigated with the objective of making raise-boring an economically viable technique in hard abrasive rock. A Robbins 61R raise-borer was made available to the Research and Development team and a number of raises have been drilled. During these trials two advances in cutter design were tested. This paper presents the results obtained, including drilling costs, and provides details of the equipment used.

By R. G. B. Pickering, H. H. Haase

Few innovations in the South African gold mining industry could have a more significant impact on improving profitability than non-explosive methods of mining. The far-reaching benefits of this approach are explained and the progress made through development work funded by the industry is described. Three methods are considered: impact ripping, sloting with abrasive waterjets and diamond saws, and breaking from drilled holes with waterguns and electric pulses. Of these methods, impact ripping is the most advanced and requires only minor refinements before production applications can be initiated. Although this method, based on current performance, is expected to yield considerably increased profits, it is predicted that it could perform several times better than at present with further development. The other methods of rockbreaking also show potential. Waterguns and electric rockbreaking would be attractive in unfractured rock for difficult geological conditions, and for confined areas such as gullies and development ends. Methods based on sloting could be combined with any of the other methods to enhance their effectiveness and thus yield further improvements in profitability; also, they could be used to advantage in specific applications. Al the discussed methods, therefore, deserve to be developed further.

Jan 1, 1991

By F. L. D. Cloete, A. K. Haines, T. D. Sampson, T. H. Tunley, W. A. M. te Riele

The recovery of zinc from pickle liquors by ion exchange A. K. HAINES. Ph.D. (Visitor) T. H. TUNLEY. B.Sc;.(Chem.Eng.)(Visitor), W. A. M. TE RIELE. pr, Eng.. Ph. D. (Visitor), F. L. D. CLOETE. M.Sc. (Chem..Eng.)(Visitor), and T. P. SAMPSON. Pr. Eng.. BSc, (Chem.Eng,). B. Econ. (Visitor) Picklers and galvanizers in and around Johannesburg are encountering an ever-increasing problem in disposing of spent liquors from their hydrochloric acid pickling baths. Particularly troublesome is the zinc-contaminated liquor that is produced as a result of the clean-up of rejects from the galvanizing operation. Because of the volatility of zinc chloride. this liquor presents difficulties when processed in a conventional pyrohydrolysis acid-recovery unit. The paper describes the Metsep Process. developed by the National Institute for Metallurgy and Woodall-Duckham S.A. (Pty) Ltd. which involves the use of continuous ion exchange for the separation of the zinc from the pickle liquor. and the use of liquid-liquid extraction for the conversion of zinc chloride eluate to salable zinc sulphate. A description of laboratory and pilot-plant tests is given. and the approach used in the design of a full-scale continuous- ionexchange plant is outlined.

Jan 11, 1973

By P. R. Janisch

This paper reviews the sources, production, and technology of gold in South Africa. First of al it details the geographical distribution of gold-bearing materials, together with the mineralogy and distribution of gold within those materials. It goes on to the geological origins, and to the discovery and early exploitation, of the gold deposits. The laws relating to the mining and disposal of the metal are explained, after which an outline is given of gold exploration, processing, and refining. The economics of gold production are discussed briefly, and it is concluded that, although present expertise in the financial and technological aspects of a gold-mining venture have largely reduced the risks involved, one severe risk remains: that the rate of cost inflation will not be matched by the rate of escalation in the gold price.

Jan 1, 1986

The Annual General Meeting of the South African Institute of Mining and Metallurgy was held in Kelvin House, Johannesburg, on Wednesday, 27th August, 1980. Mr D. A. Viljoen (President) was in the chair and declared the meeting open at 4.05 p.m. Obituaries President: It is my sad duty to announce the death of the following members of the Institute: T. C. A. Meyer (Past President, 1941 to 1942); E. G. Harding, T. A. Stannard, C. T. Hardy, W. C. Jackson, J. S. Sinton, G. H. Duggan, H. H. A. Muller (Life Fellows); W. M. Frames, K. Gebhard, W. M. Walker, S. L. S. Swart, N. W. Stansmore, H. E. Allen, B. W. F. Towne, R. A. Wilson, D. Waterman (Fellows), R. M. Peterson (Life Member); D. L. Gibbs (Member); B. M. Williams (Asso¬ciate Member); D. B. T. Cresswell, P. G. Guernier (Associates). As a mark of respect to the memory of the deceased, and in sympathy with the bereaved, please rise and observe a few moments of silence. Notules President: Kan ons die notules van die Algemene Jaar¬vergadering, wat op 22 Augustus 1979 gehou was en in die September uitgawe van ons Joernaal gepubliseer is, bevestig? Bevestig.

Jan 1, 1980

By J. A. C. Diering

All underground openings are three-dimensional, and in many cases it is not valid to analyse two-dimensional sections. This has been a problem in the past owing to the magnitude and complexity of three-dimensional stress analysis. In this paper a three-dimensional boundary element approach, using non-conforming quadratic elements, which is specifically applicable to underground excavations, is described. In addition, the philosophy of application of stress analyses is discussed. Three case histories are presented to demonstrate the practical nature of the approach as a tool in solving mining problems.

Jan 1, 1987

By A. J. Feltenstein

A theoretical model for prediction of dissolved gold loss from a rotary vacuum filter was developed as part of a program to implement optimizing control on gold plants The filter was modelled using a modification of the Hagen-Poiseuille equation and the Choudhury and Dahlstrom washing equation. The model has three parameters which must be determined from accumulated data before predictions can be made. These are the cake and cloth resistances and the filter washing efficiency. The model predicts with a fair degree of accuracy the response of the filter to changes in the independent variables and will therefore be a useful tool in the plant optimization study.

Jan 1, 1987

By J. W. Wilson, J. G. Taylor

The mechanization of haulage drilling in the gold mines of Anglo American Corporation by J. w. WILSON, Ph. D., C.Eng., M.AIME, F.!.Min.E., F.I.M.M. (Fellow), and J. G. TAYLOR, A.C.S.M., C.Eng., M.!.M.M. (Visitor) Some one-thousand kilometres of tunnels are mined annually in the gold mines of South Africa. Until two years ago, mechanized drilling on South African gold mines was not an economic proposition because of the availability of inexpensive labour and the fact that mechanized equipment developed for other mining markets could not perform satisfactorily in the tough, abrasive quartzites of theWitwatersrand System. A project team from the Technical Development Services Organisation of the Anglo American Corporation, in collaboration with various manufac turers of drill rigs and drill steel, has been concerned with the development of suitable equipment for mechanized main-haulage drilling. After two-and-a-half years of extensive testing and development of drifters, drill steels, and bits, many of the problems encountered have been sotved, and gradually jumbos mounting pneumatically and hydraulically powered drifters are being phased into production on various gold mines of the Group. A description of the development work is given, and actual operating results are recorded, together with details of the drilling and blasting techniques used.

Jan 1, 1975

By Ralph H. Nafziger

This paper reviews the major deposits of lower-grade chromite in the world, and a wide variety of methods used for the recovery of chromium from them. Gangue materials in more coarsely sized ores can be separated by gravity means, whereas flotation techniques are required for finer-grained materials. However, unless there is considerable Iron In the ores, physical means cannot increase the Cr/Fe ratios. Chemical techniques such as hydrometallurgical methods, chlorination, roasting and leaching, and smelting are required for this purpose. A greater understanding of the physical properties of chromites and the chemical reactions that take place in the recovery operations is required before. the recoveries from lower-grade chromites can be maximized. More efficient recovery operations can be realized If It can be shown definitively that the reduction of chromites occurs via either a gas-solld or solid-solid mechanism, for example. The effects of specific impurities on the chromite reduction reactions need to be better understood, as do reagent and pH control in the flotation of chromite.

Jan 1, 1982

By M. David

This paper addresses the problem of technological transfer in geostatistics. Expert systems have become popular in certain fields because the needs of the industry are not provided for by traditional concepts and systems of education. The explicit knowledge approach in developing expert systems is presented through two experiments. The first describes a dedicated system written in GOLDEN LISP and the second a shell, using INSIGHT2, which has more general applications. Using expert systems forces on the user a new approach to parameter definition, and as an example an original method for the research of any anisotropy axes is developed which might well be useful in traditional programming. Two examples of application to a coal and a gold deposit are given.

Jan 1, 1987

By R. K. Brummer

A simplified two-dimensional plane strain numerical technique for the non- linear modelling of a tabular mining excavation in brittle host rock under high stress conditions is described. The model has been developed using relatively straightforward assumptions based on extensive underground investigation of the fracturing and deformation of rock at the stope face in deep gold mines on the Witwatersrand, together with observed rock behaviour under laboratory conditions. The reef rock is modelled as a linear string of yielding elements which interact horizontally, while the elastic rockmass remote from the reef is modelled using boundary element techniques. This elementary technique is shown to produce results which agree closely with the observed behaviour of the fractured rock during the mining of a remnant pillar

Jan 1, 1987

The auriferous Carbon Leader reef which is the subject of this study can be subdivided into two types of sedimentological units, each with its characteristic spatial variability. For the longwall mining method applied at Western Deep Levels gold mine, subdivision of the orebody improves the estimation of the actual error variance, but not the grade estimates themselves. This can only be achieved by choosing oreblocks of a size and shape that are maximal parallel to the longwall and minimal at right angles to it, within the limits of mining restrictions. While simple kriging is the only method that gives unbiased results, the difference between untransformed and logtransformed kriging is negligible.

Jan 1, 1987

By M. H. Moys

The capacity of grinding mills can be maximized by use of measurements of mill power and bearing pressures. The criterion is as follows. If the derivatives with respect to time of the power and bearing pressure signals have the same sign, the volume of the mill load is smaller than the optimum value; if they have different signs, the volume of the mill load is greater than the optimum value. Few attempts have been made to use measurements of bearing pressure in the estimation of absolute values for the parameters that define the state of the mill load (e.g, mass, volume, and dynamic angle of repose) because the bearing-pressure signal is a complex function of these and other parameters. This paper gives a mathematical model that relates bearing pressures to these parameters. The theoretical values obtained from this model are compared with experimental values, and it is concluded that the model constitutes a good description of experimental reality. If accurate measurements of the load supported by each bearing are available, the model can be used in the estimation of the mass of the load in the mill. If independent estimates of the volume of the load or the dynamic angle of repose are available, the other parameter can be estimated from measurements of the bearing loads.

Jan 1, 1980

By L. A. Vermeulen, D. D. Howat

New distribution functions are derived to describe the size distribution of grinding elements in ball mils. The formulations are based on the assumption that abrasive as well as impactive interactions occur during bal milling-an assumption that is supported by a large body of experimental evidence. It is shown that the functions can be used in the estimation of the magnitudes of abrasive and impactive components in the total rate of bal wear. The relative magnitudes of the wear components provide a basis for optimization of the chemical and metallurgical properties of the balls in a given milling situation. However, it is contended that these quantities are also useful indicators of the relative intensities of the abrasive and impactive interactions that are operative in the size reduction of mineral particles within ball mils. These quantities can be determined for any industrial ball mil, and their magnitudes provide practical guidelines for mil operation. The theory is used in an analysis of samples of ball charges from two industrial ball mils, and it is also applied to al the data on bal-size distributions found in the literature. The qualitative correlation between the calculated values of the wear components and the reported operating conditions is good for a variety of industrial ball mils, in conformity with the hypothesis that the relative magnitudes of the wear components are related to the milling conditions.

Jan 1, 1986

By M. A. de Ruijter

Bracken Gold Mine ceased mining operations during February 1993. The clean-up of the gold plant, which had already commenced in September 1992, was completed in January 1994. The mine had been in production since early in 1962 but, because of a decreasing ore reserve, increasing working costs, and a relatively low gold price, closure had become inevitable. The closure had been under consideration since August 1983, when the first estimate was made regarding the amount of gold that could be recovered from the clean-up operations. Until that stage, it had been accepted that Bracken would conform to the commonly accepted idea that 0.25% of the total gold produced by the plant would be recovered during the clean-up operation. This idea was dispelled when the initial estimates indicated that the gold recovery would vary between 0.049 and 0.095%. The actual figure realized was 0.036%, showing that there is no generalforl1ula for the calculation of the amount of gold to be recovered from such clean-up operations. During the clean-up operation, Bracken became an unexpected contributor to the State's Reconstruction and Development Programme by having al the mine and plant buildings purchased and converted into a community development centre. This shortene4 the time available for the clean-up, and several of the buildings remained intact. However, the foundations and sub-soils had been sampled extensively, and it is considered that no recoverable gold was left behind.

Jan 1, 1996

By L. C. Stilwell

The paper will place into perspective the contribution that platinum makes to the South African economy. It will use statistics from official sources, namely the Department of Minerals and Energy, the Department of Customs and Excise, the South African Reserve Bank and Statistics South Africa. Surprisingly few people are aware of these statistics, especially Supply and Usage tables, published by Statistics South Africa, and trade statistics, published by the Customs and Excise division of the South African Revenue Service. The paper will therefore contain a concise explanation of input-output tables and supply usage tables, as well as the derivation of gross domestic product and an outline of the System of National Accounts, of which Input-Output Tables and supply and usage tables are components. GDP is a commonly used, but poorly understood, measure of the wealth of an economy. The paper will explain the methods used by SSA to calculate this indicator and its place in the System of National Accounts (SNA). South Africa exports almost all its platinum production (87.5% in 2002). Exports are a final demand, as opposed to intermediate demand from secondary industries, and therefore do not enter the value-adding process, which is the essence of GDP. By definition, therefore, platinum on its own is not a major contributor to GDP. The platinum industry does, however, have an impact (known as the multiplier effect) on other sectors of the economy. The paper will explain the meaning and derivation of these multipliers, using a model based on an Inverse Leontief Matrix.

Jan 1, 2004

By F. Lombard

We consider in this paper the use of a modified version of Hotelling?s statistic in the analysis of particle size distributions. The statistic can be adversely affected by the presence of outliers among the data. We propose a competitor to the statistic that is based on ranks, and hence is less sensitive to outlier effects. The results of a Monte Carlo study suggest that the rank test is highly competitive with the Hotelling test in its ability to detect differences between two mass size distributions. The calculation of the rank statistic is explained in detail and its application is illustrated on two sets of data.

Jan 1, 2012

By P V. Savage, T Glück, RCA Minnitt, C Bothma

Manganese Metal Operations ?Manganese Metal Company (MMC), a subsidiary of Samancor BHP Billiton, has two production facilities for electrolytic manganese metal in South Africa and produces a range of about 44 Mn metal products. ?The company is accredited with ISO 9000 and uses Six SigmaTM for continuous improvement. ?The control of the process relies on the effective functioning of approximately 250 different control loops at 50% automation.. ?Approximately 50000 samples are analysed every month. ?There are pyro, hydro and physical unit operations for the production of electrolytic manganese metal flake and value added products ? [ ]

Jan 1, 2005