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By J. F. Shaw

MINE fires are usually extinguished by constructing seals in the approaches to the areas to exclude air from the fire areas, which smothers the fires in an oxygen-depleted atmosphere. Seals should be substantially constructed and made as nearly airtight as possible and should be provided with a sampling pipe so that samples of the atmospheres behind the seals may be collected at regular intervals. Methods of constructing seals and of sampling and analysing mine atmospheres are fully described in Bureau of Mines publications. (1, 2). Information obtained on the composition of atmospheres behind fire seals is helpful in determining if a fire has been extinguished or if there is any danger of an explosion when a fire area is being sealed or unsealed. The progress of a mine fire can best be determined by studying percentages of carbon dioxide, carbon monoxide, and hydrogen in the atmosphere behind the seals. Hydrogen will be formed in a bituminous- or subbituminous-coal mine when the temperature exceeds 480° F. and in an anthracite mine when the temperature exceeds 660° F. (3). Carbon monoxide and carbon dioxide are both products of combustion of coal, wood, or other organic compounds. The presence of carbon monoxide has long been accepted as an indication of a mine fire. A sealed fire area should not be reopened until the carbon monoxide has disappeared. Trends in the percentage of carbon dioxide are also useful in determining the status of a mine fire. Carbon dioxide is sometimes liberated by rock strata. In this case, carbon dioxide in the atmosphere behind a seal will be from two sources-the rock strata and the fire. When the, fire is extinguished, carbon dioxide will be liberated from only I source, the rock strata, and when the percentages of carbon dioxide are plotted, the slope of the curve will not be as steep as when this gas was being liberated from 2 sources. If the only source is the fire, the percentages of carbon dioxide will gradually decrease after the fire has been extinguished. By studying analyses of a mine-fire atmosphere, it is possible to determine if the atmosphere is explosive; if the mixture is capable of becoming explosive when mixed with air; and if the mixture can be made nonexplosive or be prevented from becoming explosive by being mixed with an inert gas. These factors can be computed mathematically or determined graphically. The mathematical calculations advanced by Ash and Felegy (7) are discussed, and graphical solutions of their equations are presented. It is believed that the graphical solution will be extremely helpful in determining the characteristics of a mine-fire atmosphere when fighting a fire, because the results can be obtained in a matter of minutes, and there is less likelihood of an error being made under the stress incident to control efforts. The experimental and theoretical work upon which the formulas are based have been adequately described and are not discussed at this time (5) (6).

Jan 1, 1955

By G. A. Howes

This is one of a series of circulars dealing with the cost of equipping and developing mining properties in the United States and Canada, prepared and published by the Bureau of Mines in cooperation with various mining and exploration companies. This group of circulars is designed to supplement an earlier series which covered the methods and costs of mining and milling at a large number of producing properties. ACKNOWLEDGMENTS The authors desire to thank Robert A. Bryce, president of Macassa Mines (Ltd.), for permission to use the data presented in this paper, and to acknowledge the cooperation of A. J. Keast, under whose direction as manager the plant was installed and equipped and the shaft was sunk to a depth of approximately 2,000 feet.

Jan 1, 1932

By T. S. Chen

A study was made by the Bureau of Mines of the temperature and thermal stress distributions in thin circular disks subjected to peripheral thermal shock at various rates of heat transfer. The theoretical analysis is based on one-dimensional radial heat flow by conduction in the disk, and on heat exchange by convection between the disk and its surroundings. Preliminary experimental data obtained from shock tests on thin circular disks of basalt, quartzite, and taconite show reasonably good agreement with theory. The case of constant properties and plane stress is treated. Solutions of the stress distribution are presented for both cooling and heating shocks. The elastic energy stored at fracture is examined, and on this basis an average stress theory is formulated. Physical properties vital to the studies include thermal conductivity, thermal diffusivity, tensile strength, Young's modulus, and linear coefficient of thermal expansion. This work is of importance in predicting the thermal shock responses of a rock body of finite size.

Jan 1, 1966

By Joseph A. DeCarlo

The rapid growth of the organic chemical industry in the United States and abroad has focused attention on the future raw-material sources for this important industry. Chemical products are essential to modern civilization; and millions of tons of organic chemicals are used annually, ranging from basic raw materials to finished chemical products such as drugs, cosmetics, and soaps. Hundreds of chemical products are made directly or indirectly from coal, but in this report "coal chemicals" will be limited to crude tar, crud light oil, and ammonia recovered in the high-temperature carbonization of bituminous coal and the important principal products obtained by processing these materials. Specifically these include benzene} toluene, xylene, naphthalene, creosote oil, tar acid oil, pitch, and ammonium sulfate. Therefore the term "coal chemicals", wherever used in this report, includes only these products and does not include the secondary or intermediate products such as styrene, synthetic phenol, aniline, phthalic anhydride, or finished products made from these, such as synthetic rubber, plastics, and dyes. The United States leads the world in production and consumption of coal chemicals. In the past five years nearly one-fourth of the total output of coal-tar crudes in the world was produced in the United States. Consumption of some of the more important products derived from these crudes such as benzene, toluene, xylene, and naphthalene, however, ranged from about one-third to one-half of the world total because of imports and production of benzene, toluene, and xylene from petroleum. The synthetic organic chemical industry of the United States was established during World War I on chemical raw materials obtained by the high-temperature carbonization of bituminous coal but this source of supply currently furnishes less than 40 percent. More than 60 percent of the chemical raw materials used to produce organic and inorganic chemical is supplied by the petroleum industry and production of petrochemicals is rising rapidly.

Jan 1, 1960

Objective To identify techniques to reduce the probability of gob gas explosions. Background In the last 6 years, seven explosions of methane and/or coal dust occurred within worked-out, sealed areas (gobs) of underground U.S. coal mines. These explosions, believed to have been started by lightning, destroyed many mine seals and caused much damage external to the sealed area. Three of these gob gas explosions occurred in one mine in Alabama over a 3-year period. Fortunately, the explosion forces and the toxic gases that vented from the sealed gob area did not cause fatalities or injuries, but they destroyed several large seals. If miners had been inspecting or working near these areas, the potential for serious injury and/or death would have been high. The United Mine Workers of America and the Mine Safety and Health Administration (MSHA) requested that the National Institute for Occupational Safety and Health (NIOSH) help identify the mechanisms for lightning penetration into the gob and recommend ways to reduce the probability of occurrence of future explosions from such lightning penetrations into sealed areas of underground coal mines. Because three of the explosions occurred in a single mine, special attention was focused on these particular explosions. The first occurred in April 1994 in a sealed area, which enclosed about 1.35square miles of abandoned workings (gob). This explosion destroyed 3 of the 38 seals that surrounded the gob. These seals were less than 2,000 ft away from three 4.5-in-diam steel-cased test wells that extended from the surface into the mine entry. At the time of the explosion, the National Lightning Detection Network (NLDN)verified 12 lightning strikes within 10 miles of the mine, including several above the gob. After the 1994 explosion, the damaged seals were rebuilt using an acceptable seal design capable of with standing a 20-psi explosion, as required by 30 CFR 75.335. On January 26,1996, a second gob explosion destroyed five more cementitious pumpable seals less than 2,000 ft away from those destroyed in 1994and even closer to the steel-cased wells. The NLDN verified72 lightning strikes in the area of this second gob explosion. Compressive strength analyses of fragments from the destroyed seals showed that strengths ranged from 11 to 138 psi, with an average of83 psi. This is over 100 psi below the minimum 200-psi compressive strength requirement for cementitious pumpable seals. These seals were again replaced. On July 9, 1997, the third and most violent explosion occurred in the same vicinity of the last two explosions. Three more cementitious pumpable seals were destroyed, including one newer seal that exceeded the minimum 200-psi compressive strength requirement. The NLDN verified 695 lightning strikes above the mine during the time in which the explosion occurred. MSHA's

May 1, 2001

By Lloyd Williams

1. The investigation shows that the bed identified as Wilder in this report is the only bed in Overton County that has produced commercial coal and is the only bed in which coal reserves were estimated for this report. Three other coal horizons were recognized but lacked enough data for reserve estimates. 2. Known measured and indicated reserves of coal, based on a minimum bed thickness of 14 inches and on 1,800 tons per acre-foot of coal in place, are estimated to be 19 million short tons, as of January 1, 1953. Of this total, 10 million tons represents coal 28 inches and more thick. Areas of the Wilder bed were omitted from the estimate because available data relative to the bed characteristics were too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1955

By C. F. McCarroll

[Laboratory research and, control in the u?odnction an; utilization of petroleum and its product s have eqLmde& greatly during the past decade, rind much of the routine control and experimental equipment noirr requires the con-stant daily use of liquid nercury. In spite of this greater use, very little consideration has becn given to the hazard that might be occasioned by the toxic vapors of mercury unavoicl.a~l.p spilled or otherwise exposed to the atmosphere during the normcl 2rgced1u.e of ln30r~tor;~r operations. A sfmple visual exami~stion gf' sone of the laborztories reveals the prescnce of a considerable quantity of mercury in the craclcs of floors, on work tebles, ad on and mo7md eql~ipmeilt st.ads. Usually this yercurj ie contaminated with oily and dirt BO th~t it remint; in R finely divided state and a srnarl amount presents a relativell- lag? surface for evaporation. Since mercury shows meas~rable vo!-atility st a tempero.turc as lor^ 2s 8.5O F., mercury vapor will bo present in the atnosphere of anjr laboratory wbr.e mercury is exposed. promiscuously]

Jan 1, 1939

In order to reduce waste and improve resource conservation, mine planning, and development, the U.S. Bureau of Mines is investigating the effects of multiple seam interactions associated with longwall coal mining. Field investigations were conducted at a mine located in Boone County, WV, where a longwall panel was operating subjacent to room-and-pillar workings in an overlying seam. To assess the effects of overlying workings on longwall headgate stability, the Bureau gathered various geotechnical information at this minesite. Headgate pillars and entries were instrumented and monitored to study their behavior during side-abutment loading as the longwall panel approached and passed beneath the overlying room-and-pillar developments. The two operations are separated by 800 ft of interburden, and although interactions between operations separated by this distance are uncommon, geomechanical measurements indicate the occurrence of an interaction. These measurements show that convergence on the headgate entries was most adverse subjacent to barrier pillars in the overlying mine. Pillar measurements indicate that side-abutment pressure increases were slightly greater than predicted values. Several factors related to both geology and mine design, believed responsible for this large interactive distance, are discussed.

Jan 1, 1990

By Stanton L. Tainter

"INTRODUCTION Molybdenite, the only common mineral and ore of molybdenum, occurs wide¬-spread but is concentrated as the main ore mineral in commercial quantities in only a few known deposits. Consequently, the Government sought additional sources of the minerals as a precaution against the possible shortage of moylbdenm for war uses. Upon request by the War Production Board, the New Year’s Eve and Esperanza properties of the Amargosa Molybdenum & Copper Corp. were investigated by the Geological Survey 3/ and the bureau of Mines 4/. The Survey appraised the mineral potentialities of the deposit and prepared topographic and geologic maps, and the Bureau made a preliminary engineering examination. The deposits were previously examined by W. J. Vanderwilt, consulting engineer. It was largely due to his recommendations that interest was stimulated in the deposits.Development on the New Year’s Eve deposit indicated a small tonnage of sub marginal ore. There was little development at the Esperanza, but surface examination revealed a large volume of rock containing a little molybdenite and a trace of copper in the oxidized outcrops. Some molybdic oxide was noted suggesting that some molybdenite might have been leached from the oxidized outcrops and that the molybdenite content in the sulfide zone might be higher."

Feb 1, 1947

By D. Harrington

Most of those in the Health and Safety Branch, Bureau of Mines, necessarily participate in activities associated with essentially all phases of the mineral industries, including coal and noncoal mines, quarries, smelters, metallurgical plants, and various petroleum operations. One of the strictly war activities of the branch - the Explosives Control Division, which administers the Federal Explosives Act of December 26, 1941 - has functions that require contacts not only with nearly all phases of the mining and allied industries but also with those engaged in scores of other occupations that manufacture, store, use, or possess explosives, or many of the ingredients of explosives. The field men of the Health and Safety Branch (approximately 300 in number) Are occupied full time in health and safety activities and annually make thousands of contacts with people in the mineral industries as well as the plants in which they work. From these they formulate several thousand written reports containing sources of thousands of conclusions and recommendations aimed at reduction of health end safety hazards in these industries. Although such activities have been greatly increased during the war and immediate pro-war periods, they have been in effect to a considerable extent since the Bureau of Mines was created in 1910.

Jan 1, 1944

By W. H. Kerns

The Taylor Creek lead-zinc deposit is on Taylor Creek, approximately 1-1/2 miles from tidewater, at the head of Duncan Canal, on the east side of Kupreanof Island, Petersburg district, southeastern Alaska. The property was located in 1903, and a 30-foot discovery cut was put to the west tank of the creek. Very little prospecting end developing has been done since that time. The property was examined by J. C. Roehm, associate mining engineer, Territorial Department of Mines, Juneau, Alaska, in June 1946. From exposure n the creek, a mineralized zone with possible dimensions of 1,700 feet by 1,000 feet was indicated. The general strike was northwest, and the dip was low and variable to the northwest. During September through November 1948, the Bureau of Mines conducted a project on the property. Four diamond-drill holes, totaling 770.5 linear feet, were drilled from the surface and 280 lineal feet of hand trenching done. The mineral deposit was found to occur as patches that appear to be a replacement in dolomitic limestone. The patches of mineralization are small, irregularly shaped, and irregularly distributed. Maps showing the location of the drill holes and trenches, analyses of the cores from the drill holes, and anal lee of the samples from the trenches accompany this report (see, also, appendixes A, B, and C).

Jan 1, 1950

This paper has peen translated from the Russian by the United States Bureau of Mines and is issued as one of a series of circulars dealing with mining methods and costs in connection with a general study of this subject sponsored by the bureau. The paper presents some interesting features in connection with the methods employed in Russia and describes certain variations in standard methods which might conceivably be applied to a limited extent in this country.

Jan 1, 1930

By J. T. Dunham

The Bureau of Mines studied by dilatometry the effect of titanium on the thermal expansivity of hot-rolled zinc and Zn-l percent Cu alloy. The titanium content of the alloys was varied up to 0.3 percent. Expansion coefficients were determined from measurements made both parallel and perpendicular to the plane of the rolled sheet. Titanium reduced expansion parallel to the plane of the sheet, especially in the rolling direction, but increased expansion perpendicular to the sheet. Basal-plane pole figures showed that the degree of preferred orientation increased with the titanium content in the alloy, and that anisotropic expansion can be correlated to sheet texture.

Jan 1, 1965

By E. C. Pattee

A mobile spectroscopic laboratory was completed by the Bureau of Mines in 195 to provide a rapid, inexpensive means of field testing samples for beryl¬lium and other associated metals of possible commercial importance. Spectro-copes have been used in laboratories for many years in various types of research and routine analyses, but this spectroscope is probably the first mobile unit. The laboratory provides for spectroscopic, radioactivity, fluorescent, and limited chemical tests of samples. The unit has been a valuable reconnaissance tool. It has been used to search for beryllium, cesium, columbium, tantalum, rubidium, and lithium in Idaho, Washington, and Montana. Several very low grade deposits of these elements were found, and occurrences of other important elements were identified; however, none are of economic importance. The spectroscope permits the detection of elements by analysis of visible light produced when elements in a small powdered sample are volatilized in an electric arc., A total of 70 elements can be detected; 29 can be detected at or below 0.01 percent, Electric power for the arc is supplied by a gasoline motor-driven generator, Equipment is housed in an aluminum van, mounted on a 4-wheel-drive vehicle for easy maneuverability on mountain roads, A trailer with crushing, pulverizing, and splitting equipment permits the reduction of samples to a small representative pulp.

Jan 1, 1963

By M. E. Tyrrell, C. W. Houck

Mixtures of zirconium diboride and refractory metals of group VI were resistance sintered to high - density compacts using modified electric welding equipment . To evaluate the use of chromium , molybdenum , or tungsten as binders for zirconium diboride the sintered compacts were examined in polished sections and tested for crushing strength , hardness , microhardness , oxidation rate , and resistance to mechanical shock . Chromium yielded the highest compressive strength , the greatest resistance to mechanical shock and oxidation , and a satisfactory Rockwell hardness . Molybdenum did not yield a satisfactory cermet . Tungsten yielded compacts having high microhardness but very low mechanical strength .

Jan 1, 1964

By A. A. Cochran

The objective of the research was to determine the final distribution of cerium additions to steel, their effect on sulfide inclusions, and the usefulness of radiotracer methods in investigating steel problems. Fifty-gram heats of steel were prepared that contained either cerium 141 and nonradioactive sulfur, or sulfur 35 and nonradioactive cerium. These steels were studied by autoradiography, measurements of their surface radioactivities, optical microscopy, and chemical analysis. Samples of the crucibles were analyzed quantitatively for cerium or sulfur by radioactivity counting methods. The addition of cerium to steel melts reduced the size and number of iron sulfide inclusions in the resulting steel. A significant fraction of the sulfur and most of the cerium penetrated into the MgO crucible during the melting operation, The cerium inclusions in steel were identified as cerium sulfide. Radiotracer methods were found to be versatile and highly sensitive.

Jan 1, 1963

By Paul L. Russell

This property has been examined several times in the last few years , and findings have been reported . In the fall of 1942 , the author supervised sampling both lode and placer deposits . The ore was beneficiated , and the results obtained are incorporated in this report . stia The Morgan Group , which comprises seven unpatented mining claims and the Black Cat placer claims , was purchased by the Manganese Products Corp. from H. D. Hill of Hatch , N. Mex . , and Dr. A. C. White of Hot Springs , N. Mex . Arthur L. McRowe , 876 27th Avenue , San Francisco , is president of the corporation , and David Fewer, 824 Times Building, Long Beach, is treasurer . J. T. Murray is in charge of operations .

Feb 1, 1947

By H. G. Iverson

Solid state reactions of manganese with silica were investigated in high-temperature tests. Reactions of 0.5 to 4.0 moles manganese (Mn) with 1 mole silica (SiO2) at 1,100° C and of 2.0 Mn:SiO2 mole-ratio mixtures at 1,000° to 1,150° C yielded products consisting of a slag phase and a metallic phase. At 1,100° C, the slag phase from reactions of the low Mn:SiO2 mole-ratio mixtures was composed of SiO2 and rhodonite (MnSiO3), and the slag phase from the high Mn:SiO2 mixtures was composed of MnSiOs and tephroite (Mn2SiO4). The metallic phase from the corresponding low Mn:SiO2 mole-ratio reactants consisted of two manganese silicides, Mn5Si3 and Mn3Si; from the high Mn:SiOg mixtures, it was Mn and the manganese silicide (Mn5Si). For the higher mole ratios of MnSiO2 the manganese content in the metallic phase increased, while the manganese and silica contents of the slag phase remained nearly constant. The slags did not contain free or uncombined manganese oxide (MuO). For the 2.5 to 4.0 Mn:SiO2 mole-ratio mixtures reacted at 1,100° C, the maximum quantities of silica reduced and of the manganese in the slag appeared to become asymptotical at about 41 and 48 percent, respectively. A brominating procedure was developed that was highly selective in removing the metallic constituents from the reaction product, leaving the slag phase as residue. X-ray diffraction patterns were obtained on prepared silicides Mn5Si, Mn3Si, and MnSi.

Jan 1, 1967

By Floyd G. Anderson

The Federal Bureau of Mines promotes the use of safe and effective dust-collecting devices for rock drilling in coal mines. To insure that such devices are available to the coal-mining industry, the Bureau issues certificates of performance for dust-collecting systems and certificates of approval for dust collectors and rock drills or other mining equipment with integral dust-collecting systems that meet the requirements of an established Schedule.4/ Investigations are conducted under the provisions of the current revision of this Schedule by engineers of the Branch of Health Research. This circular describes briefly the requirements and procedure for obtaining certificates of performance or approval and lists equipment that has been certified as permissible under Schedule 25 or its revisions as of January 31, 1961. The names and addresses of companies to which certificates have been issued are listed alphabetically at the end of this circular.

Jan 1, 1961

By Raymond B. Lucas

"Distinction between Tripoli and Diatomaceous EarthMuch confusion exists both in the literature and in the trade as to the proper use of the terms tripoli, tripolite diatomeceons or infusoriai earth, and kieseigunr. All of these terms are often used synonymously by the trade and even in mineralogists and other reference books. Actually, tripoli is a ma- is a material of definite and distinct physical and chemical properties and all of the other terms belong to a different material with just as definite and distinct properties.Originally the term tripolite (loosely called tripole) was given to a diatomaceous cart from Tripoli in Northern Africa. Dena (J.D. Dana, A System of Mineralogy 6th Ed.) calls this material tripolite and gives no authority for the use of the terms tripoli. Between 1880 and 1890 the deposits near Missouri, were opened and the material placed on the market as ""Tripoli"" no doubt due to its resemblance in some respect to the original tripolite or diatomaceous worth from Tripoli. Since that time the term tripoli has with increasing definitenesss been reserved for the Seneca material and other siliceous of similar origin and physical properties, while all siliceous material of organic origin, containing dilators, has been called diatomaceous earth (or its synonyms infusorial earth, kiselguhr, etc.). Rottenstone is sometimes classed with tripoli."

Nov 1, 1920