Search Documents

By L. R. Fisher

The purpose of this investigation was twofold: (1) To devise a rapid method for determining quantitatively the porphyrin-carboxylic acid content of a particular crude-oil porphyrin aggregate, and (2) to isolate porphyrins in the crystalline state from crude-oil porphyrin aggregates. The first purpose was accomplished by applying adsorption chromatography. In fulfillment of the second aim three different crystalline porphyries were isolated by methods which involved both adsorption chromatography and fractionation of benzene solutions with hydrochloric acid of varying strength. The three porphyrins had etio, rhodo-, and phyllo-type absorption spectra, respectively. INTRODUCTION Many samples of petroleum have, as interesting minor constituents, chemical compounds known as metalloporphyrins. Their presence in crude oil and other bituminous materials was first discovered by Treibs a quarter century ago. Much experimental work has been done on metalloporphyrins because of their importance to the petroleum industry. They have a deleterious effect on refining catalysts. The ash resulting from the burning of heavy fuel oil is very reactive, We to the presence of metallic constituents, particularly vanadium. In oil-fired gas turbines, the ash may build up on the blades, causing imbalance of the rotors and, in addition, severe corrosion. In industrial boilers, the ash residue is responsible for severe damage to boiler tubes and to the refractory brickwork (15).4 Through study of the chemical constitution of the various metalloporphyrins found in petroleum, much can be learned concerning the origin, migration, and history of crude oils.

Jan 1, 1961

By John C. Machisak

INJURY data and experience, with related employment statistics, at coal mines in the United States for 1958 are presented in this publication under the following general sections: (A) General injury experience: Tables 1 to 6: Current data on number of injuries, degree of injury, frequency and severity rates, average severity, and related employment and production data by work location. (B) Selected injury experience: Tables 7 to 38: Current data on principal agencies of injuries, distribution of injuries by part of body injured, days of disability, extent of hand and machine loading, experience by employment and production groups, and various other operating factors and physical conditions related to the occurrence of injuries at the Nation's coal mines. (C) Injury experience by States: Tables 39 to 43: Current data on injuries, their causes, rates of occurrence and severity; employment and production data by work location, by States. (D) Major disasters: Table 44: Data on major disasters from 1949 to 1958. A major disaster is defined as a single accident in which, or as a result of which, five persons or more are killed instantly or die at any time thereafter. (E) Historical coal-mine-fatality experience: Tables 45 to 49: Data on fatalities and their causes at bituminous coal, lignite, and anthracite mines from the earliest records through 1958.

Jan 1, 1961

By William K. Tolley

The U.S. Bureau of Mines (USBM) is investigating hydrometallurgical processing techniques to recycle metals from semiconductors and other advanced materials. Cadmium and tellurium were recovered from mixed CdTe/CdS scrap produced in the manufacture of thin-film photovoltaic devices. Selective cadmium dissolution was achieved using oxygen-pressure leaching in dilute sulfuric acid. Leaching the scrap for 90 min at 110° C in 2.2NH2S04 under 400 psig 02 yielded 97% Cd extraction; however, cadmium content of the residue ranged between 4% and 7%. Soluble iron was added to the lixiviant to catalyze oxidation of the CdS component. Tellurium and sulfur remained in the leach residue primarily in the elemental form. The iron and tellurium were removed from the cadmium-rich leach liquor by adjusting the pH to 5.3. The cadmium was recovered as cadmium sulfate crystals by evaporating the solution. Alternative leaching and purification schemes are discussed.

Jan 1, 2010

By D. A. Reynolds, C. R. Holmes

The Bureau of Mines - American Gas Association ( EM - AGA) carbonization test has been used to determine the carbonizing properties of 66 American coals and a larger number of coal blends . A summary of the results obtained for the first 30 coals , including 6 blends , has been published ,4/ and results for individual coals have been reported as the investigations were completed . A bibliography of all publications pertaining to this work has been issued recently . Many of the coals were carbonized at 800 ° and 900° C. in two sizes of retorts ( 13- and 18 - inch diameters ) ; and , because the quality of coke is affected by changing the size of the retort , this report has been prepared to show the average physical properties of coke from the two sizes . This report also purposes to extend the correlation of the physical properties of coke with the rank of coal made by Fieldner and Davis in their summary of the EM-AGA tests on the first 30 coals .

Jun 1, 1942

By James S. Browning

Heavy liquids have been used to separate minerals of different specific gravities for many years.4 5 6 7 8 9/ The method permits substantially quantitative evaluation of a variety of minerals and requires much less time than the usual methods of chemical analysis. This Bureau of Mines investigation was conducted to determine the applicability of heavy liquid mineral separation to the evaluation of certain spodumene and kyanite ores, prepared mixtures, and plant products. After careful standardization of the particular mineral and associated gangue, estimates of chemical analyses could be obtained from results of heavy liquid separations.

Jan 1, 1960

By Leon E. Esparza

In 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the 16,927-acre Pryor Mountain Wilderness Study Area (MT-067-206), part of the 3,955-acre Burnt Timber Canyon Wilderness Study Area (MT-067-205), and part of the 4,550-acre Big Horn Tack-On Wilderness Study Area (MT-067-207) to evaluate their identified mineral resources. The Burnt Timber and Big Horn Tack-On study areas contain 3,430 and 2,550 acres, respectively. The three areas are in Carbon County, MT, and Big Horn County, WY, about 13 miles north of Lovell, WY. No identified resources exist in any of the study areas. Bureau of Mines personnel reviewed literature, searched county mining records and examined prospects, claims, and mineralized areas to determine whether identified mineral resources existed. The three study areas are within the Pryor Mountain unorganized mining district. U.S. Department of Energy production records indicate there were 223,000 pounds of uranium oxide (U308) and 236,000 pounds of vanadium pentoxide (V205) produced from 19 properties within the mining district. The average ore grade was 0.36 percent [3,600 ppm (parts per million)] U308 and 0.416 percent (4,160 ppm) V20S. Only the Pryor Mountain study area has current claims, the 50 claims of the S0S group.

Jan 1, 1986

By P. M. Sullivan

At its College Park Metallurgy Research Center in Maryland, the Bureau of Mines has installed and is operating a 5-ton-per-hour pilot plant for continuous mechanical separation of values contained in raw urban refuse. The entire sys tern was assembled using commercially available equipment. The process relies on multistage processing including shredding, air classification, screening, gravity concentration, and electrostatic separation. Compactor trucks deliver raw refuse collected along typical routes in metropolitan Washington, D.C., to the pilot plant. The loads are separated into concentrates of (1) light-gage iron, (2) massive metals, (3) glass, (4) putrescibles and waste combustibles, (5) paper, and (6) plastics. While some refinements remain to be made in the processing system flow-sheet, the data obtained to date have been highly encouraging, indicating favorable economics for commercial-size plants.

Jan 1, 1973

By R. G. Warncke, J. H. East, D. Harrington

The mining industry of the United States has long been severely criti- cized because of its high rate of accident occurrence, not only as compared with other industries of the United States but also with the mining industries of other countries, particularly Europe. Statistics, often not strictly com- parable, indicate that the accident-frequency rate in all mining is currently about three times and the accident-severity rate is about seven times as great as the average for general industrial work in the United States. These fig- ures are by no means comforting to humanitarian mining men, irrespective of their status in the industry, and they constitute a challenge that certainly cannot continue to be ignored much longer. The picture becomes much darker when the above statistics are augmented with data indicating that on an exposure basis our mines (more particularly our coal mines) have accident rates two, three, or even more times as great as more or less similar mines in Europe, particularly England, Wales, Belgium, France, and Germany. The sting is alleviated to some extent by the knowledge that our coal mines produce about 4 to 5 times as much coal per man day as is produced in at least some European mines. However, all of these foreign acci- dent statistics should be analyzed carefully before we become very much con- cerned about them, because they are not strictly comparable, for several reasons, not the least of which is the fact that foreign methods of compiling or recording accident statistics often differ materially from ours. Moreover, foreign mining and other conditions are definitely dissimilar to ours in many phases, and numerous other factors affect the comparability of foreign mine- accident statistics with those of the United States. Unquestionably, it should also be taken into consideration that the accident rate of the 140,000,000 or more constituting the populace of the United States as a whole is much higher than that of any other major country in the world and is two, three, or more times the rate of the European countries that have more favor- able mine-accident rates than those of the United States (table 1). Moreover, it is significant that the mine-accident-severity rate of British mines is about six times the average accident-severity rate of the major industries of the British Isles, or but little more favorable than the comparable figures in the United States; namely, that mining has an accident severity rate about seven times the average of about 30 of the major industries of this country.

Apr 1, 1949

By Doris M. Hyde

The Bahama's petroleum-dominated minerals sector constricted again in 1985. The declines were mostly the result of a soft market demand for crude oil and petroleum products. In early 1984, it was a growing unprofitability that prompted Charter Oil Co. to cease using the 350,000-barrel-per-day Bahamas Oil Refining Co. facility that it jointly owns with Chevron Oil Bahamas Ltd. After midyear 1985, because of poor petroleum economics, Chevron announced it would close the refinery, leaving only a maintenance crew. In 1984, the refinery exported less than 26 million barrels of petroleum products. Chevron's throughput was reported as averaging about 8,000 barrels per day at the time of the announcement. The crude oil transshipment terminal also registered declining activity and financial losses in 1984 and 1985. Transshipments of petroleum in 1985 amounted to about 100,000 barrels per day, one-half as much as in 1982.

Jan 1, 1987

By D. J. Parker

The ease of ignition and violence of explosion of Utah coal dusts, together with the large volumes of methane given off in some of the mines of the State, made it imperative to abandon obsolete equipment and obviously hazardous practices for up-to-date equipment and safer methods of mining if reasonable progress wore to be attained in fire and explosion prevention. Although much can still be done to improve safety conditions in Utah coal mines, considerable progress has been made in the past 10 years. The fundamentals of such progress include increased use of permissible electrical equipment in gassy mines, closed lights, rock-dusting, more liberal use of water at the face, butter ventilation, permissible explosives fired electrically both within and without the mine, partial inhibition of blasting while the shift is in the mine, 100-percent first-aid training, increased supervision and inspection, and mass safety meetings.

Jan 1, 1935

By Ulrich Neumann

Mining coal by employing a method called longwall mining is gaining more and more popularity in the United states since it offers many advantages over the conventional deep mining methods. Those advantages are a higher productivity, an almost total extraction of the mineral since no pillars must be left behind for support, and an increase in safety since the personnel are protected by the shield supports and rarely have to work near unsupported, exposed root. However, on some longwalls, the dust levels liberated by various equipment such as belt conveyors, chain conveyors, crushers, longwall shearers, and moving shield supports can exceed the maximum permissible limits and therefore have an adverse effect on productivity. Many attempts have been made over the past years to reduce the dust liberation by changing designs, installing various types of sprays or scrubbers, treating the mine water with wetting agents, or even using foam to catch dust before it becomes airborne. In the year 1984, the Bureau of Mines awarded Eickhoff Corporation a contract to demonstrate a water-jet-assisted cutting system for the multiple purposes of reducing dust levels, improving bit consumption, and increasing material size. During the previous phases of this contract, various trials were conducted aimed to design, build, and test d shearer loader to meet the objective of the contract. In the early stages of the research program, it was expected to see a reduction in the overall power consumption of the machine due to the fact that the high-pressure water jet would pre-cut the mineral in front of the bit. This, in turn, would then reduce the bit wear. Since there is less cutting action performed by the bit, a reduction of the dust liberation and a reduction of product fines was sought.

Jan 1, 1991

By S. Gallagher, C. A. Hamrick, A. G. Mayton, R Sonier, R. L. Unger

Introduction Industrial safety professionals recognize that adequate illumination is essential to a safe and productive work environment. The need for effective, lighting in underground coal mines is even greater.1 Designing appropriate lighting systems for these mines is no easy [ ] task because of the unique environment and work procedures encountered in underground coal-mining operations. Miners must depend totally on artificial lighting systems to see. Moreover, the working face is a low-reflectivity and low-contrast environment and is continually advancing or retreating.2 Laboratory mock-ups have been a major part of the process lighting equipment manufacturers must under- go to design an underground machine-mounted lighting system. The mock-ups often have taken considerable time. Furthermore, modifications to a lighting system (using different luminaires with an existing configuration or changing a luminaire's location, orientation, etc.) could require more time with additional mock-ups and laboratory measurements. Understanding the need to improve this situation, the US Bureau of Mines has developed an alternate method for facilitating lighting system mock-ups. A PC-Program (CAP),* with the latest software technology enables users to design, alter, and evaluate under- ground machine-mounted illumination systems. Lux levels and distance are measured as the luminaire is moved incrementally through angular traverses about horizontal and vertical axes. The measurements and angles subsequently are entered into the model. From this input data, three-dimensional isolux or isofootcandle profiles are constructed for luminaires that can be placed at various locations and orientations on a mining machine. As an example, Figure 1 shows a computer display of 21.5 Ix or 2.00 fc profiles for luminaires mounted on a simulated mine-shuttle car. Using this information, the model allows the user to determine the lux level at different locations in space about the shuttle car. How the model calculates illumination During initial development of the CAP model, the isolux profile of the luminaire was determined using the inverse square law (ISL) .3 The method of gathering data comprised recording a single measurement of distance at 21.5 ± 1.21x (2.00 ±11 fc) for angular traverses following 0.09 rad (5 degree) increments. This data was then used to find the illumination in space for any other distance at a given azimuth and elevation using the ISL. Limitations, however, exist with this method.4 The main one is that the ISL assumes a luminaire is a single point source of light, so long as the distance is greater than five times the 1al;gest dimension of the luminous area of the luminaire.5 Also, by using a single measurement to calculate the illumination for a given luminaire in the CAP model a large error could result from an inaccurate measurement.

Australia is tightening its rules governing mineral processing and the purchase of rural land by foreign investors" Rural land purchasers in the future will have to demonstrate to the Foreign Investment Review Board, the applicable governing body, that they will introduce new techniques or developments that will benefit Australia. In mineral processing, the criterion will be the availability of maximum opportunities for Australian equity capital. The changes are designed to discourage absentee landlords and speculators from abroad. A diamond field discovered several years ago in the northern section of Western Australia, known as the Kimberley region, is now thought to be one of the largest in the world, according to Conzinc Riotinto of Australia Ltd. (CRA). Figures released late in 1981 by CRA indicate that the main orebody of at least 100 million metric tons contains possibly 500 million carats of diamonds with a conservative market value of $8 billion. The diamond stones in the 100-acre deposit are about 10% gem-quality, 30% near gem, and 60% industrial. Initial production is expected to be about 17 million carats annually, which could be expanded to 25 million carats annually. World production of natural diamonds has been about 40 million carats per year from a reserve base of about 700 million carats.

Jan 1, 1982

By Chas. F. Jackson

The annual reports of the supervising engineering of the nine sections comprising the Mining Division are assembled in the following pages and constitute the annual report of the division. In planning activities, the aim is to adapt them to changes in conditions, in the needs of the mining industries, and in the public interest; those current activities that contribute most to problems of present concern are emphasized, investigations of less immediate importance being recessed, if necessary.

Jan 1, 1940

By Chas. F. Jackson

The annual reports of the supervising engineers of the nine sections comprising the Mining Division are assembled in tie following pages and constitute the annual report of the division. In planning activities, the aim is to adapt them to changes in conditions, in the needs of the mining industries, and in the public interest; those current activities that contribute most to problem of present concern are emphasized, investigations of less immediate importance being recessed, if necessary.

Jan 1, 1940

By P. A. Wasson

Drill cores from 15 holes in the West Central Mesabi Range were studied as part of the Lake Superior iron resource investigation begun in 1957 by the Bureau of Mines. Chemical, petrographic, and metallurgical analyses were made to determine grade, mineralogy, magnetic characteristics, and response to beneficiation. Data in this report were developed to provide a better under-standing of the nature and character of low-grade iron ore occurrences, to measure potential of usable ore, and to provide a basis for comparison with bank samples previously taken in the same general area. The average iron content of 4,445 feet of core was 31.8 percent. Iron oxides present were hematite, goethite, and magnetite; the gangue minerals were chiefly quartz, iron silicate, and iron-bearing carbonates.

Jan 1, 1962

By Louis H. Berkelhamer

"INTRODUCTION The method of differential thermal analysis suggested by Le Chatelier (1)1 in 1887 has recently emerged as an outstanding means of studying the constitution of various substances, particularly clays, soils, and miscellaneous hydrous materials (2). The literature ably discusses the applications and results obtained but has paid too little attention to specific details of construction of the apparatus. Knowledge of the apparatus is of importance to the experienced research man as is extremely useful to the novice v ho ventures into this field of analysis. Further, it is generally acknowledged that the variations in design and conditions of operation are one of the essential causes for differences in characteristic temperatures as reported by various investigators. A step forward in the elimination of such differences is the publication of the details of construction and operation of a simple and inexpensive apparatus that has proved useful at the southern Experiment station of the Bureau of Mines, where it was used in cooperation with the University of Alabama, Tuscaloosa, Ala."

Jul 1, 1944

By Michael G. Zabetakis

The autoignition temperatures (A.I.T.'s) of natural and synthetic lubricants in air were generally found to decrease with increasing pressure. Of the two types of fluids, synthetic and natural, studied in some detail, the phosphate esters had higher A.I.T.'s at any pressure between 1 and 200 atmospheres than the mineral oils. Most of the A.I.T. data obtained in this study obeyed the relationship predicted by Semenov's theory of ignition.

Jan 1, 1962

By L. Allan White

Instrumental analysis is an indispensable tool to many phases of research on rare-earth metals and their compounds; therefore, the development of new and improved instrumental techniques is essential. This report describes an emission spectrometric analytical method using direct-current carbon-arc excitation of various rare-earth-oxide mixtures. Lanthanum oxide serves the dual purpose of an internal standard and a constant major constituent. The versatility of the method was demonstrated by three different applications: (a) Analysis of complex rare-earth concentrates; (b) determination of impurities in high-purity rare-earth oxides; and (c) detection of rare-earth elements in other types of matrices, such as those resulting from beneficiation of rare-earth ores. The average error of analysis in the concentration range of 0.2 to 10.0 percent was 14.6 percent for a group of complex synthetic mixtures of rare-earth oxides. An average error of analysis in the concentration range of 0.05 to 0.50 percent was 21 percent for a group of high-purity rare-earth oxides.

Jan 1, 1959

By B. W. Madsen

A modified transpiration apparatus was devised by the Bureau of Mines to permit rapid and accurate measure of the vapor transport and vapor diffusion coefficients of antimony sulfide (Sb2S3) and other compounds at temperatures to 1,045 K. The apparatus was equipped with dual condensers and valves to switch the flow of vapor in a fraction of a second from one condenser to the other, thus allowing short-interval sampling under equilibrium conditions. Reliability of the technique was established by measuring the vapor pressure of ZnC12 as a function of temperature and comparing the results with published data. As part of an investigation of the vapor concentrations and species of accessory element sulfides associated with copper and zinc smelting, the apparatus was used to measure the rate of vapor transport and diffusion coefficients of vapor over liquid Sb2S3 as a function of temperature between 870 and 1,045 K. The calculated vapor density was combined with published direct measurements of vapor pressure to calculate the average molecular weight of the gaseous species. Average molecular weight of the vapor in equilibrium with Sb2S3 ranged from 286 to 112 g/mol over the temperature range studied.

Jan 1, 1983