Search Documents

By Martin Hertzberg

The concept of limit burning velocities is being used to formulate a quantitative theory of flammability limits. Competing and complicating processes dissipate power from a combustion wave and quench propagation at some characteristically low limit velocity. Two earlier reports dealt with process (a), natural convection (RI 8127); and with process (b), conductive-convective wall losses (RI 8469). This report considers process (c), radiative losses, and process (d), selective diffusional demixing. The limit burning velocity for radiative losses is [(SU)c ~ e cp] It is normally not a significant process for premixed gas flames; however, for laminar flame propagation in a gravity-free environment, it is the only loss process present. Accordingly, limit velocities at zero gravity should be much lower than on earth, and premixed gases should be flammable over wider composition ranges. For highly emissive dusts, soot, or ash-forming flames, radiative losses are significant even under normal gravity conditions. Selective diffusional demixing is a complication that manifests itself in the form of cellular flame structures and wide gaps in composition between upward and downward propagation limits. It induces a burning velocity shift (?Su)d, causing the flame to behave as though it were richer or leaner than its initial composition, depending on whether the fuel or the oxidizer mole¬cule has the higher diffusivity. A simple pertubation analysis shows that the process generates stable cellular flames whenever [dsu] > 0, where ci is the concentration of the reactant with the higher diffusivity. The same analysis indicates that at the opposite stoichiometry, where [dcu] < 0, laminar structures are stabilized. A simple formula for the diameter of cellular flames is derived, which predicts that dcell should vary inversely with the product of the diffusivity difference Di -DJ, and the burning velocity slope [dc ]. Those predictions are in good agreement with the available data. Buoyancy forces for upward propagation induce flame front curvature, and hence buoyancy and selective diffusion are mutually supportive in upward propagation. Thus large gaps in composition between upward and downward limits are present in those composition domains where cellular flames are stable.

Jan 1, 1981

By B. H. Eccleston

Experimental data were obtained from two medium-duty diesel engines derated to qualify for use in underground mines. Gaseous and particulate emissions from these engines were measured and results provide information on the effect of exhaust treatment devices on the emissions. The devices in the study were a catalyst, a particulate trap, and an exhaust gas cooler of the water scrubber type. Emission levels of carbon monoxide and hydrocarbons were observed to be very low in comparison with emission levels of comparable engines in full-rated operation. Oxides of nitrogen and benzo(a)pyrene content of the exhaust also were found to be somewhat low in comparison with previous findings. For particulate reduction, the combination of a particulate trap and a scrubber was observed to be the most effective combination tried; in some cases, over 60 pct particulate reduction was effected by the trap-scrubber combination.

Jan 1, 1981

By F. D. DeVaney

In the course of the investigation by the U. S. Bureau of Mines and the Missouri School of Mines and Metallurgy at the Mississippi Valley Experiment Station at Rolla, Mo., on the beneficiation of the low-grade manganese ores of the country, some samples from the Cuyuna District, Linn., have been examined. The work was done under the direction of W. H. Coghill, supervising engineer of the Mississippi Valley Experiment Station. Joseph and Kinney in writing about the relative importance of Minnesota deposits of low-grade ore compared to the total reserves say: "***It has been estimated that 26 to 35 million tons of ore contain 5 to 35 per cent of manganese, and the total domestic tonnage is from 75 to 48 million tons. The mean of these values is 30.5 million and 42 million tons, so it is seen that about 75 per cent of the reserves are in Minnesota." The manganese-bearing ores of the Cuyuna district maybe roughly grouped into two classes. The most abundant ore is of the low-silica, low-manganese, and high-phosphorus type called brown are. The other type is the so-called black ore, which is characterized by a higher manganese and silica content and by a lowe phosphorus analysis than the brown ore. As a general rule the brown ore carries less than 10 per cent of manganese while the black ore contains about 15 per cent and sometimes as high as 22 per cent of manganese.

Jan 1, 1930

By John W. Cole

As part of a general preliminary investigation of lead-zinc deposits in Stevens County, Wash., the Electric Point and Gladstone mines on Gladstone Mountain, in the Northport Mining District, were examined by R. M. Gammell, an engineer of the Bureau of Mines, in June 1946. A trenching and sampling program was executed later the same year under&apos; the supervision of Miro Mihelich and the author. This report presents the factual data obtained from the trenching and sampling operations.

Jan 1, 1949

By Wilder D. Foster

In estimating the hazardous qualities of a dusty atmosphere it is frequently desirable to determine the composition of the air-borne dust. Samples collected from ledges or from the rock itself are likely to be unsatisfactory for this purpose owing to the possibilities of differential disintegration of the rock and of variations in settling rates of the different components of the minerals. It may be necessary, therefore, to collect samples of dust from the air. Samples collected from the air may be analyzed chemically, by X-ray diffraction, and by the petrogrephic microscope. Chemical methods are unsatisfactory owing to the small samples usually available and to the limitations and complexities of present methods. X-ray technique requires expensive apparatus not ordinarily available except in research laboratories. Owing to the simplicity and rapidity of petrographic examination of atmospheric mineral dusts, it was considered worthy of further study.

Jan 1, 1938

By W. H. Ode, W. A. Selvig

"INTR0DUCTIONAccording to the Standard Specifications for Classification of Coals by Rank of the American Society for Testing Materials (A.S.T.M. Designation: D388-38).1/ high-volatile bituminous coals, subbituminous coals, and lignites are classified on the basis of calorific values on the ""moist"", mineral-matter-free basis. The moist basis refers to coal containing its natural bed moisture but not including visible water on the surface of the coal. It is assumed that the natural bed moisture of coal in the ground represents the moisture-holding capacity of the coal when in equilibrium with air at approximately 100 percent relative humidity. This moisture is sometimes referred to as inherent moisture as opposed to extraneous moisture, which wets the surface of the coal.To simplify procedures for determining the moisture-holding capacity of coal it is assumed, for all practical purposes that the moisture content of coal when brought to a standard condition of moisture equilibrium in an atmosphere of 97 percent relative humidity and 300 C. represents the bed moisture of the coal. The A.3.T.M. specifications provide that this condition of moisture equilibrium shall be obtained by bringing the coal to a standard condition of moisture equilibrium at 300 C. in a vacuum desiccator containing a saturated solution of potassium sulfate (97 percent relative humidity) according to the procedure proposed by Stanfield and Gilbart. 4/ No mention is made in the specifications for bringing partly air-dried samples to their natural bed moisture condition probably because of the hysteresis effect that has been noted by various investigators. 5/ In this connection it has been found from sorption studies that the adsorption and desorption curves for lignite are not entirely reversible. The hysteresis effect has been explained by some investigators as resulting from shrinkage of the lignite during drying, which causes a collapse of some of the capillaries, so the dried lignite cannot take up as much water as it held originally."

Apr 1, 1953

By R. H. Lien

The Bureau of Mines investigated nitrous oxide (N20) stability when used as a solvent for organic removal from metal powder surfaces. Both supercritical and subcritical conditions were studied. This investigation was prompted by the occurrence of a violent reaction when supercritical N20 was being used to deoil a metal powder grinding waste sample that contained 20 to 25 wt pct cutting oil. Tests were conducted to determine the cause of the reaction and to define stability limits. Test data showed that the waste&apos;s oil fraction reacted violently with N20 acting as an oxidizer; the metal powder acted as a promoter to reduce the ignition temperature. Although the data were scattered, this temperature appeared to reach a minimum at a certain pressure (dependent on vessel and sample size). The minimum ignition temperature for a 0.64-g sample in a 72-cm3 vessel was 360° C at 200 psig. As the sample size increased, the ignition temperature decreased. For example, when the sample size was increased to 10 g, a reaction occurred at 240° C and 600 psig. Because of the variability of ignition temperature with pressure and sample size, safe operating conditions were not established. Overall, this research showed that extreme caution should be exercised when using N20 in an organic or organic-metal system.

Jan 1, 2011

By A. Gene Collins

Some of the geochemical relationships that exist between subsurface fluids and the associated geologic strata in petroleum producing areas of Louisiana have been determined. Samples of petroleum-associated water were obtained from 126 wells in Louisiana that produced from sediments of three geologic ages: Tertiary, Cretaceous, and Jurassic. The samples were trans-ported to a central laboratory for analysis of chemical composition, using standard methods, to determine if the compositions varied with the geologic strata of their source and, if so, why. The dissolved constituents were com-pared with those of a brine that was concentrated by evaporation. The concentrations of bromide, calcium, and strontium were useful in distinguishing the brines produced from sediments of a late age from those of an earlier age. The concentration ratios of Mg&apos; (total equivalent magnesium) and bromide indicated that dolomitization probably had occurred and altered the composition of the brines. A principal-components analysis of the data indicated an inverse relationship between depth and concentrations of bromide, strontium, calcium, and lithium.

Jan 1, 1970

By K. K. Kershner

The purpose of this investigation was to develop methods on a laboratory scale for recovering tin from metallurgical slime, Tin chlorides were volatilized using mixtures of hydrogen chloride and reducing gases, such as hydrogen, carbon monoxide, hydrogen sulfide, ethane, propane, and butane. Optimum conditions were found to be n mixture of 3:1 of hydrogen and hydrogen chloride at 475° C. Over 95 percent of the tin was volatilized as chlorides. Low temperatures and relatively rapid rates of reaction are distinct advantages of the chloride volatilization process. Research is being continued with various slimes and will be extended to tin ores, where the method offers interesting economic possibilities in comparison with current tin-smelting practice.

Jan 1, 1957

By John B. Umhau

[&apos; is ann.tal surve:&apos; gives sta.tistical data regC:ll~dirg rims.ry and feCOA-dUTY or ~cra:p tin used in thL United States by industries anc. includcc dc..ta l&apos; is ann.tal surve:&apos; gives sta.tistical data regC:ll~dirg rims.ry and feCOA-dUTY or ~cra:p tin used in thL United States by industries anc. includcc dc..ta ]

Jan 1, 1938

By Harold M. Smith

The production of oil during the early development of new oil fields is usually accompanied by large quantities of natural gas. Since In most fields gas under pressure is the main source of the energy causing the oil to move throug the sands into the wells and thence to the surface, this coincident production of natural gas will contime as long as present day producing methods are used. Generally the use of this gas is restricted, and markets are not readily available Consequently, a large portion of the gas produced at such times is often wasted by being blown into the air.

Dec 1, 1930

By Leroy Dockter

The grinding characteristics of lignite in a ball mill were investigated. The variables studied were initial lignite moisture content, degree of in-the-mill drying, and lignite source. The mill tested was a pilot-p1ant-size conical ball mill which had a maximum output of from 80 to 180 lb/hr pulverized product depending on the lignite and test conditions. The capacity of the test mill ranged from 82 to 103 lb/hr depending upon mine source, in pulverization of as-mined lignite with minimum drying, The capabilities of the ball mill could not be correlated to Hardgrove index of the individual lignites or other observed physical properties. Predrying lignite from its 35 to 40 percent raw moisture content to about 10 percent moisture before grinding improved the mill capacity 87 percent, compared to an increase in capacity of 74 percent with in-the-mi11 drying to the same product moisture.

Jan 1, 1967

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States was made in accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. By agreement with the American Petroleum Institute, identification of the items is confidential. It presents analytical data for 4,857 samples, representing the products of 103 companies. The samples were collected during June, July, and August 1955. As in previous surveys, the gasolines covered by this survey include those from both large and small suppliers. The data were obtained by laboratories of various refiners, motor manufacturers, and chemical companies and submitted to the Bureau of Mines for compilation. A list of the National Motor Gasoline Survey reports published during the past 10 years is given on page 5.

Jan 1, 1956

By Kung-Lee Wang

This Bureau of Mines study illustrates the economic significance of the Florida phosphate industry to the State and to the Nation. Environmental considerations related to phosphate industry activity are discussed briefly. Based on forecasts of Florida phosphate production in 1975, and using 1972 dollars, regional and national output value, income, and employment created by the phosphate industry were estimated for 1975. State and Federal government tax revenues generated by the phosphate industry, are also measured. Further, the concentrated impact of the phosphate industry on certain Florida areas and on regional industries is examined. Finally, the phosphate industry&apos;s importance to the U.S. balance of payments, U.S. agricultural production, and the Frasch sulfur industry is considered, in addition to byproduct fluorine, and potential byproduct uranium from fertilizer manufacturing.

Jan 1, 1974

By Wilder D. Foster

In estimating the hazardous qualities of a dusty atmosphere it is frequently desirable to determine the composition of the air-borne dust. Samples collected from ledges or from the rock itself are Likely to be unsatisfactory for this purpose owing to the possibilities of differential disintegration of the rock and of variations in settling rates of the different components of the minerals. It may be necessary, therefore, to collect samples of dust from the air. Samples collected from the air may be analyzed chemically, by X-ray diffraction, and by the petrographic microscope. Chemical methods are unsatisfactory owing to the small samples usually available and to the limitations and complexities of: present methods. X-ray technique requires expensive apparatus not ordinarily available except in research laboratories. Owing to the simplicity and rapidity of petrographic is examination of atmospheric mineral dusts, it was considered worthy of further study.

Jan 1, 1938

By Forrest T. Moyer

THIS CHAPTER of the Minerals Yearbook (Volume III) contains overall injury experience for coal mines, both anthracite and bituminous coal, coke plants, petroleum and natural gas, peat, and asphalt and related bitumens (native); metal mines, metallurgical plants, including ore-dressing plants and primary nonferrous reduction plants and refineries; nonmetal mines; nonmetal mills; sand and gravel operations; slag (iron blast-furnace) plants; and stone quarries and their related plants. Volume I of the yearbook contains a chapter showing injury experience and employment data treated separately by categories: Metal mines, nonmetal mines, quarries and their related plants, metallurgical plants (ore-dressing plants and primary nonferrous reduction plants and refineries are shown separately), nonmetal mills, sand and gravel plants, and iron blast-furnace slag plants. Volume II contains injury and employment experience in the fuel industries (anthracite, bituminous coal including lignite, coke, petroleum and natural gas, native asphalt and related bitumens, and peat). Injury and employment data were collected from coal producers on the regular mandatory basis as required by the Federal Coal Mine Safety Act (30 U.S.C., sec. 455). Similar data for 1962 from metal, nonmetal (except well and brine operations), stone, and sand and gravel producers were collected by a. mandatory reporting system under the provisions of the Act of September 26, 1961, Public Law 87-300 (75 Stat. 649). Before 1962, these nonfuel producers reported voluntarily to the Bureau of Mines. Producers of all other minerals (fuel and nonfuel) reported the requested injury and employment data voluntarily to the Bureau for 1962, the same as in preceding years.

Jan 1, 1963

By J. W. Eckerd, W. S. Sanner, P. L. Woolf, R. E. McKeever

The Bureau of Mines experimental blast furnace was operated successfully with anthracite metallurgical briquets . Tuyère pressures were higher and more erratic than for operations using coke , and furnace " hangs " occurred more frequently . Higher hot - blast temperatures were required to maintain the quality of the metal . By using higher hot blast temperatures , the fuel and production rates and slag volumes were comparable to those obtained for all - coke operation . The anthracite metallurgical briquets exhibited excellent mechanical strength and descended through the shaft of the furnace with little breakage or reduction in size .

Jan 1, 1964

By Jim F. Lemons

The Bureau of Mines Minerals Availability System collected and analyzed data for 34 nonlaterite and 9 nickeliferous laterite domestic chromite deposits in order to assess their viability as sources of chromium under present technologic and economic conditions. These 43 deposits, none currently in production, contain approximately 6.3 and 22.3 million metric tons of Cr203 at the demonstrated and identified resource levels, respectively. Approximately 4.6 and 15.6 million metric tons of Cr203 are recoverable at the demonstrated and identified levels, respectively, for the 34 nonlaterite deposits. None of these resources are economically recoverable at January 1981 market prices. Production of metallurgical-grade chromite (market price $128 to $144) would require a minimum chromite market price of $237 per metric ton. Chemical-grade chromite production (market price $74 to $85) would require a chromite market price in excess of $188 per metric ton. From the 34 nonlaterite deposits, roughly 5.4 and 17.6 million metric tons of ferrochrome could be produced at the demonstrated and identified resource levels, respectively; however, a minimum market price of $770 per metric ton of ferrochrome would be required to stimulate production. The nine nickeliferous laterite deposits were not evaluated through production stages because of uncertainties in process technology and cost.

Jan 1, 1982

By John B. Gayle

During studies of the various methods for determining and specifying the factors that indicate whether a particular coke is better or worse than other cokes for metallurgical uses, questions arose as to the precision of screen-analysis tests on coke. Although the usual index of precision, the standard deviation of the test result, gives a measure of the precision of these data, the experimental determination of the standard deviation for a particular set of conditions requires tests on a large number of duplicate samples. Because this procedure necessaily involves a great deal of labor, an equation for predicting standard deviations from theoretical considerations has been developed. Results predicted with this equation agree satisfactorily with the experimental values and are applicable to tests on coal, coke, gravel, and other bulk materials.

Jan 1, 1952

By V. A. Marple, K. L. Rubow, S. M. Behm

"An eight-stage cascade impactor, with cut-sizes ranging from 0.056 to 18 um at a flow rate of 30 L/min, has been developed, calibrated, and tested in field programs. This impactor, called a microorifice uniform deposit impactor, has several features not normally found in cascade impactors. Ultrafine particles as small as 0.056 um are collected while keeping the pressure drop moderate by utilizing multiple nozzles (up to 2000) as small as 52 um in diameter. At each stage the collected particles are deposited uniformly over the entire impaction plate by rotating the impaction plate relative to the nozzles and by the correct radial placement of the nozzles. The particle cutoff characteristics (collection efficiency curves) of each stage and inter-stage losses were determined by means of monodisperse aerosols. The cutoff characteristics were found to be sharp and similar for all stages.Inertial impactors are widely used for the size-selective collection of aerosol particles. One reason for their wide usage is that the principle of operation is simple: a jet of particle-laden air is directed at a flat impaction plate. Large particles are collected on the plate while smaller particles follow the airflow out of the impaction region and are not collected. The division between the size of particles collected and those that are not is quite sharp. Secondly, the particles in an impactor are classified by their aerodynamic diameter (an important size parameter in many fields of study, including those related to respirable particle health effects). Thirdly, it is easy to collect particles in discrete size ranges by passing the aerosol through a number of stages (one stage consisting of a nozzle and impaction plae) in series, with each subsequent stage collecting particles smaller than the one before it. This is known as a cascade impactor. Finally, impactors can classify particles over a wide range of particle sizes: as low as 0.005 um (Fernandez de la Mora et al., 1990) and as large as approximately 50 um (Vanderpool et al., 1987).This paper describes a general purpose cascade impactor that has been developed in our laboratory and used in a variety of studies including visibility studies (McMurry et al., 1986; McMurry and Zhang, 1989), underground mine studies (Marple et al., 1986; Rubow and Marple, 1988; Rubow et al., 1988), and general atmospheric pollution studies (Macias et al., 1981; Dzubay et al., 1984). The impactor, called a microorifice uniform deposit impactor (MOUDI model 100, MSP Corp., Minneapolis, Minn.), is the integration of two earlier impactor de¬velopments: the microorifice impactor (M01) (Kuhlmey et al., 1981) and the uniform deposit impactor (UDI) (Marple et al., 1981).The MOUDI has several features normally not found in other cascade impactors. These include collection of particles as small as 0.056 um in aerodynamic diameter with a moderate pressure drop, uniform particle collection on the impaction plates, inter-changeable impaction plates to allow for the plates to be easily and quickly changed in the field, and covers for these substrates to provide a means for safe storage and/or transport of the collected particles to the laboratory for analysis."

Mar 1, 1992