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By S. R. Zimmerley, John Gross

"The investigation discussed in this paper was undertaken to obtain fundamental data on crushing and grinding and has been confined, so far, to work on quartz.The results of crushing or grinding have hitherto been judged entirely by the amount of the various-sized particles produced, based. on sieve sizing for particles above 74 microns in size and on microscopic measurement or elutriation for particles below 74 microns - a method which could give only a general idea of what had been accomplished.There was a distinct need of a ""yardstick"" for the measurement of crushed material. It appeared that no advance in the fundamental investigation of crushing and grinding could be made without a reliable method of surface measurement and that such a measurement would have to be based on some property of the surface of the crushed material.A number of attempts based on various surface actions, such as adsorption and heat of wetting, were made to measure surface on quartz particles, but all gave unsatisfactory results. After some preliminary work it was decided that a dissolution method based on Wenzel's law-- ""the reaction velocity between solids and liquids is proportional to the area. of contact""4 -- would be the most feasible.Early use of the dissolution method had been made for surface measurements5, and lately Dr. Geoffrey Martin and his coworkers in England used the dissolution method to determine surface on quartz. They compared the amount of quartz dissolved from a sample in one hour by a hydrofluoric acid solution, with the amountdissolved from a measured quartz cuboid6,After investigating the solvent power of sodium carbonate, sodium hydroxide, and hydrofluoric acid for quartz, hydrofluoric acid was selected as the most suitable solvent, and a dissolution method was developed which gives very reliable results.During the dissolution of quartz in hydrofluoric acid, the reaction velocity changes for two reasons: there is a change in concentration of solution, and a change of surface of the solid. The amount of quartz dissolved in a definite period of time is therefore not a true measure of surface. If, however, the reaction velocity or rate of dissolution for various periods of time be plotted, a curve will be obtained which, if extrapolated to the zero time ordinate, will give the rate of dissolution before any change of surface or any change in the solvent has taken place, and which is a true index of surface. This rate of dissolution, expressed in percentage of the original sample at the zero time ordinate, is designated herein as the ""Initial Rate"" or as simply ""I. R."""

Jul 1, 1928

By Kevin Connor

The Government's ban on all commercial mining operations, except for small-scale artisan exploitation of alluvial gold deposits, continued throughout 1985. Minerals produced were kaolin and lime for agricultural uses, and experimental peat harvesting for energy applications. The total value of the minerals produced during the year was estimated at $1.1 million .2 In early 1985, an agreement between the Government and Amoco International Oil Co. was ratified for a petroleum exploration concession covering 248,000 hectares of Lake Tanganyika. Onshore exploration in the Ruzizi Plain was already under way the last half of 1985. By yearend, enough seismic information was available that Amoco hoped to complete data analyses, determine onshore drilling sites, and begin drilling operations before the end of 1986. Also to begin in the latter part of 1986 were seismic studies of Lake Tanganyika. Throughout 1985, Amoco officials were negotiating with the Government of Zaire for expanding the exploration acreage into that country's portion of northern Lake Tanganyika and the Ruzizi Plain. An agreement between Amoco and Zaire could have important beneficial economic implications for both Zaire and Burundi, and onshore seismic work in Zaire logistically supported from Bujumburi could begin almost immediately.

Jan 1, 1987

By Thomas V. Falkie, R. Venkataramani

The empirical nature of this investigation required measurements of variables under operating conditions in underground coal mines. The variables to be measured were based on the postulated character¬istics of the loading function, as described in the previous chapter. One class of variables presumed to influence the loading function are geological variables. Accordingly, the sites for data collection were selected in different bituminous coal seams at dispersed locations in order that variation in geological conditions would exist. Seven mines in central and western Pennsylvania and one mine in northern West Virginia were selected as data collection sites. Five different coal seams were represented by these mines. The remaining classes of variables - geometric, mechanical, and procedural - were measured as they occurred in the mines. A description of the measurements, and the conversion of these measurements to forms which could be-analyzed for effect on the loading function is given. Mining Dimensions At the underground working face, the following dimensions were measured: a. Thickness of coal excavated. b. Thickness of shale excavated. c. Total height excavated. d. Width excavated. e. Depth of penetration of each machine cut. With the exception of the last of these dimensions, all were measured

Jan 1, 1972

By Thomas M. Barczak

The success of longwall mining can largely be traced to the development of powered roof support systems. The most significant improvement in powered support design has been the shield support, which improved kinematic stability and promoted the application of longwall mining in difficult-to- control caving conditions where chock and frame supports were inadequate. The most obvious trend in shield design has been an increase in shield size and capacity. This U.S. Bureau of Mines report examines shield design and operation practices and their consequences for the utilization of high-capacity shield support systems. An optimization goal is to minimize support loading by selecting an active shield setting force that is compatible with strata behavior and shield loading characteristics. Shield stiffness is an important design parameter that is often overlooked. A consequence of increasing shield capacity by incorporating larger diameter leg cylinders is a proportional increase in shield stiffness. Setting forces have also increased in direct proportion to the increase in shield capacity. The increased stiffness and higher setting force cause the available capacity to be consumed more quickly, severely limiting the ability of high-capacity supports to last longer and provide reserve capacity for difficult mining conditions.

Jan 1, 1992

By Thaddeus B. Evans

This information circular is one of a series describing mining methods and costs, being published by the Bureau of Mines. The Sunbright mine of the Foote Mineral Co. at Sunbright, Va., is the southernmost underground limestone mine in the State. It is a comparatively recent operation, and a description of its rapid development to production stage may have particular interest for the limestone-mining industry. ACKNOWLEDGMENTS Acknowledgment is made to the executives of the Foote Mineral Company including F. B. Shay, vice president in charge of production, W. B. Towner, general production manager; and to the members of the company staff at Sunbright for their assistance in preparing this paper.

Jan 1, 1957

By E. G. King

Heats of formation of three crystalline oxides of rhenium (Re02, ReO3 and Re207) have been determined by the method of solution calorimetry, using an aqueous perchloric acid--ceric perchlorate solvent. Copper metal and cupric oxide were utilized as auxiliary substances. Heats were determined at 298' K for the reactions Re + 2CuO = Re02 + 2Cu, Re + 3CuO = ReO3 + 3Cu, and 2Re + 7CuO = Re207 + 7Cu. Standard heats of formation were derived using the value of -37.23 ±0,15 kcal/mole as the heat of formation of CuO. The standard molal heats of formation of the rhenium oxides were determined: Re02, -107.3 ±0.8 kcal; ReO3, -140.8 ±0.9 kcal; and Re207, -301.9 ±1.8 kcal.

Jan 1, 1969

By M. J. Ferrante

Low-temperature heat capacities and high-temperature enthalpies for syn¬thetic Cu2S and CuS were measured. This investigation is part of the Bureau of Mines goals to provide thermodynamic data essential to the more efficient processing of copper ores, and thereby minimize the current dislocations in energy, environment, and mineral supply. Heat capacities were measured with an adiabatic calorimeter from 5 to 310 K, and resulted in S°298 = 27.76 for Cu2S(c) and S°298 = 16.05 cal/deg mole for CuS(c). Low-temperature values are tabulated for Cp°, S°, -(G°-Ho°)/T, and H°-Ho°. Enthalpies were measured with a copper block calorimeter from 298.15 to 1,600 K for Cu2S(c,1) and 298.15 to 780 K for CuS(c). The thermal behavior of CuS showed no transitions or other significant anomalies for the low- or high-temperature investigations. Cu2S showed reversible transitions at 376 K with an isothermal heat absorption of 0.865 kcal/mole, 720 K with an isothermal absorption of 0.280 kcal/mole, and approximately 1,400 K (congruent melting point) with a heat of fusion of 3.070 kcal/mole. High-temperature data are tabulated for H°-H°298, Cp°, S°, and -(G°-H°298)/T. Enthalpies are also expressed in equation form. The low¬and high-temperature data were combined with data from the literature to cal¬culate and tabulate ?Hf°, ?Gf°, and log Kf as a function of temperature.

Jan 1, 1978

By W. H. Engelmann

The electrokinetic (zeta) potentials of a charcoal granite in an aluminum chloride (AlCl3) solution and in an oleylanunonium acetate (C18H35NH3+ -OCOCH3) solution have been correlated with the specific damping values as measured by the pendulum sclerometer. This investigation shows that the pendulum specific damping attains a minimum at the isoelectric point for the charcoal granite-aluminum chloride and charcoal granite-oleylammonium acetate systems, and thus indicates that the penetration of the diamond points is a maximum at the isoelectric point.

Jan 1, 1967

By Fred N. Kissell, Maurice Deul, T. D. Moore

Methane emission from two surface gob-degasification boreholes was measured by the Bureau of Mines. The investigation took place during mining of a 3,200-foot longwall panel in the Lower Kittanning coalbed in central Pennsylvania. The first hole was 500 feet from the start of mining, and the second hole was 2,200 feet. The first hole went on natural draft as soon as the longwall face passed it. This caused the methane flow in the return entries to drop 75 pct. In the 6 months required to complete the panel, the two holes emitted 69 MMcf of methane in varying percentages of concentration in air. In 3 years, the holes emitted a total of 150 MMcf of methane.

Jan 1, 1976

By Paul W. Jeran, Michael A. Trevits, William P. Diamond

In this U.S. Bureau of Mines study, production trends have been analyzed for 82 gob gas ventholes on 7 longwall panels in the Lower Kittanning Coalbed, Pennsylvania. Cumulative production from individual holes was found to vary considerably, ranging from 0.03 x 106 to 10.1 x 106 m3. Peak production rates were generally about 0.03 x 106 to 0.06 x 106 m3/d, but rates over 0.10 x 1@ m3/d were observed. The variability of gas production from individual holes can be attributed to several factors, including completion practices and problems, the extent of fracture development in the strata above the extracted panel, water production, and location on the panel. Of particular significance is hole location. Holes on the ends of the panels, where overburden strata are in tension because of the support of the surrounding pillars, were generally the highest and longest producers. This observation led to the experimental placement of gob gas ventholes in the zone of tension along the margin of a panel, instead of in the traditional centerline location, which is in compression. Analysis of 7 months of gas production data indicates that the experimental near-margin holes produced 77 pct more gas than did centerline holes on the same panel.

Jan 1, 1994

By A. L. Johnson

In this Bureau of Mines report, time-resolved infrared emission spectra and corresponding pressure and temperature histories are reported for large-scale propagations of CH4-air, CH4-air-N2, and CH4-air-CF3Br ignitions in a 12-ft-diam sphere. Absolute spectral radiances were obtained throughout combustion over the 1.6- to 4.8-gym range, and the radiance growth patterns for the H20 (2.5-µm) bands are presented as a function of methane stoichiometry and diluent concentration. Flame temperatures were determined from the C02-band emissions, which approximated unit emissivity shortly after ignition. Burning velocities are also given for some of the test-mixture compositions. Measured flame temperatures were in excellent to fair agreement with theoretical adiabatic values for the CH.-air and CH4-air-N2 mixtures; the best agreement was for the stoichiometric CH4-air mixture. The CH4-air-CF3Br mixtures with =2 pct CF3Br gave poor agreement with theory. The measured temperatures were significantly lower during the early stage of combustion; furthermore, the later stage of combustion was uninhibited and yielded unexpectedly high pressures. Supplemental data from a 2-ft-diam sphere at various initial pressures confirmed that the CF3Br inhibition effectiveness decreases with increased pressure. The possible effects of buoyancy, turbulence, and changing kinetics are discussed.

Jan 1, 1977

By Fred N. Kissell

Methane flows and pressures were measured in mines in the Pittsburgh, Hartshorne, and Pocahontas No. 3 coalbeds. From the data, the permeability of each of these coal beds was computed. It was found to depend strongly on the type of coal and on the amount of water in the coalbed, and it was found to increase with time. All of the coalbeds had a high-permeability zone adjacent to the face or rib, and the Pittsburgh bed exhibited directional anisotropy. Surprisingly, little or no overburden effect was observed.

Jan 1, 1972

By F. D. Wang

The Bureau of Mines has developed a computer program for evaluating pit slope stability by the finite element stress analysis and limiting equilibrium method. The program includes the finite element method of stress analysis using triangular elements, finite-element model mesh generation, plotting of the model mesh and stress contours, calculation of a factor of safety along a circular or a plane failure surface, and location of a critical circular failure surface. Instructions for preparation of input data, an example problem, and the program listing are presented.

Jan 1, 1972

By Roy H. Grau, John C. LaScola

"This Bureau of Mines report contains a tabulation of methane emissions during 1980 for all coal mines located in the United States with emissions greater than 0.1 MMcfd. Listed for each mine are methane emission quantity, location, and coalbed. The report also compares records of 1975 and 1980 and describes relationships between emissions in 1980 and the Bureau's coalbed gas content data on 11 mines.INTRODUCTIONMethane gas is a threat to safety in underground coal mines. Research by Government and industry has led to great gains in reducing methane gas ignitions and explosions. The development of advanced methane control techniques is necessary for the safe operation of more gassy mines and the implementation of rapid mining techniques.As part of this research, the Bureau of Mines has surveyed total methane emission data from underground bituminous coal mines in the United States and tabulated emissions from mines producing over 0.1 MMcfd of methane. This report is an update of similar studies previously described in Information Circulars 8733, 8659, and 8558 (2-4).3The data from 1980 were compiled from Mine Safety and Health Administration (MSHA) records of air quality-quantity inspections made quarterly at each mine. The inspections involve measuring airflow and collecting air samples in the main returns. From these data, an average methane emission is calculated and used to represent the daily mine emission for each quarter. The methane emissions given in this report are the averages of the four 1980 quarters and do not include mine emissions from other sources such as degasification projects. Since a previous Bureau study showed that emissions from mines emitting less than 0.1 MMcfd represented only 2 pct of all emissions, 0.1 MMcfd was chosen as a lower limit for data collection (4)."

Jan 1, 1982

By Forrest T. Moyer

THE SAFETY record of the mineral and mineral-fuel-mining-and-processing industries retrogressed slightly in 1964, as indicated by the 3-percent increase in the frequency rate of all injuries. A slight improvement in the fatality rate was more than offset by the less-favorable rate of occurrence of nonfatal injuries. The overall-operating activity of these industries was lower in 1964 as measured by slight declines in employment and total man-hours of worktime. Injury Experience.-The rate of occurrence of all disabling work injuries in the mineral industries was 18.00 per million man-hours. This overall rate in 1964 comprised frequencies of 0.29 for fatal injuries and 17.71 for nonfatal work disabilities, which compared with respective rates of 0.30 and 17.20 in 1963. Fatalities totaled 538 or 30 less than in 1963. However, the total nonfatal disabilities of 33,151 in 1964 was 492 higher than in the preceding year.

Jan 1, 1965

By John Nagy

The Bureau of Mines examined explosion development in a closed spherical vessel, mathematically correlating flame travel, pressure, and time with parameters defining the reaction. The model assumes that burnt and unburnt zones are separated by a thin, radially moving flame front. Isothermal and adiabatic systems are considered. Correlation with gas and dust explosion data is better for the adiabatic system, but the isothermal development is simpler and in reasonably good agreement. Interpretation of the explosion phenomena is facilitated by expressing the rate of mole change in the flame front in terms of elementary parameters. This expression is developed by examining the components of spatial-flame velocity.

Jan 1, 1969

Roof bolting is a slow, expensive, and absolutely necessary mining activity. Roof-bolting activities also account for the largest percentage of lost-time injuries in underground coal mines. Dull bits result in the application of excessive force, which bends drill steel; and changing starter and finisher steel was the most significant source of injuries associated with roof bolting. The tungsten carbide (WC) roof-bolt drill bits currently used in American, Canadian, and Australian coal mines are capable of drilling only one or two 4-ft holes and then they are resharpened once or twice to drill another one or two holes. Often, in medium-hard rock formations (sandstone), as many as 20 to 30 bits may be required to drill a single 4-ft hole. Objective To compare the performance, longevity, and cost of newly developed polycrystalline diamond compact (PDC) roof-bolt drill bits against WC bits. Research and Background Diamonds for industrial use have been scarce throughout history and continuous attempts have been made to produce synthetic diamonds. The first synthetic diamonds were manufactured in 1953. Economically produced synthetic diamonds are 1 to 10 µm in size, but in this size range, they are totally unsuitable for industrial applications. In 1972, General Electric Co. developed a process to sinter the artificially developed, minuscule diamond particles into usable products. In this process, several layers of diamond-particles-and cobalt mixture are overlaid on WC substrates and sintered at 2,350° F and 1,000,000 psi. The final product is known as PDC. Today, PDC's are available in many shapes, but their size is limited to 3/4 in, or less, in length or diameter, because pressures greater than 1,000,000 psi are required to manufacture larger PDC's. At present, diamond and PDC arc the hardest and strongest commercial materials available for wear surfaces. The PDC used in this study had a hardness 3.61 times greater than that of WC.

Jan 1, 1992

By Ted C. Briggs

The Bureau of Mines is evaluating the thermodynamic properties of helium and helium-containing mixtures. Twenty-two compressibility runs were made with helium at 0° C and pressures to 800 atmospheres using a Burnett-type apparatus. Data from the 22 runs were treated simultaneously and as separate runs while different functional forms and weighting factors were used. A fourth-degree-polynomial equation in the pressure gives a statistically satisfactory representation of the compressibility factor when the data are treated simultaneously and a weighting factor of Pr-3/4 is used. The second virial coefficient of helium at 0° C from this investigation is 11.997±0.015 cm3 mole-1. The stated uncertainty is the random error standard deviation. Compressibility factors determined by this investigation are precise to better than 0.01 percent and are believed to be accurate to better than 0.02 percent.

Jan 1, 1969

By Joan C. Biordi

In this research by the Bureau of Mines, slightly lean CH4-O2-Ar flames at 0.042 atm with and without small amounts of the inhibitor CF3Br were probed using molecular beam and mass spectrometric techniques. Ratios of product concentrations to reactant concentrations were formed and compared with the equilibrium constant for seven reactions--(l) H+O2 = OH+O, (2) O+H2 = OH+H, (3) OH+H2 = H2O+H, (4) OH+OH = H2O+O, (5) CO+OH = CO2+H, (6) Br+HBr = Br2+H, and (7) H+HBr =H2+Br--to determine to what extent they may be considered balanced in various regions of the flame. With the possible exception of reaction 4, none of the reactions are completely balanced until maximum flame temperature is reached. Once the reactions become equilibrated, their balance is maintained as the temperature and radical concentrations falloff in the secondary reaction zone. Reaction 7, in inhibited flames, is balanced at relatively low temperatures, comparable to reaction 4. Reaction 6 was found not to balance in either the secondary or primary reaction zones. Radical decay in the secondary reaction zone was analyzed using the pool-decay concept. The important recombination reactions were judged to be H+OH+M~H2O+M, and H+O2+M?HO2+M. A rate coefficient of 2x1016 cm6 mole-2 sec-1 is calculated for M = the burnt gas mixture of Ar, HaO, CO2, and 5x1015 cm6 mole-a sec-1 is calculated for M = Ar (both for T = 1,750±150 K).

Jan 1, 1977

By Howard C. Turnage, Dana T. Updyke

An evaluation was made of one of several improved underground communication systems sponsored by the U.S. Bureau of Mines. The system evaluated was installed in a typical metal/non-metal room and pillar mine and utilized UHF repeaters connected to a unique distributed antenna and passive reflector system which provided mine-wide communications. A microprocessor controlled data collection system was assembled and installed for the evaluation. Data consisting principally of times and durations of messages and identities of the originating transceivers was collected between February and August of 1982 (6 mos.). Analysis of the data shows that the principal benefits are reduction in time required for unscheduled maintenance and repair, enhancement of safety, and better coordination of production activities. A cost benefit analysis shows a net benefit over cost, although it is also concluded that the capacity of the system is greater than can be justified by current activity in the mine.

Jan 2, 1983